CN101712873A - Production method of agricultural multifunctional liquid mulching film and application thereof - Google Patents
Production method of agricultural multifunctional liquid mulching film and application thereof Download PDFInfo
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- CN101712873A CN101712873A CN200810073043A CN200810073043A CN101712873A CN 101712873 A CN101712873 A CN 101712873A CN 200810073043 A CN200810073043 A CN 200810073043A CN 200810073043 A CN200810073043 A CN 200810073043A CN 101712873 A CN101712873 A CN 101712873A
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Abstract
Domestic and overseas water saving agents mostly adopt macromolecular water absorbent polymers to store water and hold water; a plastic mulching film leads to white pollution; a humic acid multifunctional liquid mulching film has the disadvantages of 30 percent evaporation prevention, low heat insulation and water holding performance and fast cooling; and a guilspare liquid mulching film has high cost and a pH value of 13, and requires an investment of more than 100 Yuan per mu of land. The invention relates to an agricultural multifunctional liquid mulching film, which is novel in ideas and formula, maintains characteristics of the traditional mulching film, overcomes defects of the prior mulching film, adopts weathered coal and potassium silicate effects and combines hydrophobic groups and hydrophilic groups of organic silicon and humic acid, wherein the hydrophobic groups cut off earth surface soil capillaries to prevent moisture from evaporating; and the hydrophilic groups absorb and keep soil moisture to achieve the purpose of saving water. The agricultural multifunctional liquid mulching film has the following technical indexes: 50 to 70 percent evaporation prevention, 30 to 50 percent water conservation, 10 to 15 percent increase in grain and cotton yield and 15 to 30 percent increase in fruits and vegetables, and is applied to the fields of agriculture and forestry. The agricultural multifunctional liquid mulching film has the characteristics of environmental protection, water conservation, land fertilization, pressing alkali, yield increase and low cost.
Description
Technical field
The present invention relates to chemical field, this mulch film adopts weathered coal and potassium silicate effect, resultant contains organosilicon, humic acids and potassium humate, organosilicon, inorganic silicon, contain hydrophobic group, and corruption is implanted with hydrophilic group, hydrophobic group can cut off face of land kapillary, reduce evaporation, and hydrophilic group and organic matter receive and keep soil moisture, reach water saving, press alkali, infertile field, the multiple function of environmental protection.
Technical background
The current plastic film of extensively using is based upon volume increase on the basis of sacrificing soil potential, is a kind of predation formula mode of production, and it is infinite to leave a legacy of trouble.China's mulch film is residual generally at 60-90kg/hm at present
2, reach as high as 165kg/hm
2, the annual 64.5-105.6% that increases, China has 2 * 10 with the existing 25 years history of mulch film
9Kg/hm
2, mulch film enters soil, and about 200-400, mulch film can not decompose in soil, and the people relies on soil existence, and the soil is destroyed, jeopardizes the human survival condition.
In order to solve white pollution, currently testing a kind of humic acid multifunctional degradable mulch film.
What is the humic acid multifunctional degradable liquid-state mulch film?
So-called humic acid multifunctional degradable liquid-state mulch film is meant that with petroleum pitch or residual oil be raw material, perhaps with the tangerine bar, or with the contour dense organic waste water of papermaking wastewater, wine brewing, molasses, starch and marine alga with brown coal or weathered coal modification, and add a kind of liquid state material that other additives and auxiliary material produce.This material is sprayed onto on the soil and forms the very thin chocolate polymolecular chemoproection film of one deck on its surface, with obturator of the bonding one-tenth of soil surface, stops the volatilization of soil moisture, but rainwater, agricultural chemicals, nutritive substance etc. are fully infiltrated.This material sprays 40-60 days natural degradations gradually through field low-temperature oxidation and action of microorganisms.Be degraded to humic-acid kind (fertilizer) in 2-3 month, turn over be pressed into soil after, be the fine soil improvement agent.Because this fluent meterial promptly has the effect that heats, preserves soil moisture, keeps a full stand of seedings of plastic film, also has stronger adhesive capacity, grogs can be coupled to the ideal coacervate, corruption is decomposed into humic acids, thoroughly solved plastic film to the pollution of soil and environment with increased the characteristics of farming that integrate simultaneously again through, fertilizer and plastic sheeting for farm use, with after turn over and be pressed into soil, can become soil improvement agent, therefore be called as the humic acid multifunctional degradable black liquid-state mulch film.
What is the meaning that the humic acid multifunctional degradable liquid-state mulch film is developed?
1, helps eliminating the atmospheric pollution that water pollution that white pollution that plastic film causes and various organic wastewater with high concentration cause and straw on-site incineration cause; the chronic illness of influence flight and traffic safety is for agricultural production and income and soil and environment protection provide technical support.
2, agriculture production and land management, desert treatment and the Pollution abatement for China provides new means and measure;
3, can be for implementing the water saving and the ecological agriculture, the Sustainable development of promotion China agricultural provides and provides powerful support for.
How is the effect of humic acid multifunctional degradable liquid-state mulch film?
Soil surface sprays humic acids can make soil improve 1-4 ℃ of temperature by liquid-state mulch film, and the evaporation inhibiting rate is 30%.The soil moisture content increase rate is greater than 20%, the soil weight reduces 6%-10%, water stability group material quantity in the soil (>0.25mm) can increase more than 10%, the crop growth phase shifts to an earlier date 3-10 days, the saltiness of the 0-50cm soil body reduces about 50%, and the amount of increase in production of Different Crop is many more than 20%, uses simultaneous test and shows, that liquid-state mulch film has is significantly cold-resistant, the effect of heating and precocious effect of increasing production, and wheat, corn increase by 20% to be.Increasing both production and income such as potato class, vegetables are more than 25%.The ground temperature rise is gathered in the crops in advance, and to reach the purpose of increasing both production and income, for the low area of year-round average temperature, effect is particularly remarkable.Can also reduce simultaneously the loss of fertilizer and agricultural chemicals, especially for the area of heavy rainfull, advantage is then more outstanding.In addition, add little fertilizer and weeding and pest-killing agent that various farm crop produce to be needed, more help to improve crop yield.
Should the liquid mulch film effect of humic acids be sure.
Soil moisture, plant absorbing are about 30% as everybody knows, and 70% be evaporated, and the liquid mulch film evaporation of humic acids inhibiting rate 30% that is to say that 40% moisture evaporation is still arranged, reduce evaporation again? let us is looked at.
Nestle company research centre, develop a kind of product innovation that reduces plant moisture evaporation in the desert greatly, spray agent, the Preliminary experiment results of Agricultural Research Institute of Sultanate of Oman Bu Si university shows, this novel spray agent, can make soil moisture reduce evaporation 75%, make this farm crop water reduce half.
The effective ingredient of " this handkerchief star of silicon " is a silicon gas alkane, and a kind of final can absorption by sandy soil belongs to the nontoxic biological degradation compound.
Using method is: mixing with water, every square feet sprays one earlier, and every public affairs are inclined with 75-80 kilogram spray ground, cultivate spray once at every turn.
After the drying, can form one deck silicon at desert surface, as seemingly baby diaper---water can penetrate this waterproof layer, enter soil, do not evaporate under the high temperature yet, in fact moisture content is stored in dry surface layer, (can also weed a garden), the following concrete degree of depth of certain degree of depth is determined that by concentration the spray back rises to face of land 5-20 centimetre to water layer, eliminates salinity, prevent that dust storm is at face of land pinching dew, a kind ofly be used for indoor plant and potted plant, " this handkerchief star of silicon " can reduce 3/4ths to water substantially, to 6/7.
But vaporization prevention 75% has overcome the deficiency of humic acids mulch film, and still, why silicon Si Pali does not promote, raw material is rare, and price height, pH value are 13, according to marketing information, every mu of fund that will drop into more than 100 yuan that sale provides, this is concerning the peasant, and acceptability is restricted.
React in ether with lithium aluminum hydride and silicon halide and to prepare.
SiCl
4+ LiAlH
4 EtherSiH
4+ LiCl+AlCl
3
SiCl
3+ 2LiAlH
4 EtherSi
3H
8+ 2LiCl+2AlCl
3
The author draws the advantage of humic acids and silicon Si Pali, adopts brand-new prescription, brings into play the strong point of the two, avoids the deficiency of the two.
A kind of multifunctional agricultural mulch film is through test of long duration, and scheme is feasible as a result.Kept the advantage of liquid mulch film of humic acids and silicon Si Pali, emphasis is avoiding evaporating, and has the environment-friendly function of humic acids, and cost descends.
The prescription of silicon Si Pali
Summary of the invention:
A kind of agricultural multifunctional liquid mulching film
The present invention relates to the effect of a kind of development and use potassium silicate (water glass takes second place) and weathered coal (brown coal), generate organosilicon (Si-CSi-O-Si), Si, C, H ... Deng hydrophobic group, that organosilicon has is hydrophobic, sealing, bonding, solidify function, the two syntheticly has a liquid mulch film function, be sprayed on the face of land, hydrophobic group and cut off the above kapillary in the face of land, stoped moisture to rise to ground, also made simultaneously and saline and alkalinely risen to the face of land by kapillary.The saline and alkaline rising sinking of being obstructed has protected arable layer to avoid saline and alkaline harm.
Organosilicon is decomposed into SiO2 and humic acids is combined into humic acid Si through uviolizing, is activation silicon, fertilizer efficiency the best.Silicon is important nutritive element in the plant materials, and plant needs more than the summation of silicon nitrogen phosphorus potassium, and silicon can improve photosynthesis.Strengthen the resistibility of crop to disease and pest, lodging-prevention, plant materials intrinsic permeability strengthen, and improve resistance, reduce the curing of phosphorus in soil, help the storage and the transportation of agricultural-food, and silicon is the crops quality element.
Humic acids has green functionals such as ion-exchange, chelating, absorption, cohesion, peptization, reduction, because of environment protection there being irreplaceable effect.
Potassium humate
Has the promoter action rooting effect with cell-activating agent, it is the activator of plant metabolism plurality of enzymes, participate in the generation of organic sugar and starch, transportation and conversion, promote protease activities, increase is to nitrogen, the absorption of phosphorus and multiple element, improve Protein content in plant and the fruit, strengthen protoplasma colloidal wetting ability, increase drought resistance, strengthen the deposit of sugar in the body, improve winter resistance, a little less than the seedling that each kind of plant potassium deficiency is drawn, short and small, Huang Ye, leaf roll, leaf is withered, tikka, fallen flowers, fallen leaves, shedding (bud drop) effect is remarkable, improves to contain sugar and tinctorial yield, improve crop quality, improve and make matter output.
Technical indicator
Reduce steam output 50%-70% solubility water
Water saving 30%-50% film forming properties is good
The nontoxic potential of hydrogen 6-8 of the solvable synthetics of attribute
Color black humic acid content 25%
Solid content is about 40% degradation time 6-12 month of weight
Effective ingredient is about 50% packing of product plastic tank of weight
The present invention realizes by the following method
Pulverizer is that the powdered coal of keeping watch is broken, granularity is about 200 orders, coal dust is placed the acid and alkali-resistance reactor, add the two ratio of potassium silicate (or water glass takes second place) and stir evenly at 1: 2, be heated to 65 ℃-70 ℃, leave standstill half an hour, then the clear at the middle and upper levels rare material of reactor is filtered (sieve mesh 200 orders) with filter, finished product is packed with plastic tank, does not contact non-ferrous metal (use and press the working instructions use), 5 ℃-50 ℃ of storing temps.1 year quality guaranteed period.
Embodiment
Below in conjunction with embodiment the present invention is further described, a kind of agricultural multifunctional liquid film mode of production and utilization, embodiment is as follows:
Embodiment 1:
A kind of agricultural multifunctional liquid mulching film, prescription and technology (operative norm is undetermined).
Raw material; 1) weathered coal, brown coal, consumption 50g contain humic acids 50-70%, and be moisture, 15-20%, granularity 200 orders;
2) potassium silicate, modulus 3
3) with weathered coal and potassium silicate in 1: 2 ratio laggard reactor of inserting earlier
4) the reactor raw material stirring is even.
5) with reactor with steam heating to 60 ℃-70 ℃.
6) leave standstill half an hour.
7), the clear at the middle and upper levels rare material of reactor is filtered waste with filter 200 eye mesh screens.
8) product after the filtration is packed with the molten device of plastics, does not contact non-ferrous metal.
9) preserve in 5 ℃ of-50 ℃ of scopes.
Embodiment 2:
A kind of agricultural multifunctional liquid mulching film, prescription and technology (operative norm is undetermined).
Raw material: 1) weathered coal, brown coal, consumption 50g, contain humic acids 50-70%, moisture, 15-20%, granularity 200 orders;
2) water glass, modulus 3
3) with weathered coal and water glass in 1: 2 ratio laggard reactor of inserting earlier
4) the reactor raw material stirring is even.
5) with reactor with steam heating to 60 ℃-70 ℃.
6) leave standstill half an hour.
7), the clear at the middle and upper levels rare material of reactor is filtered waste with filter 200 eye mesh screens.
8) product after the filtration is packed with the molten device of plastics, does not contact non-ferrous metal.
9) preserve in 5 ℃ of-50 ℃ of scopes.
Accompanying drawing is a product work program skeleton diagram
Drawing explanation: 1, select weathered coal; 2, pulverize weathered coal; 3, select potassium silicate; 4, the two ratio is put into reactor at 1: 2; 5, stir; 6, steam heating; 7, leave standstill half an hour; 8, filter; 9, packing.
Claims (11)
1. production method of agricultural multifunctional liquid mulching film, it is characterized in that described method raw material is that weathered coal, brown coal, peat add water glass (potassium), ratio by successively insert reactor stirs, heats, leaves standstill, filters, packs at 1: 2, uses by specification to require to use.
2. according to claim: 1) described agricultural multifunctional liquid mulching film is characterized in that described method, raw material is to adopt weathered coal to contain humic acids 50-70%, granularity 200 orders, add water glass modulus 3, the two ratio is to insert in reactor at 1: 2, stir, heat, leave standstill, filter, pack, use by specification to use.
3. according to claim: 1) described agricultural multifunctional liquid mulching film is characterized in that, described method, optimum feed stock is that employing weathered coal (humic acids content 70%) potassium silicate modulus is 3, ratio adds in the reactor at 1: 2, stir, heat, leave standstill, filter, pack, use and press the working instructions use.
4. according to claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock brown coal contain humic acids 70%, granularity 200 orders, potassium silicate modulus are 3, and ratio adds in the reactor at 1: 2, stir, heat, leave standstill, filter, pack, use and press the working instructions use.
5. according to claim: described agricultural multifunctional liquid mulching film is characterized in that described method, the optimum feed stock weathered coal contains humic acids 70%, and granularity 200 orders, potassium silicate modulus are 3, ratio adds in reactor at 1: 2, stirs, heats, leaves standstill, filters, packs.
6. according to claim: described agricultural multifunctional liquid mulching film is characterized in that described method, the optimum feed stock weathered coal contains humic acids 70%, and granularity 200 orders, potassium silicate modulus are 3, ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill, filters, packs.
7. according to claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filtration, packing.
8. according to claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filters 200 orders, packing.
9. by claim: described agricultural multi-functions liquid-state mulch film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filters 200 orders, the molten device of packaging plastics.
10. according to claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, potassium silicate modulus are 3, and ratio adds in the reactor at 1: 2, stir, heat 60 ℃-70 ℃, leave standstill half an hour, filter 200 orders, the molten device of packaging plastics, 5 ℃-50 ℃ of storage temperatures.Use and press the working instructions use.
11. according to claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, every mu of ground adds 650 kilograms in water by 10 kilograms, after planting, evenly is sprayed on the face of land, and the details by specification uses.
5, by claim: described agricultural multifunctional liquid mulching film is characterized in that described method, the optimum feed stock weathered coal contains humic acids 70%, and granularity 200 orders, potassium silicate modulus are 3, ratio adds in reactor at 1: 2, stirs, heats, leaves standstill, filters, packs.
6, by claim: described agricultural multifunctional liquid mulching film is characterized in that described method, the optimum feed stock weathered coal contains humic acids 70%, and granularity 200 orders, potassium silicate modulus are 3, ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill, filters, packs.
7, by claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filtration, packing.
8, by claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filters 200 orders, packing.
8, by claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, the potassium silicate modulus is 3, and ratio adds in reactor at 1: 2, stirs, heats 60 ℃-70 ℃, leaves standstill half an hour, filters 200 orders, the molten device of packaging plastics.
9, by claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, the optimum feed stock weathered coal contains humic acids 70%, granularity 200 orders, potassium silicate modulus are 3, and ratio adds in the reactor at 1: 2, stir, heat 60 ℃-70 ℃, leave standstill half an hour, filter 200 orders, the molten device of packaging plastics, 5 ℃-50 ℃ of storage temperatures.Use and press the working instructions use.
10, by claim: described agricultural multifunctional liquid mulching film, it is characterized in that, described method, every mu of ground adds 650 kilograms in water by 10 kilograms, after planting, evenly is sprayed on the face of land, and the details by specification uses.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106866307A (en) * | 2017-03-03 | 2017-06-20 | 王书秀 | A kind of liquid-state mulch film constituted as major ingredient with feces of livestock and poultry and preparation method |
CN113563896A (en) * | 2021-08-17 | 2021-10-29 | 河北硅谷肥业有限公司 | Saline-alkali soil improver capable of preventing saline-alkali rising and preparation method and application thereof |
CN114059231A (en) * | 2021-09-30 | 2022-02-18 | 河海大学 | Composite fiber felt material and preparation method and application thereof |
-
2008
- 2008-12-30 CN CN200810073043A patent/CN101712873A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106866307A (en) * | 2017-03-03 | 2017-06-20 | 王书秀 | A kind of liquid-state mulch film constituted as major ingredient with feces of livestock and poultry and preparation method |
CN113563896A (en) * | 2021-08-17 | 2021-10-29 | 河北硅谷肥业有限公司 | Saline-alkali soil improver capable of preventing saline-alkali rising and preparation method and application thereof |
CN114059231A (en) * | 2021-09-30 | 2022-02-18 | 河海大学 | Composite fiber felt material and preparation method and application thereof |
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