CN104522029A - Weed control composition for preventing and controlling annual weeds in wheat field - Google Patents
Weed control composition for preventing and controlling annual weeds in wheat field Download PDFInfo
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- CN104522029A CN104522029A CN201410783689.XA CN201410783689A CN104522029A CN 104522029 A CN104522029 A CN 104522029A CN 201410783689 A CN201410783689 A CN 201410783689A CN 104522029 A CN104522029 A CN 104522029A
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- preventing
- herbicidal combinations
- flucarbazone
- kill
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Links
- 241000196324 Embryophyta Species 0.000 title claims abstract description 46
- 241000209140 Triticum Species 0.000 title claims abstract description 24
- 235000021307 Triticum Nutrition 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 32
- GINFBXXYGUODAT-UHFFFAOYSA-N flucarbazone Chemical compound O=C1N(C)C(OC)=NN1C(=O)NS(=O)(=O)C1=CC=CC=C1OC(F)(F)F GINFBXXYGUODAT-UHFFFAOYSA-N 0.000 claims abstract description 26
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 12
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 54
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 27
- 239000005864 Sulphur Substances 0.000 claims description 27
- 150000003851 azoles Chemical class 0.000 claims description 27
- 150000002148 esters Chemical class 0.000 claims description 27
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 27
- 244000025254 Cannabis sativa Species 0.000 claims description 26
- 239000000375 suspending agent Substances 0.000 claims description 10
- 238000009472 formulation Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000000361 pesticidal effect Effects 0.000 claims description 2
- 239000004009 herbicide Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 3
- 239000005597 Pinoxaden Substances 0.000 abstract description 2
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 abstract description 2
- XSKZXGDFSCCXQX-UHFFFAOYSA-N thiencarbazone-methyl Chemical compound COC(=O)C1=CSC(C)=C1S(=O)(=O)NC(=O)N1C(=O)N(C)C(OC)=N1 XSKZXGDFSCCXQX-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003111 delayed effect Effects 0.000 abstract 1
- 241000209764 Avena fatua Species 0.000 description 14
- 235000007320 Avena fatua Nutrition 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 235000004535 Avena sterilis Nutrition 0.000 description 8
- 241000209202 Bromus secalinus Species 0.000 description 7
- 241000544785 Bromus japonicus Species 0.000 description 6
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 230000005764 inhibitory process Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- UOUXAYAIONPXDH-UHFFFAOYSA-M flucarbazone-sodium Chemical compound [Na+].O=C1N(C)C(OC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1OC(F)(F)F UOUXAYAIONPXDH-UHFFFAOYSA-M 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 102000000452 Acetyl-CoA carboxylase Human genes 0.000 description 2
- 108010016219 Acetyl-CoA carboxylase Proteins 0.000 description 2
- 240000001592 Amaranthus caudatus Species 0.000 description 2
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 2
- 108010018763 Biotin carboxylase Proteins 0.000 description 2
- 244000058871 Echinochloa crus-galli Species 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000005737 synergistic response Effects 0.000 description 2
- WTLNOANVTIKPEE-UHFFFAOYSA-N 2-acetyloxypropanoic acid Chemical compound OC(=O)C(C)OC(C)=O WTLNOANVTIKPEE-UHFFFAOYSA-N 0.000 description 1
- 108010000700 Acetolactate synthase Proteins 0.000 description 1
- 241000743985 Alopecurus Species 0.000 description 1
- 240000003173 Drymaria cordata Species 0.000 description 1
- 244000025670 Eleusine indica Species 0.000 description 1
- 235000014716 Eleusine indica Nutrition 0.000 description 1
- 240000003461 Setaria viridis Species 0.000 description 1
- 235000002248 Setaria viridis Nutrition 0.000 description 1
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- KSCFJBIXMNOVSH-UHFFFAOYSA-N dyphylline Chemical group O=C1N(C)C(=O)N(C)C2=C1N(CC(O)CO)C=N2 KSCFJBIXMNOVSH-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IZBNNCFOBMGTQX-UHFFFAOYSA-N etoperidone Chemical class O=C1N(CC)C(CC)=NN1CCCN1CCN(C=2C=C(Cl)C=CC=2)CC1 IZBNNCFOBMGTQX-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a weed control composition for preventing and controlling annual weeds in wheat field. The active ingredients of the weed control composition comprise thiencarbazone-methyl, pinoxaden and flucarbazone or sodium salt thereof. The weed control composition has the synergism effect, and has better effect for preventing and controlling annual weeds in wheat field compared with all single dosages used independently, the weed control spectrum is expanded, the composition using amount is reduced, the herbicide resistance of the weeds is delayed, and the environment pollution is alleviated.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to the Synergistic response Herbicidal combinations that one is grand with thiophene ketone sulphur, azoles quinoline grass ester, flucarbazone (or its sodium salt) are active ingredient, be applicable to prevent and kill off wheat paddock annual weed.
Background technology
Thiophene ketone sulphur grand (thiencarbazone-methyl) is sulfonyl-amino-carbnyl triazolinone class weed killer herbicide, be inhibitor of acetolactate synthetase, thiophene ketone sulphur is grand is effectively can prevent and kill off wheat paddock grassy weed if lady's-grass, eleusine indica, barnyard grass, amur foxtail, Alopecurus and part broad leaved weed are as chickweed, clearvers etc.
Azoles quinoline grass ester (pinoxaden), azoles quinoline grass ester belongs to neophyl pyrazolines weed killer herbicide, the mechanism of action is acetyl-CoA carboxylase (ACC) inhibitor, cause fatty acid biosynthesis block, cell division is made to stop cell membrane destructurized containing fat, cause weeds dead, to wheatland wild oat, barnyard grass, green foxtail, there is good preventive effect.
Flucarbazone (flucarbazone), flucarbazone is sulfonylurea internal-suction type efficient wheat field herbicidal, to wild oat, bromegrass, the grassy weeds such as amur foxtail and multiple broadleaf weed have obvious preventive effect, its active ingredient can be absorbed by the root of weeds and cauline leaf, by suppressing the activity of acetolactate synthestase in weeds body, destroy the normal Physiological and Biochemical Metabolism of weeds and play activity of weeding, effectively can prevent and kill off wheat paddock major part grassy weed, simultaneously also can effective control section broad leaved weed, can very fast metabolism in wheat body, to wheat, there is fabulous safety.
The present invention possesses the prospect of industrial applications, by certain technological means, can excipient for ease of the formulation of agricultural use, as suspending agent, oil-suspending agent, water dispersible granules, wetting powder etc.
The present inventor is grand to thiophene ketone sulphur, azoles quinoline grass ester, flucarbazone and sodium salt mixture thereof conduct in-depth research, find that thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone and sodium salt mixture thereof have Synergistic to respond to target weeds, especially have obvious Synergistic to respond to bromegrass (Bromus japonicus), wild oat (Avena fatua).
Thiophene ketone sulphur is grand, the ternary built of azoles quinoline grass ester, flucarbazone and sodium salt thereof is applied to preventing and kill off without relevant report of wheat paddock annual weed.
Summary of the invention
The object of the invention is to solve in prior art to farmland weed develop immunity to drugs problem and actual control efficiency poor, provide a kind of efficient, low toxicity, quick-acting are good and the lasting period is long, are conducive to the Herbicidal combinations of the farmland weed comprehensive regulation.
Another object of the present invention is used for preventing and kill off farmland weed by this Herbicidal combinations, is particularly useful for preventing and kill off wheat paddock annual weed etc.
Technical scheme of the present invention is: a kind of Herbicidal combinations for preventing and kill off wheat paddock annual weed, the careless ester of, azoles quinoline grand with thiophene ketone sulphur, flucarbazone (or its sodium salt) are for active ingredient, the grand percentage by weight in Herbicidal combinations of thiophene ketone sulphur is 0.1% ~ 40%, the azoles quinoline grass percentage by weight of ester in Herbicidal combinations is 0.1% ~ 30%, flucarbazone or the percentage by weight of its sodium salt in Herbicidal combinations are 0.1% ~ 30%, and all the other be allow use and acceptable auxiliary element in agricultural chemicals.
Described Herbicidal combinations according to well known to a person skilled in the art method, can be selected suitable pesticidal preparations auxiliary element, can be processed into the application forms that the applicable agricultural productions such as suspending agent, oil-suspending agent, water dispersible granules, wetting powder use.
The auxiliary element that the present invention uses comprises wetting agent, stabilizing agent, dispersant, disintegrant, thickener, pH adjusting agent, defoamer, antifreezing agent, filler etc., be all auxiliary agent conventional in Pesticide formulation, concrete composition and consumption are determined by test according to recipe requirements.
Herbicidal combinations provided by the invention, is applicable to prevent and kill off wheat paddock annual weed.
The frequency of administration of Herbicidal combinations provided by the invention and amount of application change with crops, weeds, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Product described in the invention can the form of finished product preparation provide, and namely in composition, each material mixes, and the composition of composition also can the form of single dose provide, and directly mixes in tank or bucket, be then diluted to required concentration before using.
Compared with prior art, the invention has the advantages that:
1, Herbicidal combinations of the present invention has obvious synergistic function, uses than single dose or binary built the control efficiency significantly improved weeds, expands herbicide spectrum, decreases Pesticide use amount, reduce use cost, alleviate the pollution to environment.
2, the Herbicidal combinations active ingredient mechanism of action of the present invention is different, can delay the generation of herbicide resistance.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Example of formulations 1:21% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone water dispersible granules.
Above-mentioned material is added in cone-type mixer together and mixes; pulverize by airslide disintegrating mill; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 600 mesh standard sieves; add in kneader and be kneaded into plasticity material; finally this material is put into Squeezinggranulator extruder grain, after drying, screening, after granulation, namely obtain 21% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone water dispersible granules.
Example of formulations 2:20% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone sodium salt wetting powder.
Above-mentioned material is added in cone-type mixer together and mixes, pulverize by airslide disintegrating mill, material after pulverizing is again through cone-type mixer mixing, and mixed fineness of materials 98%, by 600 mesh standard sieves, obtains 20% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone sodium salt wetting powder.
Example of formulations 3:11% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone suspending agent.
Pulverized in advance in proportion by above-mentioned formula, then add in sand mill and grind, after high shear mixing, allotment obtains 11% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone suspending agent.
Example of formulations 4:11% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone oil-suspending agent.
Above-mentioned material (except organobentonite) is joined in reactor mixer together, stir 2 hours, open pan feeding valve at the bottom of still, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material puts into high-shear emulsifying still again together with the organobentonite dissolved in advance, namely can be made into the 11% thiophene ketone sulphur grand azoles quinoline grass ester flucarbazone sodium salt oil-suspending agent that flowing to property is good after emulsification.
Assays Example 1: thiophene ketone sulphur is grand, the test of azoles quinoline grass ester, flucarbazone and the composite Toxicity Determination to bromegrass (Bromusjaponicus), wild oat (Avena fatua) thereof.
Evaluate weed killer herbicide associated form (NY/T 1155.7-2006) according to Colby method, its formula is as follows:
In formula:
A be thiophene ketone sulphur grand alone with certain dosage time fresh weight inhibition to target weeds;
B be azoles quinoline grass ester alone with certain dosage time fresh weight inhibition to target weeds;
C be flucarbazone and sodium salt thereof alone with certain dosage time fresh weight inhibition to target weeds;
N is the weed killer herbicide kind number of mixture;
E
0for thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone and sodium salt thereof three kinds of pharmacy mix time theoretical value to target weeds fresh weight inhibition;
E is that thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone and sodium salt thereof three kinds of pharmacy mix time be the measured value of contrast to target weeds fresh weight inhibition.
Evaluation criterion: work as E
0during ﹣ E > 10%, be expressed as synergistic function; As ﹣ 10%≤E
0during ﹣ E≤10%, show as collaborative summation action; Work as E
0during ﹣ E < ﹣ 10%, show as joint action of antagonism.
Table one, thiophene ketone sulphur are grand, azoles quinoline grass ester, flucarbazone and the composite Toxicity Determination result to bromegrass (Bromus japonicus) thereof
Evaluate weed killer herbicide associated form according to Colby method, table one data show, and thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone triple combination are remarkable to bromegrass (Bromus japonicus) synergistic effect, E
0-E value is all greater than 20%.
Table two, thiophene ketone sulphur are grand, azoles quinoline grass ester, flucarbazone and the composite Toxicity Determination result to wild oat (Avena fatua) thereof
Evaluate weed killer herbicide associated form according to Colby method, table two data show, and thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone triple combination are remarkable to wild oat (Avena fatua) synergistic effect, E
0-E value is all greater than 20%.
Assays Example 2: prevent and kill off wheat paddock annual weed field control effectiveness test.
Table three, thiophene ketone sulphur are grand, azoles quinoline grass ester, flucarbazone composition is to preventing and kill off wheat paddock annual weed field control effectiveness test result
In sum, instant component is reasonable, there is Synergistic response, especially to bromegrass (Bromusjaponicus), wild oat (Avena fatua), there is remarkable synergy response, expand herbicide spectrum, especially the wheat paddock being advantage weeds with bromegrass (Bromus japonicus), wild oat (Avena fatua) for wheat paddock provides excellent weed control solution, is applicable to prevent and kill off wheat paddock annual weed.
Claims (4)
1. one kind for preventing and kill off the Herbicidal combinations of wheat paddock annual weed, it is characterized in that: active ingredient is that thiophene ketone sulphur is grand, azoles quinoline grass ester, flucarbazone (or its sodium salt), the grand percentage by weight in Herbicidal combinations of thiophene ketone sulphur is 0.1% ~ 40%, and the azoles quinoline grass percentage by weight of ester in Herbicidal combinations is 0.1% ~ 30%, flucarbazone or the percentage by weight of its sodium salt in Herbicidal combinations are 0.1% ~ 30%.
2. a kind of Herbicidal combinations for preventing and kill off wheat paddock annual weed according to claim 1, is characterized in that: described Herbicidal combinations also contains pesticidal preparations auxiliary element, to make the application forms of applicable agricultural use.
3. a kind of Herbicidal combinations for preventing and kill off wheat paddock annual weed according to claim 2, is characterized in that: its formulation is the one in suspending agent, oil-suspending agent, water dispersible granules, wetting powder.
4. a kind of Herbicidal combinations for preventing and kill off wheat paddock annual weed according to claim 1 is preventing and kill off the application in wheat paddock annual weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410783689.XA CN104522029B (en) | 2014-12-16 | 2014-12-16 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410783689.XA CN104522029B (en) | 2014-12-16 | 2014-12-16 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104522029A true CN104522029A (en) | 2015-04-22 |
| CN104522029B CN104522029B (en) | 2017-11-14 |
Family
ID=52837810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410783689.XA Expired - Fee Related CN104522029B (en) | 2014-12-16 | 2014-12-16 | For preventing and kill off the Herbicidal combinations of wheat paddock annual grassy weeds |
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| Country | Link |
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| CN (1) | CN104522029B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105454274A (en) * | 2015-12-23 | 2016-04-06 | 汤云鹤 | Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields |
| CN107873724A (en) * | 2017-12-25 | 2018-04-06 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of thifensulfuron methyl and its application |
| CN108077301A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with nicosulfuron of sulphur of ketone containing thiophene |
| CN109691445A (en) * | 2019-01-21 | 2019-04-30 | 深圳市爱美町植物营养免疫科技有限公司 | A kind of agricultural builder of palm oil and its preparation method and application |
| WO2022212185A1 (en) * | 2021-03-30 | 2022-10-06 | Stepan Company | Agricultural formulations |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| WO2012107539A1 (en) * | 2011-02-11 | 2012-08-16 | Basf Se | Herbicidal compositions comprising topramezone and pinoxaden |
| CN102823615A (en) * | 2012-09-28 | 2012-12-19 | 江苏省农用激素工程技术研究中心有限公司 | Weeding composition containing flucarbazone, pinoxaden and florasulam |
-
2014
- 2014-12-16 CN CN201410783689.XA patent/CN104522029B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1449247A (en) * | 2000-06-30 | 2003-10-15 | 拜尔农作物科学股份公司 | Aryl sulfonyl amino carbonyl triazole based selective herbicides |
| WO2012107539A1 (en) * | 2011-02-11 | 2012-08-16 | Basf Se | Herbicidal compositions comprising topramezone and pinoxaden |
| CN102823615A (en) * | 2012-09-28 | 2012-12-19 | 江苏省农用激素工程技术研究中心有限公司 | Weeding composition containing flucarbazone, pinoxaden and florasulam |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105454274A (en) * | 2015-12-23 | 2016-04-06 | 汤云鹤 | Pesticide composition containing flucarbazone and pinoxaden and application thereof to control of weeds in wheat fields |
| CN107873724A (en) * | 2017-12-25 | 2018-04-06 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of thifensulfuron methyl and its application |
| CN108077301A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with nicosulfuron of sulphur of ketone containing thiophene |
| CN109691445A (en) * | 2019-01-21 | 2019-04-30 | 深圳市爱美町植物营养免疫科技有限公司 | A kind of agricultural builder of palm oil and its preparation method and application |
| WO2022212185A1 (en) * | 2021-03-30 | 2022-10-06 | Stepan Company | Agricultural formulations |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104522029B (en) | 2017-11-14 |
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