CN101715761B - Cyanogens traniliprole suspending agent and preparation method thereof - Google Patents
Cyanogens traniliprole suspending agent and preparation method thereof Download PDFInfo
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- CN101715761B CN101715761B CN 200910110487 CN200910110487A CN101715761B CN 101715761 B CN101715761 B CN 101715761B CN 200910110487 CN200910110487 CN 200910110487 CN 200910110487 A CN200910110487 A CN 200910110487A CN 101715761 B CN101715761 B CN 101715761B
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- suspending agent
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- 239000000375 suspending agent Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002270 dispersing agent Substances 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 74
- 241000238631 Hexapoda Species 0.000 claims description 39
- 150000001408 amides Chemical class 0.000 claims description 38
- 239000004576 sand Substances 0.000 claims description 28
- 239000002002 slurry Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 238000003801 milling Methods 0.000 claims description 15
- -1 succinic acid Sulfonates Chemical class 0.000 claims description 15
- 150000002170 ethers Chemical class 0.000 claims description 11
- 229920001285 xanthan gum Polymers 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 229920002223 polystyrene Polymers 0.000 claims description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 8
- 239000004299 sodium benzoate Substances 0.000 claims description 8
- 235000010234 sodium benzoate Nutrition 0.000 claims description 8
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical class C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 7
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 230000003750 conditioning effect Effects 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 150000007942 carboxylates Chemical class 0.000 claims description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004334 sorbic acid Substances 0.000 claims description 4
- 235000010199 sorbic acid Nutrition 0.000 claims description 4
- 229940075582 sorbic acid Drugs 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000008107 benzenesulfonic acids Chemical class 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229940043237 diethanolamine Drugs 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 150000003871 sulfonates Chemical class 0.000 claims description 2
- 238000001238 wet grinding Methods 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 claims 1
- 229920013820 alkyl cellulose Polymers 0.000 claims 1
- 125000004181 carboxyalkyl group Chemical group 0.000 claims 1
- 238000009313 farming Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 13
- 238000009826 distribution Methods 0.000 abstract description 12
- 238000003860 storage Methods 0.000 abstract description 11
- 239000000575 pesticide Substances 0.000 abstract description 5
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- 239000007798 antifreeze agent Substances 0.000 abstract 1
- 230000000740 bleeding effect Effects 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 33
- 238000009472 formulation Methods 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 9
- 102220042174 rs141655687 Human genes 0.000 description 9
- 102220076495 rs200649587 Human genes 0.000 description 9
- 102220043159 rs587780996 Human genes 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000011324 bead Substances 0.000 description 7
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- 235000012216 bentonite Nutrition 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 229920001983 poloxamer Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000005660 Abamectin Substances 0.000 description 3
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000005889 Cyantraniliprole Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- DVBUIBGJRQBEDP-UHFFFAOYSA-N cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- KDGQGEKLPWYCGO-UHFFFAOYSA-N 1-butoxybutane;urea Chemical compound NC(N)=O.CCCCOCCCC KDGQGEKLPWYCGO-UHFFFAOYSA-N 0.000 description 1
- 241000934067 Acarus Species 0.000 description 1
- 241001600407 Aphis <genus> Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 241000209763 Avena sativa Species 0.000 description 1
- 235000007558 Avena sp Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- AHRPPZAIMASBIR-UHFFFAOYSA-N C=O.C(CCC)OS(=O)(=O)C1=CC=CC2=CC=CC=C12.[Na] Chemical compound C=O.C(CCC)OS(=O)(=O)C1=CC=CC2=CC=CC=C12.[Na] AHRPPZAIMASBIR-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 239000005903 Gamma-cyhalothrin Substances 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000005663 Pyridaben Substances 0.000 description 1
- 241001253920 Ryania Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 108010053950 Teicoplanin Proteins 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- 108091006084 receptor activators Proteins 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
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- 239000002689 soil Substances 0.000 description 1
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- 238000001228 spectrum Methods 0.000 description 1
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- BJNLLBUOHPVGFT-QRZIFLFXSA-N teichomycin Chemical compound CCCCCCCCCC(=O)N[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)OC=2C(=CC(=CC=2)[C@@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@H]2C(N[C@H](C3=CC(O)=CC(O[C@@H]4[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O4)O)=C3C=3C(O)=CC=C(C=3)[C@@H](NC3=O)C(=O)N2)C(O)=O)=O)Cl)=C(OC=2C(=CC(C[C@H](C(N4)=O)NC(=O)[C@H](N)C=5C=C(O6)C(O)=CC=5)=CC=2)Cl)C=C1[C@H]3NC(=O)[C@@H]4C1=CC6=CC(O)=C1 BJNLLBUOHPVGFT-QRZIFLFXSA-N 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention provides a cyanogens traniliprole suspending agent and a preparation method thereof, belonging to the technical field of pesticide preparations. The cyanogens traniliprole suspending agent contains the following components in percentage by weight: 1-50 percent of cyanogens traniliprole, 2-15 percent of dispersant, 1-5 percent of wetting agent, 0-6 percent of functional auxiliary agent, 0.2-1 percent of defoaming agent, 0-10 percent of antifreeze agent, 0.1-5 percent of thickening agent, 0.05-0.8 percent of mildewproof agent, 0-2 percent of pH regulating agent and the balance of water. The cyanogens traniliprole suspending agent has the characteristics of small preparation grain size, narrow grain size distribution, stability of long-term storage at normal temperature, no bottom knots, extremely small bleeding quantity, and the like, can improve the utilization rate of active constituents, and avoid pollutions to environment and damages to the health of people and animalsof conventional preparations such as missible oil, and the like. The preparation method has the characteristics of simple preparation process, environmental protection, and the like.
Description
Technical field
The invention belongs to technical field of pesticide preparations, relate in particular to suspending agent of cyanogen insect amide and preparation method thereof.
Background technology
Cyanogen insect amide (English common name cyantraniliprole) is the second generation ryania receptor activators of the up-to-date exploitation of E.I.Du Pont Company, than chlorine insect amide the more insecticidal activity of wide spectrum is arranged.
CA registration number: 219714-96-2
Molecular formula: C
19H
14BrClN
6O
2
The structure of cyanogen insect amide (cyantraniliprole) is as follows:
The cyanogen insect amide high-efficiency broad spectrum can very effective control be chewed class and suck class pest, and usage amount is 10-100 gram (a.i)/hectare, can prevent smelting diptera leaf mining insects, food leaf class coleoptera class, Lepidoptera class, fruit bat class, aleyrodid etc.Preliminary on probation confirm to prevent eliminating aphis, thrips, weevil, wood louse, aleyrodid, little cycle of sixty years, leaf roller, cotton leaf flea beetle etc.Cyanogen insect amide has stronger permeability, and medicament can pass stem's cuticular cellulose and enter xylem, thereby conducts to other position along xylem.The optional face spraying that gets rid of leaves of using method, drip irrigation, soil light irrigation method, seed treatment etc.Cyanogen insect amide can be used for the pest control of crops such as leguminous plant, corn, cotton, paddy rice, wheat, oat, beet, tomato, potato, eggplant coffee, citrus, brassicaceous vegetable, grape, muskmelon, improves quality and the harvest of crop.
Pesticide original medicine, except the minority volatility big or in water solvability big can directly use, all must be processed into various formulations.Common formulation has missible oil, pulvis, granule, aqueous emulsion, suspending agent etc.Especially formulation such as aqueous emulsion, suspending agent because use for environmentally friendly water as dispersion medium, greatly reduces the people of favor solvent in the regular dosage form more and more is subjected to to(for) the influence of environment.Suspending agent refers to water to be dispersant, the pesticidal preparations that pesticide original medicine and various auxiliary agent (wetting agent, dispersant, antifreezing agent etc.) are obtained through the wet method ultramicro grinding.Suspending agent can mix with arbitrary proportion with water, and is easy to use, has the advantage of wetting powder and missible oil concurrently, can reach bigger coverage rate after the dilution.Suspending agent once once was called epoch-making novel form by domestic and international pesticide industry.Be that dispersion medium makes it have environmental protection, cheap characteristics with water, do not need a large amount of auxiliary agents, production process safety, pollution-free problem simultaneously again.Suspending agent can be processed to the formulation of high concentration, and this also is one of trend of suspending agent development at present.Aspect drug effect, the suspending agent herbicide effects is better than wetting powder, and the insecticide effect is then close with missible oil.
At present as yet not relevant for the report of cyanogen insect amide related preparations.
Summary of the invention
The objective of the invention is to overcome the defective that prior art does not have the cyanogen insect amide preparation, provide a kind of preparation of novel cyanogen insect amide, i.e. the suspending agent of cyanogen insect amide.Characteristics such as it is little that this suspending agent has a preparation particle diameter, and narrow diameter distribution, and the normal temperature long term storage is stable, do not have the knot end, and condensate rate is minimum.
The suspending agent of cyanogen insect amide of the present invention, contain following component by mass percent: cyanogen insect amide 1%-50%, dispersant 2%-15%, wetting agent 1%-5%, functional aid 0%-6%, defoamer 0.2%-1%, antifreezing agent 0%-10%, thickener 0.1%-5%, mould inhibitor 0.05%-0.8%, pH conditioning agent 0%-2%, surplus is water.
The used dispersant of the present invention comprises: anion surfactants such as phosphoric acid ester, lignin sulfonic acid salt, naphthalenesulfonate, dispersant NNO, dispersant M series, benzene sulfonic acid salt, polystyrene-based phenol polyethenoxy ether sulfate, metal carboxylate, succinic acid Sulfonates, and non-ionic surface active agent such as EO/PO block copolymer, agricultural newborn 1601#, polystyrene-based phenol polyethenoxy ethers, available one of them or its combination; Usage amount is the 1%-15% of total formulation weight amount, is preferably 2%-10%, is preferably 3%-8%.
The used wetting agent of the present invention comprises: polyoxyethylene nonylphenol ether class (NP-10), polystyrene-based polyethenoxy ether class, agricultural newborn 602*, alkyl naphthalene sulfonic acid salt, fatty alcohol polyethenoxy ether class etc., available one of them or its combination; Usage amount is the 1%-5% of total formulation weight amount, is preferably 1%-3%, is preferably 1.5%-3%.
The used defoamer of the present invention comprises: silicone based defoamer, mineral oils, alcohols etc., available one of them or its combination; Usage amount is the 0.2%-1% of total formulation weight amount, is preferably 0.3%-0.8%, is preferably 0.4%-0.6%.
The used antifreezing agent of the present invention comprises ethylene glycol, propane diols, diethylene glycol, urea etc., and usage amount is the 0%-10% of total formulation weight amount, is preferably 3%-10%, is more preferred from 4%-9%, is preferably 5%-7%.
The used thickener of the present invention comprises xanthans, carboxymethyl cellulose, Magnesiumaluminumsilicate, bentonite etc., available one of them or its combination, and usage amount is the 0.1%-5% of total formulation weight amount, is preferably 0.1%-1.5%, is preferably 0.1%-1%.
The used mould inhibitor of the present invention comprises benzisothiazole ketone, Sodium Benzoate, formaldehyde, sorbic acid, polyhydroxy benzenes propyl formate etc., and usage amount is the 0.05%-0.8% of total formulation weight amount.
The used pH conditioning agent of the present invention comprises sodium hydroxide, potassium hydroxide, diethanol amine, triethanolamine etc., and usage amount is preferably the 0%-2% of total formulation weight amount.
In order to reduce the surface tension of suspending agent on blade, strengthen and sprawl permeability, thereby increase drug effect, can in suspending agent, add functional aid, the used functional aid of the present invention comprises: the dialkyl succinylsuccinate Sulfonates, the branched fatty alcohol polyethenoxy ether class, penetrant t X, alkylol polyethenoxy ether class (JFC) etc., available one of them or its combination, usage amount is the 0%-6% of total formulation weight amount, is preferably 1%-4.5%, is preferably 2%-4%.
For satisfying the actual needs of agricultural production, as a kind of improvement of the present invention, suspending agent active ingredient of the present invention is except cyanogen insect amide, can also comprise other active component, as multiple killing teichomycin, Avermectin, emamectin-benzoate, thiophene worm piperazine, gamma cyhalothrin, capillary, spiral shell mite ester, Acarus tritici urea, Hostathion, chlopyrifos, Buprofezin, butyl ether urea, pyridaben etc.
Another object of the present invention provides a kind of preparation method of the suspending agent of above-mentioned cyanogen insect amide.The technology that the present invention prepares suspending agent is the method for wet-milling, former medicine, dispersant, wetting agent, functional aid, antifreezing agent, defoamer, thickener (also can add), pH conditioning agent (can add) and water are mixed into the slurry of homogeneous phase according to prescription behind sand milling after sand milling is finished, feed in the horizontal sand mill continuously, make the particle diameter of suspending agent reach required requirement several times through sand milling repeatedly, or in vertical grinding machine, also can reach the qualified suspending agent of particle diameter requirement in sand milling 1-2 hour.
Technology of the present invention makes the liquid that the suspending agent outward appearance is the thickness homogeneous phase, and the particle diameter of the suspending agent that technology of the present invention makes is measured through the laser particle size distribution instrument, and its average grain diameter is at the 2-4 micron, and D90 is less than 10 microns.The suspensibility of measured preparation＞95% can guarantee the shelf life in 2 years.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explaining the present invention, and be not used in restriction the present invention.
Embodiment 1:5% cyanogen insect amide SC
In the beaker of 150mL, add 3 gram dispersant M-9 (lignosulfonates), 1.5 gram polyoxyethylene nonylphenol ether (NP-10), 2 gram JFC, 5 gram propane diols, 0.3 gram silicone defoaming agent, 0.01 gram Sodium Benzoate, 5 gram bentonites, 0.4 gram xanthans, 77.49 gram water.Stirring makes that surfactant is dissolved in the water fully in the beaker, add 5.3 gram cyanogen insect amides, 95% industrial goods then, stir the final form slurry thing of material that makes in the cup again, the laboratory vertical little sand mill of 0.1L that bead is arranged in this slurry thing is poured into, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.795 μ m, D50=3.008 μ m, D90=4.368 μ m.Sample normal temperature suspensibility is 96.3%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, and the bleed rate is 0.5%.
Embodiment 2:10% cyanogen insect amide SC
In the beaker of 150mL, add 3 gram EO/PO block copolymer phosphates, the agricultural newborn 602* of 1.5 grams, 3 gram penetrant t X, 5 gram ethylene glycol, 0.3 gram isooctanol, 0.01 gram formaldehyde, 5 gram bentonites, 0.4 gram xanthans, 1 gram triethanolamine, 70.19 gram water.Stirring makes that surfactant is dissolved in the water fully in the beaker, adds 10.6 grams, 95% cyanogen insect amide industrial goods then.Stir the final form slurry thing of material that makes in the cup again, the laboratory vertical little sand mill of 0.1L of bead is arranged in this slurry thing is poured into, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.9864 μ m, D50=3.101 μ m, D90=4.892 μ m.Sample normal temperature suspensibility is 96%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, and the bleed rate is 0.3%.
Embodiment 3:20% cyanogen insect amide SC
In the beaker of 2000mL, add the two sodium butylnaphthalenesulfonate formaldehyde condensation products of 40 gram dispersants, 15 gram polyoxyethylene nonylphenol ether (NP-15), 30 gram JFC, 50 gram ethylene glycol, 3 gram silicone defoaming agents, 0.1 gram sorbic acid, 20 gram bentonites, 25 gram xanthans, 198.1 gram water.Stirring makes that surfactant is dissolved in the water fully in the beaker, add 606.3 grams, 95% cyanogen insect amide industrial goods then, stir the final form slurry thing of material that makes in the cup again, this slurry thing feeds in the horizontal sand mill (DYNO-mill laboratory sand mill) continuously, and the circulation sand milling gets the suspending agent sample 3 times
Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.864 μ m, D50=3.015 μ m, D90=4.892 μ m.Sample normal temperature suspensibility is 97.1%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, bleed.
Embodiment 4:30% cyanogen insect amide SC
In the beaker of 150mL, add 4 gram Pluronic PE, 10500 (EO/PO block copolymer, BASF products), the agricultural newborn 602* of 2 grams, 3 gram penetrant t X, 5 gram glycerine, 0..3 restrains silicone defoaming agent, 0.01 gram sorbic acid, 1.5 the gram bentonite, 0.2 gram xanthans, 57.89 gram water.Stirring makes that surfactant is dissolved in the water fully in the beaker, add 6.3 grams, 80% pleocidin industrial goods then, 31.6 restrain 95% industrial goods, stir the final form slurry thing of material that makes in the cup again, the laboratory vertical little sand mill of 0.1L that bead is arranged in the slurry thing is poured into, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.896 μ m, D50=3.065 μ m, D90=5.102 μ m.Sample normal temperature suspensibility is 95.8%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, and the bleed rate is 0.3%.
Embodiment 5:40% cyanogen insect amide SC
In the beaker of 150ml, add 4 gram dispersant M-17 (desugar decolouring wooden sodium sulfonate), the agricultural newborn 1601* of 2 gram Pluronic PE 10500,2 grams, 2 gram NP-10,3 gram JFC, 5 gram propane diols, 0.4 gram isooctanol, 0.01 the gram Sodium Benzoate, 0.2 gram xanthans, 39.19 gram water.Stirring makes that surfactant is dissolved in the water fully in the beaker, add 42.2 grams, 95% cyanogen insect amide industrial goods then, stir the final form slurry thing of material that makes in the cup again, this slurry thing feeds in the horizontal sand mill (DYNO-mill laboratory sand mill) continuously, and the circulation sand milling gets the suspending agent sample 3 times.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.996 μ m, D50=3.209 μ m, D90=4.962 μ m.Sample normal temperature suspensibility is 96.1%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, bleed rate 0.3%.
Embodiment 6:50% cyanogen insect amide SC
In the beaker of 2000mL, add 40 gram polystyrene-based phenol polyethenoxy ethers, 15 gram Pluronic PE10500 (EO/PO block copolymers, the BASF product), the agricultural newborn 602* of 15 grams, 30 gram penetrant t X, 50 gram ethylene glycol, 0.3 the gram silicone defoaming agent, 0.1 gram Sodium Benzoate, 5 gram sodium hydroxide, 2 gram xanthans, 316.2 gram water.Stirring makes that surfactant is dissolved in water fully in the beaker, add 526.4 grams, 95% cyanogen insect amide industrial goods then, stir the final form slurry thing of material make in the cup again, the laboratory that bead arranged in this slurry thing is poured into is with horizontal little sand mill, circulation sand milling 3 times obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.990 μ m, D50=3.295 μ m, D90=5.082 μ m.Sample normal temperature suspensibility is 95.9%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, bleed.
Embodiment 730% cyanogen insect amide * Avermectin SC
In the beaker of 150ml, add 3 gram polystyrene-based phenol polyethenoxy ether phosphates, 2 gram NP-10,3 gram JFC, 5 gram glycerine, 0..3 restrains silicone defoaming agent, 0.01 gram Sodium Benzoate, 0.2 the gram xanthans, 1 gram butylhydroxy anisole (antioxidant), 53.59 gram water.Stirring makes that surfactant is dissolved in water fully in the beaker, add 26.4 grams, 95% cyanogen insect amide industrial goods then, 5.5 restrain 92% Avermectin industrial goods, stir the final form slurry thing of material that makes in the cup again, the bead laboratory vertical little sand mill of 0.1L in pouring into, this slurry thing is arranged, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.796 μ m, D50=3.005 μ m, D90=5.002 μ m.Sample normal temperature suspensibility is 96.3%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, and the bleed rate is 0.1%.
Embodiment 822% cyanogen insect amide * Affirm (Merck Co.) first dimension salt SC
In the beaker of 150ml, add 3 gram Pluronic PE, 10500 (EO/PO block copolymers, the BASF product), 1 gram carboxylate, 1 gram NP-10,3 gram JFC, 5 gram glycerine, 0..3 the gram silicone defoaming agent, 0.01 gram Sodium Benzoate, 0.2 gram xanthans, 1 gram butylhydroxy anisole (antioxidant), 61.49 gram water.Stirring makes that surfactant is dissolved in water fully in the beaker, add 21.1 grams, 95% cyanogen insect amide industrial goods then, 2.9 restrain 70% emamectin-benzoate industrial goods, stir the final form slurry thing of material that makes in the cup again, the bead laboratory vertical little sand mill of 0.1L in pouring into, this slurry thing is arranged, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.846 μ m, D50=3.105 μ m, D90=5.112 μ m.Sample normal temperature suspensibility is 96.5%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, no bleed.
Embodiment 945% cyanogen insect amide * thiophene worm piperazine SC
In the beaker of 150ml, add 3 gram Pluronic PE, 10500 (EO/PO block copolymer, BASF products), 2 gram carboxylates, 1 gram NP-10,3 gram JFC, 5 gram glycerine, 0..3 restrains silicone defoaming agent, 0.01 the gram Sodium Benzoate, 0.12 gram xanthans, 38.17 gram water.Stirring makes that surfactant is dissolved in water fully in the beaker, add 31.6 grams, 95% cyanogen insect amide industrial goods then, 15.8 restrain 95% thiophene worm piperazine industrial goods, stir the final form slurry thing of material that makes in the cup again, the bead laboratory vertical little sand mill of 0.1L in pouring into, this slurry thing is arranged, sand milling is 1.5 hours continuously, obtains the suspending agent sample.Sample detects particle diameter with Ma Erwen laser particle size distribution instrument at normal temperatures, records particle diameter D10=1.956 μ m, D50=3.210 μ m, D90=5.312 μ m.Sample normal temperature suspensibility is 96.7%, and sample was through 0 ℃ of cold storage 7 days, and 54 ℃ of heat were store 14 days, and sample does not have the oil of analysing, the knot end, and the bleed rate is 0.3%.
Because the present invention selects high performance dispersant when preparing suspending agent for use, in prescription, add functional aid simultaneously, the little and narrowly distributing of the particle diameter of preparation, the prepared suspending agent suspensibility of such technology height, properties of product are stable, and to deposit condensate rate minimum for normal temperature in 2 years.
The above only is preferred embodiment of the present invention, not in order to limiting the present invention, all any modifications of doing within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. the suspending agent of a cyanogen insect amide, it is characterized in that, contain following component by mass percent: cyanogen insect amide 1%-50%, dispersant 2%-10%, wetting agent 1%-3%, functional aid 1%-4.5%, defoamer 0.3%-0.8%, antifreezing agent 4%-9%, thickener 0.1%-1.5%, mould inhibitor 0.05%-0.8%, pH conditioning agent 0%-2%, surplus is water, and described dispersant is the phosphoric acid ester dispersant, the naphthalenesulfonate dispersant, dispersant NNO, dispersant M series, benzene sulfonic acid salt dispersant, polystyrene-based phenol polyethenoxy ether sulfate, the metal carboxylate dispersant, succinic acid Sulfonates dispersant, the EO/PO block copolymer, the newborn 1601# of farming, the combination of one or more in the polystyrene-based phenol polyethenoxy ethers dispersant; Described functional aid is one or more the combination in dialkyl succinylsuccinate Sulfonates, branched fatty alcohol polyethenoxy ether class, penetrant t X, the alkylol polyethenoxy ether class functional aid; Described wetting agent is one or more the combination in polyoxyethylene nonylphenol ether class, polystyrene-based polyethenoxy ether class, agricultural newborn 602#, alkyl naphthalene sulfonic acid salt, the fatty alcohol polyethenoxy ether class wetting agent.
2. the suspending agent of cyanogen insect amide according to claim 1 is characterized in that, described defoamer is one or more the combination in silicone based, mineral oils, the alcohol defoaming agent;
Described thickener is one or more the combination in xanthans, carboxyl alkyl cellulose class, Magnesiumaluminumsilicate, the bentonite thickener;
Described mould inhibitor is one or more the combination in benzisothiazole ketone, Sodium Benzoate, formaldehyde, sorbic acid, the polyhydroxy benzenes propyl formate;
Described pH conditioning agent is one or more the combination in sodium hydroxide, potassium hydroxide, diethanol amine, the triethanolamine;
Described antifreezing agent is one or more the combination in ethylene glycol, propane diols, diethylene glycol, the urea.
3. the suspending agent of cyanogen insect amide according to claim 1 and 2 is characterized in that, the quality percentage composition of described dispersant is 3%-8%; The quality percentage composition of described wetting system is 1.5%-3%; The quality percentage composition of described defoamer is 0.4%-0.6%; The quality percentage composition of described antifreezing agent is 5%-7%; The quality percentage composition of described thickener is 0.1%-1%; The quality percentage composition of institute's functional aid is 2%-4%.
4. the preparation method of the suspending agent of claim 1 or 2 described cyanogen insect amides, it is characterized in that, adopt wet grinding, according to prescription former medicine, dispersant, wetting agent, functional aid, antifreezing agent, defoamer, thickener, mould inhibitor or pH conditioning agent and water are mixed into uniform slurry under the stirring fast in a container, feed slurry in the horizontal sand mill continuously, sand milling circulate repeatedly several times, and product cut size reaches requirement and can pack; Or above-mentioned slurry all added in the vertical grinding machine continuously sand milling several hours, product cut size reaches requirement and can pack.
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| TWI547238B (en) | 2009-09-04 | 2016-09-01 | 杜邦股份有限公司 | Anthranilic diamide compositions for propagule coating |
| CN102308805A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Compound pesticide |
| CN102308815A (en) * | 2011-10-19 | 2012-01-11 | 北京燕化永乐农药有限公司 | Pesticide composition |
| CN102405929A (en) * | 2011-11-20 | 2012-04-11 | 广东中迅农科股份有限公司 | Pesticidal composition containing cyantraniliprole and cyfluthrin |
| CN102428932B (en) * | 2011-11-28 | 2013-07-24 | 北京燕化永乐农药有限公司 | Insecticidal composition |
| EP2793581B1 (en) | 2011-12-19 | 2016-03-02 | E. I. du Pont de Nemours and Company | Nanoparticles compositions containing polymers and anthranilic acid diamide insecticides for propagule coating |
| CN102696656A (en) * | 2012-06-11 | 2012-10-03 | 联保作物科技有限公司 | Insecticidal composition and preparation thereof |
| CN104585240A (en) * | 2014-12-15 | 2015-05-06 | 江西省新龙生物科技有限公司 | Viral insecticidal suspending agent containing cyantraniliprole |
| CN106417304A (en) * | 2015-08-11 | 2017-02-22 | 上海中冠生物科技有限公司 | Oil suspension agent of bisamide pesticide and preparation method thereof |
| CN105941460A (en) * | 2016-06-21 | 2016-09-21 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing cyantraniliprole and thiamethoxam and application thereof |
| CN106359375B (en) * | 2016-08-26 | 2020-04-14 | 广州方中化工有限公司 | Phosphate wetting dispersant, preparation method and application thereof |
| CN116634869A (en) * | 2020-11-27 | 2023-08-22 | Upl有限公司 | Quick release insecticidal compositions |
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Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China |