CN101730725B - 硅烷化的研磨热解法二氧化硅 - Google Patents
硅烷化的研磨热解法二氧化硅 Download PDFInfo
- Publication number
- CN101730725B CN101730725B CN200880016826XA CN200880016826A CN101730725B CN 101730725 B CN101730725 B CN 101730725B CN 200880016826X A CN200880016826X A CN 200880016826XA CN 200880016826 A CN200880016826 A CN 200880016826A CN 101730725 B CN101730725 B CN 101730725B
- Authority
- CN
- China
- Prior art keywords
- silicon
- pyrogenic silica
- dioxide
- coating formulation
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 139
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 64
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 46
- 239000008199 coating composition Substances 0.000 claims abstract description 22
- 238000000227 grinding Methods 0.000 claims abstract description 18
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims abstract description 11
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 10
- 238000002444 silanisation Methods 0.000 claims abstract description 10
- 229960001866 silicon dioxide Drugs 0.000 claims description 59
- 235000012239 silicon dioxide Nutrition 0.000 claims description 59
- 239000000463 material Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 15
- 229920005862 polyol Polymers 0.000 claims description 12
- 150000003077 polyols Chemical class 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 8
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229920005906 polyester polyol Polymers 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- 239000013008 thixotropic agent Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000005051 trimethylchlorosilane Substances 0.000 claims description 4
- AAPLIUHOKVUFCC-UHFFFAOYSA-N trimethylsilanol Chemical compound C[Si](C)(C)O AAPLIUHOKVUFCC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 description 20
- 239000011248 coating agent Substances 0.000 description 19
- 239000003973 paint Substances 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 229910002012 Aerosil® Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000006887 Ullmann reaction Methods 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241001466460 Alveolata Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- -1 stablizer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- GMMAPXRGRVJYJY-UHFFFAOYSA-J tetrasodium 4-acetamido-5-hydroxy-6-[[7-sulfonato-4-[(4-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].OC1=C2C(NC(=O)C)=CC=C(S([O-])(=O)=O)C2=CC(S([O-])(=O)=O)=C1N=NC(C1=CC(=CC=C11)S([O-])(=O)=O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 GMMAPXRGRVJYJY-UHFFFAOYSA-J 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/309—Combinations of treatments provided for in groups C09C1/3009 - C09C1/3081
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3009—Physical treatment, e.g. grinding; treatment with ultrasonic vibrations
- C09C1/3018—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3081—Treatment with organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Paints Or Removers (AREA)
- Silicon Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007024365A DE102007024365A1 (de) | 2007-05-22 | 2007-05-22 | Pyrogen hergestellte silanisierte und vermahlene Kieselsäure |
| DE102007024365.2 | 2007-05-22 | ||
| PCT/EP2008/055556 WO2008141923A1 (en) | 2007-05-22 | 2008-05-06 | Fumed silanized and ground silica |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101730725A CN101730725A (zh) | 2010-06-09 |
| CN101730725B true CN101730725B (zh) | 2013-12-04 |
Family
ID=39580439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200880016826XA Active CN101730725B (zh) | 2007-05-22 | 2008-05-06 | 硅烷化的研磨热解法二氧化硅 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8163080B2 (enExample) |
| EP (1) | EP2147058B1 (enExample) |
| JP (1) | JP2010528132A (enExample) |
| CN (1) | CN101730725B (enExample) |
| DE (1) | DE102007024365A1 (enExample) |
| PL (1) | PL2147058T3 (enExample) |
| WO (1) | WO2008141923A1 (enExample) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007035952A1 (de) * | 2007-07-30 | 2009-04-09 | Evonik Degussa Gmbh | Oberflächenmodifizierte, pyrogen hergestellte Kieselsäuren |
| JP6089173B2 (ja) * | 2010-12-28 | 2017-03-08 | 日本メナード化粧品株式会社 | 分散安定剤及びこの製造方法 |
| EP2670803B1 (en) * | 2011-02-02 | 2017-11-22 | Ashland Licensing And Intellectual Property, LLC | Scratch resistant gelcoat |
| WO2013126874A2 (en) * | 2012-02-24 | 2013-08-29 | Coating Supply, Inc. | Seed coating composition and related methods |
| US9221210B2 (en) | 2012-04-11 | 2015-12-29 | Whirlpool Corporation | Method to create vacuum insulated cabinets for refrigerators |
| US9140481B2 (en) | 2012-04-02 | 2015-09-22 | Whirlpool Corporation | Folded vacuum insulated structure |
| DE102012211121A1 (de) | 2012-06-28 | 2014-01-02 | Evonik Industries Ag | Granuläre, funktionalisierte Kieselsäure, Verfahren zu deren Herstellung und deren Verwendung |
| JP5809185B2 (ja) * | 2013-03-28 | 2015-11-10 | 富士フイルム株式会社 | 溶液製膜方法 |
| US9689604B2 (en) | 2014-02-24 | 2017-06-27 | Whirlpool Corporation | Multi-section core vacuum insulation panels with hybrid barrier film envelope |
| US9599392B2 (en) | 2014-02-24 | 2017-03-21 | Whirlpool Corporation | Folding approach to create a 3D vacuum insulated door from 2D flat vacuum insulation panels |
| US10052819B2 (en) | 2014-02-24 | 2018-08-21 | Whirlpool Corporation | Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture |
| CN104263150B (zh) * | 2014-09-10 | 2018-03-06 | 珠海天威飞马打印耗材有限公司 | 一种3d打印机及其工作台膜层的制备方法、涂覆在3d打印机工作台的涂料及其制备方法 |
| JP6443041B2 (ja) * | 2014-12-26 | 2018-12-26 | 三菱マテリアル株式会社 | シリカゾル分散液及びシリカ多孔質膜形成用組成物 |
| US9476633B2 (en) | 2015-03-02 | 2016-10-25 | Whirlpool Corporation | 3D vacuum panel and a folding approach to create the 3D vacuum panel from a 2D vacuum panel of non-uniform thickness |
| US10161669B2 (en) | 2015-03-05 | 2018-12-25 | Whirlpool Corporation | Attachment arrangement for vacuum insulated door |
| US9897370B2 (en) | 2015-03-11 | 2018-02-20 | Whirlpool Corporation | Self-contained pantry box system for insertion into an appliance |
| US9441779B1 (en) | 2015-07-01 | 2016-09-13 | Whirlpool Corporation | Split hybrid insulation structure for an appliance |
| US10429125B2 (en) | 2015-12-08 | 2019-10-01 | Whirlpool Corporation | Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein |
| US10041724B2 (en) | 2015-12-08 | 2018-08-07 | Whirlpool Corporation | Methods for dispensing and compacting insulation materials into a vacuum sealed structure |
| US10222116B2 (en) | 2015-12-08 | 2019-03-05 | Whirlpool Corporation | Method and apparatus for forming a vacuum insulated structure for an appliance having a pressing mechanism incorporated within an insulation delivery system |
| US11052579B2 (en) | 2015-12-08 | 2021-07-06 | Whirlpool Corporation | Method for preparing a densified insulation material for use in appliance insulated structure |
| US10422573B2 (en) | 2015-12-08 | 2019-09-24 | Whirlpool Corporation | Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein |
| US10422569B2 (en) | 2015-12-21 | 2019-09-24 | Whirlpool Corporation | Vacuum insulated door construction |
| US9840042B2 (en) | 2015-12-22 | 2017-12-12 | Whirlpool Corporation | Adhesively secured vacuum insulated panels for refrigerators |
| US9752818B2 (en) | 2015-12-22 | 2017-09-05 | Whirlpool Corporation | Umbilical for pass through in vacuum insulated refrigerator structures |
| US10018406B2 (en) | 2015-12-28 | 2018-07-10 | Whirlpool Corporation | Multi-layer gas barrier materials for vacuum insulated structure |
| US10610985B2 (en) | 2015-12-28 | 2020-04-07 | Whirlpool Corporation | Multilayer barrier materials with PVD or plasma coating for vacuum insulated structure |
| US10030905B2 (en) | 2015-12-29 | 2018-07-24 | Whirlpool Corporation | Method of fabricating a vacuum insulated appliance structure |
| US10807298B2 (en) | 2015-12-29 | 2020-10-20 | Whirlpool Corporation | Molded gas barrier parts for vacuum insulated structure |
| US11247369B2 (en) | 2015-12-30 | 2022-02-15 | Whirlpool Corporation | Method of fabricating 3D vacuum insulated refrigerator structure having core material |
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| CN111918849A (zh) * | 2018-04-04 | 2020-11-10 | 积水化学工业株式会社 | 夹层玻璃用中间膜和夹层玻璃 |
| US10907888B2 (en) | 2018-06-25 | 2021-02-02 | Whirlpool Corporation | Hybrid pigmented hot stitched color liner system |
| AU2020268167A1 (en) * | 2019-05-07 | 2021-12-02 | W.R. Grace And Co.- Conn | Coating compositions for hydrophobic films and articles having hydrophobic surfaces |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0076377A2 (de) * | 1981-10-01 | 1983-04-13 | Degussa Aktiengesellschaft | Verfahren zur Verringerung des Grindometerwertes von hochdispersen Kieselsäuren |
| CN1190644A (zh) * | 1996-12-21 | 1998-08-19 | 希尔斯硅股份有限公司 | 使硅酸解聚集的方法 |
| US5959005A (en) * | 1996-04-26 | 1999-09-28 | Degussa-Huls Aktiengesellschaft | Silanized silica |
| EP1236773A2 (de) * | 2001-02-28 | 2002-09-04 | Degussa AG | Oberflächenmodifizierte, dotierte, pyrogen hergestellte Oxide |
| EP1406129A2 (en) * | 2002-10-02 | 2004-04-07 | Canon Kabushiki Kaisha | Silicia fine particle, toner, two-component developer and image forming method |
| CN1678695A (zh) * | 2002-08-28 | 2005-10-05 | 德古萨股份公司 | 二氧化硅 |
| CN1930249A (zh) * | 2004-03-05 | 2007-03-14 | 德古萨股份公司 | 硅烷化的硅石 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE819399A (fr) * | 1973-09-07 | 1974-12-16 | Produit anti-mousse | |
| DE2414478C3 (de) | 1974-03-26 | 1978-07-13 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Aerogelartige strukturierte Kieselsäure und Verfahren zu ihrer Herstellung |
| ES476904A0 (es) * | 1979-01-16 | 1981-02-16 | Krafft S A | Mejoras introducidas en los procesos de fabricacion de composiciones endurecibles a base de silicona. |
| JPS55154354A (en) * | 1979-05-16 | 1980-12-01 | Toray Silicone Co Ltd | Silicone composition for treating glass fiber |
| US4874518A (en) * | 1985-11-01 | 1989-10-17 | E. I. Du Pont De Nemours And Company | Porous silica microspheres having a silanol enriched surface |
| US5032266A (en) * | 1985-11-01 | 1991-07-16 | E. I. Du Pont De Nemours And Company | Porous silica microspheres having silanol-enriched and silanized surfaces |
| DE69208498T2 (de) * | 1991-04-09 | 1996-10-02 | Shinetsu Chemical Co | Siloxan-Beschichtungszusammensetzung für einen Sicherheitsluftsack |
| JP2679460B2 (ja) * | 1991-07-10 | 1997-11-19 | 信越化学工業株式会社 | シリコーンゴム皮膜形成用組成物及びシリコーンゴム皮膜並びにシリコーンゴム被覆物品 |
| JP2590650B2 (ja) * | 1991-10-08 | 1997-03-12 | 信越化学工業株式会社 | エアバッグ用コーティング剤及びエアバッグ |
| JP3291588B2 (ja) * | 1992-05-27 | 2002-06-10 | 日本アエロジル株式会社 | 樹脂充填材用二酸化珪素微粉末 |
| DE4402370A1 (de) * | 1994-01-27 | 1995-08-03 | Degussa | Silanisierte Kieselsäuren |
| DE19616781A1 (de) * | 1996-04-26 | 1997-11-06 | Degussa | Silanisierte Kieselsäure |
| US5928726A (en) * | 1997-04-03 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Modulation of coating patterns in fluid carrier coating processes |
| HK1049101A1 (zh) * | 1999-10-01 | 2003-05-02 | The Procter & Gamble Company | 具有能防止護膚組分擴散的隔離片的吸收性產品 |
| EP1199336B1 (de) * | 2000-10-21 | 2014-01-15 | Evonik Degussa GmbH | Funktionalisierte, strukturmodifizierte Kieselsäuren |
| ATE496098T1 (de) * | 2000-10-21 | 2011-02-15 | Evonik Degussa Gmbh | Strahlenhärtende lacksysteme |
| ATE492607T1 (de) * | 2000-10-21 | 2011-01-15 | Evonik Degussa Gmbh | Funktionalisierte kieselsäuren |
| DE10145162A1 (de) * | 2001-09-13 | 2003-04-10 | Wacker Chemie Gmbh | Kieselsäure mit geringem Gehalt an Kieselsäure-Silanolgruppen |
| DE10150274A1 (de) * | 2001-10-12 | 2003-04-30 | Wacker Chemie Gmbh | Kieselsäure mit homogener Silyliermittelschicht |
| DE10239423A1 (de) * | 2002-08-28 | 2004-03-11 | Degussa Ag | Kieselsäure |
| JP2004210875A (ja) * | 2002-12-27 | 2004-07-29 | Nippon Aerosil Co Ltd | 粉体塗料用流動化剤および粉体塗料組成物 |
| US8986442B2 (en) * | 2003-01-22 | 2015-03-24 | Evonik Degussa Gmbh | Specially precipitated silicic acids for rubber applications |
| DE102004005222A1 (de) * | 2004-02-03 | 2005-08-18 | Degussa Ag | Silikonkautschuk |
| US20060219133A1 (en) * | 2005-04-01 | 2006-10-05 | Toda Kogyo Corporation | Colored resin particles, water-based dispersion containing the colored resin particles, and ink for ink-jet printing or color filter |
| EP1801166A1 (de) * | 2005-12-23 | 2007-06-27 | Degussa GmbH | Pyrogen hergestelltes silanisiertes Siliciumdioxid |
-
2007
- 2007-05-22 DE DE102007024365A patent/DE102007024365A1/de not_active Ceased
-
2008
- 2008-05-06 EP EP08759426.3A patent/EP2147058B1/en active Active
- 2008-05-06 JP JP2010508776A patent/JP2010528132A/ja not_active Withdrawn
- 2008-05-06 PL PL08759426T patent/PL2147058T3/pl unknown
- 2008-05-06 WO PCT/EP2008/055556 patent/WO2008141923A1/en not_active Ceased
- 2008-05-06 US US12/597,800 patent/US8163080B2/en not_active Expired - Fee Related
- 2008-05-06 CN CN200880016826XA patent/CN101730725B/zh active Active
-
2012
- 2012-03-01 US US13/409,715 patent/US20120152151A1/en not_active Abandoned
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0076377A2 (de) * | 1981-10-01 | 1983-04-13 | Degussa Aktiengesellschaft | Verfahren zur Verringerung des Grindometerwertes von hochdispersen Kieselsäuren |
| US5959005A (en) * | 1996-04-26 | 1999-09-28 | Degussa-Huls Aktiengesellschaft | Silanized silica |
| CN1190644A (zh) * | 1996-12-21 | 1998-08-19 | 希尔斯硅股份有限公司 | 使硅酸解聚集的方法 |
| EP1236773A2 (de) * | 2001-02-28 | 2002-09-04 | Degussa AG | Oberflächenmodifizierte, dotierte, pyrogen hergestellte Oxide |
| CN1678695A (zh) * | 2002-08-28 | 2005-10-05 | 德古萨股份公司 | 二氧化硅 |
| EP1406129A2 (en) * | 2002-10-02 | 2004-04-07 | Canon Kabushiki Kaisha | Silicia fine particle, toner, two-component developer and image forming method |
| CN1930249A (zh) * | 2004-03-05 | 2007-03-14 | 德古萨股份公司 | 硅烷化的硅石 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008141923A1 (en) | 2008-11-27 |
| JP2010528132A (ja) | 2010-08-19 |
| CN101730725A (zh) | 2010-06-09 |
| US8163080B2 (en) | 2012-04-24 |
| US20100126387A1 (en) | 2010-05-27 |
| EP2147058B1 (en) | 2017-01-18 |
| PL2147058T3 (pl) | 2017-07-31 |
| DE102007024365A1 (de) | 2008-11-27 |
| US20120152151A1 (en) | 2012-06-21 |
| EP2147058A1 (en) | 2010-01-27 |
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