CN101558092B - 可交联的氟乙烯共聚物涂层薄膜以及它们的制备方法 - Google Patents
可交联的氟乙烯共聚物涂层薄膜以及它们的制备方法 Download PDFInfo
- Publication number
- CN101558092B CN101558092B CN200780046544XA CN200780046544A CN101558092B CN 101558092 B CN101558092 B CN 101558092B CN 200780046544X A CN200780046544X A CN 200780046544XA CN 200780046544 A CN200780046544 A CN 200780046544A CN 101558092 B CN101558092 B CN 101558092B
- Authority
- CN
- China
- Prior art keywords
- fluoropolymer coating
- film
- monomer
- mole
- coating film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/20—Vinyl fluoride
- C08F214/202—Vinyl fluoride with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/20—Vinyl fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/38—Carbon pastes or blends; Binders or additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87644206P | 2006-12-21 | 2006-12-21 | |
| US60/876,442 | 2006-12-21 | ||
| US96408507P | 2007-08-09 | 2007-08-09 | |
| US60/964,085 | 2007-08-09 | ||
| PCT/US2007/026287 WO2008079395A1 (en) | 2006-12-21 | 2007-12-21 | Crosslinkable vinyl fluoride copolymer coated film and process for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101558092A CN101558092A (zh) | 2009-10-14 |
| CN101558092B true CN101558092B (zh) | 2011-11-16 |
Family
ID=39326706
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780046544XA Expired - Fee Related CN101558092B (zh) | 2006-12-21 | 2007-12-21 | 可交联的氟乙烯共聚物涂层薄膜以及它们的制备方法 |
| CN2007800468058A Expired - Fee Related CN101563375B (zh) | 2006-12-21 | 2007-12-21 | 可交联的氟乙烯共聚物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800468058A Expired - Fee Related CN101563375B (zh) | 2006-12-21 | 2007-12-21 | 可交联的氟乙烯共聚物 |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US20080149887A1 (enExample) |
| JP (1) | JP2010514140A (enExample) |
| CN (2) | CN101558092B (enExample) |
| WO (1) | WO2008079393A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2094747B1 (en) * | 2006-12-21 | 2012-10-17 | E.I. Du Pont De Nemours And Company | Crosslinkable vinyl fluoride copolymers |
| US20100092759A1 (en) * | 2008-10-13 | 2010-04-15 | Hua Fan | Fluoropolymer/particulate filled protective sheet |
| JP5494497B2 (ja) * | 2009-02-12 | 2014-05-14 | ダイキン工業株式会社 | リチウム二次電池の正極合剤用スラリー、該スラリーを用いた正極およびリチウム二次電池 |
| EP2403038B1 (en) * | 2009-02-27 | 2017-09-20 | Zeon Corporation | Electrode for lithium-ion secondary battery |
| US8785054B2 (en) | 2009-12-18 | 2014-07-22 | GM Global Technology Operations LLC | Lithium ion battery |
| CN104945795B (zh) * | 2010-11-24 | 2019-05-21 | Agc株式会社 | 机动车用密封圈或者工业气体压缩机用密封圈或滑动构件 |
| CN103265778B (zh) * | 2011-09-01 | 2016-03-02 | 苏州斯迪克新材料科技股份有限公司 | 太阳能光伏背膜用含氟树脂切片 |
| US9240586B2 (en) | 2012-01-18 | 2016-01-19 | E I Du Pont De Nemours And Company | Compositions, layerings, electrodes and methods for making |
| US9093710B2 (en) | 2012-01-18 | 2015-07-28 | E I Du Pont De Nemours And Company | Compositions, layerings, electrodes and methods for making |
| WO2013110740A1 (en) * | 2012-01-25 | 2013-08-01 | Solvay Sa | Fluoropolymers as binder for the electrodes in supercapacitors |
| JP6048636B2 (ja) * | 2012-02-13 | 2016-12-21 | Jsr株式会社 | 電極用バインダー組成物、電極用スラリー、電極および蓄電デバイスの製造方法 |
| US20150017486A1 (en) | 2012-03-14 | 2015-01-15 | Ei Du Pont De Nemours And Company | Mcm-48 templated carbon compositions, electrodes, cells, methods for making and methods for using |
| WO2013191791A1 (en) | 2012-06-19 | 2013-12-27 | E. I. Du Pont De Nemours And Company | Ionomer composite membranes, methods for making and using |
| EP2862217A1 (en) | 2012-06-19 | 2015-04-22 | E. I. Du Pont de Nemours and Company | Electrochemical cells comprising electrolyte additives and ionomer articles, !and methods for making and using the same |
| JP5966693B2 (ja) * | 2012-07-05 | 2016-08-10 | 三菱レイヨン株式会社 | 非水電解質電池電極用バインダ樹脂組成物ならびに該バインダ樹脂組成物を含むスラリー組成物、電極および電池 |
| CN104781350B (zh) * | 2012-11-14 | 2017-09-05 | 3M创新有限公司 | 适用于光伏组件膜的含氟聚合物涂料 |
| CN104218275B (zh) * | 2013-05-31 | 2018-03-27 | 华为技术有限公司 | 一种锂空气电池及其制备方法 |
| WO2015151440A1 (ja) * | 2014-04-01 | 2015-10-08 | 住友精化株式会社 | 電気二重層キャパシタ電極用バインダー、このバインダーを含む電気二重層キャパシタ電極、この電極を用いた電気二重層キャパシタ及び電気機器 |
| US20150299498A1 (en) * | 2014-04-17 | 2015-10-22 | E I Du Pont De Nemours And Company | Transparent fluoropolymer coated films, building structures and liquid fluoropolymer coating compositions |
| US20150332805A1 (en) * | 2014-05-16 | 2015-11-19 | E I Du Pont De Nemours And Company | Electrode compositions and energy storage devices |
| US20150329659A1 (en) * | 2014-05-16 | 2015-11-19 | E I Du Pont De Nemours And Company | Soluble vinyl fluoride interpolymers and polymer binder solutions |
| CN106832077A (zh) * | 2015-12-04 | 2017-06-13 | 浙江省化工研究院有限公司 | 一种具有自交联结构的ectfe氟树脂及其制备方法 |
| MX2020003337A (es) * | 2017-09-27 | 2020-10-28 | Arkema Inc | Copolimeros de olefinas halogenadas y co-monomeros halogenados. |
| EP3714009A1 (en) * | 2017-11-24 | 2020-09-30 | Solvay Specialty Polymers Italy S.p.A. | Fluoropolymer composition stabilized against changes in ph |
| EP3730295B1 (en) * | 2017-12-20 | 2024-11-06 | Agc Inc. | Decorative film and manufacturing method for three-dimensional molding with decorative film |
| WO2019169217A2 (en) * | 2018-03-02 | 2019-09-06 | Arkema Inc. | Fluoropolymer binder coating for use in electrochemical devices |
| US20210324120A1 (en) * | 2018-08-09 | 2021-10-21 | Solvay Specialty Polymers Italy S.P.A. | Self crosslinking pvdf |
| CN110978669A (zh) * | 2019-12-31 | 2020-04-10 | 苏州锂盾储能材料技术有限公司 | 一种高耐腐蚀多涂氟层型软包铝离子电池铝塑膜及其制造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2409948A (en) * | 1945-03-01 | 1946-10-22 | Du Pont | Polymeric materials |
| US3531441A (en) * | 1966-03-01 | 1970-09-29 | Du Pont | Interpolymers of vinyl fluoride |
| US3895029A (en) * | 1974-02-13 | 1975-07-15 | Du Pont | Fluoropolymer coating compositions |
| CN1092438A (zh) * | 1993-01-14 | 1994-09-21 | 日本梅克特隆株式会社 | 含氟弹性体组合物 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5239647B2 (enExample) * | 1974-05-27 | 1977-10-06 | ||
| US4482478A (en) * | 1974-11-01 | 1984-11-13 | General Electric Company | Blends of branched chain phthalate esters and halogenated benzene compounds |
| JPS5858365B2 (ja) * | 1976-07-02 | 1983-12-24 | 東ソー株式会社 | 陽イオン交換膜の製法 |
| US4408259A (en) * | 1979-02-09 | 1983-10-04 | Matsushita Electric Industrial Company, Limited | Electrochemical double-layer capacitor |
| US4409354A (en) * | 1980-01-21 | 1983-10-11 | Daikin Kogyo Co., Ltd. | Fluorinated resin coating composition containing micaceous iron oxide |
| JPS5883066A (ja) * | 1981-11-12 | 1983-05-18 | Daikin Ind Ltd | 非粘着導電性フツ素ゴム塗料 |
| DE3502994A1 (de) * | 1985-01-30 | 1986-07-31 | Obi 6254 Elz Jacobson | Mit fuellstoffen versehene fluor-kohlenstoff-polymere |
| JPH0693025A (ja) * | 1992-09-11 | 1994-04-05 | Kureha Chem Ind Co Ltd | 変性ポリフッ化ビニリデン系樹脂組成物及び変性ポリフッ化ビニリデン系樹脂の製造方法 |
| US5688884A (en) * | 1995-08-31 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Polymerization process |
| US6242547B1 (en) * | 1997-04-15 | 2001-06-05 | E. I. Du Pont De Nemours And Company | Vinyl fluoride interpolymers of low crystallinity |
| JPH1167274A (ja) * | 1997-08-22 | 1999-03-09 | Daikin Ind Ltd | リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤 |
| US6025092A (en) * | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| JP2000021408A (ja) * | 1998-06-30 | 2000-01-21 | Shin Kobe Electric Mach Co Ltd | 非水電解液二次電池 |
| US6275371B1 (en) * | 1998-08-12 | 2001-08-14 | Hitachi Maxwell, Ltd. | Electrode material for electrochemical capacitor, electrochemical capacitor comprising the same, and method for the production of the same |
| US6747110B2 (en) * | 2002-06-13 | 2004-06-08 | Acushnet Company | Golf balls comprising non-ionomeric fluoropolymer |
| JP2004265680A (ja) * | 2003-02-28 | 2004-09-24 | Sanyo Electric Co Ltd | 非水二次電池 |
| WO2005106993A1 (ja) * | 2004-04-30 | 2005-11-10 | Seimi Chemical Co., Ltd. | リチウム二次電池正極用のリチウム含有複合酸化物の製造方法 |
| JP4525419B2 (ja) * | 2005-03-30 | 2010-08-18 | 東レ株式会社 | 直描型水なし平版印刷版原版および直描型水なし平版印刷版原版用シリコーンゴム層溶液 |
| US20060228608A1 (en) * | 2005-04-11 | 2006-10-12 | Tze-Chiang Chung | High temperature and low relative humidity polymer/inorganic composite membranes for proton exchange membrane fuel cells |
| US7214740B2 (en) * | 2005-05-03 | 2007-05-08 | 3M Innovative Properties Company | Fluorinated ionomers with reduced amounts of carbonyl end groups |
-
2007
- 2007-12-21 CN CN200780046544XA patent/CN101558092B/zh not_active Expired - Fee Related
- 2007-12-21 JP JP2009542964A patent/JP2010514140A/ja active Pending
- 2007-12-21 WO PCT/US2007/026285 patent/WO2008079393A1/en not_active Ceased
- 2007-12-21 CN CN2007800468058A patent/CN101563375B/zh not_active Expired - Fee Related
- 2007-12-21 US US11/962,133 patent/US20080149887A1/en not_active Abandoned
-
2009
- 2009-11-19 US US12/621,565 patent/US20100068622A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2409948A (en) * | 1945-03-01 | 1946-10-22 | Du Pont | Polymeric materials |
| US3531441A (en) * | 1966-03-01 | 1970-09-29 | Du Pont | Interpolymers of vinyl fluoride |
| US3895029A (en) * | 1974-02-13 | 1975-07-15 | Du Pont | Fluoropolymer coating compositions |
| CN1092438A (zh) * | 1993-01-14 | 1994-09-21 | 日本梅克特隆株式会社 | 含氟弹性体组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010514140A (ja) | 2010-04-30 |
| WO2008079393A1 (en) | 2008-07-03 |
| CN101563375B (zh) | 2011-10-05 |
| CN101563375A (zh) | 2009-10-21 |
| CN101558092A (zh) | 2009-10-14 |
| US20100068622A1 (en) | 2010-03-18 |
| US20080149887A1 (en) | 2008-06-26 |
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