CN101747231B - 在气相中制备异氰酸酯的方法 - Google Patents

在气相中制备异氰酸酯的方法 Download PDF

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Publication number
CN101747231B
CN101747231B CN200910261577.7A CN200910261577A CN101747231B CN 101747231 B CN101747231 B CN 101747231B CN 200910261577 A CN200910261577 A CN 200910261577A CN 101747231 B CN101747231 B CN 101747231B
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CN
China
Prior art keywords
nozzle
amine
reaction
phosgene
reaction space
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN200910261577.7A
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English (en)
Chinese (zh)
Other versions
CN101747231A (zh
Inventor
R·布伦斯
F·波尔
F·斯特芬斯
V·米谢勒
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Carcoustics Techconsult GmbH
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Carcoustics Techconsult GmbH
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Publication of CN101747231A publication Critical patent/CN101747231A/zh
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Expired - Fee Related legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00—Preparation of derivatives of isocyanic acid
    • C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/55—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers driven by the moving material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/45—Magnetic mixers; Mixers with magnetically driven stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00252—Formation of deposits other than coke
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00254—Formation of unwanted polymer, such as "pop-corn"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/192—Details relating to the geometry of the reactor polygonal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1947—Details relating to the geometry of the reactor round oval or ellipsoidal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
CN200910261577.7A 2008-12-18 2009-12-17 在气相中制备异氰酸酯的方法 Expired - Fee Related CN101747231B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008063728.9 2008-12-18
DE102008063728A DE102008063728A1 (de) 2008-12-18 2008-12-18 Verfahren zur Herstellung von Isocyanaten in der Gasphase

Publications (2)

Publication Number Publication Date
CN101747231A CN101747231A (zh) 2010-06-23
CN101747231B true CN101747231B (zh) 2014-06-25

Family

ID=41785750

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910261577.7A Expired - Fee Related CN101747231B (zh) 2008-12-18 2009-12-17 在气相中制备异氰酸酯的方法

Country Status (12)

Country Link
US (1) US20100160673A1 (enExample)
EP (1) EP2199277B1 (enExample)
JP (1) JP5602422B2 (enExample)
KR (1) KR20100071009A (enExample)
CN (1) CN101747231B (enExample)
AT (1) ATE526310T1 (enExample)
DE (1) DE102008063728A1 (enExample)
ES (1) ES2373628T3 (enExample)
PL (1) PL2199277T3 (enExample)
PT (1) PT2199277E (enExample)
RU (1) RU2528336C2 (enExample)
TW (1) TWI464139B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8871062B2 (en) * 2010-11-23 2014-10-28 Charles David Gilliam Falling film evaporator
US8877978B2 (en) 2010-12-21 2014-11-04 Kao Corporation Method for producing tertiary amine
JP5090567B2 (ja) * 2010-12-21 2012-12-05 花王株式会社 ３級アミンの製造方法
WO2012088671A1 (zh) * 2010-12-29 2012-07-05 烟台万华聚氨酯股份有限公司 一种快速混合反应器及其应用
DE102011087654A1 (de) 2011-12-02 2013-06-06 Bayer Materialscience Aktiengesellschaft Verfahren zur Herstellung von Isocyanaten
WO2013139703A1 (de) 2012-03-19 2013-09-26 Bayer Intellectual Property Gmbh Verfahren zur herstellung von isocyanaten
EP2829533A1 (de) 2013-07-26 2015-01-28 Bayer MaterialScience AG Verfahren zur herstellung von isocyanaten
CN106715385B (zh) 2014-09-19 2020-04-14 科思创德国股份有限公司 在气相中制备异氰酸酯的方法
WO2018114846A1 (de) 2016-12-21 2018-06-28 Covestro Deutschland Ag Verfahren zur herstellung eines isocyanats
CN110914236B (zh) 2017-06-08 2023-01-31 科思创德国股份有限公司 制备异氰酸酯的方法
EP3634947B1 (de) 2017-06-08 2022-09-07 Covestro Intellectual Property GmbH & Co. KG Verfahren zur herstellung von isocyanaten in der gasphase
EP4031526B1 (de) 2019-09-17 2024-07-10 Covestro Deutschland AG Verfahren zur herstellung von isocyanaten
WO2022106716A1 (en) 2020-11-23 2022-05-27 Basf Se Process for producing isocyanates

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3321283A (en) * 1963-12-23 1967-05-23 Mobay Chemical Corp Apparatus for conducting rapid chemical reactions
CN1530361A (zh) * 2003-02-20 2004-09-22 在气相中制备（多）异氰酸酯的方法
CN101155627A (zh) * 2005-04-08 2008-04-02 亨茨曼国际有限公司 螺旋混合喷嘴和用于混合两种或多种流体的方法及用于制造异氰酸酯的工艺
CN101205197A (zh) * 2006-12-13 2008-06-25 拜尔材料科学股份公司 在气相中制备异氰酸酯的方法

Family Cites Families (21)

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Publication number Priority date Publication date Assignee Title
GB1165831A (en) 1967-01-26 1969-10-01 Ici Ltd Process for the Production of Isocyanates and Carbamyl Chlorides
ATA50084A (de) 1984-02-15 1986-06-15 Lift Verkaufsgeraete Gmbh Karteikastenartige vorrichtung zur aufnahme von steifen, flachen gegenstaenden
DE3714439A1 (de) 1987-04-30 1988-11-10 Bayer Ag Verfahren zur herstellung von (cyclo)aliphatischen diisocyanaten
DE3717057A1 (de) 1987-05-21 1988-12-01 Bayer Ag Verfahren zur herstellung von isocyanaten
US4931445A (en) 1988-10-06 1990-06-05 Irwin Goldstein Agents for treatment of male impotence
DE4217019A1 (de) * 1992-05-22 1993-11-25 Bayer Ag Verfahren zur Herstellung von aromatischen Diisocyanaten
FR2697017B1 (fr) * 1992-10-16 1995-01-06 Rhone Poulenc Chimie Procédé de préparation de composés du type isocyanates aromatiques en phase gazeuse.
DE19523385A1 (de) 1995-06-23 1997-01-09 Bayer Ag Verfahren zur Herstellung von Triisocyanaten
FI107311B (fi) 1998-11-06 2001-06-29 Nokia Networks Oy Signalointimenetelmä
DE10026142A1 (de) * 2000-05-26 2001-12-13 Basf Ag Verfahren und Vorrichtung zur kontinuierlichen Herstellung von organischen Mono- oder Polyisocyanaten
US7086778B2 (en) * 2000-10-09 2006-08-08 Levtech, Inc. System using a levitating, rotating pumping or mixing element and related methods
DE10161384A1 (de) 2001-12-14 2003-06-18 Bayer Ag Verbessertes Verfahren für die Herstellung von (/Poly)-isocyanaten in der Gasphase
DE10222023A1 (de) 2002-05-17 2003-11-27 Bayer Ag Verfahren zur Herstellung von Isocyanaten in der Gasphase
DE10245704A1 (de) 2002-09-30 2004-04-01 Bayer Ag Verfahren zum Quenchen eines gasförmigen Reaktionsgemisches bei der Gasphasenphosgenierung von Diaminen
DE10349504A1 (de) 2003-10-23 2005-05-25 Bayer Technology Services Gmbh Verfahren zur Herstellung von Isocyanaten in der Gasphase
DE10359627A1 (de) 2003-12-18 2005-07-21 Bayer Materialscience Ag Verfahren zur Herstellung von Diisocyanaten
DE102005036870A1 (de) 2005-08-02 2007-02-08 Bayer Materialscience Ag Verfahren zur Gasphasenphosgenierung
US20070049482A1 (en) 2005-08-11 2007-03-01 Shin-Etsu Chemical Co., Ltd. Synthetic quartz glass substrate for excimer lasers and making method
US7547801B2 (en) * 2006-06-26 2009-06-16 Bayer Materialscience Llc Process for the continuous preparation of isocyanates
WO2008055898A1 (de) 2006-11-07 2008-05-15 Basf Se Verfahren zur herstellung von isocyanaten
DE102006058634A1 (de) 2006-12-13 2008-06-19 Bayer Materialscience Ag Verfahren zur Herstellung von Isocyanaten in der Gasphase

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3321283A (en) * 1963-12-23 1967-05-23 Mobay Chemical Corp Apparatus for conducting rapid chemical reactions
CN1530361A (zh) * 2003-02-20 2004-09-22 在气相中制备（多）异氰酸酯的方法
CN101155627A (zh) * 2005-04-08 2008-04-02 亨茨曼国际有限公司 螺旋混合喷嘴和用于混合两种或多种流体的方法及用于制造异氰酸酯的工艺
CN101205197A (zh) * 2006-12-13 2008-06-25 拜尔材料科学股份公司 在气相中制备异氰酸酯的方法

Also Published As

Publication number Publication date
JP2010143899A (ja) 2010-07-01
EP2199277B1 (de) 2011-09-28
TWI464139B (zh) 2014-12-11
CN101747231A (zh) 2010-06-23
JP5602422B2 (ja) 2014-10-08
PL2199277T3 (pl) 2012-02-29
RU2009146846A (ru) 2011-06-27
US20100160673A1 (en) 2010-06-24
EP2199277A1 (de) 2010-06-23
DE102008063728A1 (de) 2010-06-24
ES2373628T3 (es) 2012-02-07
TW201035023A (en) 2010-10-01
KR20100071009A (ko) 2010-06-28
RU2528336C2 (ru) 2014-09-10
PT2199277E (pt) 2012-01-02
ATE526310T1 (de) 2011-10-15

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SE01 Entry into force of request for substantive examination
C53 Correction of patent of invention or patent application
CB02 Change of applicant information

Address after: Germany Leverkusen

Applicant after: BAYER MATERIALSCIENCE AG

Address before: Germany Leverkusen

Applicant before: BAYER MATERIALSCIENCE AG

COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: BAYER AG TO: CARCOUSTICS TECHCONSULT GMBH

EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20100623

Assignee: Bayer Intellectual Property GmbH

Assignor: BAYER MATERIALSCIENCE AG

Contract record no.: 2012990000854

Denomination of invention: Method for producing isocyanates in gas phase

License type: Common License

Record date: 20121128

LICC Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140625

Termination date: 20151217

EXPY Termination of patent right or utility model