CN105454274A - Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields - Google Patents
Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields Download PDFInfo
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- CN105454274A CN105454274A CN201510996142.2A CN201510996142A CN105454274A CN 105454274 A CN105454274 A CN 105454274A CN 201510996142 A CN201510996142 A CN 201510996142A CN 105454274 A CN105454274 A CN 105454274A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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Abstract
The invention relates to a herbicide composition containing flucarbazone and pinoxaden and an application thereof. The mass ratio of flucarbazone to pinoxaden, the active ingredients of the pesticide composition, is (0.5-5) to (1-40). The pesticide composition has the advantages that the pesticide composition shows obvious synergistic effects in the ratio range, thus reducing the dosage of pesticides, the number of pesticide use, the pesticide use cost and the adverse impacts of the pesticides on the ecological environment; as the weed control spectrum is expanded, the problems of grassy weeds and part of broadleaf weeds in wheat fields are solved by using the pesticides once, thus making up for the defects and limitation during single agent use; the service life of the agent is prolonged, which is of important significance to comprehensive treatment of the resistance of the weeds; the pesticide composition takes effect quickly, has long duration, is low in use cost and can be used for controlling the grassy weeds and part of broadleaf weeds in the wheat fields.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of composition pesticide containing flucarbazone and azoles quinoline grass ester preventing and kill off grass family and part broad leaved weed for wheat paddock.
Background technology
According to statistics world's cereal produce annual due to illness, worm, crop smothering loss 14%, the loss that wherein crop smothering causes is about 11%, and Weed infestation is the key factor of restriction crop yield.The use of chemical herbicide is one of important symbol of agricultural modernization.In recent years, the sales volume of weed killer herbicide increases year by year, and the proportion accounting for agricultural chemicals sales volume increases year by year, uses area and expands year by year.Wheat is the crops that Consumption of China amount is maximum, cultivated area is maximum, gross yield is maximum, per unit area yield is the highest, has consequence in the world.But the serious of wheat crop smothering is the major obstacle restricting its high yield, stable yields.Current wheat weeds is prevented and kill off mainly based on cauline leaf spraying after weeds seedling, and weed killer herbicide kind is based on acetyl-CoA carboxylase inhibitor class.The continuous Long-Time Service of single herbicide causes herbicide resistance obvious, and the weeds such as wheatland Alopecurus, amur foxtail, Wang grass, ox chickweed, shepherd's purse all create obvious resistance to multiple weed killer herbicide.In addition, cornfield haulm process weed killer herbicide is slightly poor to Safe to wheat, and medicine processus aboralis is met low temperature and is easy to produce poisoning, threatens Wheat Production.Use after exploring wheat weeds seedling, effectively prevent and kill off resistance, efficient, the safety herbicide of malignant weed seem particularly important.
Flucarbazone, chemical name: N-(2-Trifluoromethoxyphen-l sulfonyl)-4,5-bis-chloro-3-methoxyl group-4-methyl-5-oxygen-1H-1,2,4-formamidetriazole sodium salt.Belong to sulfonylurea herbicide, absorbing mainly through root and cauline leaf the reaction suppressing the predecessor acetolactate synthestase producing side chain amino acid, leucine, isoleucine and knot propylhomoserin, is cauline leaf process weed killer herbicide after selectivity seedling.Flucarbazone is efficient, broad-spectrum herbicide, can be applicable to prevent and kill off grass family and some important broad leaved weedses in wheat paddock, to second stubble crop safety.
Azoles quinoline grass ester, chemical name: 2-chloro-2 ', 6 '-diethyl-N-(2-Among) antifebrin.Belong to neophyl pyrazolines weed killer herbicide, the mechanism of action is acetyl-CoA carboxylase inhibitor.Cause fatty acid biosynthesis block, cell division is stopped, cell membrane is destructurized containing fat, causes weeds dead, has Uptake and translocation, can be applicable to wheat paddock and prevent and kill off annual gramineous weed.
Patent azoles quinoline grass ester florasulam (application number: 201110175578.7) be background information is had according to azoles quinoline grass ester, azoles quinoline grass ester florasulam to wheatland part grass family and part broad leaved weed cauline leaf treatment effect outstanding, a drug is difficult to solve wheat weeds harm, flucarbazone azoles quinoline grass ester to wheatland grass family and part broad leaved weed cauline leaf treatment effect outstanding, expand herbicide spectrum, a drug can solve wheat Weed infestation, has saving of labor, labour-saving advantage.
Summary of the invention
Goal of the invention: in prior art to farmland weed develop immunity to drugs problem, single use control efficiency poor, once use the problem being difficult to effectively to control Weed infestation in wheat whole breeding time, the object of this invention is to provide a kind of composition pesticide containing flucarbazone and azoles quinoline grass ester, make it have efficient, wide spectrum, environmentally friendly, be beneficial to the features such as the wheat weeds comprehensive regulation.Another object of the present invention is to provide a kind of above-mentioned application containing the composition pesticide of flucarbazone and azoles quinoline grass ester.
Technical scheme: in order to realize foregoing invention object, the technical solution used in the present invention is:
Contain a composition pesticide for flucarbazone and azoles quinoline grass ester, it is characterized in that: active component is flucarbazone and azoles quinoline grass ester, and the mass ratio of flucarbazone and azoles quinoline grass ester is 0.5-5: 1-40.
The preferred mass ratio of flucarbazone and azoles quinoline grass ester is 1: 10,1: 9,1: 15,2: 15 or 2: 7.
Contain a pesticidal preparations for flucarbazone and azoles quinoline grass ester, described preparation becomes any one formulation acceptable on agricultural chemicals by the composition pesticide containing flucarbazone and azoles quinoline grass ester with the acceptable auxiliaries of field of pesticide preparation.
The formulation of described pesticidal preparations is wetting powder, water dispersible granules, suspending agent, suspension emulsion or oil-suspending agent.
In described pesticidal preparations, two kinds of herbicidal active components account for the 1-90% of pesticidal preparations gross weight.
Described auxiliary material is selected from wetting agent, dispersant, spreader-sticker, stabilizing agent, bleeding agent, thickener, antifreezing agent, defoamer, filler, solvent; Wherein, described wetting agent is one or more among neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether; Described dispersant be lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and polycarboxylic acid salt one or more; Described stabilizing agent is that epoxidized vegetable oil is as one or more in epoxidised soybean oil, epoxidized linseed; Described spreader-sticker is one or more in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly-trisiloxanes, triethanolamine oleate; Described solvent is one or more in soybean oil, methyl oleate, white oil, turpentine oil methyl naphthalene higher aliphatic hydrocarbon ils; Described filler is one or more in white carbon, corn starch, kaolin, diatomite, sodium sulphate, ammonium sulfate.
The described composition pesticide containing flucarbazone and azoles quinoline grass ester prevents and kill off the application in grass family and part broad leaved weed at wheat paddock.When preventing and treating weeds of wheat, use to wheat 6 ~ 7 leaf phase before seedling after Wheat Sowing.
The described pesticidal preparations containing flucarbazone and azoles quinoline grass ester prevents and kill off the application in grass family and part broad leaved weed at wheat paddock.When preventing and treating weeds of wheat, use to wheat 6 ~ 7 leaf phase before seedling after Wheat Sowing.
The described production technology containing the various application forms of the composition pesticide of flucarbazone and azoles quinoline grass ester all belongs to existing known technology.
Composition pesticide and the pesticidal preparations thereof containing flucarbazone and azoles quinoline grass ester provided by the invention, usually adopts the method use of spraying, also can adopt other operation techniques agriculturally applied as required.
Beneficial effect: compared with prior art, the composition pesticide containing flucarbazone and azoles quinoline grass ester of the present invention, tool has the following advantages:
1) composition pesticide containing flucarbazone and azoles quinoline grass ester of the present invention, obvious synergistic effect is shown in certain ratio range, the control efficiency of composition is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2) composition pesticide containing flucarbazone and azoles quinoline grass ester of the present invention, the combination of two kinds of active ingredients, expands herbicidal spectrum, and a drug had both solved various weed problem, compensate for defect when single dose uses and limitation.
3) composition pesticide containing flucarbazone and azoles quinoline grass ester of the present invention, active ingredient mechanism of action is different, the shortcoming that long-term single use easily produces resistance can be overcome, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4) composition pesticide containing flucarbazone and azoles quinoline grass ester of the present invention, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and to wheat safety, it applies huge economic benefit and social benefit.
Specific embodiments
Below in conjunction with specific embodiment, the present invention is further illustrated.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
In following examples, unless otherwise indicated, all percentage is mass percent.
Embodiment 1:11% flucarbazone azoles quinoline grass ester suspending agent
Each component of composition pesticide containing flucarbazone and azoles quinoline grass ester is: flucarbazone 1%, azoles quinoline grass ester 10%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, ethylene glycol 5%, aluminium-magnesium silicate 2%, defoamer 0.5%, preservative 0.1%, xanthans 0.1%, water to 100%.
After azoles quinoline grass ester is mixed with filling adsorption, again other above-mentioned materials (except xanthans) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material is putting into high-shear emulsifying still together with the xanthans dissolved in advance, namely can be made into 11% flucarbazone azoles quinoline grass ester suspending agent after emulsification.
Embodiment 2:10% flucarbazone azoles quinoline grass ester oil suspending agent
Each component of composition pesticide containing flucarbazone and azoles quinoline grass ester is: flucarbazone 1%, azoles quinoline grass ester 9%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, epoxidized soybean oil 5%, organobentonite 5%, methyl oleate to 100%.
After azoles quinoline grass ester is mixed with filling adsorption, again other above-mentioned materials (except organobentonite) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material is putting into high-shear emulsifying still together with the organobentonite dissolved in advance, namely can be made into 10% flucarbazone azoles quinoline grass ester oil suspending agent after emulsification.
Embodiment 3:16% flucarbazone azoles quinoline grass ester suspending agent
Each component of composition pesticide containing flucarbazone and azoles quinoline grass ester is: flucarbazone 1%, azoles quinoline grass ester 15%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, ethylene glycol 5%, aluminium-magnesium silicate 2%, defoamer 0.5%, preservative 0.1%, xanthans 0.1%, water to 100%.
After azoles quinoline grass ester is mixed with filling adsorption, again other above-mentioned materials (except xanthans) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material is putting into high-shear emulsifying still together with the xanthans dissolved in advance, namely can be made into 16% flucarbazone azoles quinoline grass ester suspending agent after emulsification.
Embodiment 4:17% flucarbazone azoles quinoline grass ester wetting powder
Each component of composition pesticide containing flucarbazone and azoles quinoline grass ester is: flucarbazone 2%, azoles quinoline grass ester 15%, sodium butylnaphthalenesulfonate 3%, calcium lignosulfonate 5%, white carbon 5%, kaolin to 100%.
After azoles quinoline grass ester is mixed with filling adsorption, add in cone-type mixer together with other above-mentioned material and mix, pulverize by airslide disintegrating mill, material after pulverizing is again through cone-type mixer mixing, and mixed fineness of materials 98% is by 325 mesh standard sieves i.e. obtained 17% flucarbazone azoles quinoline grass ester wetting powder.
Embodiment 5:9% flucarbazone azoles quinoline grass ester water dispersible granules
Each component of composition pesticide containing flucarbazone and azoles quinoline grass ester is: flucarbazone 2%, and azoles quinoline grass ester 7%, metal carboxylate 5%, urea 10%, adds kaolin to 100%.
After azoles quinoline grass ester is mixed with filling adsorption; add in cone-type mixer together with other above-mentioned material and mix; pulverize by airslide disintegrating mill; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 325 mesh standard sieves; add in kneader and be kneaded into plasticity material, finally this material is put into Squeezinggranulator extruder grain, through dry, screening i.e. obtained 9% flucarbazone azoles quinoline grass ester water dispersible granules after granulation.
The optimum proportioning screening of embodiment 6 flucarbazone and azoles quinoline grass ester
1) flucarbazone and the screening of azoles quinoline grass ester optimum proportioning
In order to understand flucarbazone and azoles quinoline grass ester mixture further to the synergy of weeds, the present inventor has carried out formulation screening test to flucarbazone and azoles quinoline grass ester mixture.
Gong Shi Wang grass (Beckmanniasyzigachne (Steud.) Fern.), ox chickweed (Malachiumaquaticum (L.) Fries), in October, 2013 picks up from experimental field, Jiangsu Province Agriculture Science Institute, adopt natural air drying under rear room temperature condition, load paper bag, be placed in 4 DEG C ± 0.5 Refrigerator store.
Test apparatus: PWT-510 type spray tower, plum Teller AB135-S electronic balance, volumetric flask, triangular flask, beaker, graduated cylinder, polypots, pipette, chi, scissors etc.
Test method: the flucarbazone and the former medicine of azoles quinoline grass ester that first take certain mass, add the Tween 80 aqueous solution dilution that methyl alcohol fully dissolves rear use 0.1%, be mixed with single dose mother liquor, arrange serial proportioning according to mixture object, it is stand-by that each proportioning arranges 5-7 concentration gradient.Polypots (15cm × 11cm × 7cm) is filled air-dry fine earth, in infiltrating irrigation mode bottom polypots, makes soil completely moistening.Soil be horse liver soil, pH6.7, the content of organic matter 1.6%, air-dry sieve after for subsequent use.Each polypots Bo Wang grass, ox chickweed, broadcast rear fine earth and cover, thickness is about 0.2cm.When weeds 2 ~ 3 leaf phase, weeds are fixed to 15 strains/alms bowl, put into Jiangsu Province Agriculture Science Institute 300m after spraying process
2greenhouse by solar heat is cultivated.
Ding after medicine phase Guan Cha Wang grass, ox chickweed growing state.After medicine, 30 days investigation weeds overground part fresh weights, calculate fresh weight inhibition namely to the preventive effect of target weeds.Adopt DPS data handling system to obtain the virulence regression equation of each process, calculate ED
50value and 95% confidence limit.Co-toxicity coefficient is calculated by the abundant method of Sun Yun.Co-toxicity coefficient is greater than 120 and is expressed as synergistic effect, is less than 80 and is expressed as antagonism, be expressed as summation action between 80 ~ 120.
Result of the test: medicine post processing is observed for 20 days, flucarbazone azoles quinoline grass ester mixture uses Hou Wang grass, ox chickweed partial blade jaundice inhibitory action that is careless to withered Dui Wang, ox chickweed rises ， Dui Wang grass with the increase of drug concentration, ox chickweed has very high biologically active.
1) flucarbazone and azoles quinoline grass ester mixture preventive effect
After medicine 30 days, the fresh weight of flucarbazone and azoles quinoline grass ester 9 binary mixture Zu He Dui Wang grass had obvious inhibitory action (table 1).In 9 proportionings, the co-toxicity coefficient of 0.5: 40,0.5: 1,5: 40,5: 1,1: 10,1: 9,1: 15,2: 15 and 2: 7 proportionings is respectively 238.5430,141.1589,222.8225,372.0429,204.9699,205.4755,215.3856,157.7073 and 216.6776, co-toxicity coefficient is greater than 120, shows as synergistic effect.
The synergy of table 1 flucarbazone-azoles quinoline grass ester Hun Pei Wang grass fresh weight
After medicine 30 days, flucarbazone and 9 the binary mixtures combinations of azoles quinoline grass ester had obvious inhibitory action (table 2) to the fresh weight of ox chickweed.In 9 proportionings, the co-toxicity coefficient of 0.5: 40,0.5: 1,5: 40,5: 1,1: 10,1: 9,1: 15,2: 15 and 2: 7 proportionings is respectively 212.6867,136.8003,186.6355,174.5197,221.5946,246.0692,279.4804,267.0443 and 186.8706, co-toxicity coefficient is greater than 120, shows as synergistic effect.
The synergy of table 2 flucarbazone-azoles quinoline grass ester mixture ox chickweed fresh weight
Flucarbazone broad weed-killing spectrum, lasting period are long, and cauline leaf process effectively can prevent and kill off the multiple grass family of wheat paddock and part broad leaved weed, and azoles quinoline grass ester has good inhibitory action to annual dogstail, and the two mixture can prevent and kill off the multiple weeds of wheat paddock simultaneously.Flucarbazone and azoles quinoline grass ester, in 0.5-5: 1-40 ratio mixture, show as synergistic effect.
Embodiment 7 field control effectiveness test
Reagent agent: select mixed herbicide prepared in embodiment 1 ~ 4.
Contrast medicament: 70% flucarbazone WDG (commercial)
50g/L azoles quinoline grass ester EC (commercial)
If clear water contrasts
Using method: adopt spray-on process.
Spraying time: sowing on October 22nd, 2013 wheat (Huaihe River wheat 18, raise wheat 16, peaceful wheat 13), dispenser on November 24.。
Respondent and method: Wang grass, amur foxtail, ox chickweed, shepherd's purse and wheat, 30 days investigation fresh weights of weeds and the fresh weight of wheat and plant height after medicine.
Test results and analysis are in table 3.
30 days field control effectiveness test results after table 3 medicine
As can be seen from Table 3, the present invention has obvious effect to little Mai field Wang grass, amur foxtail, ox chickweed, shepherd's purse, and preventive effect higher than single dose preventive effect, and has good quick-acting and lasting effect; From table 4 we find out the present invention to Huaihe River wheat 18, raise wheat 16, peaceful wheat 13 safety.
30 days Plant Height in Wheats and fresh weight after table 4 medicine
Embodiment 8
With reference to the method for embodiment 7, the mixed herbicide obtained to embodiment 1,3,5 carries out field control effectiveness test, confirms: each mixed herbicide has obvious synergistic effect, has better preventive effect to wheat paddock grass family and broad leaved weed, Be very effective is better than single dose and uses, and the lasting period is long.
Claims (12)
1. a Herbicidal combinations, is characterized in that: it comprises flucarbazone and azoles quinoline grass ester, and the mass ratio of flucarbazone and azoles quinoline grass ester is 0.5-5: 1-40.
2. a Herbicidal combinations preparation, is characterized in that: described preparation becomes any one formulation acceptable on agricultural chemicals by the acceptable auxiliaries of Herbicidal combinations according to claim 1 and field of pesticide preparation.
3. Herbicidal combinations preparation according to claim 2, is characterized in that: the formulation of described preparation is wetting powder, water dispersible granules, suspending agent, microemulsion, finish, suspension emulsion, missible oil, water dispersible granules, aqueous emulsion or oil-suspending agent.
4. Herbicidal combinations preparation according to claim 2, is characterized in that: in described preparation, active ingredient accounts for the 1-90% of weight of formulation.
5. Herbicidal combinations preparation according to claim 2, is characterized in that: described auxiliary material is selected from wetting agent, dispersant, spreader-sticker, stabilizing agent, bleeding agent, thickener, antifreezing agent, defoamer, filler, solvent.
6. Herbicidal combinations preparation according to claim 5, is characterized in that: described wetting agent is at least one among neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether; Described dispersant is at least one of lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and polycarboxylic acid salt; Described stabilizing agent is that epoxidized vegetable oil is as at least one in epoxidised soybean oil, epoxidized linseed; Described spreader-sticker is at least one in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly-trisiloxanes, triethanolamine oleate; Described solvent is at least one in soybean oil, methyl oleate, white oil, turpentine oil, methyl naphthalene higher aliphatic hydrocarbon ils; Described filler is at least one in white carbon, corn starch, kaolin, diatomite, sodium sulphate, ammonium sulfate.
7. a method for anti-wheat paddock grass family and part broad leaved weed, is characterized in that: Herbicidal combinations formulation application described in Herbicidal combinations described in claim 1 or any one of 2-6 is prevented and kill off grass family and part broad leaved weed in wheat paddock.
8. method according to claim 7, is characterized in that: when preventing and treating weeds of wheat, uses to wheat 6 ~ 7 leaf phase after Wheat Sowing before seedling.
9. described in the Herbicidal combinations described in any one of claim 1 or any one of claim 2-6, the application in grass family and part broad leaved weed prevented and kill off by Herbicidal combinations preparation at wheat paddock.
10. application according to claim 9, is characterized in that: when preventing and treating weeds of wheat, uses to wheat 6 ~ 7 leaf phase after Wheat Sowing before seedling.
11. Herbicidal combinations according to claim 1, is characterized in that: the mass ratio of described flucarbazone and azoles quinoline grass ester is 1: 10,1: 9,1: 15,2: 15 or 2: 7.
12. Herbicidal combinations preparations according to any one of claim 2-6, is characterized in that: the mass ratio of described flucarbazone and azoles quinoline grass ester is 1: 10,1: 9,1: 15,2: 15 or 2: 7.
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| CN106465722A (en) * | 2016-08-29 | 2017-03-01 | 广东中迅农科股份有限公司 | Herbicidal combinations containing clodinafop-propargyl and pinoxaden and flucarbazone |
| CN106719761A (en) * | 2017-02-17 | 2017-05-31 | 江苏莱科化学有限公司 | A kind of Herbicidal combinations containing flucetosulfuron Yu pinoxaden |
| CN108566952A (en) * | 2018-07-26 | 2018-09-25 | 捷利诺华作物保护（安徽）有限公司 | A kind of herbicidal composition containing mesosulfuron, flucarbazone and pinoxaden |
| CN108651485A (en) * | 2018-03-05 | 2018-10-16 | 南京高正农用化工有限公司 | A kind of Herbicidal combinations and application thereof comprising pinoxaden |
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| CN111903695A (en) * | 2020-09-07 | 2020-11-10 | 安徽省四达农药化工有限公司 | Preparation and application of pinoxaden preparation |
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| CN106465722A (en) * | 2016-08-29 | 2017-03-01 | 广东中迅农科股份有限公司 | Herbicidal combinations containing clodinafop-propargyl and pinoxaden and flucarbazone |
| CN106719761A (en) * | 2017-02-17 | 2017-05-31 | 江苏莱科化学有限公司 | A kind of Herbicidal combinations containing flucetosulfuron Yu pinoxaden |
| CN108719314A (en) * | 2017-04-20 | 2018-11-02 | 燕化永乐（乐亭）生物科技有限公司 | A kind of Herbicidal combinations |
| CN108651485A (en) * | 2018-03-05 | 2018-10-16 | 南京高正农用化工有限公司 | A kind of Herbicidal combinations and application thereof comprising pinoxaden |
| CN108566952A (en) * | 2018-07-26 | 2018-09-25 | 捷利诺华作物保护（安徽）有限公司 | A kind of herbicidal composition containing mesosulfuron, flucarbazone and pinoxaden |
| CN111903695A (en) * | 2020-09-07 | 2020-11-10 | 安徽省四达农药化工有限公司 | Preparation and application of pinoxaden preparation |
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