CN105028415A - Pesticide composition containing fluroxypyr and dicamba and application of pesticide composition in control of lemnaceae plants - Google Patents

Pesticide composition containing fluroxypyr and dicamba and application of pesticide composition in control of lemnaceae plants Download PDF

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CN105028415A
CN105028415A CN201510366265.8A CN201510366265A CN105028415A CN 105028415 A CN105028415 A CN 105028415A CN 201510366265 A CN201510366265 A CN 201510366265A CN 105028415 A CN105028415 A CN 105028415A
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dicamba
fluroxypyr
pesticide composition
application
plant
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王红春
孙宇
贺建荣
李小艳
娄远来
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Jiangsu Academy of Agricultural Sciences
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Jiangsu Academy of Agricultural Sciences
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Abstract

The invention discloses a pesticide composition containing fluroxypyr and dicamba and an application of the pesticide composition in control of lemnaceae plants. The pesticide composition comprises active components such as fluroxypyr and dicamba in a mass ratio of (2-100): (5-100). According to the pesticide composition disclosed by the invention, a remarkable synergistic effect is shown in the ratio range, the application dosage of the pesticide composition is lowered, the application frequency is reduced, the application cost is reduced and the adverse effects of the pesticide composition to the ecological environment are decreased; the weeding spectrum is enlarged, the problem of harms from various lemnaceae plants is solved by once application, and the defect and the limitation in a use process of single dosage are remedied; the service life of the pesticide composition is prolonged, and the pesticide composition has an important meaning in comprehensive control to the resistance of weeds; the pesticide composition disclosed by the invention is rapid in effect taking, long in duration, low in use cost and capable of being used for preventing and removing the lemnaceae plants.

Description

The composition pesticide of a kind of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba and preventing and treating the application in plant and of its applications
Technical field
The invention belongs to technical field of pesticide, being specifically related to a kind of composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba for preventing and kill off plant and of its applications.
Background technology
In recent years, along with the sustained and rapid development of national economy, water environment pollutes day by day serious, and plant and of its applications spreads quickening, and river course, some areas, lake, reservoir duckweed large area spread unchecked harm, the serious harm ecological balance.At present, the plant and of its applications in large area covering river course mainly contains duckweed, blue or green duckweed, wolffia arrhiza etc.Duckweed growth need consume the nutritive salt such as nitrogen, phosphorus in water body, and a small amount of duckweed has catharsis to water quality.But large area overgrows, and will cause severe contamination to water body.The main harm of duckweed relates to: 1. polluted water, threatens drinking water safety; 2. hide navigation channel, hinder navigation, affect shipping safety; 3. polluted-water, affects culture fishery and develops in a healthy way; 4. polluted water, grows germ; 5. destroy the aspects such as water ecology balance.At present, duckweed has large area in national zones of different and spreads unchecked harm report, and its control mainly lays particular emphasis on artificial salvaging, and cost is high, efficiency is low and control efficiency is not obvious, it is serious that regeneration spreads harm, urgently seeks efficient, low cost, environmentally safe the method for control.Duckweed is paved with river course, keeps the sun off and causes water body muddy, large amount of organic generation chemical reaction, increase toxic bacteria, reduce water body oxygen content, the aquatiles such as harm fishes and shrimps, heavy damage river channel ecology environment.
Fluroxypyr, chemical name: the fluoro-pyridine of the chloro-6-of 4-amino-3.5-two-2-pyridine fluoroacetic acid 1-methyl-heptyl ester.Belonging to pyridines weed killer herbicide, is inner sucting conduction type herbicide after seedling.Be absorbed by plants very soon after medicine, make sensitive plant occur reaction plant deformity, the distortion of classical hormones class weed killer herbicide.Be applicable to the ground such as wheat, barley, corn, grape, orchard, pasture, forest land, lawn and prevent and kill off broad leaved weed.
Dicamba, the chloro-O-Anisic Acid of chemical name: 3,6-bis-.Belong to phenoxy carboxylic acid herbicides; for spraying after seedling; medicament can very soon by the leaf of weeds, stem, root absorption; conducted up and down by phloem; focus mostly at meristematic tissue and the vigorous position of metabolic activity; hinder the normal activity of plant hormone, thus make it dead, have significant preventive effect to broadleaved herb.
Summary of the invention
Goal of the invention: in the waters such as prior art and river, lake, the overgrowing of plant and of its applications large area lacks the problem of effective the method for control.The object of this invention is to provide the composition pesticide of a kind of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba, make it have efficient, wide spectrum, environmentally friendly, be beneficial to the features such as the integrated control of the water ecology balance waters such as the comprehensive regulation and river, lake plant and of its applications.Another object of the present invention is to provide the application of the composition pesticide of a kind of above-mentioned fluroxypyr and dicamba.
Technical scheme: in order to realize foregoing invention object, the technical solution used in the present invention is:
A composition pesticide for containing chlorine fluorine pyrrole fluoroacetic acid and dicamba, active ingredient is fluroxypyr and dicamba, and the mass ratio of fluroxypyr and dicamba is 2-100: 5-100.
The preferred mass ratio of fluroxypyr and dicamba is 8: 50,8: 75,10: 60,12: 70 or 15: 90.
A pesticidal preparations for containing chlorine fluorine pyrrole fluoroacetic acid and dicamba, described preparation becomes agricultural chemicals on acceptable any one formulation with the composition pesticide of dicamba with the acceptable auxiliaries of field of pesticide preparation by containing chlorine fluorine pyrrole fluoroacetic acid.
The formulation of described pesticidal preparations is wetting powder, water dispersible granules, suspending agent or oil-suspending agent.
In described pesticidal preparations, three kinds of herbicidal active components account for the 1-90% of pesticidal preparations gross weight.
Described auxiliary material is selected from wetting agent, dispersant, spreader-sticker, stabilizing agent, bleeding agent, thickener, antifreezing agent, defoamer, filler, solvent; Wherein, described wetting agent is one or more among neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether; Described dispersant be lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and polycarboxylic acid salt one or more; Described stabilizing agent is that epoxidized vegetable oil is as one or more in epoxidised soybean oil, epoxidized linseed; Described spreader-sticker is one or more in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly-trisiloxanes, triethanolamine oleate; Described solvent is one or more in soybean oil, methyl oleate, white oil, turpentine oil methyl naphthalene higher aliphatic hydrocarbon ils; Described filler is one or more in white carbon, corn starch, kaolin, diatomite, sodium sulphate, ammonium sulfate.
Described containing chlorine fluorine pyrrole fluoroacetic acid and the composition pesticide of dicamba are preventing and treating the application in plant and of its applications.When preventing and treating plant and of its applications, plant and of its applications thallus uses after launching.
Described containing chlorine fluorine pyrrole fluoroacetic acid and the pesticidal preparations of dicamba are preventing and treating the application in plant and of its applications.When preventing and treating plant and of its applications, use after plant and of its applications thallus is launched.
The production technology of the various application forms of the composition pesticide of described containing chlorine fluorine pyrrole fluoroacetic acid and dicamba all belongs to existing known technology.
The composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid provided by the invention and dicamba and pesticidal preparations thereof, usually adopt the method for spraying to use, also can adopt other operation techniques agriculturally applied as required.
Beneficial effect: compared with prior art, the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid of the present invention and dicamba, tool has the following advantages:
1) composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid of the present invention and dicamba, obvious synergistic effect is shown in certain ratio range, the control efficiency of composition is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2) composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid of the present invention and dicamba, the combination of two kinds of active ingredients, expands herbicidal spectrum, and a drug had both solved various plant and of its applications problem, compensate for defect when single dose uses and limitation.
3) composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid of the present invention and dicamba, active ingredient mechanism of action is different, the shortcoming that long-term single use easily produces resistance can be overcome, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4) composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid of the present invention and dicamba, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Specific embodiments
Below in conjunction with specific embodiment, the present invention is further illustrated.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
In following examples, unless otherwise indicated, all percentage is all weight percentage.
Embodiment 1:12.75% fluroxypyr dicamba oil-suspending agent
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 6%, dicamba 6.75%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, epoxidized soybean oil 5%, organobentonite 5%, methyl oleate to 100%.
After fluroxypyr is mixed with filling adsorption, again other above-mentioned materials (except organobentonite) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material, putting into high-shear emulsifying still together with the organobentonite dissolved in advance, namely can be made into 12.75% fluroxypyr dicamba oil-suspending agent after emulsification.
Embodiment 2:20% fluroxypyr dicamba suspending agent
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 8%, dicamba 12%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, ethylene glycol 5%, aluminium-magnesium silicate 2%, defoamer 0.5%, preservative 0.1%, xanthans 0.1%, water to 100%.
After fluroxypyr is mixed with filling adsorption, again other above-mentioned materials (except xanthans) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material, putting into high-shear emulsifying still together with the xanthans dissolved in advance, namely can be made into 20% fluroxypyr dicamba suspending agent after emulsification.
Embodiment 3:35% fluroxypyr dicamba wetting powder
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 20%, dicamba 15%, sodium butylnaphthalenesulfonate 3%, calcium lignosulfonate 5%, white carbon 5%, kaolin to 100%.
After fluroxypyr is mixed with filling adsorption, add in cone-type mixer together with other above-mentioned material and mix, pulverize by airslide disintegrating mill, material after pulverizing is again through cone-type mixer mixing, and mixed fineness of materials 98% is by 325 mesh standard sieves i.e. obtained 35% fluroxypyr dicamba wetting powder.
Embodiment 4:75% fluroxypyr dicamba water dispersible granules
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 35%, dicamba 40%, metal carboxylate 5%, and urea 10%, adds kaolin to 100%.
After fluroxypyr is mixed with filling adsorption; add in cone-type mixer together with other above-mentioned material and mix; pulverize by airslide disintegrating mill; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 325 mesh standard sieves; add in kneader and be kneaded into plasticity material, finally this material is put into Squeezinggranulator extruder grain, through dry, screening i.e. obtained 75% fluroxypyr dicamba water dispersible granules after granulation.
Embodiment 5:23% fluroxypyr dicamba oil-suspending agent
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 13%, dicamba 10%, lauryl sodium sulfate 2%, sodium butylnaphthalenesulfonate 3%, calcium lignosulfonate 5%, white carbon 5%, kaolin to 100%.
After fluroxypyr is mixed with filling adsorption, again other above-mentioned materials (except organobentonite) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material, putting into high-shear emulsifying still together with the organobentonite dissolved in advance, namely can be made into 23% fluroxypyr dicamba oil-suspending agent after emulsification.
Embodiment 6:30% fluroxypyr dicamba suspending agent
Each component of the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid and dicamba is: fluroxypyr 14%, dicamba 16%, phenethyl phenol APEO 5%, sodium lignin sulfonate 8%, ethylene glycol 5%, aluminium-magnesium silicate 2%, defoamer 0.5%, preservative 0.1%, xanthans 0.1%, water to 100%.
After fluroxypyr is mixed with filling adsorption, again other above-mentioned materials (except xanthans) are joined in reactor mixer together, stir, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material, putting into high-shear emulsifying still together with the xanthans dissolved in advance, namely can be made into 30% fluroxypyr dicamba suspending agent after emulsification.
Embodiment 7 fluroxypyr and the screening of dicamba optimum proportioning
In order to understand fluroxypyr and dicamba mixture further to the synergy of plant and of its applications, the present inventor has carried out formulation screening test to fluroxypyr and dicamba mixture.
Test material: duckweed (SpirodelapolyrhizaL), blue or green duckweed (Lemnaminor), in June, 2014 salvages in river course, district, Taizhou City Jiangyan City of Jiangsu Province.
Test apparatus: PWT-510 type spray tower, plum Teller AB135-S electronic balance, volumetric flask, triangular flask, beaker, graduated cylinder, polypots, pipette, chi, scissors etc.
Test method: the fluroxypyr and the former medicine of dicamba that first take certain mass, add the Tween 80 aqueous solution dilution that methyl alcohol fully dissolves rear use 0.1%, be mixed with single dose mother liquor, arrange serial proportioning according to mixture object, it is stand-by that each proportioning arranges 5-7 concentration gradient.Polypots (15cm × 11cm × 7cm) is filled water, selects healthy duckweed, blue or green duckweed, through tap water rinse decontamination dirt and impurity, take 5g (100% surface coverage) and render to polypots.Jiangsu Province Agriculture Science Institute 300m is put into after spraying process 2greenhouse by solar heat is cultivated, and every day keeps the skin wet.
The growing state of routine observation duckweed, duckweed after medicine.Within after medicine 30 days, investigate the fresh weight of duckweed, blue or green duckweed, calculate fresh weight inhibition namely to the preventive effect of target weeds.Adopt DPS data handling system to obtain the virulence regression equation of single dose and 9 binary mixture agent, calculate ED 50value and 95% confidence limit.Co-toxicity coefficient is calculated by the abundant method of Sun Yun.Co-toxicity coefficient is greater than 120 and is expressed as synergistic effect, is less than 80 and is expressed as antagonism, be expressed as summation action between 80 ~ 120.
Result of the test: medicine post processing is observed for 20 days, fluroxypyr and dicamba use rear duckweed, the jaundice of blue or green duckweed partial blade to withered in 2-100: 5-100 ratio mixture, the inhibitory action of duckweed, blue or green duckweed is risen with the increase of drug concentration, to duckweed, blue or green duckweed, there is very high biologically active.
After medicine 30 days, fluroxypyr and dicamba 9 binary mixtures combinations had obvious inhibitory action (table 1) to the fresh weight of duckweed, blue or green duckweed.The co-toxicity coefficient of 9 proportioning 2: 5,2: 100,8: 50,8: 75,10: 60,12: 70,15: 90,100: 5 and 100: 100 proportionings is respectively 185.5752,152.4426,169.4141,191.2710,161.7981,193.0814,163.9053,154.7338 and 172.7751, co-toxicity coefficient is all greater than 120, shows as synergistic effect (table 1).
Table 1 fluroxypyr-dicamba mixture is to the synergy of duckweed, blue or green duckweed fresh weight
Fluroxypyr has good inhibitory action to multiple annual broadleaf weed and perennial broadleaf weed, and dicamba has good inhibitory action to multiple broad leaved weed, and the two mixture can prevent and kill off multiple Lemnaceae weeds simultaneously.Fluroxypyr and dicamba, in 2-100: 5-100 ratio mixture, show as synergistic effect.
Embodiment 8 field control effectiveness test
Reagent agent: select mixed herbicide prepared in embodiment 1 ~ 4.
Contrast medicament: 20% fluroxypyr EC (commercial)
48% dicamba AS (commercial)
If blank
Using method: adopt spray-on process.
Spraying time: the river course dispenser being covered with duckweed, blue or green duckweed and wolffia arrhiza in district of Taizhou City Jiangyan City of Jiangsu Province on June 25th, 2014.
Respondent and method: duckweed, blue or green duckweed, wolffia arrhiza, after medicine, 20d estimates the preventive effect of plant and of its applications.
Test results and analysis are respectively in table 2.
Table 2 field control effectiveness test result (after medicine 20d)
Treatment agent Consumption (g/ mu) Preventive effect (%)
Embodiment 1 200 95.44
Embodiment 2 150 96.43
Embodiment 3 100 94.59
Embodiment 4 50 96.55
20% fluroxypyr EC 60 65.50
48% dicamba AS 60 63.50
As can be seen from Table 2, the present invention has obvious effect to duckweed, blue or green duckweed, wolffia arrhiza, and preventive effect higher than single dose preventive effect, and has good quick-acting and lasting effect.
Embodiment 9
With reference to the method for embodiment 8, the mixed herbicide obtained to embodiment 5-8 carries out field control effectiveness test, confirms: each mixed herbicide has obvious synergistic effect, has significant preventive effect to plant and of its applications, Be very effective is better than single dose and uses, and the lasting period is long.

Claims (10)

1. a composition pesticide for containing chlorine fluorine pyrrole fluoroacetic acid and dicamba, is characterized in that: active component is fluroxypyr and dicamba, and the mass ratio of fluroxypyr and dicamba is 2-100: 5-100.
2. a pesticidal preparations for fluroxypyr and dicamba, is characterized in that: described preparation becomes agricultural chemicals on acceptable any one formulation with the composition pesticide of dicamba with the acceptable auxiliaries of field of pesticide preparation by containing chlorine fluorine pyrrole fluoroacetic acid according to claim 1.
3. the pesticidal preparations of fluroxypyr according to claim 2 and dicamba, is characterized in that: the formulation of described pesticidal preparations is wetting powder, water dispersible granules, suspending agent, microemulsion, finish, suspension emulsion, missible oil, water dispersible granules, aqueous emulsion or oil-suspending agent.
4. the pesticidal preparations of containing chlorine fluorine pyrrole fluoroacetic acid according to claim 2 and dicamba, is characterized in that: in described preparation, active ingredient accounts for the 1-90% of weight of formulation.
5. the pesticidal preparations of fluroxypyr according to claim 2 and dicamba, is characterized in that: described auxiliary material is selected from wetting agent, dispersant, spreader-sticker, stabilizing agent, bleeding agent, thickener, antifreezing agent, defoamer, filler, solvent; Wherein, described wetting agent is one or more among neopelex, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, lignosulfonates, alkyl phenol formaldehyde resin polyoxyethylene ether, aliphatic alcohol sulfate, phenethyl phenol polyethenoxy ether, polyoxyethylene nonylphenol ether; Described dispersant be lignosulfonates, alkylbenzenesulfonate, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, alkyl ethyl sulfonate, alkylnaphthalene sulfonate formaldehyde condensation products and polycarboxylic acid salt one or more; Described stabilizing agent is that epoxidized vegetable oil is as one or more in epoxidised soybean oil, epoxidized linseed; Described spreader-sticker is one or more in polyvinyl alcohol, alkyl diphenyl ether disulphonic acid sodium, poly-trisiloxanes, triethanolamine oleate; Described solvent is one or more in soybean oil, methyl oleate, white oil, turpentine oil methyl naphthalene higher aliphatic hydrocarbon ils; Described filler is one or more in white carbon, corn starch, kaolin, diatomite, sodium sulphate, ammonium sulfate.
6. the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid according to claim 1 and dicamba is preventing and treating the application in plant and of its applications.
7. application according to claim 6, is characterized in that: when preventing and treating plant and of its applications, uses after plant and of its applications thallus is launched.
8. the containing chlorine fluorine pyrrole fluoroacetic acid described in any one of claim 2-5 and the pesticidal preparations of dicamba are preventing and treating the application of plant and of its applications.
9. application according to claim 8, is characterized in that: when preventing and treating plant and of its applications, uses after plant and of its applications thallus is launched.
10. the composition pesticide of containing chlorine fluorine pyrrole fluoroacetic acid according to claim 1 and dicamba, is characterized in that: the mass ratio of described fluroxypyr and dicamba is 8: 50,8: 75,10: 60,12: 70 or 15: 90.
CN201510366265.8A 2015-06-25 2015-06-25 Pesticide composition containing fluroxypyr and dicamba and application of pesticide composition in control of lemnaceae plants Pending CN105028415A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106614597A (en) * 2016-11-23 2017-05-10 盐城市大丰区小海镇农业技术推广综合服务中心 Pesticide for grubbing alternanthera philoxeroides
CN107787976A (en) * 2016-08-30 2018-03-13 南京华洲药业有限公司 A kind of Herbicidal combinations and its application containing Mediben and dithiopyr
WO2024115744A1 (en) * 2022-12-02 2024-06-06 Upl Mauritius Limited A stable agrochemical composition

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CN107787976A (en) * 2016-08-30 2018-03-13 南京华洲药业有限公司 A kind of Herbicidal combinations and its application containing Mediben and dithiopyr
CN106614597A (en) * 2016-11-23 2017-05-10 盐城市大丰区小海镇农业技术推广综合服务中心 Pesticide for grubbing alternanthera philoxeroides
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