CN101548680A - Pesticidal composition containing emamectin benzoate and chlorantraniliprole - Google Patents
Pesticidal composition containing emamectin benzoate and chlorantraniliprole Download PDFInfo
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- CN101548680A CN101548680A CNA2009100389786A CN200910038978A CN101548680A CN 101548680 A CN101548680 A CN 101548680A CN A2009100389786 A CNA2009100389786 A CN A2009100389786A CN 200910038978 A CN200910038978 A CN 200910038978A CN 101548680 A CN101548680 A CN 101548680A
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- benzoate
- emamectin
- rynaxypyr
- chlorantraniliprole
- pesticidal combination
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Abstract
The invention relates to a pesticidal composition containing emamectin benzoate and chlorantraniliprole. The pesticidal composition takes emamectin benzoate and chlorantraniliprole as effective constituents with mass proportion of 10:1 to 1:20 and the mass percentage content of the emamectin benzoate and chlorantraniliprole is between 1 percent and 50 percent. The pesticidal composition is used for preventing resistant insects in agriculture, and particularly used for preventing rice Cnaphalocrocis medinalis and the like.
Description
Technical field
The composition pesticide that the present invention relates to is to be active ingredient with emamectin-benzoate and Rynaxypyr, is used to prevent and treat the insect on the agricultural, is particularly useful for preventing and treating paddy rice rice leaf roller etc.
Background technology
Rice leaf roller is commonly called as tortrix moth, white leaf worm, scrapes leaf worm, bract worm etc., belongs to the Lepidoptera Pyralidae, is a kind of migratory pest, and widely distributed, all there is generation in each rice district of China, is one of insect pest of rice.Newly hatched larvae is got the food lobus cardiacus, syringe needle shape point occurs, increase age, weave silk and sew rice leaf both sides leaf margin with worm, vertical leaf roll sheet becomes cylindric worm bud, larva is hidden oneself and gnaws mesophyll in it, stays the epidermis streak that is white in color, and influences paddy rice and grows, reduce thousand kernel weight, not plump paddy increases, and the general underproduction 10%～20% reaches more than 60% when serious.At present, the method for preventing and treating to rice leaf roller mainly contains: (1) cultural control: select pest-resistant cultivar for use, strengthen rich water quality management, the rational application of fertilizer is baked the field moderately and at the right moment, impels the healthy and strong leaf of paddy rice very, alleviates and causes harm.(2) biological control: mainly utilize the control action of parasite to each worm attitude of rice leaf roller.(3) chemical control: dispenser when reaching index for control, the main conventional dose that adopts has: chlopyrifos, dimehypo, desinsection list, bacillus thuringiensis,Bt, Avermectin etc.
But of the prior art actual control efficiency is bad, and a kind of agricultural chemicals of long-term single use to rice leaf roller control medicament, and insect easily develops immunity to drugs.
Being mixed of different pesticide species is the common methods of the agriculture resistant insect of control.By the formulation of pesticide screening, filter out rational prescription, can effectively improve actual control efficiency, reduce dosage, reduce cost, delay the generation of pest resistance to insecticide, be the important means of the insect comprehensive regulation.Insects such as the control paddy rice rice leaf roller that is mixed of emamectin-benzoate and Rynaxypyr still do not have report at present and use.
Emamectin-benzoate (emamectin benzoate), efficient, wide spectrum, the longevity of residure are long, are good insecticidal/acaricidal agent, and its mechanism of action hinders pest movements nerve information transmission and makes the death of health paralysis.The mode of action is main action of contace poison with stomach toxicity, and crop is not had interior absorption energy, uses crop epidermal tissue but can effectively infiltrate, thereby has the longer longevity of residure.To Lepidoptera, mite class, coleoptera and homoptera pest have high activity, and do not intersect with other crops generation, soil and in easily degraded noresidue, free from environmental pollution, in the routine dose scope to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.Because emamectin-benzoate uses separately all the year round continuously in the large tracts of land of China, and pest resistance to insecticide is constantly strengthened, and dispenser dosage is continued to increase, and is unfavorable for the comprehensive regulation of insect.
Rynaxypyr (chlorantraniliprole) belongs to the O-formammidotiazol-benzamide insecticide.Mainly be to activate blue Buddhist nun's alkali acceptor, discharge the calcium ion of storing in smooth muscle and the striated muscle cell, cause that the muscle adjusting is weak, paralysis is until last insect death.This active ingredient shows mammal and the extremely significant selective difference of the blue Buddhist nun's alkali of insect acceptor, has improved greatly mammal and other vertebrate safeties.
Summary of the invention
Technical problem to be solved: the objective of the invention is to solve in the prior art develop immunity to drugs problem and actual control efficiency of insect relatively poor, a kind of efficient, low toxicity is provided, quick-acting is good and the lasting period is long, the Pesticidal combination that helps the insect comprehensive regulation can effectively be prevented and treated paddy rice rice leaf roller etc.
Technical scheme: the invention provides the Pesticidal combination that a kind of active ingredient is made up of emamectin-benzoate and Rynaxypyr for achieving the above object, the mass ratio of emamectin-benzoate and Rynaxypyr is 10: 1-1: between 20.
The described Pesticidal combination that contains emamectin-benzoate and Rynaxypyr, the mass percentage content of active ingredient emamectin-benzoate and the two accumulation of Rynaxypyr is between 1%-50%.
The described Pesticidal combination that contains emamectin-benzoate and Rynaxypyr is made the application forms that comprises missible oil, microemulsion, aqueous emulsion, suspending agent, wetting powder or water dispersible granules when practical application.
The described auxiliary agent that uses in the Pesticidal combination of emamectin-benzoate and Rynaxypyr that contains comprises solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, PH conditioning agent, defoamer, antifreezing agent, deionized water, filler etc., all be various auxiliary agents commonly used in the pesticidal preparations processing, concrete composition and consumption require to determine by simple test according to prescription.
The described production technology that contains the various application forms of Pesticidal combination of emamectin-benzoate and Rynaxypyr all belongs to existing known technology, does not repeat them here.
Technology of the present invention source and effect:
Go up the paddy rice rice leaf roller that produces resistance in order effectively to administer agricultural, the inventor has carried out the prescription screening study to active ingredients such as emamectin-benzoate and Rynaxypyrs:
Gather the female moth egg of rice leaf roller from the field.Female worm is released into (cage footpath 15cm, high 30cm) in cylindrical the shrouding, interior wall liner one deck paraffin paper, the outer cover black cloth is fed and is raised 10% hydromel.Cut pieces of an egg to put in the culture dish with paraffin paper and preserve moisture next day, and raise with the fresh rice leaf of indoor cultivation the hatching back.Insectary temperature (28 ± 1) ℃, the photoperiod 16 (L): 8 (D).
Test medicine adopts the former medicine of 90% emamectin-benzoate, and the former medicine of 95% Rynaxypyr is mixed with required preparation by Huizhou City Zhongxun Chemical Industry Co., Ltd research and development centre.
The drop method that adopts NY/T1154.1-2006 to recommend is measured.With micro-dropper solvent clean, regulate dropper to stand-by state.Choose the examination worm of neat and consistent with writing brush and use CO
2Slight anesthesia is placed in the 9cm culture dish, then with micro-dropper with medicament by a drop on the pronotary that tries worm, every some drops physic liquor 1.0ul, with drop 1.0ul do not contain medicament but the processing that contains corresponding organic solvent compares.It is normally to cultivate in 75% the culturing room that examination worm behind the drop is transferred to (28 ± 2) ℃, relative moisture respectively.Every processing 4 times repeats, and whenever repeats to try 20 of worms, and each handles examination worm is 80.Handle back 48h investigation examination worm death condition (judging that for examination worm death standard be gently to sting no autonomic response with pin), write down total borer population and dead borer population.
According to survey data, calculate the corrected mortality that each is handled.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1154.1-2006.If contrast lethality＜5% is not proofreaied and correct; The contrast lethality is proofreaied and correct between 5%-20%; Contrast lethality＞20%, test need be reformed.Logarithm value with drug concentration (mg/L) is independent variable x, is dependent variable y with the probit value of corrected mortality, sets up the virulence regression equation formula respectively, adopts DPS software to calculate the LC of single agent and each proportioning mixture
50, LC
90, 95% confidence limit and mixture co-toxicity coefficient thereof, relatively synergy situation.
Table 1, emamectin-benzoate and Rynaxypyr and different proportioning are to paddy rice rice leaf roller toxicity test result
| Reagent agent (active ingredient weight ratio) | Virulence regression equation y=a+bx | LC 50(mg/L) (95% confidence limit) | Co-toxicity coefficient (CTC value) |
| Emamectin-benzoate | 4.3708+1.5048x | 2.12(1.50～2.63) | -- |
| Rynaxypyr | 4.7347+1.4760x | 1.42(0.89～2.22) | -- |
| Emamectin-benzoate: Rynaxypyr (10: 1) | 3.8402+1.4282x | 1.19(0.63～1.49) | 157.55 |
| Emamectin-benzoate: Rynaxypyr (5: 1) | 3.8321+1.5010x | 1.03(0.77～1.54) | 166.01 |
| Emamectin-benzoate: Rynaxypyr (1: 1) | 3.9072+1.4776x | 1.24(0.73～1.98) | 179.52 |
| Emamectin-benzoate: Rynaxypyr (1: 5) | 3.9291+1.5584x | 0.57(0.40～1.37) | 225.68 |
| Emamectin-benzoate: Rynaxypyr (1: 10) | 3.9045+1.4684x | 0.63(0.47～1.41) | 188.49 |
| Emamectin-benzoate: Rynaxypyr (1: 20) | 3.8571+1.4581x | 0.78(0.60～1.49) | 158.71 |
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC value) 〉=120 shows as synergistic effect; Co-toxicity coefficient (CTC value)≤120 shows as antagonism; 120＜co-toxicity coefficient (CTC value)＜120 shows as summation action.As can be seen from Table 1, emamectin-benzoate and Rynaxypyr are 10: 1-1: in the scope of 20 (by quality), the paddy rice rice leaf roller is shown as synergistic effect.Emamectin-benzoate and Rynaxypyr are mixed and have reasonability and feasibility.
Beneficial effect of the present invention is: 1. two kinds of pesticide active ingredient combinations in the Pesticidal combination of the present invention, in certain ratio range, insect is had the notable synergistic effect, and improved drug effect, reduced the usage amount of pesticide active ingredient, reduced cost.2. the pesticide active ingredient mechanism of action in the Pesticidal combination of the present invention has nothing in common with each other, and can effectively delay the generation of pest resistance to insecticide, helps the comprehensive regulation of insect.
Embodiment
The present invention describes by following specific embodiment, but the invention is not restricted to following specific embodiment.In following examples, unless otherwise indicated, all percentages all are weight percentage.
Example of formulations one (21% emamectin-benzoate Rynaxypyr missible oil)
Press emamectin-benzoate 1%, Rynaxypyr 20%, the APEO 4% of nonionic, epoxidized soybean oil 1%, p-aminobenzoic acid 0.5%, emulsifier 1601#10%, emulsifier 500#5%, surplus is ethanol and dimethylbenzene, is mixed with missible oil.
Example of formulations two (8% emamectin-benzoate Rynaxypyr microemulsion)
Press emamectin-benzoate 0.5%, Rynaxypyr 7.5%, emulsifier 602 5%, emulsifier NP-10 5%, sodium lignin sulfonate 10%, ring ethyl ketone 5%, dimethylbenzene 5%, surplus is a deionized water, is mixed with microemulsion.
Example of formulations three (11% emamectin-benzoate Rynaxypyr wetting powder)
Press emamectin-benzoate 1%, Rynaxypyr 10%, wetting agent draw back powder 3%, dispersant NNO 8%, and talcum powder 5%, surplus is a kaolin, is mixed with wetting powder.
Example of formulations four (15% emamectin-benzoate Rynaxypyr suspending agent)
Press emamectin-benzoate 2.5%, Rynaxypyr 12.5%, emulsifier 1601#10%, wetting agent LS 5%, dispersant SOPA-270 4%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus is a deionized water, is mixed with suspending agent.
Example of formulations five (10% emamectin-benzoate Rynaxypyr water-dispersible granules)
Press emamectin-benzoate 5%, Rynaxypyr 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 2%, polyethylene glycol 3%, surplus is a kaolin, is mixed with water-dispersible granules.
Example of formulations six (6% emamectin-benzoate Rynaxypyr aqueous emulsion)
Press emamectin-benzoate 5%, Rynaxypyr 1%, N-Methyl pyrrolidone 8%, neopelex 6%, polyvinyl alcohol 4%, emulsifier 500#5%, silicone defoaming agent 0.4%, surplus is a deionized water, is mixed with aqueous emulsion.
Example of formulations seven (5.5% emamectin-benzoate Rynaxypyr water-dispersible granules)
Press emamectin-benzoate 5%, Rynaxypyr 0.5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 2%, polyethylene glycol 3%, surplus is a kaolin, is mixed with water-dispersible granules.
Biological Examples one
Pesticidal combination according to the invention that employing is made by above-mentioned 7 example of formulations has carried out the field control effectiveness test of control paddy rice rice leaf roller respectively.
Test medicine:
(1) 21% emamectin-benzoate Rynaxypyr missible oil (1#);
(2) 8% emamectin-benzoate Rynaxypyr microemulsions (2#);
(3) 11% emamectin-benzoate Rynaxypyr wetting powders (3#);
(4) 15% emamectin-benzoate Rynaxypyr suspending agents (4#);
(5) 10% emamectin-benzoate Rynaxypyr water-dispersible granules (5#);
(6) 6% emamectin-benzoate Rynaxypyr aqueous emulsions (6#);
(7) 5.5% emamectin-benzoate Rynaxypyr water-dispersible granules (7#).
The contrast medicament:
(1) 5% emamectin-benzoate missible oil (8#);
(2) 20% Rynaxypyr suspending agents (9#).
Spraying time: convert the water even spraying in the paddy rice rice leaf roller ovum hatching peak phase.
Result of the test: see Table 2.
The field control effectiveness test result of table 2, control paddy rice rice leaf roller
| Reagent agent | Preparation usage amount (gram/mu) | 1 day preventive effect (%) behind the medicine | 3 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine | 14 days preventive effects (%) behind the medicine |
| 1# | 5 | 61.7 | 85.3 | 93.2 | 92.6 |
| 2# | 15 | 63.4 | 86.1 | 91.7 | 93.9 |
| 3# | 10 | 57.5 | 85.9 | 87.8 | 86.3 |
| 4# | 8 | 65.8 | 87.4 | 95.8 | 96.0 |
| 5# | 12 | 54.9 | 86.6 | 90.4 | 89.2 |
| 6# | 10 | 58.2 | 86.0 | 92.4 | 93.6 |
| 7# | 12 | 55.1 | 85.3 | 89.3 | 91.1 |
| 8# | 15 | 50.3 | 76.1 | 79.5 | 77.1 |
| 9# | 10 | 47.2 | 82.7 | 90.3 | 88.7 |
By above field control effectiveness test result as can be seen, after the dispenser 3 days, Pesticidal combination of the present invention to the control efficiency of paddy rice rice leaf roller all more than 85%, significantly better than single agent; After the dispenser 7 days and 14 days, Pesticidal combination of the present invention also significantly better than single agent, illustrated that Pesticidal combination of the present invention all is being better than single agent aspect quick-acting and the lasting effect to the control efficiency of paddy rice rice leaf roller.Two kinds of pesticide active ingredient combinations in the Pesticidal combination of the present invention have the notable synergistic effect to insect in certain ratio range, improved drug effect, have reduced the usage amount of pesticide active ingredient, have reduced cost.
Simultaneously, we find that in process of the test Pesticidal combination of the present invention also has good control efficiency to rice-stem borer, paddy stem borer.
Claims (3)
1, a kind of Pesticidal combination that contains emamectin-benzoate and Rynaxypyr, it is characterized in that: active ingredient is made up of emamectin-benzoate and Rynaxypyr, and the ratio of quality and the number of copies of emamectin-benzoate and Rynaxypyr is 10: 1-1: 20.
2, the Pesticidal combination that contains emamectin-benzoate and Rynaxypyr according to claim 1, the mass percentage content that it is characterized in that active ingredient emamectin-benzoate and the two accumulation of Rynaxypyr is between 1%-50%.
3, the Pesticidal combination that contains emamectin-benzoate and Rynaxypyr according to claim 1 is characterized in that making the application forms that comprises missible oil, microemulsion, aqueous emulsion, suspending agent, wetting powder or water dispersible granules when practical application.
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| CN112471163A (en) * | 2020-12-31 | 2021-03-12 | 南京保丰农药有限公司 | Emamectin benzoate/chlorantraniliprole compounded suspending agent as well as preparation method and application thereof |
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Application publication date: 20091007 |