CN101687955B - 含有全氟烷基的共聚物及其水性分散体 - Google Patents

含有全氟烷基的共聚物及其水性分散体 Download PDF

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Publication number
CN101687955B
CN101687955B CN200880021729XA CN200880021729A CN101687955B CN 101687955 B CN101687955 B CN 101687955B CN 200880021729X A CN200880021729X A CN 200880021729XA CN 200880021729 A CN200880021729 A CN 200880021729A CN 101687955 B CN101687955 B CN 101687955B
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copolymers
unit
derive
monomer
multipolymer
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CN101687955A (zh
Inventor
R·穆尔斯
W·阿特纳
I·雷滕巴彻尔
E·希德克
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Angao International Germany Co ltd
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Huntsman Textile Effects Germany GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2915—Rod, strand, filament or fiber including textile, cloth or fabric

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Paper (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
CN200880021729XA 2007-06-27 2008-05-14 含有全氟烷基的共聚物及其水性分散体 Active CN101687955B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07012551A EP2009035A1 (de) 2007-06-27 2007-06-27 Copolymere mit Perfluoralkylgruppen und wässrige Dispersionen davon
EP07012551.3 2007-06-27
PCT/EP2008/003845 WO2009000370A1 (en) 2007-06-27 2008-05-14 Copolymers containing perfluoroalkyl groups and aqueous dispersions thereof

Publications (2)

Publication Number Publication Date
CN101687955A CN101687955A (zh) 2010-03-31
CN101687955B true CN101687955B (zh) 2012-03-21

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CN200880021729XA Active CN101687955B (zh) 2007-06-27 2008-05-14 含有全氟烷基的共聚物及其水性分散体

Country Status (11)

Country Link
US (2) US8349976B2 (enExample)
EP (2) EP2009035A1 (enExample)
JP (1) JP5548124B2 (enExample)
KR (1) KR101490137B1 (enExample)
CN (1) CN101687955B (enExample)
AT (1) ATE496950T1 (enExample)
BR (1) BRPI0810643B1 (enExample)
DE (1) DE602008004771D1 (enExample)
ES (1) ES2358166T3 (enExample)
MX (1) MX2009012017A (enExample)
WO (1) WO2009000370A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008035906A1 (de) 2008-08-02 2010-02-04 Huntsman Textile Effects (Germany) Gmbh Zusammensetzungen mit Fluor enthaltendem Polymeren und Siloxan
KR101600101B1 (ko) * 2008-03-12 2016-03-04 아사히 가라스 가부시키가이샤 공중합체 및 그 제조 방법
EP2233633A1 (de) * 2009-03-28 2010-09-29 Huntsman Textile Effects (Germany) GmbH Fluorfreie wässrige Dispersion für die Behandlung von textilen Flächengebilden
EP2302130A1 (de) 2009-09-26 2011-03-30 Huntsman Textile Effects (Germany) GmbH Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien
EP3301220A1 (en) 2016-09-30 2018-04-04 Coöperatie Avebe U.A. Greaseproof paper

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0234724A1 (en) * 1986-01-23 1987-09-02 E.I. Du Pont De Nemours And Company Oil- and water-repellent copolymers
US5387640A (en) * 1992-01-22 1995-02-07 Bayer Aktiengesellschaft Fluorine-containing copolymers and aqueous dispersions prepared therefrom
CN1120847A (zh) * 1993-04-14 1996-04-17 纳幕尔杜邦公司 防水、抗油的氟代(甲基)丙烯酸酯共聚物
EP1365000A1 (en) * 2001-01-30 2003-11-26 Daikin Industries, Ltd. Water- and oil-repellent composition, process for producing the same and use thereof
CN1539860A (zh) * 2003-11-03 2004-10-27 长春赛纳纳米服饰有限公司 一种纳米材料改性的织物整理剂及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491169A (en) * 1966-07-22 1970-01-20 Du Pont Oil and water repellent
DE1669046A1 (de) * 1967-09-21 1971-06-03 Schramm Lack & Farbenfab Elektroisolierlack
JPS503438B1 (enExample) 1969-01-17 1975-02-04
US4060681A (en) 1976-02-11 1977-11-29 Ciba-Geigy Corporation Unsaturated esters of polyfluoroalkylthioalcohols
JPS608068B2 (ja) * 1978-09-28 1985-02-28 ダイキン工業株式会社 撥水撥油剤
DE4039193A1 (de) * 1990-12-08 1992-06-11 Bayer Ag In wasser dispergierbare, elektrolytstabile polyetherester-modifizierte polyurethanionomere
US6326447B1 (en) * 1998-06-19 2001-12-04 E. I. Du Pont De Nemours And Company Polymeric compositions for soil release on fabrics
DE60041121D1 (de) * 1999-10-29 2009-01-29 Asahi Glass Co Ltd In wasser dispergierte wasser- und ölabweisende zusammensetzung und verfahren zu ihrer herstellung
WO2002072727A1 (en) * 2001-03-09 2002-09-19 Daikin Industries, Ltd. Water-and-oil repellant composition with improved suitability for cold cure
US6479605B1 (en) * 2001-05-15 2002-11-12 E. I. Du Pont De Nemours And Company High-durability, low-yellowing repellent for textiles
JP2005146102A (ja) * 2003-11-14 2005-06-09 Daikin Ind Ltd 撥水撥油剤組成物の製造方法
WO2008022985A1 (en) * 2006-08-25 2008-02-28 Clariant International Ltd Oil-, water- and soil-repellent perfluoroalkylethyl methacrylate copolymers
CN101679548B (zh) * 2007-06-06 2012-07-18 3M创新有限公司 氟化组合物以及由其制备的表面处理剂
EP2172495A1 (en) * 2008-10-03 2010-04-07 Ineos Europe Limited Method for the production of polymers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0234724A1 (en) * 1986-01-23 1987-09-02 E.I. Du Pont De Nemours And Company Oil- and water-repellent copolymers
US5387640A (en) * 1992-01-22 1995-02-07 Bayer Aktiengesellschaft Fluorine-containing copolymers and aqueous dispersions prepared therefrom
CN1120847A (zh) * 1993-04-14 1996-04-17 纳幕尔杜邦公司 防水、抗油的氟代(甲基)丙烯酸酯共聚物
EP1365000A1 (en) * 2001-01-30 2003-11-26 Daikin Industries, Ltd. Water- and oil-repellent composition, process for producing the same and use thereof
CN1539860A (zh) * 2003-11-03 2004-10-27 长春赛纳纳米服饰有限公司 一种纳米材料改性的织物整理剂及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
周钰明等."含氟整理剂的研究进展".《现代化工》.2001,第21卷(第5期),9-12.
李俊等."含氟丙烯酸酯聚合物研究进展".《高分子材料科学与工程》.2005,第21卷(第5期),14-18.

Also Published As

Publication number Publication date
DE602008004771D1 (de) 2011-03-10
BRPI0810643A2 (pt) 2014-11-04
KR20100036268A (ko) 2010-04-07
US8568875B2 (en) 2013-10-29
JP5548124B2 (ja) 2014-07-16
BRPI0810643B1 (pt) 2018-04-10
ATE496950T1 (de) 2011-02-15
EP2160420A1 (en) 2010-03-10
US20100193724A1 (en) 2010-08-05
CN101687955A (zh) 2010-03-31
US8349976B2 (en) 2013-01-08
JP2010531370A (ja) 2010-09-24
WO2009000370A1 (en) 2008-12-31
US20130102724A1 (en) 2013-04-25
MX2009012017A (es) 2010-03-26
EP2160420B1 (en) 2011-01-26
KR101490137B1 (ko) 2015-02-05
EP2009035A1 (de) 2008-12-31
ES2358166T3 (es) 2011-05-06

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Address after: Wade, Germany

Patentee after: Angao International (Germany) Co.,Ltd.

Country or region after: Germany

Address before: Wade, Germany

Patentee before: HUNTSMAN TEXTILE EFFECTS (GERMANY) GmbH

Country or region before: Germany