CN101606517A - A kind of farm chemical emulsion preparation - Google Patents
A kind of farm chemical emulsion preparation Download PDFInfo
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- CN101606517A CN101606517A CNA2009100414114A CN200910041411A CN101606517A CN 101606517 A CN101606517 A CN 101606517A CN A2009100414114 A CNA2009100414114 A CN A2009100414114A CN 200910041411 A CN200910041411 A CN 200910041411A CN 101606517 A CN101606517 A CN 101606517A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention provides a kind of farm chemical emulsion preparation, it comprises pesticide activity component 1%～70%, stabilizing agent 0～8%, cosolvent 1%～25%, emulsifier 5%～20% and plant resource solvent surplus, described plant resource solvent is one or more in australene, D-hesperidene, the Jatropha curcas oil methyl esters, and aforementioned percentage all is mass percent.Compared with prior art, do not contain other non-environmental protection soluble additives such as any aromatic hydrocarbons organic solvent in the farm chemical emulsion preparation of the present invention, environmentally friendly, safety, to people and crop safety height, safety is good in production, accumulating and the use, and integrated control effect all is better than using the farm chemical emulsion preparation of aromatic hydrocarbon solvent preparation.
Description
Technical field
The present invention relates to a kind of farm chemical emulsion preparation, especially a kind of to people and crop safety height, environment amenable farm chemical emulsion preparation.
Background technology
Missible oil is one of basic formulation of agricultural chemicals tradition, compare with other formulations of pesticide, advantage such as missible oil has that active constituent content is higher, excellent storage stability, manufacture craft are simple, and in the missible oil owing to contain a large amount of organic solvents, make soup wetting on crop, polypide and weeds easily, opening up, the easier medicament that makes is penetrated in crop, polypide and the weeds body, therefore has better control efficiency.
But, produce emulsifiable concentrate pesticide and need use a large amount of organic solvents, mainly contain aromatic hydrocarbon solvent and N such as benzene,toluene,xylene, dinethylformamide (DMF), methyl alcohol isopolarity solvent, wherein the annual consumption of aromatic hydrocarbon solvent is up to ten thousand tons of 20-30, and it is low, inflammable and explosive and to shortcomings such as human and environment toxicity height, after these organic solvents enter environment along with the sprinkling of agricultural chemicals that these solvents have a flash-point, not only can cause severe contamination, also can damage health environment.
The order that Environmental Protection Agency USA (EPA) once successively decreased according to toxicity, harmfulness and management intensity with agricultural chemicals with solvent and other auxiliary agent be divided into 1,2,3,4A, 4B five big classes, wherein 1 class is to be proved there are harm in human health and environment, comprise the material of some carcinogens, neurotoxin, chronic toxicity material, harm reproduction and environment is had the material of pollution, as N, dinethylformamide, aniline, carbon tetrachloride, chloroform, dimethyl sulfoxide (DMSO), trichloro-ethylene etc.; 2 classes are to be necessary to carry out auxiliary agent toxicity test, that genotoxic potential is arranged, as toluene, cyclohexanone, dimethylbenzene, phenol, nonyl phenol etc.; 3 classes are the still indefinite materials of some toxicity, as D-hesperidene, N-Methyl pyrrolidone, N-octylpyrrolidone, turpentine oil, benzoic acid, nicotinic acid etc.; The 4A class is low-risk, comprises inert substance and those materials as food additives, as acetate, soya-bean oil, corn oil, White Mineral Oil, glycerine, oleic acid etc.; Some may be poisonous in the 4B class, but under specific service condition public health and environment are not had adverse effect, as australene, propane diols, isopropyl alcohol, ethanol, n-butanol etc.
1992, U.S. government put into effect the regulation of organic solvents such as forbidding toluene, dimethylbenzene in pesticidal preparations, and after this, European countries have also put into effect similar regulation in succession; By the end of in February, 2006,38 kinds of organic solvents that use in the Pesticidal products such as China Taiwan agricultural commission paraxylene, aniline, benzene, carbon tetrachloride, trichloro-ethylene management of having carried out limiting the quantity of, the content of dimethylbenzene, cyclohexanone can not surpass 10% in the agricultural chemicals finished product, dimethyl formamide and methyl alcohol should be less than 30%, and the content of ethylbenzene can not surpass 2%.
Along with the structural adjustment of National Development and Reform Committee's increasing to formulations of pesticide product, the output of missible oil product is compressed, and agricultural chemicals enterprise presses for to be sought efficient soluble additive environmentally friendly, that toxicity is low, easy degraded, renewable resources are derived and replace petrochemical industry series products or derivatives thereof.In existing patent documentation, existing report adopts vegetable oil or its derivative to use as pesticide solvent, and as adopting soybean oil, corn oil, rapeseed oil, cottonseed oil, soybean oil methyl esters etc., but these greases all exist with the people and strive food, the more high shortcoming of price.
In view of this, the necessary farm chemical emulsion preparation that a kind of safety, environmental protection are provided.
Summary of the invention
The objective of the invention is to: the farm chemical emulsion preparation that a kind of safety, environmental protection are provided.
The applicant attempts and the experiment discovery through a large amount of, australene in the plant resource solvent, D-hesperidene, Jatropha curcas oil methyl esters can use as solvent in emulsifiable concentrates for agricultural chemicals, it can substitute original other non-environmental protection soluble additives such as aromatic hydrocarbons organic solvent fully, and pesticide activity component is had significant synergies.In view of the above, the invention provides a kind of farm chemical emulsion preparation, it comprises pesticide activity component 1%～70%, stabilizing agent 0～8%, cosolvent 1%～25%, emulsifier 5%～20% and plant resource solvent surplus, described plant resource solvent is one or more in australene, D-hesperidene, the Jatropha curcas oil methyl esters, and aforementioned percentage all is mass percent.
The D-hesperidene is a kind of monocyclic terpene ene compound that extensively exists in the natural plant essential oils, chemical name is D-1-methyl-4-(1-methyl ethylene) cyclohexene, claim limonene, dipentene again, burning-point is 48 ℃, it is the good plants essential oil of a kind of solubility property, be mainly derived from rutaceae etc., all contain the D-hesperidene in a lot of plants such as oranges and tangerines, vegetables.It can not had teratogenesis, carcinogenic, mutagenic potentiality to the mankind by microbial decomposition, has been assert by FDA (Food and Drug Adminstration) to can be used as food additives.
Australene is terebinthine main component, and chemical name is 2,6,6-trimethyl-dicyclo (3.1.1)-2-heptene, and flash-point is 33 ℃, is mainly derived from pinaceae plant, the dry fruit content of Oleaceae plant is also higher.
The little seeds of a tung oil tree also claim little tung oil tree, Jatropha curcas (Jatropha curcas L.), are euphorbia plants, and the whole world has 200 kinds approximately.In the torrid areas, cultivated area is wider in China cultivation or semi-wild, and resource is than horn of plenty.According to the study, the dry fruit output of the wild little seeds of a tung oil tree is 4500-12000kg/hm2, can extract the Jatropha curcas oil that processes about 2700kg, and its methylate Jatropha curcas oil methyl esters only uses as a kind of biofuel at present.The processing cost of one ton of Jatropha curcas oil methyl esters of present every production is no more than 4500 yuan, compares with the vegetable oil of present use to have good development potentiality.
Described stabilizing agent can choose 2 wantonly, one or more in 6-BHT, butylated hydroxy anisole, epoxidized soybean oil, the methyl oleate.
Described cosolvent can be chosen one or more in N-Methyl pyrrolidone, N-octylpyrrolidone, isopropyl alcohol, n-butanol, propane diols, ethanol, the ethylene glycol wantonly.
Described emulsifier is divided into two kinds of non-ionic surface active agent and anion surfactants, and described non-ionic surface active agent can be chosen at least a in polyoxyethylene polyoxypropylene block copolymer, C12-14 alcohol APEO, sorbitol polyoxyethylene ether, castor oil polyoxyethylene ether, ethylene glycol APEO, anhydrosorbitol acid anhydride oleate, anhydrous sorbitol acid anhydride trioleate, sorbitan monooleate, polyoxyethylene (20) sorbitan monolaurate, the alkane polyoxyethylene 20 sorbitan monooleate wantonly; Described anion surfactant can be chosen at least a in straight chain calcium dodecyl benzene sulfonate, straight chain DBSA triethylamine, alkyl polyglycol ether phosphate, the ethoxylated alkyl phosphate wantonly.Above surfactant all has biodegradability.
Described pesticide activity component is meant the pesticide original medicine that can dissolve in the mixed solvent that plant resource solvent of the present invention and cosolvent mix with arbitrary proportion, comprising:
1, when agricultural chemicals is insecticidal/acaricidal agent, can choose Avermectin wantonly, ivermectin, emamectin-benzoate, thiophene worm piperazine, thiophene worm quinoline, flufenoxuron, capillary, Bifenazate, fenazaquin, Nitenpyram, gamma cyhalothrin, decis, betacyfluthrin, sumicidin, beta-cypermethrin, cypermethrin, fenpropathrin, Biphenthrin, ether chrysanthemum ester, Buprofezin, butene-fipronil, Acetamiprid, the Acarus tritici urea, fluorine bell urea, fluorine pyridine urea, diflubenzuron, chlopyrifos, Hostathion, Profenofos, phoxim, dichlorvos, the malathion, methidathion, diazinon, quinalphos, carbosulfan, Bassa, the worm hydrazides, Mobucin, spiral shell mite ester, azoles mite ester, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, alkynes mite spy, pyridaben, azacyclotin, the compounded combination of one or more in the fenbutatin oxide.
When 2, agricultural chemicals is bactericide, can choose one or more the compounded combination in Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, Difenoconazole, triazolone, propiconazole, fluorine ring azoles, Flusilazole, Tebuconazole, own azoles alcohol, Flutriafol, Isoprothiolane, the iprobenfos wantonly.
When 3, agricultural chemicals is weed killer herbicide, can choose wantonly Quizalotop-ethyl, efficient haloxyfop-methyl spirit, efficient fluazifop,
The compounded combination of one or more in cyhalofop-butyl, Acetochlor, butachlor, isopropyl methoxalamine, clethodim, sethoxydim, Oxyfluorfen, clomazone, the oxadiazon.
The preparation method of above-mentioned farm chemical emulsion preparation comprises following processing step:
1, takes by weighing pesticide original medicine, plant resource solvent, cosolvent and be mixed in the reactor, stir;
2, stabilizing agent, emulsifier are added in the reactor, stir, get final product farm chemical emulsion preparation of the present invention.
Compared with prior art, do not contain other non-environmental protection soluble additives such as any aromatic hydrocarbons organic solvent in the farm chemical emulsion preparation of the present invention, environmentally friendly, safety, to people and crop safety height, safety is good in production, accumulating and the use, and integrated control effect all is better than using the farm chemical emulsion preparation of aromatic hydrocarbon solvent preparation.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that all any modifications of being made within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with appended claims.
If no special instructions, all percentages of this specification all refer to mass percent.
Embodiment 1
Taking by weighing 50 kilograms of Avermectin, 660 kilograms of D-hesperidenes, isopropyl alcohol double centner, ethanol is mixed in the reactor for 50 kilograms, after the stirring and dissolving, add 40 kilograms of polyoxyethylene polyoxypropylene block copolymers, 30 kilograms of C12-14 alcohol APEOs, 50 kilograms of straight chain calcium dodecyl benzene sulfonates, 20 kilograms of epoxidized soybean oils, mix, promptly obtain 1000 kilogram 5% abamectin emulsifiable concentrate.
Use the abamectin emulsifiable concentrate control citrus red mite of present embodiment, according to active ingredient 5 gram/mu thin up field sprays, the control efficiency of 2 days and 5 days is respectively 84.1% and 92.4% behind the medicine, and the abamectin emulsifiable concentrate of application aromatic hydrocarbon solvent dimethylbenzene preparation, adopt with quadrat method according to same dose and to use, the preventive effect of 2 days and 5 days is respectively 73.5% and 79.6% behind the medicine.As seen embodiment of the invention abamectin emulsifiable concentrate is better than the abamectin emulsifiable concentrate of using xylene solvent to the preventive effect of two spotted spider mite.
Embodiment 2
Taking by weighing 50 kilograms of thiophene worm piperazines, 675 kilograms of australenes, 120 kilograms of N-Methyl pyrrolidone, n-butanol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 40 kilograms of 50 kilograms of ethylene glycol APEOs, 30 kilograms of alkyl polyoxyethylene sorbitan monooleates, straight chain DBSA triethylamine, 2,15 kilograms of 6-BHTs, mix, obtain 1000 kilogram 5% thiophene worm piperazine missible oil.
Use the thiophene worm piperazine missible oil of present embodiment to prevent and treat rice hoppers, spray by active ingredient 1.5 gram/mu thin ups, the control efficiency of 3 days and 7 days is respectively 88.9%, 97.4% behind the medicine; And use the thiophene worm piperazine missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, and adopting with quadrat method according to same dose and use, 3 days, 7 days preventive effect is respectively 64.1% and 70.3% behind the medicine.As seen the thiophene worm piperazine missible oil of present embodiment is better than the thiophene worm piperazine missible oil of using xylene solvent to the preventive effect of rice fulgorid.
Embodiment 3
Taking by weighing 10 kilograms of Avermectin, 50 kilograms of thiophene worm piperazines, 680 kilograms of australenes, N-Methyl pyrrolidone double centner, isopropyl alcohol double centner is mixed in the reactor, after the stirring and dissolving, add 50 kilograms of 35 kilograms of polyoxyethylene polyoxypropylene block copolymers, 35 kilograms of castor oil polyoxyethylene ethers, alkyl polyglycol ether phosphate, 2,10 kilograms of 6-BHTs, 20 kilograms of epoxidized soybean oils, mix, obtain Avermectin thiophene worm piperazine missible oil.
Use the Avermectin of present embodiment. thiophene worm piperazine missible oil control pear sucker, by 1000 extraordinarily water dilution sprayings, the control efficiency of 2 days and 5 days is respectively 83.4% and 94.6% behind the medicine, and use the Avermectin of aromatic hydrocarbon solvent dimethylbenzene preparation. thiophene worm piperazine missible oil adopts with quadrat method according to same dose and uses, and the control efficiency of 2 days and 5 days behind the pear sucker medicine is respectively 69.2% and 81.1%.As seen the Avermectin of present embodiment. thiophene worm piperazine missible oil is better than the Avermectin of using aromatic hydrocarbon solvent to the preventive effect of pear sucker. thiophene worm piperazine missible oil.
Embodiment 4
Taking by weighing 10 kilograms of emamectin-benzoates, 50 kilograms of thiophene worm piperazines, 620 kilograms of australenes, N-Methyl pyrrolidone double centner, ethylene glycol is mixed in the reactor for 80 kilograms, after the stirring and dissolving, add 30 kilograms of C12-14 APEOs, 50 kilograms of ethylene glycol APEOs, 40 kilograms of straight chain calcium dodecyl benzene sulfonates, 20 kilograms of butylated hydroxy anisoles, mix, obtain emamectin-benzoate thiophene worm piperazine missible oil.
Use the emamectin-benzoate thiophene worm piperazine missible oil control pear sucker of present embodiment, by 1000 extraordinarily water dilution sprayings, the control efficiency of 2 days and 5 days is respectively 86.4% and 95.6% behind the medicine, and the emamectin-benzoate thiophene worm piperazine missible oil of using the preparation of aromatic hydrocarbon solvent trimethylbenzene adopts with quadrat method according to same dose and uses, and the control efficiency of 2 days and 5 days is respectively 75.1% and 88.1% behind the medicine.The emamectin-benzoate thiophene worm piperazine missible oil of present embodiment is better than the emamectin-benzoate thiophene worm piperazine missible oil of using the trimethylbenzene solvent to the preventive effect of pear sucker.
Embodiment 5
Taking by weighing 150 kilograms of indenes worm prestige, 570 kilograms of Jatropha curcas oil methyl esters, 120 kilograms of N-Methyl pyrrolidone, isopropyl alcohol is mixed in the reactor for 30 kilograms, after the stirring and dissolving, add 40 kilograms of polyoxyethylene polyoxypropylene block copolymers, 45 kilograms of polyoxyethylene (20) sorbitan monolaurates, 45 kilograms of ethoxylated alkyl phosphate, mix, obtain the indenes worm prestige missible oil of present embodiment preparation.
Use the indenes worm prestige missible oil control wild cabbage prodenia litura of present embodiment, by 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day and 3 days is respectively 88.9%, 97.4% behind the medicine, and the indenes worm prestige missible oil of application aromatic hydrocarbon solvent dimethylbenzene preparation, adopt with quadrat method according to same dose and to use, the control efficiency of 1 day and 3 days is respectively 71.6% and 82.4% behind the medicine.As seen the indenes worm prestige missible oil of present embodiment is better than the indenes worm prestige missible oil of using xylene solvent to the preventive effect of wild cabbage prodenia litura.
Embodiment 6
Taking by weighing 10 kilograms of Avermectin, 150 kilograms of indenes worm prestige, 510 kilograms of D-hesperidenes, 120 kilograms of N-Methyl pyrrolidone, 50 kilograms of isopropyl alcohols, n-butanol is mixed in the reactor for 30 kilograms, after the stirring and dissolving, add 50 kilograms of polyoxyethylene polyoxypropylene block copolymers, 25 kilograms of castor oil polyoxyethylene ethers, 35 kilograms of straight chain calcium dodecyl benzene sulfonates, 20 kilograms of methyl oleates, mix, obtain the Avermectin indenes worm prestige missible oil of present embodiment preparation.
Use the Avermectin indenes worm prestige missible oil of present embodiment, be used to prevent and treat the brassicaceous vegetable diamond-back moth, by the spraying of active ingredient 8 gram/mu thin ups, 72 hours control efficiency is 93.3% behind the medicine, and the Avermectin indenes worm prestige missible oil of application aromatic hydrocarbon solvent dimethylbenzene preparation, adopt with quadrat method according to same dose and to use, behind the medicine 72 hours control efficiency be 79.3%.As seen the Avermectin indenes worm prestige missible oil of present embodiment is better than the Avermectin of using xylene solvent to the preventive effect of diamond-back moth. indenes worm prestige missible oil.
Embodiment 7
Taking by weighing 50 kilograms of Acarus tritici ureas, 395 kilograms of australenes, 300 kilograms of D-hesperidenes, 120 kilograms of N-Methyl pyrrolidone, propane diols is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 40 kilograms of polyoxyethylene polyoxypropylene block copolymers, 30 kilograms of alkyl polyoxyethylene sorbitan monooleates, 45 kilograms of straight chain DBSA triethylamines, mix, obtain the Acarus tritici urea missible oil of present embodiment preparation.
Use the Acarus tritici urea missible oil of present embodiment, by 1000 times of dilution spraying control cotton cotton bollworms, 3 days preventive effect is 88.7% behind the medicine; And the preventive effect that the Acarus tritici urea missible oil of using the preparation of aromatic hydrocarbon solvent trimethylbenzene is sprayed by 1000 times of dilutions is 80.2%.As seen the Acarus tritici urea missible oil of present embodiment is better than the Acarus tritici urea missible oil of using the trimethylbenzene solvent to the preventive effect of diamond-back moth.
Embodiment 8
Taking by weighing 240 kilograms of spiral shell mite esters, 570 kilograms of D-hesperidenes, 50 kilograms of N-Methyl pyrrolidone, isopropyl alcohol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 30 kilograms of polyoxyethylene polyoxypropylene block copolymers, 40 kilograms of C12-14 APEOs, 50 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the spiral shell mite emulsifiable concentrate of present embodiment preparation.
Use the spiral shell mite emulsifiable concentrate of present embodiment, according to 2500 water dilution spraying control citrus red mites extraordinarily, 3 days control efficiency is 89.4% behind the medicine, and the spiral shell mite emulsifiable concentrate of application aromatic hydrocarbon solvent dimethylbenzene preparation, 3 days preventive effect is 78.6% behind the medicine, and the spiral shell mite emulsifiable concentrate of visible present embodiment is better than the spiral shell mite emulsifiable concentrate of using xylene solvent to the preventive effect of two spotted spider mite.
Embodiment 9
Taking by weighing 400 kilograms of chlopyrifos, 300 kilograms of D-hesperidenes, 180 kilograms of australenes, propane diols is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 55 kilograms of polyoxyethylene polyoxypropylene block copolymers, 45 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the chlorpyrifos ec of present embodiment preparation.
Use the chlorpyrifos ec of present embodiment, be used to prevent and treat the paddy rice rice leaf roller, spray according to active ingredient 40 gram/mu thin ups, 1 day, 7 days, 15 days preventive effect is respectively 70.2%, 86.1% and 92.4% behind the medicine, and use the chlorpyrifos ec of aromatic hydrocarbon solvent dimethylbenzene preparation, 1 day, 7 days, 15 days preventive effect is respectively 61.2%, 76.1% and 81.4% behind the medicine.As seen the chlorpyrifos ec of present embodiment is better than the chlorpyrifos ec of using xylene solvent to the preventive effect of rice leaf roller.
Embodiment 10
Taking by weighing 200 kilograms of Hostathions, 660 kilograms of Jatropha curcas oil methyl esters, isopropyl alcohol is mixed in the reactor for 30 kilograms, after the stirring and dissolving, add 50 kilograms of polyoxyethylene polyoxypropylene block copolymers, 25 kilograms of straight chain calcium dodecyl benzene sulfonates, 25 kilograms of straight chain DBSA triethylamines, 10 kilograms of epoxidized soybean oils, mix, obtain the triazophos emulsifiable solution of present embodiment preparation.
Use the triazophos emulsifiable solution of present embodiment, be used to prevent and treat rice-stem borer, by 1000 dilution thin up sprayings, 3 days, 7 days control efficiency is respectively 85.6%, 89.4% behind the medicine, and use the triazophos emulsifiable solution of aromatic hydrocarbon solvent trimethylbenzene preparation, the control efficiency under the same terms is respectively 68.3%, 77.8%.As seen the triazophos emulsifiable solution of present embodiment is better than the triazophos emulsifiable solution of using the trimethylbenzene solvent to the preventive effect of striped rice borer.
Embodiment 11
Taking by weighing 400 kilograms of phoxims, 480 kilograms of Jatropha curcas oil methyl esters, propane diols is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 30 kilograms of polyoxyethylene polyoxypropylene block copolymers, 20 kilograms of C12-14 APEOs, 40 kilograms of straight chain calcium dodecyl benzene sulfonates, 10 kilograms of epoxidized soybean oils, mix, obtain the phoxim emulsifiable concentrate of present embodiment preparation.
Use the phoxim emulsifiable concentrate of present embodiment, by 2000 times of dilution spraying control wild cabbage three ages of prodenia litura and following larva, 2 days control efficiency are 88.6% behind the medicine, and use the phoxim emulsifiable concentrate of aromatic hydrocarbon solvent trimethylbenzene preparation, and the control efficiency under the same terms is 74.0%.As seen the preventive effect of the phoxim emulsifiable concentrate of present embodiment is better than the phoxim emulsifiable concentrate of using the trimethylbenzene solvent.
Embodiment 12
Taking by weighing 250 kilograms of Difenoconazoles, 610 kilograms of D-hesperidenes, isopropyl alcohol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 50 kilograms of polyoxyethylene polyoxypropylene block copolymers, 60 kilograms of straight chain DBSA triethylamines, 10 kilograms of epoxidized soybean oils, mix, obtain the Difenoconazole missible oil of present embodiment preparation.
Use the Difenoconazole missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1000 times of dilute liquid medicines, 7 days control efficiency is 89.8% behind the medicine, and use the Difenoconazole missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, be 75.4% to the control efficiency behind the powdery mildew of cucumber medicine under the same terms.As seen the Difenoconazole missible oil of present embodiment is better than the Difenoconazole missible oil of using xylene solvent to the preventive effect of powdery mildew of cucumber.
Embodiment 13
Taking by weighing 250 kilograms of Enestroburins, 620 kilograms of D-hesperidenes, ethanol is mixed in the reactor for 30 kilograms, after the stirring and dissolving, add 35 kilograms of polyoxyethylene polyoxypropylene block copolymers, 30 kilograms of C12-14 APEOs, 35 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the Enestroburin missible oil of present embodiment preparation.
Use the Enestroburin missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1500 times of dilutions, 7 days control efficiency is 86.3% behind the medicine, and use the Enestroburin missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation preparation, the control efficiency under the same terms is 78.5%.As seen the Enestroburin missible oil of present embodiment is better than the Enestroburin missible oil of using xylene solvent to the preventive effect of powdery mildew of cucumber.
Embodiment 14
Taking by weighing 200 kilograms of kresoxim-methyls, 390 kilograms of D-hesperidenes, 250 kilograms of N-Methyl pyrrolidone, 50 kilograms of N-octylpyrrolidone ethanol, isopropyl alcohol is mixed in the reactor for 10 kilograms, after the stirring and dissolving, add 40 kilograms of polyoxyethylene polyoxypropylene block copolymers, 20 kilograms of castor oil polyoxyethylene ethers, 40 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the kresoxim-methyl missible oil of present embodiment preparation.
Use the kresoxim-methyl missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1000 times of dilutions, 7 days control efficiency is 87.0% behind the medicine, and use the kresoxim-methyl missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, the control efficiency under the same terms is 74.7%.As seen the kresoxim-methyl missible oil of present embodiment is better than the kresoxim-methyl missible oil of using xylene solvent to the preventive effect of powdery mildew of cucumber.
Embodiment 15
Taking by weighing kresoxim-methyl double centner, 200 kilograms of Isoprothiolanes, 370 kilograms of D-hesperidenes, 200 kilograms of N-Methyl pyrrolidone, ethylene glycol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 35 kilograms of C12-14 APEOs, 35 kilograms of castor oil polyoxyethylene ethers, 40 kilograms of straight chain DBSA three basic amine, mix, obtain the kresoxim-methyl Isoprothiolane missible oil of present embodiment preparation.
Use the kresoxim-methyl Isoprothiolane missible oil of present embodiment, by 2000 extraordinarily water dilution carry out field spray control rice blast, 7 days control efficiency is 92.7% behind the medicine, and uses the kresoxim-methyl Isoprothiolane missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, under the same terms control efficiency be 75.4%.As seen the kresoxim-methyl Isoprothiolane missible oil of present embodiment is better than the kresoxim-methyl Isoprothiolane missible oil of using xylene solvent to the preventive effect of rice blast.
Embodiment 16
Taking by weighing 200 kilograms of Fluoxastrobins, 360 kilograms of D-hesperidenes, 300 kilograms of N-Methyl pyrrolidone, isopropyl alcohol is mixed in the reactor for 30 kilograms, after the stirring and dissolving, add 25 kilograms of C12-14 APEOs, 35 kilograms of castor oil polyoxyethylene ethers, 50 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the Fluoxastrobin missible oil of present embodiment preparation.
Use the Fluoxastrobin missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1000 times of dilutions, 7 days control efficiency is 84.5% behind the medicine, and use the Fluoxastrobin missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, the control efficiency under the same terms is 67.7%.As seen the Fluoxastrobin missible oil of present embodiment is better than the Fluoxastrobin missible oil of using xylene solvent to the preventive effect of powdery mildew of cucumber.
Embodiment 17
Taking by weighing Fluoxastrobin double centner, 200 kilograms of Difenoconazoles, 365 kilograms of australenes, 150 kilograms of N-Methyl pyrrolidone, 50 kilograms of N-octylpyrrolidone ethanol, n-butanol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 30 kilograms of 30 kilograms of C12-14 APEOs, 40 kilograms of castor oil polyoxyethylene ethers, straight chain calcium dodecyl benzene sulfonate, 2,15 kilograms of 6-BHTs, mix, obtain the Fluoxastrobin Difenoconazole missible oil of present embodiment preparation.
Use the Fluoxastrobin Difenoconazole missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1500 times of dilutions, 7 days control efficiency is 97.6% behind the medicine, and use the Fluoxastrobin Difenoconazole missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, the control efficiency under the same terms is 84.4%.As seen the Fluoxastrobin Difenoconazole missible oil of present embodiment is better than the Fluoxastrobin Difenoconazole missible oil of using xylene solvent to the preventive effect of powdery mildew of cucumber.
Embodiment 18
Taking by weighing kresoxim-methyl double centner, 200 kilograms of Difenoconazoles, 355 kilograms of D-hesperidenes, 200 kilograms of N-Methyl pyrrolidone, isopropyl alcohol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 40 kilograms of 35 kilograms of C12-14 APEOs, 35 kilograms of castor oil polyoxyethylene ethers, straight chain calcium dodecyl benzene sulfonate, 2,15 kilograms of 6-BHTs, mix, obtain the kresoxim-methyl Difenoconazole missible oil of present embodiment preparation.
Use the kresoxim-methyl Difenoconazole missible oil of present embodiment, be used to prevent and treat powdery mildew of cucumber, carry out indoor pot experiment by 1500 times of dilutions, 7 days control efficiency is 94.3% behind the medicine, and use the kresoxim-methyl Difenoconazole missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, the control efficiency under the same terms is 80.6%.As seen the kresoxim-methyl of present embodiment. Difenoconazole missible oil is better than the kresoxim-methyl of using xylene solvent to the preventive effect of powdery mildew of cucumber. Difenoconazole missible oil.
Embodiment 19
Taking by weighing Quizalotop-ethyl double centner, 380 kilograms of D-hesperidenes, 300 kilograms of Jatropha curcas oil methyl esters, isopropyl alcohol is mixed in the reactor for 20 kilograms, after the stirring and dissolving, add 30 kilograms of polyoxyethylene polyoxypropylene block copolymers, 80 kilograms of C12 14 APEOs, 20 kilograms of castor oil polyoxyethylene ethers, 70 kilograms of straight chain calcium dodecyl benzene sulfonates, mix, obtain the Quizalotop-ethyl missible oil of present embodiment preparation.
Use the Quizalotop-ethyl missible oil of present embodiment, by 400 extraordinarily water dilution wheat seedling is carried out the indoor pot test of pesticide effectiveness, 7 days control efficiency is 82.4% behind the medicine, and uses the Quizalotop-ethyl missible oil of aromatic hydrocarbon solvent dimethylbenzene preparation, and the control efficiency under the same terms is 74.8%.As seen the preventive effect of the Quizalotop-ethyl missible oil of present embodiment is better than the Quizalotop-ethyl missible oil of using xylene solvent.
Compared with prior art, farm chemical emulsion preparation of the present invention has following significant advantage: 1, used and planted Thing source solvent, biodegradable emulsifying agent and safe cosolvent, farm chemical emulsion preparation of the present invention In do not contain other non-environmental protection soluble additive such as any aromatic hydrocarbons organic solvent, environmentally friendly, safety, to the people and The crop safety height has reduced aromatic hydrocarbons organic solvent etc. effectively to environment and crops such as soil, water sources Contamination hazard. 2, botanical solvent is renewable resource, does not strive food, wide material sources with the people, to big section Divide the solubility of farm chemical ingredients suitable with the aromatic hydrocarbons organic solvent, therefore all can change existing farm chemical emulsion preparation Make and be farm chemical emulsion preparation of the present invention. 3, botanical solvent has good permeability, the anti-drift of opening up With with target stronger affinity is arranged, therefore pesticide activity component is had significant synergies (referring to reality Execute the routine test of pesticide effectiveness), the integrated control effect of the farm chemical emulsion preparation of appliable plant source solvent preparation all is better than using virtue The cream preparation of varsol preparation. 4, owing to botanical solvent flash-point height, [〉=33 ℃ (remaining silent), (diformazan Benzene is 25 ℃)], the burning-point height, the farm chemical emulsion preparation security performance of production is good, production, accumulating and used Safe in the journey.
Claims (7)
1, a kind of farm chemical emulsion preparation, it is characterized in that: comprise pesticide activity component 1%～70%, stabilizing agent 0～8%, cosolvent 1%～25%, emulsifier 5%～20% and plant resource solvent surplus in the described preparation, described plant resource solvent is one or more in australene, D-hesperidene, the Jatropha curcas oil methyl esters, and aforementioned percentage all is mass percent.
2, farm chemical emulsion preparation according to claim 1 is characterized in that: described stabilizing agent is 2, one or more in 6-BHT, butylated hydroxy anisole, epoxidized soybean oil, the methyl oleate.
3, farm chemical emulsion preparation according to claim 1 is characterized in that: described pesticide activity component is the insecticidal/acaricidal agent Avermectin, ivermectin, emamectin-benzoate, thiophene worm piperazine, thiophene worm quinoline, flufenoxuron, capillary, Bifenazate, fenazaquin, Nitenpyram, gamma cyhalothrin, decis, betacyfluthrin, sumicidin, beta-cypermethrin, cypermethrin, fenpropathrin, Biphenthrin, ether chrysanthemum ester, Buprofezin, butene-fipronil, Acetamiprid, the Acarus tritici urea, fluorine bell urea, fluorine pyridine urea, diflubenzuron, chlopyrifos, Hostathion, Profenofos, phoxim, dichlorvos, the malathion, methidathion, diazinon, quinalphos, carbosulfan, Bassa, the worm hydrazides, Mobucin, spiral shell mite ester, azoles mite ester, fenisobromolate, methamidophos, tebufenpyrad, Hexythiazox, alkynes mite spy, pyridaben, azacyclotin, the compounded combination of one or more in the fenbutatin oxide; Or one or more the compounded combination in the bactericide Fluoxastrobin, kresoxim-methyl, pyrrole metsulfovax, ZEN 90160, Difenoconazole, triazolone, propiconazole, fluorine ring azoles, Flusilazole, Tebuconazole, own azoles alcohol, Flutriafol, Isoprothiolane, iprobenfos; Or one or more the compounded combination in the weed killer herbicide Quizalotop-ethyl, efficient haloxyfop-methyl spirit, efficient fluazifop, cyhalofop-butyl, Acetochlor, butachlor, isopropyl methoxalamine, clethodim, sethoxydim, Oxyfluorfen, clomazone, oxadiazon.
4, according to any described farm chemical emulsion preparation in the claim 1 to 3, it is characterized in that: described cosolvent is one or more in N-Methyl pyrrolidone, N-octylpyrrolidone, isopropyl alcohol, n-butanol, propane diols, ethanol, the ethylene glycol.
5, according to any described farm chemical emulsion preparation in the claim 1 to 3, it is characterized in that: described emulsifier comprises at least a non-ionic surface active agent and at least a anion surfactant.
6, farm chemical emulsion preparation according to claim 5 is characterized in that: described non-ionic surface active agent is one or more in polyoxyethylene polyoxypropylene block copolymer, C12-14 alcohol APEO, sorbitol polyoxyethylene ether, castor oil polyoxyethylene ether, ethylene glycol APEO, anhydrosorbitol acid anhydride oleate, anhydrous sorbitol acid anhydride trioleate, sorbitan monooleate, polyoxyethylene (20) sorbitan monolaurate, the alkane polyoxyethylene 20 sorbitan monooleate.
7, farm chemical emulsion preparation according to claim 5 is characterized in that: described anion surfactant is one or more in straight chain calcium dodecyl benzene sulfonate, straight chain DBSA triethylamine, alkyl polyglycol ether phosphate, the ethoxylated alkyl phosphate.
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Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5731264A (en) * | 1996-10-17 | 1998-03-24 | Isp Investments Inc. | Stabilized liquid emulsifiable concentrate for a sulfonyl or sulfamoylurea herbicide |
| CN1218636C (en) * | 2002-11-21 | 2005-09-14 | 中国农业科学院植物保护研究所 | Pirimicarb microemulsion and preparation process thereof |
| CN1836522A (en) * | 2006-04-18 | 2006-09-27 | 红河森菊生物有限责任公司 | Pyrethrin missible oil formulation using neem oil as synergistic agent |
-
2009
- 2009-07-27 CN CN2009100414114A patent/CN101606517B/en active Active
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Effective date of registration: 20160204 Address after: 266603 Qingdao City, Shandong province Laixi City, Jiang Shan town before the village (Busan Industrial Park) Patentee after: Qingdao Star Cropscience Co., Ltd. Address before: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Patentee before: Nuopuxin Agricultural Chemical Co., Ltd., Shenzhen |
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