CN104522029B - For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds - Google Patents
For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds Download PDFInfo
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- CN104522029B CN104522029B CN201410783689.XA CN201410783689A CN104522029B CN 104522029 B CN104522029 B CN 104522029B CN 201410783689 A CN201410783689 A CN 201410783689A CN 104522029 B CN104522029 B CN 104522029B
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- Prior art keywords
- pinoxaden
- kill
- grand
- flucarbazone
- herbicidal combinations
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- 241000196324 Embryophyta Species 0.000 title claims abstract description 36
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 29
- 241000209140 Triticum Species 0.000 title claims abstract description 22
- 235000021307 Triticum Nutrition 0.000 title claims abstract description 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000005864 Sulphur Substances 0.000 claims abstract description 29
- 239000005597 Pinoxaden Substances 0.000 claims abstract description 28
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 claims abstract description 28
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims description 17
- UOUXAYAIONPXDH-UHFFFAOYSA-M flucarbazone-sodium Chemical compound [Na+].O=C1N(C)C(OC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1OC(F)(F)F UOUXAYAIONPXDH-UHFFFAOYSA-M 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- -1 dodecyl sodium sulfonate calcium salt Chemical class 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- SRGHCTFUBDUEEJ-UHFFFAOYSA-N C1(=CC=CC=C1)O.C(C)C1=CC=CC=C1.C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)O.C(C)C1=CC=CC=C1.C1=CC=CC=C1 SRGHCTFUBDUEEJ-UHFFFAOYSA-N 0.000 claims 1
- 235000019482 Palm oil Nutrition 0.000 claims 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims 1
- 229940073769 methyl oleate Drugs 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 claims 1
- 239000002540 palm oil Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- GINFBXXYGUODAT-UHFFFAOYSA-N flucarbazone Chemical compound O=C1N(C)C(OC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1OC(F)(F)F GINFBXXYGUODAT-UHFFFAOYSA-N 0.000 abstract description 21
- 239000004009 herbicide Substances 0.000 abstract description 11
- 159000000000 sodium salts Chemical class 0.000 abstract description 8
- 230000002195 synergetic effect Effects 0.000 abstract description 7
- 239000004480 active ingredient Substances 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 3
- 230000003111 delayed effect Effects 0.000 abstract 1
- 230000008092 positive effect Effects 0.000 abstract 1
- 241000209764 Avena fatua Species 0.000 description 13
- 235000007320 Avena fatua Nutrition 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 230000004083 survival effect Effects 0.000 description 12
- 239000000375 suspending agent Substances 0.000 description 8
- 235000004535 Avena sterilis Nutrition 0.000 description 7
- 241000544785 Bromus japonicus Species 0.000 description 6
- 241000209202 Bromus secalinus Species 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000004562 water dispersible granule Substances 0.000 description 4
- 239000004563 wettable powder Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 244000058871 Echinochloa crus-galli Species 0.000 description 2
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical class [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 230000005737 synergistic response Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- 241000743985 Alopecurus Species 0.000 description 1
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 240000003173 Drymaria cordata Species 0.000 description 1
- 244000025670 Eleusine indica Species 0.000 description 1
- 235000014716 Eleusine indica Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 102000003960 Ligases Human genes 0.000 description 1
- 108090000364 Ligases Proteins 0.000 description 1
- 241000287127 Passeridae Species 0.000 description 1
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 210000002390 cell membrane structure Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
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- IZBNNCFOBMGTQX-UHFFFAOYSA-N etoperidone Chemical class O=C1N(CC)C(CC)=NN1CCCN1CCN(C=2C=C(Cl)C=CC=2)CC1 IZBNNCFOBMGTQX-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 244000230342 green foxtail Species 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- XSKZXGDFSCCXQX-UHFFFAOYSA-N thiencarbazone-methyl Chemical compound COC(=O)C1=CSC(C)=C1S(=O)(=O)NC(=O)N1C(=O)N(C)C(OC)=N1 XSKZXGDFSCCXQX-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Abstract
The present invention relates to a kind of Herbicidal combinations for being used to prevent and kill off wheat paddock annual grassy weeds, active ingredient is grand thiophene ketone sulphur, pinoxaden, flucarbazone (or its sodium salt)；Herbicidal combinations of the present invention have synergistic function, prevent and kill off the positive effect of wheat paddock annual grassy weeds and are used alone better than each single dose, and expand herbicide controlling spectrum, while reduce dosage, have delayed the generation of herbicide resistance, have alleviated pollution to environment.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to it is a kind of with thiophene ketone sulphur is grand, pinoxaden, flucarbazone (or its
Sodium salt) for active ingredient Synergistic respond Herbicidal combinations, suitable for preventing and kill off wheat paddock annual grassy weeds.
Background technology
Thiophene ketone sulphur grand (thiencarbazone-methyl) is sulfonyl-amino-carbnyl triazolinone class herbicide, is acetyl
Lactic acid synthetase inhibitors, it is that can effectively prevent and kill off wheat paddock grassy weed such as lady's-grass, eleusine indica, barnyard grass, see wheat that thiophene ketone sulphur is grand
Ma, Alopecurus and part broad leaved weed such as chickweed, clearvers etc..
Pinoxaden (pinoxaden), pinoxaden category neophyl pyrazolines herbicide, the mechanism of action are that acetyl is auxiliary
Enzyme A carboxylases (ACC) inhibitor, causes aliphatic acid biosynthesis block, cell division is stopped cell membrane structure containing fat and is broken
It is bad, cause weeds dead, there is preferable preventive effect to wheatland wild oat, barnyard grass, green bristlegrass.
Flucarbazone (flucarbazone), flucarbazone is sulfonylurea internal-suction type efficient wheat field herbicidal, to open country
The grassy weeds such as oat, bromegrass, amur foxtail and a variety of broadleaf weeds have obvious preventive effect, and its active ingredient can be by weeds
Root and cauline leaf absorb, and by suppressing the activity of acetolactate synthestase in weeds body, destroy the normal Physiological and Biochemical Metabolism of weeds
And play activity of weeding, can effectively prevent and kill off wheat paddock major part grassy weed, at the same also can effectively control section broad-leaved it is miscellaneous
It grass, can be quickly metabolized in wheat body, there is fabulous security to wheat.
The present invention possesses the prospect of industrial applications, can be with excipient for ease of agricultural use by certain technological means
Formulation, such as suspending agent, oil-suspending agent, water dispersible granules, wettable powder.
The present inventor is grand to thiophene ketone sulphur, pinoxaden, flucarbazone and its sodium salt mixture have made intensive studies, and finds
Thiophene ketone sulphur is grand, pinoxaden, flucarbazone and its sodium salt mixture have Synergistic response to target weeds, especially to bromegrass
(Bromus japonicus), wild oat (Avena fatua) have obvious Synergistic to respond.
Thiophene ketone sulphur is grand, the ternary built of pinoxaden, flucarbazone and its sodium salt is applied to wheat paddock annual grassy weeds
Prevent and kill off no relevant report.
The content of the invention
It is an object of the invention to solve developed immunity to drugs in the prior art to farmland weed problem and actual prevention effect
It is poor, there is provided a kind of efficient, low toxicity, quick-acting are good and the lasting period is grown, and are advantageous to the Herbicidal combination of the farmland weed comprehensive regulation
Thing.
It is another object of the present invention to be used to the Herbicidal combinations prevent and kill off farmland weed, particularly for preventing and kill off wheat paddock
Annual grassy weeds etc..
The technical scheme is that：A kind of Herbicidal combinations for being used to prevent and kill off wheat paddock annual grassy weeds, with thiophene ketone sulphur
Grand, pinoxaden, flucarbazone (or its sodium salt) are active ingredient, the grand percentage by weight in Herbicidal combinations of thiophene ketone sulphur
For 0.1%~40%, percentage by weight of the pinoxaden in Herbicidal combinations is 0.1%~30%, flucarbazone or its sodium
Percentage by weight of the salt in Herbicidal combinations is 0.1%~30%, and remaining is to allow in agricultural chemicals using auxiliary with acceptable
Co-ingredients.
Described Herbicidal combinations can be auxiliary from suitable pesticidal preparations according to well known to a person skilled in the art method
Co-ingredients, it can be processed into what is used in the suitable agricultural production such as suspending agent, oil-suspending agent, water dispersible granules, wettable powder
Application forms.
The auxiliary element that the present invention uses include wetting agent, stabilizer, dispersant, disintegrant, thickener, pH adjusting agent,
Defoamer, antifreezing agent, filler etc., all it is the auxiliary agent commonly used in Pesticide formulation, specific composition and dosage are according to recipe requirements
It is determined by experiment.
Herbicidal combinations provided by the invention, suitable for preventing and kill off wheat paddock annual grassy weeds.
The frequency of administration of Herbicidal combinations provided by the invention and amount of application with crops, weeds, weather condition change and
There are small variations, the purpose effectively prevented and treated can be reached by using appropriate dosage.
Product described in the invention can be provided in the form of finished product preparation, i.e., each material is blended in composition, group
The composition of compound can also single dose form provide, directly mixed using preceding in tank or bucket, be then diluted to required for it is dense
Degree.
Compared with prior art, the advantage of the invention is that：
1st, Herbicidal combinations of the present invention have obvious synergistic function, used substantially than single dose or binary built
The prevention effect to weeds is improved, expands herbicide controlling spectrum, reduces Pesticide use amount, reduces use cost, is alleviated pair
The pollution of environment.
2nd, the Herbicidal combinations active ingredient mechanism of action of the present invention is different, can delay the generation of herbicide resistance.
Embodiment
In order that the objects, technical solutions and advantages of the present invention are more concise, present invention specific examples below
Illustrate, but the present invention is only limitted to absolutely not these examples.As described below is only the preferable embodiment of the present invention, is used only for
The description present invention, it is impossible to be interpreted as limiting the scope of the present invention.It is it should be pointed out that all in the spiritual and former of the present invention
All any modification, equivalent and improvement done within then etc., should be included in the scope of the protection.
Example of formulations 1：The 21% grand pinoxaden flucarbazone water dispersible granules of thiophene ketone sulphur.
Above-mentioned material is added in cone-type mixer together and is well mixed, is crushed by airslide disintegrating mill, the thing after crushing
Material is mixed through cone-type mixer again, and mixed fineness of materials 98% is added in kneader and is kneaded into by 600 mesh standard sieves
Plasticity material, this material is finally put into extruder grain in Squeezinggranulator, be made after drying, screening after granulation
The 21% grand pinoxaden flucarbazone water dispersible granules of thiophene ketone sulphur.
Example of formulations 2：The grand pinoxaden flucarbazone sodium salt wettable powder of 20% thiophene ketone sulphur.
Above-mentioned material is added in cone-type mixer together and is well mixed, is crushed by airslide disintegrating mill, the thing after crushing
Material mixes through cone-type mixer again, and it is grand to produce 20% thiophene ketone sulphur by 600 mesh standard sieves for mixed fineness of materials 98%
Pinoxaden flucarbazone sodium salt wettable powder.
Example of formulations 3：The 11% grand pinoxaden flucarbazone suspending agent of thiophene ketone sulphur.
Above-mentioned formula is crushed in advance in proportion, adds in sand mill and grinds, system is allocated after high shear mixing
Obtain the 11% grand pinoxaden flucarbazone suspending agent of thiophene ketone sulphur.
Example of formulations 4：The 11% grand pinoxaden flucarbazone oil-suspending agent of thiophene ketone sulphur.
Above-mentioned material (except organobentonite) is added in reactor mixer together, stirred 2 hours, opens kettle
Bottom pan feeding valve, material is injected in multistage sand mill and ground, and the fineness of materials 98% after grinding after 1-5 μm by discharging, material
It is put into again with together with the organobentonite dissolved in advance in high-shear emulsifying kettle, good fluidity is can be made into after emulsification
The grand pinoxaden flucarbazone sodium salt oil-suspending agent of 11% thiophene ketone sulphur.
Assays Example 1：Thiophene ketone sulphur is grand, pinoxaden, flucarbazone and its compounding are to bromegrass (Bromus
Japonicus), the Toxicity Determination experiment of wild oat (Avena fatua).
According to the Colby formula (predictive role of evaluation particular composition, referring to S.R.Colby, " Calculating
Synergistic and Antagonistic Responses of Herbicide combinations”Weeds 1967,
15,20-22)。
A, the theoretical survival rate or fresh weight survival rate that B, C are used with certain dosage
In formula：
Strain survival rates or fresh weight survival rate (%) of the A with certain dosage when alone to target weeds；
Strain survival rates or fresh weight survival rate (%) of the B with certain dosage when alone to target weeds；
Strain survival rates or fresh weight survival rate (%) of the C with certain dosage when alone to target weeds；
N is the herbicide kind number of mixture；
E0For thiophene ketone sulphur is grand, three kinds of pinoxaden, flucarbazone and its sodium salt pharmacy mix when it is residual to target weeds fresh weight
Deposit the theoretical value of rate or strain survival rate；
E is residual to target weeds fresh weight when being three kinds of grand thiophene ketone sulphur, pinoxaden, flucarbazone and its sodium salt pharmacy mix
Deposit the measured value of rate or strain survival rate.
Evaluation criterion：Strain survival rate or fresh weight survival rate observation have synergy when being less than theoretical value (synergy is made
With), i.e. E0- E is more than zero.
Table one, thiophene ketone sulphur are grand, pinoxaden, flucarbazone and its compounding are to bromegrass (Bromus japonicus) room
Interior virulence measurement result
Herbicide associated form is evaluated according to Colby methods, the data of table one show that thiophene ketone sulphur is grand, pinoxaden, fluorine azoles sulphur
Grand triple combination is notable to bromegrass (Bromus japonicus) synergistic effect, E0- E values are all higher than 20%.
Table two, thiophene ketone sulphur are grand, pinoxaden, flucarbazone and its compounding are to wild oat (Avena fatua interior poison
Power measurement result
Herbicide associated form is evaluated according to Colby methods, the data of table two show that thiophene ketone sulphur is grand, pinoxaden, fluorine azoles sulphur
Grand triple combination is notable to wild oat (Avena fatua) synergistic effect, E0- E values are all higher than 20%.
Assays Example 2：Prevent and kill off wheat paddock annual grassy weeds field control effectiveness test.
Table three, thiophene ketone sulphur are grand, pinoxaden, flucarbazone composition are to preventing and kill off wheat paddock annual grassy weeds field efficacy
Result of the test
In summary, instant component is reasonable, has Synergistic response, especially to bromegrass (Bromus
Japonicus), wild oat (Avena fatua) responds with notable synergy, and expansion herbicide controlling spectrum is wheat paddock especially with sparrow
Wheat (Bromus japonicus), wild oat (Avena fatua) provide excellent weeds for the wheat paddock of dominant weed and controlled
Solution is managed, suitable for preventing and kill off wheat paddock annual grassy weeds.
Claims (1)
- A kind of 1. Herbicidal combinations for being used to prevent and kill off wheat paddock annual grassy weeds, it is characterised in that weight ratio：Thiophene ketone sulphur grand 4%, Pinoxaden 6%, flucarbazone sodium salt 1%, benzene ethylbenzene phenol polyethenoxy ether 3%, sodium lignin sulfonate 4%, methyl oleate 15%, Organobentonite 2%, dodecyl sodium sulfonate calcium salt 3%, palm oil to 100%;Except organobentonite, by above-mentioned material, one Rise and be added in reactor mixer, stir 2 hours, open bottom pan feeding valve, material is injected in multistage sand mill and ground, is ground For fineness of materials 98% after mill by being discharged after 1-5 μm, material is put into high shear with together with the organobentonite dissolved in advance again In emulsifying kettle, the grand pinoxaden flucarbazone sodium salt oil of 11% thiophene ketone sulphur that good fluidity is can be made into after emulsification suspends Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410783689.XA CN104522029B (en) | 2014-12-16 | 2014-12-16 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410783689.XA CN104522029B (en) | 2014-12-16 | 2014-12-16 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
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| Publication Number | Publication Date |
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| CN104522029A CN104522029A (en) | 2015-04-22 |
| CN104522029B true CN104522029B (en) | 2017-11-14 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105454274A (en) * | 2015-12-23 | 2016-04-06 | 汤云鹤 | Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields |
| CN108077301A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with nicosulfuron of sulphur of ketone containing thiophene |
| CN107873724A (en) * | 2017-12-25 | 2018-04-06 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of thifensulfuron methyl and its application |
| CN109691445A (en) * | 2019-01-21 | 2019-04-30 | 深圳市爱美町植物营养免疫科技有限公司 | A kind of agricultural builder of palm oil and its preparation method and application |
| CA3214787A1 (en) * | 2021-03-30 | 2022-10-06 | Stepan Company | Agricultural formulations |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| WO2012107539A1 (en) * | 2011-02-11 | 2012-08-16 | Basf Se | Herbicidal compositions comprising topramezone and pinoxaden |
| CN102823615A (en) * | 2012-09-28 | 2012-12-19 | 江苏省农用激素工程技术研究中心有限公司 | Weeding composition containing flucarbazone, pinoxaden and florasulam |
-
2014
- 2014-12-16 CN CN201410783689.XA patent/CN104522029B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| WO2012107539A1 (en) * | 2011-02-11 | 2012-08-16 | Basf Se | Herbicidal compositions comprising topramezone and pinoxaden |
| CN102823615A (en) * | 2012-09-28 | 2012-12-19 | 江苏省农用激素工程技术研究中心有限公司 | Weeding composition containing flucarbazone, pinoxaden and florasulam |
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| CN104522029A (en) | 2015-04-22 |
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