CN102823615A - Weeding composition containing flucarbazone, pinoxaden and florasulam - Google Patents
Weeding composition containing flucarbazone, pinoxaden and florasulam Download PDFInfo
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Abstract
The invention discloses a weeding composition containing flucarbazone, pinoxaden and florasulam. The weeding composition comprises active ingredients, auxiliaries and a carrier, wherein the active ingredients include flucarbazone, pinoxaden and florasulam in a weight ratio of 1:(0.01-100):(0.01-100); the weight of the active ingredients is 1-90% of the total weight of the composition; the auxiliaries include wetting agent, dispersing agent, disintegrating agent, adhesive, emulsifying agent, thickening agent, defoaming agent and the like; the carrier is a solid or liquid carriers; and the form of the composition is wettable powder, water dispersible granules or oil suspending agent. The weeding composition disclosed by the invention has obvious synergy, wide weed-controlling spectrum, high activity, low toxicity and low cost.
Description
Technical field
The present invention relates to a kind of weed killer herbicide, be specifically related to that a kind of fluorine-containing azoles sulphur is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam.
Background technology
The chemical name of fluorine azoles sulphur grand (have another name called flucarbazonesodium, CAS number is 181274-17-9) is: N-(2-Trifluoromethoxyphen-l sulfonyl)-4,5-dihydro-3 methoxyl groups-4-methyl-5-oxygen-1H-1,2,4-triazole formamide sodium salt.Structural formula is following:
Fluorine azoles sulphur is grand to be a kind of sulfonylurea weed killer herbicide, acetolactate synthestase (ALS) inhibitor.To grassy weed and some important broad leaved weeds and to the wild oat of generation resistances such as ACC enzyme inhibitor, carbamates, dinitroaniline and green foxtail etc. good preventive effect is arranged.Its consumption is very low, and is fool proof to crops such as wheats, and the lasting period is long.
The chemical name of azoles quinoline grass ester (CAS number is 243973-20-8) is: 8-(2,6-diethyl-4-aminomethyl phenyl)-1,2,4,5-tetrahydrochysene-7-oxo-7H-pyrazolo [1,2-d] [1,4,5] oxo phenodiazine Zhuo-9-base-2,2-neopentanoic acid.Structural formula is following:
Azoles quinoline grass ester is an acetyl-CoA carboxylase inhibitor class weed killer herbicide, and medicine can be absorbed by grass cutting blade, conducts to meristematic tissue then, and the lipid that suppresses somatoblast is synthetic, causes weeds dead.48 hours susceptible weeds stop growing after the general dispenser, and grass cutting blade begins jaundice in 1～2 week, and weeds are thoroughly dead in 3～4 weeks.The grass spectrum is very wide extremely for medicine, and is fast in degraded in soil, seldom absorbed by root, has only very low soil activation, and succession crop is not had influence.But it is higher that this prescription is solely used cost, and not too be fit to low application.
The chemical name of florasulam (CAS number is 145701-23-1) is: 2', 6'-two fluoro-5-methoxyl group-8-fluorine [1,2,4] triazols [1,5-c] pyrimidine-2-sulfonanilide.Structural formula is following:
Florasulam is a kind of triazolopyrimidine sulfonamides herbicide, and is safe in utilization, and using dosage is extremely low, is about 3～10g active ingredient/hectare, fine to most of broad leaved weed preventive effects.But use behind the general seedling, service time is comparatively limited.
Do not find as yet at present that fluorine azoles sulphur is grand, the relevant report of azoles quinoline grass ester and florasulam ternary built.
Summary of the invention
The objective of the invention is to the deficiency to prior art, provide a kind of synergy obviously, the Herbicidal combinations of grand, the azoles quinoline grass ester of broad weed-killing spectrum, active fluorine-containing azoles sulphur high, that toxicity is low, cost is low and florasulam.
The technical scheme that realizes the object of the invention is: a kind of fluorine-containing azoles sulphur is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, is made up of active component, auxiliary agent and carrier.Said active component is grand by fluorine azoles sulphur, azoles quinoline grass ester and florasulam are formed, and fluorine azoles sulphur is grand, the weight ratio of the careless ester of azoles quinoline and florasulam is 1: (0.01～100): (0.01～100), preferred 1: (0.05～20): (0.05～20).The weight of active component is 1%～90% of composition total weight, preferred 15%～75%.Described auxiliary agent comprises wetting agent, dispersant, disintegrant, adhesive, emulsifier, thickener, antifoaming agent or the like.Described carrier is solid carrier or liquid-carrier.
The formulation of said composition is wetting powder, water dispersible granules, oil-suspending agent, pulvis, granule, suspending agent, dry suspending agent, missible oil, aqueous emulsion, microemulsion or suspended emulsion, preferred wetting powder, water dispersible granules or oil-suspending agent.
When the formulation of said composition was wetting powder, this wetting powder was made up of following components by part by weight: as grand 0.1～80 weight portion of the fluorine azoles sulphur of active component, as careless ester 0.1～60 weight portion of the azoles quinoline of active component, florasulam 0.1～60 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, solid carrier 5～90 weight portions.
When the formulation of said composition was water dispersible granules, this water dispersible granules was made up of following components by part by weight: as grand 0.1～80 weight portion of the fluorine azoles sulphur of active component, as careless ester 0.1～60 weight portion of the azoles quinoline of active component, florasulam 0.1～60 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, disintegrant 0.1～5 weight portion as auxiliary agent, adhesive 0～5 weight portion as auxiliary agent, solid carrier 10～80 weight portions.
The formulation of said composition is an oil-suspending agent; This oil-suspending agent comprises following components by part by weight: as grand 0.1～50 weight portion of the fluorine azoles sulphur of active component; Azoles quinoline grass ester 0.1～50 weight portion as active component; Florasulam 0.1～50 weight portion as active component; Wetting agent 0.1～10 weight portion as auxiliary agent; Dispersant 0.1～10 weight portion as auxiliary agent; Emulsifier 0.1～10 weight portion as auxiliary agent; Thickener 0.1～10 weight portion as auxiliary agent; Antifoaming agent 0～5 weight portion as auxiliary agent; Liquid-carrier 10～90 weight portions.
Described wetting agent is an alkyl sulfate; The benzene sulfonamide acid alkali metal salt; Alkylnaphthalene sulfonate; Dialkyl succinylsuccinate ester sulphonyl sodium salt; The alkyl naphthalene sulfonic acid formaldehyde condensation products; Alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt; The aralkyl naphthalene sulfonic acid-formaldehyde condensation product; Aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Fatty acid amide N methyl taurine sodium salt; Sodium sulfate of polyethenoxy ether of fatty alcohol; APES; APES sulphate; APES succinic acid half ester sulfonate; The APES formaldehyde condensation products; APES formaldehyde condensation products sulphate; APES formaldehyde condensation products succinic acid half ester sulfonate; Lignosulfonates; Polycarboxylate; AEO; Polyox-yethylene-polyoxypropylene block copolymer; Alkyl biphenyl ether sulfonic acid sodium; The dimethyl-octa glycol; Dimethyl-octa glycol ethylene oxide adduct; The tetramethyl decanediol; Tetramethyl decanediol ethylene oxide adduct; A kind of in the organophosphorus ester or two kinds or three kinds; A kind of in preferred alkyl biphenyl ether sulfonic acid sodium, sodium sulfate of polyethenoxy ether of fatty alcohol, alkyl naphthalene sulfonic acid formaldehyde condensation products, alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt, aralkyl naphthalene sulfonic acid-formaldehyde condensation product, the aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt or two kinds.
Described dispersant is the alkyl polyoxyethylene ether formaldehyde condensation products; Alkyl polyoxyethylene ether formaldehyde condensation products sulphate; Aralkyl APEO formaldehyde condensation products; Aralkyl APEO formaldehyde condensation products sulphate; The alkyl naphthalene sulfonic acid formaldehyde condensation products; Alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt; The aralkyl naphthalene sulfonic acid-formaldehyde condensation product; Aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt; APES; APES sulphate; AEO; Fatty alcohol polyoxyethylene ether sulfate; Fatty acid amide N methyl taurine sodium salt; Alkylnaphthalene sulfonate; Lignosulfonates; Polycarboxylate; The fatty acid glyceride APEO; The vegetable oil ethylene oxide adduct; Vegetable oil ethylene oxide adduct derivative; A kind of in the organophosphorus ester or two kinds or three kinds; A kind of in preferred fat alcohol APEO, fatty alcohol polyoxyethylene ether sulfate, alkylnaphthalene sulfonate, lignosulfonates, the fatty acid glyceride APEO or two kinds.
Described disintegrant is a kind of in ammonium sulfate, sodium chloride, urea, starch, the starch derivatives or two kinds or three kinds.
Described adhesive is a kind of in polyethylene glycol, Sodium Polyacrylate, polyox-yethylene-polyoxypropylene block copolymer, xanthans, the dextrin or two kinds or three kinds.
Described emulsifier is a kind of in polyox-yethylene-polyoxypropylene block copolymer, APES, aralkyl phenol polyethenoxy ether, styryl phenol polyethenoxy ether, alkyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, castor oil polyoxyethylene ether derivative, AEO, cithrol, polyol fatty acid ester, polyol fatty acid ester ethylene oxide adduct, the alkylbenzenesulfonate or two kinds or three kinds.
Described thickener is a kind of in xanthans, gelatin, gum Arabic, melon glue, sodium alginate, sodium carboxymethylcellulose, polyvinyl alcohol, polyacrylamide, gas-phase silica, aluminium-magnesium silicate, sepiolite, diatomite, organobentonite, the attapulgite or two kinds or three kinds.
Described antifoaming agent is a kind of in polyglycereol antifoaming agent, fatty acid defoamer, the silicone defoaming agent or two kinds or three kinds.
Described solid carrier is a kind of in kaolin, diatomite, attapulgite, bentonite, clay, potter's clay, talcum, float stone, white carbon, precipitated calcium carbonate, flour, bark powder, wood powder, shuck powder, corn ear powder, ammonium sulfate, the sodium sulphate or two kinds or three kinds.
Described liquid-carrier is a kind of in water, vegetable oil, vegetable oil derivatives, mineral oil, fatty acid ester, repefral, dibutyl phthalate, the dioctyl phthalate or two kinds or three kinds.
The good effect that the present invention has: after three kinds of composition combinations of (1) Herbicidal combinations of the present invention, synergy is obvious.(2) Herbicidal combinations broad weed-killing spectrum of the present invention can be prevented and treated most of grass family, and broad leaved weed comprises that multiple pernicious difficulty cuts weeds.(3) the Herbicidal combinations optimum period for applying fertilizer of the present invention wide, can be used for postemergence weed control before the seedling, but barley 2 leaf all dispensers in 1 heart stage to flowering stage behind the seedling, method of application is also more flexible.And no any antagonism between three kinds of compositions, little to environmental influence, high to crop safety.(4) Herbicidal combinations of the present invention has reduced the consumption of active component than each medicament separately, has given full play to drug effect separately, can direct disposable medication, greatly reduce use cost.
Embodiment
(embodiment 1)
The formulation of the Herbicidal combinations of present embodiment is a wetting powder, is made up of following components by part by weight: the fluorine azoles sulphur of 10 weight portions is grand, the azoles quinoline of 10 weight portions grass ester, the florasulam of 0.5 weight portion, the butyl biphenyl ether sulfonic acid sodium as wetting agent of 2 weight portions, the lignosulfonates as dispersant of 2 weight portions, the diatomite as solid carrier of 75.5 weight portions.The weight portion of above-mentioned listed each component is also claimed prescription.Fluorine azoles sulphur in the said components is grand, azoles quinoline grass ester and florasulam are active component, and wetting agent and dispersant are auxiliary agent.
Above-mentioned fluorine azoles sulphur as active component is grand, azoles quinoline grass ester and florasulam all derive from Jiangsu Agricultural Hormone Engineering Technology Research Centre Co., Ltd., and purity all reaches the correlated quality requirement.Above-mentioned butyl biphenyl ether sulfonic acid sodium as wetting agent derives from the full woods chemical industry Industrial Co., Ltd. of Nanjing health, and commercial disignation is Areskap 100.Above-mentioned lignosulfonates as dispersant derive from OMNIChem S.A. company, and commercial disignation is Tensiofix IX.Above-mentioned diatomite as solid carrier derives from the agricultural chemicals filler level product of Mingguang City emerging glad mining industry Co., Ltd.
The preparation method is: according to above-mentioned prescription, coarse crushing becomes the powdery object of particle diameter≤420 micron for use with florasulam for active component fluorine azoles sulphur is grand, azoles quinoline grass ester; With three kinds of active components, auxiliary agent and solid carrier mixing and stirring, make the mixed material of particle diameter≤44 micron through the method for comminution by gas stream, this mixed material is the wetting powder of Herbicidal combinations.
(embodiment 2)
The formulation of the Herbicidal combinations of present embodiment still is a wetting powder; The remainder of this wetting powder is identical with embodiment 1, and difference is: described the ratio of each component is: the fluorine azoles sulphur of 12.5 weight portions is grand, the azoles quinoline of 21.5 weight portions grass ester, the florasulam of 6 weight portions, the butyl biphenyl ether sulfonic acid sodium as wetting agent of 2 weight portions, the lignosulfonates as dispersant of 3 weight portions, the diatomite as solid carrier of 51 weight portions.
(embodiment 3)
The formulation of the Herbicidal combinations of present embodiment still is a wetting powder; The remainder of this wetting powder is identical with embodiment 1, and difference is: described the ratio of each component is: the fluorine azoles sulphur of 50 weight portions is grand, the azoles quinoline of 10 weight portions grass ester, the florasulam of 2 weight portions, the butyl biphenyl ether sulfonic acid sodium as wetting agent of 3.5 weight portions, the lignosulfonates as dispersant of 4 weight portions, the diatomite as solid carrier of 30.5 weight portions.
(embodiment 4)
The formulation of the Herbicidal combinations of present embodiment is a water dispersible granules, is made up of following components by part by weight: the fluorine azoles sulphur of 20 weight portions is grand, the azoles quinoline of 15 weight portions grass ester, the florasulam of 5 weight portions, the alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt as wetting agent of 2 weight portions, the lignosulfonates as dispersant of 2 weight portions, the sodium carboxymethyl starch as disintegrant of 1 weight portion, the diatomite as solid carrier of 55 weight portions.The weight portion of above-mentioned listed each component is also claimed prescription.Fluorine azoles sulphur in the said components is grand, azoles quinoline grass ester and florasulam are active component, and wetting agent, dispersant and disintegrant are auxiliary agent.
Above-mentioned alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt as wetting agent derives from Akzo Nobel company, and commercial disignation is Morwet D-425.Above-mentioned sodium carboxymethyl starch as disintegrant derives from Roquette company, and commercial disignation is GLYCOLYS Std.The source of other composition is identical with embodiment 1.
The preparation method is: according to above-mentioned prescription; Three kinds of active components, auxiliary agent and solid carrier are mixed pulverizing; After water-wet; Through the Squeezinggranulator granulation, carrying out drying, screening again, to make particle diameter be 200 microns～5000 microns the granular mixed material that is, and this mixed material is the water dispersible granules of Herbicidal combinations.
(embodiment 5)
The formulation of the Herbicidal combinations of present embodiment still is a water dispersible granules; The remainder of this water dispersible granules is identical with embodiment 4, and difference is: described the ratio of each component is: the fluorine azoles sulphur of 35 weight portions is grand, the azoles quinoline of 5 weight portions grass ester, the florasulam of 5 weight portions, the alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt as wetting agent of 2.5 weight portions, the lignosulfonates as dispersant of 2 weight portions, the sodium carboxymethyl starch as disintegrant of 1.5 weight portions, the diatomite as solid carrier of 49 weight portions.
(embodiment 6)
The formulation of the Herbicidal combinations of present embodiment still is a water dispersible granules, and this water dispersible granules is made up of following components by part by weight: the fluorine azoles sulphur of 60 weight portions is grand, the azoles quinoline of 10 weight portions grass ester, the florasulam of 5 weight portions, the alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt as wetting agent of 3 weight portions, the lignosulfonates as dispersant of 3.5 weight portions, the sodium carboxymethyl starch as disintegrant of 1.5 weight portions, the polyethylene glycol as adhesive of 0.5 weight portion, the diatomite as solid carrier of 16.5 weight portions.Binding agent in the said components also is an auxiliary agent.
Above-mentioned polyethylene glycol as adhesive derives from SANYO company, and commercial disignation is Macrogol 200.The source of other composition is identical with embodiment 4.
The preparation method is with embodiment 4.
(embodiment 7)
The formulation of the Herbicidal combinations of present embodiment is an oil-suspending agent, is made up of following components by part by weight: the fluorine azoles sulphur of 8 weight portions is grand, the azoles quinoline of 16 weight portions grass ester, the florasulam of 4 weight portions, the fatty alcohol polyoxyethylene ether sulfate as wetting agent of 2 weight portions, the fatty acid glyceride APEO as dispersant of 2 weight portions, the polyox-yethylene-polyoxypropylene block copolymer as emulsifier of 4 weight portions, the gas-phase silica as thickener of 1 weight portion, the dimethyl silicone polymer as antifoaming agent of 0.3 weight portion, the epoxidized soybean oil as liquid-carrier of 62.7 weight portions.The weight portion of above-mentioned listed each component is also claimed prescription.Fluorine azoles sulphur in the said components is grand, azoles quinoline grass ester and florasulam are active component, and wetting agent, dispersant, emulsifier, thickener, antifoaming agent are auxiliary agent.
It is identical that above-mentioned active component derives from embodiment 1.Above-mentioned fatty alcohol polyoxyethylene ether sulfate as wetting agent derives from the Texapon N70 of BASF AG.Above-mentioned fatty acid glyceride APEO as dispersant derives from ICI Specialty Chemicals company, and commercial disignation is ATLOX 1285.Above-mentioned polyox-yethylene-polyoxypropylene block copolymer as emulsifier derives from BASF AG, and commercial disignation is Pluronic PE6200.Above-mentioned gas-phase silica as thickener derives from Rhodia company, and commercial disignation is Tixosil 38A.Above-mentioned dimethyl silicone polymer as antifoaming agent derives from Dow Corning company, and commercial disignation is DSP.Above-mentioned epoxidized soybean oil as liquid-carrier derives from the first class product of Shanghai Jiu-State Chemical Co., Ltd.
The preparation method is: according to above-mentioned prescription; Three kinds of active components, wetting agent, dispersant, thickener, antifoaming agent and partial emulsifiers and partially liq carrier are added in the sand milling still; After being ground to certain fineness, in mass transport to homogeneous blender, add remaining emulsifier and liquid-carrier again; Behind homogeneous blender mixing, be the oil-suspending agent of Herbicidal combinations.
(embodiment 8)
The formulation of the Herbicidal combinations of present embodiment still is an oil-suspending agent; The remainder of this oil-suspending agent is identical with embodiment 7, and difference is: described the ratio of each component is: the fluorine azoles sulphur of 12 weight portions is grand, the azoles quinoline of 10 weight portions grass ester, the florasulam of 2 weight portions, the fatty alcohol polyoxyethylene ether sulfate as wetting agent of 2 weight portions, the fatty acid glyceride APEO as dispersant of 2.2 weight portions, the polyox-yethylene-polyoxypropylene block copolymer as emulsifier of 4.5 weight portions, the gas-phase silica as thickener of 1 weight portion, the dimethyl silicone polymer as antifoaming agent of 0.2 weight portion, the epoxidized soybean oil as liquid-carrier of 67 weight portions.
(application examples)
The herbicidal effect of, azoles quinoline grass ester grand and florasulam ternary weeding compound for checking fluorine azoles sulphur; Herbicidal combinations to embodiment 1,2,5,6,8 has carried out the sub-district field control effectiveness test; With 70% commercially available fluorine azoles sulphur precititation dispersible granule, 50g/L azoles quinoline grass emulsifiable concentrate and 50g/L florasulam suspending agent compare simultaneously.70% fluorine azoles sulphur precititation dispersible granule derives from Ai Lisida biochemicals North America Co., Ltd, and 50g/L azoles quinoline grass emulsifiable concentrate derives from Switzerland and just reaching earlier crop protection Co., Ltd, and 50g/L florasulam suspending agent derives from the agricultural Co., Ltd of LG-DOW benefit.
Trial crops is a winter wheat, and soil property is a loam, and main weeds has clearvers, Japanese amur foxtail, amur foxtail, Triticum tauschii, broadcasts ma's punt-pole, deceives grass, wild oat, shepherd's purse etc.Each dosing is that consumption is recommended in the land for growing field crops, establishes 9 processing altogether, and every processing repeats for 4 times, handles the sub-district for totally 36, and district's group is arranged at random, every sub-district area 20m
2, spraying medicine in 2～5 leaf phases of wheat period of seedling establishment weeds, behind the medicine 21 days, 4 points, every some 0.25m were got in every sub-district
2, investigation weeds kind, quantity is calculated the strain preventive effect; After 42 days, 4 points, every some 0.25m are got in every sub-district
2, each weeds kind of handling of investigation, fresh weight calculates preventive effect; During harvesting wheat, 10m gathers separately in each sub-district
2Survey and produce, calculate rate of growth.Estimate by the colby method, result of the test is seen table 1.
Annotate: 100 expressions are prevented and kill off fully or are dead, and 0 expression is not prevented and kill off or damaged.
Can find out from table 1; Fluorine azoles sulphur is grand, azoles quinoline grass ester and the composite back of florasulam to supply examination weeds clearvers, Japanese amur foxtail, deceive grass, the activity of weeding of broadcasting ma's punt-pole is higher than all that independent use fluorine azoles sulphur is grand, activity when azoles quinoline grass ester and florasulam, has the notable synergistic effect.After composite, the grass spectrum is wider extremely, and active component and auxiliary dosage also are reduced.In addition, at the dispenser initial stage in investigation, when 50g/L azoles quinoline grass emulsifiable concentrate and 70% fluorine azoles sulphur precititation dispersible granule used separately, wheat had slight temporary transient chlorosis symptom, and the present composition does not have this phenomenon, shows wheat fool proof.
Claims (10)
1. the Herbicidal combinations of grand, azoles quinoline grass ester of a fluorine-containing azoles sulphur and florasulam is made up of active component, auxiliary agent and carrier; It is characterized in that: said active component is grand by fluorine azoles sulphur, azoles quinoline grass ester and florasulam are formed; Fluorine azoles sulphur is grand, the weight ratio of azoles quinoline grass ester and florasulam is 1: (0.01～100): (0.01～100), the weight of active component are 1%～90% of composition total weight.
2. fluorine-containing azoles sulphur according to claim 1 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, and it is characterized in that: the formulation of said composition is wetting powder, water dispersible granules, oil-suspending agent, pulvis, granule, suspending agent, dry suspending agent, missible oil, aqueous emulsion, microemulsion or suspended emulsion.
3. fluorine-containing azoles sulphur according to claim 2 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, and it is characterized in that: the formulation of said composition is wetting powder, water dispersible granules or oil-suspending agent.
4. fluorine-containing azoles sulphur according to claim 3 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, and it is characterized in that: the formulation of said composition is a wetting powder; This wetting powder is made up of following components by part by weight: as grand 0.1～80 weight portion of the fluorine azoles sulphur of active component, as careless ester 0.1～60 weight portion of the azoles quinoline of active component, florasulam 0.1～60 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, solid carrier 5～90 weight portions.
5. fluorine-containing azoles sulphur according to claim 3 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, and it is characterized in that: the formulation of said composition is a water dispersible granules; This water dispersible granules is made up of following components by part by weight: as grand 0.1～80 weight portion of the fluorine azoles sulphur of active component, as careless ester 0.1～60 weight portion of the azoles quinoline of active component, florasulam 0.1～60 weight portion as active component, wetting agent 0.1～10 weight portion as auxiliary agent, dispersant 0.1～10 weight portion as auxiliary agent, disintegrant 0.1～5 weight portion as auxiliary agent, adhesive 0～5 weight portion as auxiliary agent, solid carrier 10～80 weight portions.
6. fluorine-containing azoles sulphur according to claim 3 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, and it is characterized in that: the formulation of said composition is an oil-suspending agent; This oil-suspending agent comprises following components by part by weight: as grand 0.1～50 weight portion of the fluorine azoles sulphur of active component; Azoles quinoline grass ester 0.1～50 weight portion as active component; Florasulam 0.1～50 weight portion as active component; Wetting agent 0.1～10 weight portion as auxiliary agent; Dispersant 0.1～10 weight portion as auxiliary agent; Emulsifier 0.1～10 weight portion as auxiliary agent; Thickener 0.1～10 weight portion as auxiliary agent; Antifoaming agent 0～5 weight portion as auxiliary agent; Liquid-carrier 10～90 weight portions.
7. the Herbicidal combinations of, azoles quinoline grass ester grand according to the described fluorine-containing azoles sulphur of one of claim 4 to 6 and florasulam is characterized in that:
Described wetting agent is an alkyl sulfate; The benzene sulfonamide acid alkali metal salt; Alkylnaphthalene sulfonate; Dialkyl succinylsuccinate ester sulphonyl sodium salt; The alkyl naphthalene sulfonic acid formaldehyde condensation products; Alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt; The aralkyl naphthalene sulfonic acid-formaldehyde condensation product; Aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Fatty acid amide N methyl taurine sodium salt; Sodium sulfate of polyethenoxy ether of fatty alcohol; APES; APES sulphate; APES succinic acid half ester sulfonate; The APES formaldehyde condensation products; APES formaldehyde condensation products sulphate; APES formaldehyde condensation products succinic acid half ester sulfonate; Lignosulfonates; Polycarboxylate; AEO; Polyox-yethylene-polyoxypropylene block copolymer; Alkyl biphenyl ether sulfonic acid sodium; The dimethyl-octa glycol; Dimethyl-octa glycol ethylene oxide adduct; The tetramethyl decanediol; Tetramethyl decanediol ethylene oxide adduct; A kind of in the organophosphorus ester or two kinds or three kinds;
Described dispersant is the alkyl polyoxyethylene ether formaldehyde condensation products; Alkyl polyoxyethylene ether formaldehyde condensation products sulphate; Aralkyl APEO formaldehyde condensation products; Aralkyl APEO formaldehyde condensation products sulphate; The alkyl naphthalene sulfonic acid formaldehyde condensation products; Alkyl naphthalene sulfonic acid formaldehyde condensation products sodium salt; The aralkyl naphthalene sulfonic acid-formaldehyde condensation product; Aralkyl naphthalene sulfonic acid-formaldehyde condensation product sodium salt; APES; APES sulphate; AEO; Fatty alcohol polyoxyethylene ether sulfate; Fatty acid amide N methyl taurine sodium salt; Alkylnaphthalene sulfonate; Lignosulfonates; Polycarboxylate; The fatty acid glyceride APEO; The vegetable oil ethylene oxide adduct; Vegetable oil ethylene oxide adduct derivative; A kind of in the organophosphorus ester or two kinds or three kinds.
8. the Herbicidal combinations of, azoles quinoline grass ester grand according to claim 4 or 5 described fluorine-containing azoles sulphurs and florasulam is characterized in that: described solid carrier is a kind of in kaolin, diatomite, attapulgite, bentonite, clay, potter's clay, talcum, float stone, white carbon, precipitated calcium carbonate, flour, bark powder, wood powder, shuck powder, corn ear powder, ammonium sulfate, the sodium sulphate or two kinds or three kinds.
9. fluorine-containing azoles sulphur according to claim 5 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, it is characterized in that:
Described disintegrant is a kind of in ammonium sulfate, sodium chloride, urea, starch, the starch derivatives or two kinds or three kinds;
Described adhesive is a kind of in polyethylene glycol, Sodium Polyacrylate, polyox-yethylene-polyoxypropylene block copolymer, xanthans, the dextrin or two kinds or three kinds.
10. fluorine-containing azoles sulphur according to claim 6 is grand, the Herbicidal combinations of azoles quinoline grass ester and florasulam, it is characterized in that:
Described emulsifier is a kind of in polyox-yethylene-polyoxypropylene block copolymer, APES, aralkyl phenol polyethenoxy ether, styryl phenol polyethenoxy ether, alkyl phenol polyethenoxy ether, castor oil polyoxyethylene ether, castor oil polyoxyethylene ether derivative, AEO, cithrol, polyol fatty acid ester, polyol fatty acid ester ethylene oxide adduct, the alkylbenzenesulfonate or two kinds or three kinds;
Described thickener is a kind of in xanthans, gelatin, gum Arabic, melon glue, sodium alginate, sodium carboxymethylcellulose, polyvinyl alcohol, polyacrylamide, gas-phase silica, aluminium-magnesium silicate, sepiolite, diatomite, organobentonite, the attapulgite or two kinds or three kinds;
Described antifoaming agent is a kind of in polyglycereol antifoaming agent, fatty acid defoamer, the silicone defoaming agent or two kinds or three kinds;
Described liquid-carrier is a kind of in water, vegetable oil, vegetable oil derivatives, mineral oil, fatty acid ester, repefral, dibutyl phthalate, the dioctyl phthalate or two kinds or three kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104522029A (en) * | 2014-12-16 | 2015-04-22 | 广东中迅农科股份有限公司 | Weed control composition for preventing and controlling annual weeds in wheat field |
| CN105145610A (en) * | 2015-07-29 | 2015-12-16 | 广东中迅农科股份有限公司 | Weeding composition containing thiencarbazone-methyl, pinoxaden and florasulam |
| CN105454274A (en) * | 2015-12-23 | 2016-04-06 | 汤云鹤 | Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields |
| CN105557734A (en) * | 2015-12-11 | 2016-05-11 | 汤云鹤 | Pesticide composition containing flucarbazone and pretilachlor and application of pesticide composition in control of weeds in wheat field |
| CN108077299A (en) * | 2017-12-22 | 2018-05-29 | 佛山市盈辉作物科学有限公司 | A kind of Herbicidal combinations for including pinoxaden, diflufenican and flucarbazone |
| CN108576034A (en) * | 2018-03-15 | 2018-09-28 | 江苏省农用激素工程技术研究中心有限公司 | Soybean field weeding composition and preparation method thereof |
| CN111972406A (en) * | 2020-07-29 | 2020-11-24 | 南京太化化工有限公司 | Auxiliary agent for dispersible oil suspending agent and nicosulfuron dispersible oil suspending agent |
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| CN102283217A (en) * | 2011-06-27 | 2011-12-21 | 陕西美邦农药有限公司 | Weeding composition containing florasulam and pinoxaden |
| CN102428945A (en) * | 2012-01-16 | 2012-05-02 | 河北博嘉农业有限公司 | Flucarbazone-Na compounded herbicide |
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| CN102283217A (en) * | 2011-06-27 | 2011-12-21 | 陕西美邦农药有限公司 | Weeding composition containing florasulam and pinoxaden |
| CN102428945A (en) * | 2012-01-16 | 2012-05-02 | 河北博嘉农业有限公司 | Flucarbazone-Na compounded herbicide |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104522029A (en) * | 2014-12-16 | 2015-04-22 | 广东中迅农科股份有限公司 | Weed control composition for preventing and controlling annual weeds in wheat field |
| CN104522029B (en) * | 2014-12-16 | 2017-11-14 | 重庆市巴南区环美金属加工厂 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
| CN105145610A (en) * | 2015-07-29 | 2015-12-16 | 广东中迅农科股份有限公司 | Weeding composition containing thiencarbazone-methyl, pinoxaden and florasulam |
| CN105557734A (en) * | 2015-12-11 | 2016-05-11 | 汤云鹤 | Pesticide composition containing flucarbazone and pretilachlor and application of pesticide composition in control of weeds in wheat field |
| CN105454274A (en) * | 2015-12-23 | 2016-04-06 | 汤云鹤 | Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields |
| CN108077299A (en) * | 2017-12-22 | 2018-05-29 | 佛山市盈辉作物科学有限公司 | A kind of Herbicidal combinations for including pinoxaden, diflufenican and flucarbazone |
| CN108576034A (en) * | 2018-03-15 | 2018-09-28 | 江苏省农用激素工程技术研究中心有限公司 | Soybean field weeding composition and preparation method thereof |
| CN111972406A (en) * | 2020-07-29 | 2020-11-24 | 南京太化化工有限公司 | Auxiliary agent for dispersible oil suspending agent and nicosulfuron dispersible oil suspending agent |
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