CN101897340A - Disinfestation composite containing thiacloprid and carbosulfan - Google Patents
Disinfestation composite containing thiacloprid and carbosulfan Download PDFInfo
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- CN101897340A CN101897340A CN2010101507015A CN201010150701A CN101897340A CN 101897340 A CN101897340 A CN 101897340A CN 2010101507015 A CN2010101507015 A CN 2010101507015A CN 201010150701 A CN201010150701 A CN 201010150701A CN 101897340 A CN101897340 A CN 101897340A
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- carbosulfan
- thiophene worm
- worm quinoline
- pesticidal combination
- medicine
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Abstract
The invention relates to a disinfestation composite containing thiacloprid and carbosulfan, which comprises effective active ingredients, an accessory ingredient and filler. The disinfestation composite is characterized in that the disinfestation composite comprises the effective active ingredients of the thiacloprid and the carbosulfan the weight percentage of which is 1-60:80-1. After the thiacloprid and the carbosulfan are formulated, the disinfestation composite has obvious synergy and continuous prevention and cure effect, enlarges insecticidal spectrum and has higher activity on vegetable cabbage caterpillars, plutella xylostella, rice planthopper, Chilosuppressalis, Scirpophaga incertulas, aphid, red spiders and the like.
Description
Technical field
The invention belongs to agricultural technology field, relate to the application that Pesticidal combination that a kind of effective active composition contains thiophene worm quinoline and carbosulfan is used to prevent and treat the vegetables insect pest.
Background technology
Thiophene worm quinoline, English common name Thiacloprid, chemical name are the inferior cyanamide of 3-(6-chloro-5-picoline)-1,3-thiazoles alkane-2-, and molecular formula is C
13H
5N
4SCl.
Thiophene worm quinoline is novel chloro nicotinic insecticide, and the mechanism of action and other conventional pesticides are different.It mainly acts on the neural caudacoria that engages of insect, by combine interference insect nervous system normal conduction with nAChR, cause the obstruction of neural channel, cause a large amount of accumulation of acetylcholine, thereby make the insect exaltation, whole body spasm, paralysis and dead.Having stronger interior suction, tag and stomach poison function, do not have cross resistance with common insecticides such as pyrethroid, organic phosphates and carbamates, thereby can be used for resistance management, is one of efficient medicament of control pierce-suck type and pests with chewing mouthparts.
Carbosulfan, English common name carbosulfan, molecular formula is C
20H
32N
2O
3S, chemical name are 2,3-dihydro-2,2-dimethyl benzofuran-7-base (dibutylamino sulphur) methyl carbamate.
Carbosulfan is a carbamate insecticide, is the poisonous red insecticidal action that rises of furans at the insect bodies intracellular metabolite, and its insecticidal mechanism is the interference insect nervous system, suppresses cholinesterase, makes muscle of insect and body of gland continue excitement, and causes insect death.Absorption in this medical instrument has insect and to tag and stomach poison function, and the lasting period is long, and insecticidal spectrum is wide, can be used for preventing and treating the various pests on fruit tree, paddy rice, the vegetables.
Often there is defective in various degree in the insecticide variety that contains the single-activity component on agricultural insect pests control: use the back insect to be easy to generate pesticide resistance continuously, access times are many will the weighting ring environment pollution.And that different component carries out is composite, can effectively overcome above shortcoming.Simultaneously, utilizing two kinds of synergistic effects that active component is mixed and is produced, can improve preventive effect, reduce the consumption of active ingredient, save drug cost, delay the generation of pest resistance to insecticide, reduce environmental pollution, is the important means of integrated control insect.At present, still nobody reported in the composite and application of thiophene worm quinoline and carbosulfan.
Summary of the invention
In order to satisfy the needs of pesticide producing, make full use of two kinds of active components be mixed the synergistic effect that produced, improve preventive effect, reduce agricultural cost and delay the generation of pest resistance to insecticide, the present invention proposes the composite Pesticidal combination that contains thiophene worm quinoline and carbosulfan.
The object of the present invention is achieved like this: a kind of Pesticidal combination that contains thiophene worm quinoline and carbosulfan, comprise effective active component, auxiliary agent and filler, and the weight hundred of effective active composition thiophene worm quinoline and carbosulfan is than being 1～60: 80～1.
The described Pesticidal combination that contains thiophene worm quinoline and carbosulfan, the percentage by weight of thiophene worm quinoline and carbosulfan are 1～40: 60～5.
The described Pesticidal combination that contains thiophene worm quinoline and carbosulfan, the percentage by weight of thiophene worm quinoline and carbosulfan are 5～25: 40～5.
Described thiophene worm quinoline and the carbosulfan insecticidal composite of containing, the percentage by weight of thiophene worm quinoline and carbosulfan is 5～20: 30～10.
Described thiophene worm quinoline and the carbosulfan insecticidal composite of containing, the optimum activity proportioning of thiophene worm quinoline and carbosulfan is 5: 1～1: 15, preferred proportioning is 1: 1～1: 10.
The described Pesticidal combination that contains thiophene worm quinoline and carbosulfan adds conventional auxiliary agent by method well-known in the art, can be made into wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
The described Pesticidal combination that contains thiophene worm quinoline and carbosulfan is mainly used in control vegetables cabbage caterpillar, diamond-back moth, rice hoppers, striped rice borer, paddy stem borer, aphid, two spotted spider mite.
The invention has the advantages that:
(1) thiophene worm quinoline and carbosulfan composite after, different fully to the mechanism of action of target pest, both are composite to have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, aphid, two spotted spider mite, rice fulgorid have been had special efficacy;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Application Example one
For the examination insect: cotton aphid, standby after 3 generations of artificial feeding.
Test medicine: agricultural chemicals Co., Ltd of U.S. nation provides by Shaanxi.
Experimental scheme: effective lethal concentration scope of determining the former medicine of thiophene worm quinoline, the former medicine of carbosulfan and the two different proportioning mixture through preliminary experiment, each medicament designs five gradient concentrations respectively by active constituent content and handles, and does contrast with the space management that does not contain former medicine.
Test method: respectively the mother liquor of thiophene worm quinoline, carbosulfan and each mixed agent is diluted to above 5 series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the fresh cotton floral leaf of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for the examination aphid, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The cotton aphid corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with thiophene worm quinoline is the standard medicament, and its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=thiophene worm quinoline
Thiophene worm quinolineTI * the P of+carbosulfan
Carbosulfan
In the formula: M is the mixture of different proportionings
P
CarbosulfanBe carbosulfan shared ratio in composition
P
Thiophene worm quinolineBe thiophene worm quinoline shared ratio in composition
Result of the test is as shown in table 1:
The different proportionings with carbosulfan of table 1 thiophene worm quinoline are to the toxicity test of cotton aphid
As shown in Table 1, thiophene worm quinoline and carbosulfan and composite product are to cotton aphid Toxicity Determination experiment discovery, the virulence of thiophene worm quinoline is higher than carbosulfan, co-toxicity coefficient is all greater than 120 when thiophene worm quinoline and carbosulfan proportioning are 5: 1,1: 1,1: 5,1: 10,1: 15, show obvious synergistic effect, thiophene worm quinoline thus: carbosulfan all had synergistic function between 5: 1 to 1: 15, especially when thiophene worm quinoline: during carbosulfan=1: 5, co-toxicity coefficient maximum, synergistic effect are the most obvious.
Application example two
20% thiophene worm quinoline carbosulfan wetting powder is prevented and treated the rice hoppers test of pesticide effectiveness
Thiophene worm quinoline 10%, carbosulfan 10%, alkyl benzene sulfonate calcium salt 2%, alkylphenol-polyethenoxy are phonetic 2%, lauryl sodium sulfate 2%, moistening bleeding agent F 2%, white carbon 32%, diatomite 40% mixture are carried out comminution by gas stream, make 20% thiophene worm quinoline carbosulfan wetting powder.This prescription is by 1000 times of dilution sprayings, and preventing and treating the rice hoppers effect in 72 hours behind the medicine is 94.13%～96.38%.48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil dilute 4500 times and 300 times of uses respectively according to same quadrat method, and 72 hours preventive effects are respectively 80.64% and 76.55% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example three
The 30% thiophene worm quinoline carbosulfan wetting powder control cotton aphid test of pesticide effectiveness
Thiophene worm quinoline 25%, carbosulfan 5%, polycarboxylate 4%, spaonin powder 4%, white carbon 30%, diatomite 32%, mixture carries out comminution by gas stream, makes 30% thiophene worm quinoline carbosulfan wetting powder.This prescription is by 1500 times of dilution sprayings, and 72 hours control cotton aphid effects are 94.74%～97.27% behind the medicine.48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil dilute 5000 times and 300 times of uses respectively according to same quadrat method, and 72 hours preventive effects are respectively 81.67% and 77.84% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example four
The 16% thiophene worm quinoline carbosulfan water dispersible granules control wild cabbage beet armyworm test of pesticide effectiveness
Thiophene worm quinoline 1%, carbosulfan 15%, lignosulfonates 6%, neopelex 4%, ammonium sulfate 2%, white carbon 34%, starch 38%, the mixed 16% thiophene worm quinoline carbosulfan water dispersible granules that gets.This proportioning is by 1000 times of dilution sprayings, 72 hours control effect wild cabbage beet armyworms really are 93.04%～96.72% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 250 times of uses respectively, 72 hours preventive effects are respectively 80.57% and 76.62% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example five
The 25% thiophene worm quinoline carbosulfan water dispersible granules control wild cabbage diamond-back moth test of pesticide effectiveness
Thiophene worm quinoline 5%, carbosulfan 20%, sodium lignin sulfonate 5%, draw back powder 5%, urea 2%, white carbon 29%, starch 20%, kaolin 18%, mixed 25% thiophene worm quinoline carbosulfan water dispersible granules.This proportioning is by 1500 times of dilution sprayings, 72 hours control wild cabbage diamond-back moth effects are 94.86%～97.43% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 5500 times and 350 times of uses respectively, 72 hours preventive effects are respectively 80.13% and 77.41% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example six
The 45% thiophene worm quinoline carbosulfan missible oil control rice-stem borer test of pesticide effectiveness
Thiophene worm quinoline 15%, carbosulfan 30%, alkylphenol polyoxyethylene class 12%, cyclohexanone 20%, pyrrolidones 15%, silicone oil 0.1%, phosphite ester 0.2%, deionized water adds to 100%, the mixed 45% thiophene worm quinoline carbosulfan missible oil that gets.This proportioning is by 1800 times of dilution sprayings, 72 hours control rice-stem borer effects are 95.13%～97.72% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 82.23% and 79.45% behind the medicine.Find that in test the present composition has no adverse effects to the target crop, to beneficial insect safety.
Application example seven
The 48% thiophene worm quinoline carbosulfan aqueous emulsion control cucumber aphid test of pesticide effectiveness
Thiophene worm quinoline 8%, carbosulfan 40%, acetonitrile 18%, toluene 13%, farming breast 400
#4%, 600
#Phosphate 4%, propane diols 4%, polyvinyl alcohol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 48% thiophene worm quinoline carbosulfan aqueous emulsion.This proportioning is by 2000 times of dilution sprayings, 72 hours control cucumber aphid effects are 94.21%～97.74% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 350 times of uses respectively, 72 hours preventive effects are respectively 83.46% and 80.12% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example eight
The 35% thiophene worm quinoline carbosulfan aqueous emulsion control paddy rice rice leaf roller test of pesticide effectiveness
Thiophene worm quinoline 5%, carbosulfan 30%, cyclohexanone 24%, N-pyrrolidones 8%, farming breast 1600
#3%, the farming breast 500
#4%, ethylene glycol 4%, polyethylene glycol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 35% thiophene worm quinoline carbosulfan aqueous emulsion.This proportioning is by 1500 times of dilution sprayings, 72 hours control paddy rice rice leaf roller effects are 93.46%～96.72% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.26% and 79.54% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example nine
The 30% thiophene worm quinoline carbosulfan microemulsion control paddy rice paddy stem borer test of pesticide effectiveness
With thiophene worm quinoline 5%, carbosulfan 25%, N-octylpyrrolidone 17%, toluene 5%, ethylene glycol monomethyl ether 4%, ethyl acetate 4%, farming breast 34
#6%, triethanolamine salt 6%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, makes 30% thiophene worm quinoline carbosulfan microemulsion.This proportioning is by 1200 times of dilution sprayings, 72 hours control paddy rice paddy stem borer effects are 94.87%～97.10% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.45% and 79.86% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example ten
The 15% thiophene worm quinoline carbosulfan microemulsion control Chinese cabbage cabbage caterpillar test of pesticide effectiveness
With thiophene worm quinoline 5%, carbosulfan 10%, N, dinethylformamide 17%, methyl alcohol 8%, N-pyrrolidones 4%, tween 4%, farming breast 600
#3%, Nongru-700
#5%, propane diols 3%, silicone oil 0.4%, deionized water supplies 100%, makes 15% thiophene worm quinoline carbosulfan microemulsion.This proportioning is by 1000 times of dilution sprayings, 72 hours control Chinese cabbage cabbage caterpillar effects are 93.89%～97.34% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 80.31% and 79.55% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 11
The 22% thiophene worm quinoline carbosulfan microcapsule suspending agent control citrus red mite test of pesticide effectiveness
Thiophene worm quinoline 2%, carbosulfan 20%, phenyl phenol polyoxy ethyl ether 10%, sorbitan monostearate 8%, shitosan 10%, dimethylbenzene 12%, hexane 5%, deionized water are supplied 100%, 22% thiophene worm quinoline carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control citrus red mite effects are 92.83%～95.37% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.35% and 79.75% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 12
The 12% thiophene worm quinoline carbosulfan microcapsule suspending agent control cucumber aphid test of pesticide effectiveness
Thiophene worm quinoline 2%, carbosulfan 10%, alkyl polyoxyethylene ether 10%, alkyl benzene calcium sulfonate 8%, gelatin 10%, acetone 12%, methyl alcohol 5%, deionized water are supplied 100%, 12% thiophene worm quinoline carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control cucumber aphid effects are 92.68%～96.07% behind the medicine, 48% thiophene worm quinoline suspending agent and 20% carbosulfan missible oil are according to same quadrat method, dilute 6000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.55% and 78.43% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Claims (6)
1. a Pesticidal combination that contains thiophene worm quinoline and carbosulfan comprises effective active component, auxiliary agent and filler, it is characterized in that: the percentage by weight of effective active composition thiophene worm quinoline and carbosulfan is 1～60: 80～1.
2. the Pesticidal combination that contains thiophene worm quinoline and carbosulfan according to claim 1 is characterized in that: the percentage by weight of thiophene worm quinoline and carbosulfan is 1～40: 60～5.
3. the Pesticidal combination that contains thiophene worm quinoline and carbosulfan according to claim 2 is characterized in that: the percentage by weight of thiophene worm quinoline and carbosulfan is 5～25: 40～5.
4. the Pesticidal combination that contains thiophene worm quinoline and carbosulfan according to claim 1 is characterized in that: composition is made wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
5. the application of Pesticidal combination on the control crop pest that contains thiophene worm quinoline and carbosulfan according to claim 1.
6. the application of Pesticidal combination on control vegetables cabbage caterpillar, diamond-back moth, rice hoppers, striped rice borer, paddy stem borer, aphid, two spotted spider mite that contains thiophene worm quinoline and carbosulfan according to claim 5.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010150701 CN101897340B (en) | 2010-04-20 | 2010-04-20 | Disinfestation composite containing thiacloprid and carbosulfan |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010150701 CN101897340B (en) | 2010-04-20 | 2010-04-20 | Disinfestation composite containing thiacloprid and carbosulfan |
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| Publication Number | Publication Date |
|---|---|
| CN101897340A true CN101897340A (en) | 2010-12-01 |
| CN101897340B CN101897340B (en) | 2013-10-09 |
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|---|---|---|---|
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102726432A (en) * | 2011-04-11 | 2012-10-17 | 浙江森得保生物制品有限公司 | Thiacloprid-containing formula for red spider |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1164172C (en) * | 1999-03-24 | 2004-09-01 | 拜尔公司 | Synergistic insecticide mixtures |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
| CN101606517A (en) * | 2009-07-27 | 2009-12-23 | 深圳诺普信农化股份有限公司 | A kind of farm chemical emulsion preparation |
-
2010
- 2010-04-20 CN CN 201010150701 patent/CN101897340B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1164172C (en) * | 1999-03-24 | 2004-09-01 | 拜尔公司 | Synergistic insecticide mixtures |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
| CN101606517A (en) * | 2009-07-27 | 2009-12-23 | 深圳诺普信农化股份有限公司 | A kind of farm chemical emulsion preparation |
Non-Patent Citations (2)
| Title |
|---|
| 《农药》 20011231 谢心宏 等 噻虫啉( Thiacloprid) -一种新的叶面施用杀虫剂 第41-42 1-6 第40卷, 第1期 * |
| 谢心宏 等: "噻虫啉( Thiacloprid) —一种新的叶面施用杀虫剂", 《农药》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102726432A (en) * | 2011-04-11 | 2012-10-17 | 浙江森得保生物制品有限公司 | Thiacloprid-containing formula for red spider |
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Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Meibang pesticide Co.,Ltd. Address before: 710075, Xi'an high tech Zone, Shaanxi hi tech Zone, Jinqiao International C block, 15 Floor Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Shaanxi Pucheng Weinan County agricultural base industrial park Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Granted publication date: 20131009 |