CN101669488B - Binary complex pesticide composition containing chlorantraniliprole - Google Patents
Binary complex pesticide composition containing chlorantraniliprole Download PDFInfo
- Publication number
- CN101669488B CN101669488B CN200910019508.5A CN200910019508A CN101669488B CN 101669488 B CN101669488 B CN 101669488B CN 200910019508 A CN200910019508 A CN 200910019508A CN 101669488 B CN101669488 B CN 101669488B
- Authority
- CN
- China
- Prior art keywords
- rynaxypyr
- parts
- composition containing
- pesticide composition
- binary complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000000575 pesticide Substances 0.000 title claims abstract description 24
- 239000005886 Chlorantraniliprole Substances 0.000 title abstract 4
- 239000000375 suspending agent Substances 0.000 claims abstract description 14
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract description 11
- 239000004480 active ingredient Substances 0.000 claims abstract description 8
- 238000009472 formulation Methods 0.000 claims abstract description 6
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 241000255967 Helicoverpa zea Species 0.000 abstract description 3
- 241000985245 Spodoptera litura Species 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 abstract description 2
- 241000426497 Chilo suppressalis Species 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 241001531327 Hyphantria cunea Species 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 2
- 241000255969 Pieris brassicae Species 0.000 abstract description 2
- 244000061456 Solanum tuberosum Species 0.000 abstract description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 230000000361 pesticidal effect Effects 0.000 abstract description 2
- 235000009566 rice Nutrition 0.000 abstract description 2
- 244000003416 Asparagus officinalis Species 0.000 abstract 1
- 235000005340 Asparagus officinalis Nutrition 0.000 abstract 1
- 240000007124 Brassica oleracea Species 0.000 abstract 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 abstract 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 abstract 1
- 241001325166 Phacelia congesta Species 0.000 abstract 1
- 235000012015 potatoes Nutrition 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 41
- 230000001154 acute effect Effects 0.000 description 25
- -1 methyl-carbamoyl Chemical group 0.000 description 21
- 229940079593 drug Drugs 0.000 description 19
- 230000000638 stimulation Effects 0.000 description 15
- 239000002131 composite material Substances 0.000 description 11
- 241000256247 Spodoptera exigua Species 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 241000283973 Oryctolagus cuniculus Species 0.000 description 9
- 235000015424 sodium Nutrition 0.000 description 9
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 230000002195 synergetic effect Effects 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 239000003053 toxin Substances 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 241000500437 Plutella xylostella Species 0.000 description 6
- 239000005937 Tebufenozide Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 235000018927 edible plant Nutrition 0.000 description 5
- 239000002917 insecticide Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000005917 Methoxyfenozide Substances 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical group COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical class [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 241001253920 Ryania Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a binary complex pesticide composition containing chlorantraniliprole, which comprises active ingredients with the content of 3-80 percent by weight and chlorantraniliprole with the content accounting for 10-90 percent by weight of the active ingredients. Complex components mainly comprise emamectin benzoate or a bishydrazide type pesticide, and can be any possible preparation formulations. The binary complex pesticide composition containing chlorantraniliprole has high efficiency, low toxicity, low residuals, broad pesticidal spectrum, remarkable synergy, can markedly lower the use cost, can be processed into the preparation formulations containing suspending agents, wettable powder, granular formulations, water-dispersible granular formulations, missible oil, microemulsion and aqueous emulsion, is suitable for controlling multiple pests on vegetables and crops including cabbages, rice, brassicaceous vegetables, cotton, potatoes and the like, has remarkable action effect on multiple plant pests including asparagus caterpillars, cabbage butterflies, prodenia litura, striped rice borers, paddy borers, cotton bollworms, fall webworms and the like, and is particularly suitable for the production of green foods.
Description
One, technical field
The present invention relates to technical field of pesticide, relate to pesticide combination technology, particularly the compounded technology of Rynaxypyr.
Two, background technology
Rynaxypyr is a kind of efficient pesticides.The bromo-N-of chemical name: 3-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-base)-1-hydrogen-pyridine-5-formamide, molecular formula: C
18h
14n
5o
2brCl
2, relative molecular weight: 481, structural formula is:
Rynaxypyr is a kind of brand-new insecticide, and the chemical constitution due to Rynaxypyr has the brand-new desinsection principle that other any insecticides do not possess, and efficiently can activate insect ryania (muscle) acceptor.Calcium ion in excessive release cells in calcium storehouse, cause insect to be paralysed dead, high to the larva activity of lepidoptera pest, insecticidal spectrum is wide, lasting effect good.Very safe to crop under different temperature condition, to person poultry safety, low toxicity.
Three, summary of the invention
The object of the present invention is to provide a kind of take Rynaxypyr as a kind of insecticides of host component, reaches the object of synergy, wide spectrum, reduction use cost.
The object of the present invention is achieved like this, based on Rynaxypyr, carries out compositely obtaining having synergy, wide spectrum, binary built preparation that use cost is low with other pesticide.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, active ingredient weight percent content is 3% ~ 80%, and Rynaxypyr accounts for 10% ~ 90% of active ingredient.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the second component composite with Rynaxypyr is emamection benaoate.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the second component composite with Rynaxypyr is bishydrazide insecticide.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the one that the bishydrazide insecticide composite with Rynaxypyr is selected from methoxyfenozide, worm hydrazides, chlorine worm hydrazides, furan tebufenozide combines.
The formulation of the binary complex pesticide composition containing Rynaxypyr that the present invention relates to is the one in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, water-dispersible granules.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, auxiliary element comprises acceptable organic solvent, emulsifier, surfactant, inert filler etc.
The present invention relates to containing the binary complex pesticide composition of Rynaxypyr, use solvent to comprise fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohol organic solvent, lipid organic solvent or organic solvent of ketone etc.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, use surfactant, comprise alkylbenzenesulfonate, lignin sulfonate, alkyl sulfate, Alkyl ethoxy carboxylate acid salt, phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, the anion surfactants such as sulfonate and formaldehyde condensation product, amine salt, quaternary amine, the cationic surfactants such as amine oxide, betain, imidazoline type, Amino acid, the amphoteric surfactantes such as phosphine ester, fatty alcohol ether, alkyl phenol ether, alkyl ether amine, the non-ionic surface active agents such as alkoxide such as polyethers, also has aliphatic alcohol ester, fatty acid alkane ester, alkylamide, the mixed surfactants such as alcohol ether type.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, other auxiliary element used also comprises xanthans, the thickeners such as sodium carboxymethyl starch, the antifreezing agents such as ethylene glycol, glycerine, urea; The fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, has efficiently, low toxicity, low-residual, insecticidal spectrum is wide, synergistic effect is remarkable, significantly can reduce use cost.
The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, be used for preventing and treating the various pests on the vegetables such as wild cabbage, paddy rice, brassicaceous vegetable, cotton, potato and crop, remarkable to various plants insect action effects such as such as beet armyworm, cabbage caterpillar, prodenia litura, striped rice borer, paddy stem borer, cotton bollworm, fall webworm, be specially adapted to the production of pollution-free food.
Four, embodiment
Be further described, to contribute to understanding of the present invention, but not as the restriction to technical scheme inventing the technical scheme related to below in conjunction with embodiment.
Except mentioning especially, in embodiment use component ratio to be weight portion.
Embodiment one
20% Rynaxypyr methoxyfenozide suspending agent
Raw material consists of 4 parts of former medicines of Rynaxypyr, 16 parts of former medicines of methoxyfenozide, 1.2 parts are pulled open powder, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.3 parts of calcium dodecyl benzene sulfonates, 3 parts of triphenoethyl benzene phenol polyethenoxy ethers, 1.5 parts of white carbons, 0.15 part of xanthans, supplies 100 parts with water, suspending agent mode of production preparation routinely.
Toxicity test, rat (female/male) acute oral LD50 > 5000mg/kg, to the no skin irritation of rabbit, has no stimulation to the eyes of rabbit.Show that Recompounded pesticide belongs to low-toxin farm chemicals.
Using dosage: control Laphygma exigua Hubner, is watered dilution 1000 ~ 2000 times, spray medicine 3 ~ 7 days, successful, preventive effect more than 95%.
Rynaxypyr and methoxyfenozide are pressed 1/10 respectively, 1/8,1/4,1/1,4/1,8/1,10/1 ratio is composite, floats agent and contrasts, carry out the Toxicity Determination of Laphygma exigua Hubner with 20% Tebufenozide suspending agent and 5% Rynaxypyr, it is 141.58 ~ 198.82 that result shows the co-toxicity coefficient (Sun Yun abundant co-toxicity coefficient computational methods under same) of each medicament to beet armyworm, wherein the most obvious with 1/4 synergistic effect.
Embodiment two
3% Rynaxypyr emamectin benzoate microemulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of Methylaminoemamectin benzoate, 5 parts of N, N-dimethylformamide, 10 parts of cyclohexanone, 5 parts of acetone, 3 parts of phenethyl phenolformaldehyde resin APEOs, 2 parts of calcium dodecyl benzene sulfonates, 3 parts of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, supply 100 parts with water, prepare in the usual way.
Toxicity test, rat acute LD50 of passing through mouth > 1000mg/kg, chmice acute LD50 of passing through mouth LD50 > 1000mg/kg, rabbit is acute is greater than 1000mg/kg through skin LD50, rat acute is greater than 1000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: control diamond-back moth, is watered dilution 1000 ~ 1500 times, spray medicine 2 ~ 5 days, successful, preventive effect more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5, the ratio of 1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, result shows: each medicament is 185.43 ~ 223.74 to the co-toxicity coefficient of diamond-back moth.Show that there is significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment three
80% Rynaxypyr worm hydrazides wetting powder
Raw material consists of 9 parts of former medicines of Rynaxypyr, 72 parts of former medicines of worm hydrazides, and 14 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 2 parts of lauryl sodium sulfate, 5 parts of calcium lignosulfonates, supply 100 parts with ammonium sulfate.Prepare in the usual way.
Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: control beet armyworm, is watered dilution 3000 ~ 5000 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 90%.
Former for Rynaxypyr medicine and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out the survey of beet armyworm indoor virulence, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 245.36.
Embodiment four
9% Rynaxypyr worm hydrazides missible oil
Raw material forms: 1 part of former medicine of Rynaxypyr, 8 parts of former medicines of worm hydrazides, 8 parts of N, N-dimethylformamide, 10 parts of methyl alcohol, 4 parts of calcium dodecyl benzene sulfonates, 4 parts of triphenoethyl benzene phenol polyethenoxy ethers, 3 parts of phenethyl phenolformaldehyde resin APEOs, supply 100 parts with toluene.Prepare in the usual way.
Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: control beet armyworm, is watered dilution 1000 ~ 1500 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 90%.
Former for Rynaxypyr medicine and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out beet armyworm Toxicity Determination, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 238.56.
Embodiment five
60% Rynaxypyr chlorine worm hydrazides water-dispersible granules
Raw material forms: 10 parts of former medicines of Rynaxypyr, 50 parts of former medicines of chlorine worm hydrazides; 1 part of calcium dodecyl benzene sulfonate, 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of naphthalenesulfonate formaldehyde condensation compounds, 5 parts of calcium lignosulfonates, 5 parts of sodium carboxymethyl starches, supply 100 parts with ammonium sulfate, and extruder grain mode is prepared routinely.
Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 5000mg/kg through skin LD50, has no stimulation, has no stimulation to eye, show that compound drug belongs to low-toxin farm chemicals to skin.
Using dosage: control prodenia litura, is watered dilution 3000 ~ 5000 times, spray medicine 4-6 days, successful, preventive effect more than 90%.
Rynaxypyr and chlorine worm hydrazides are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10, the ratio of 1/20 is composite, contrast with 5% Rynaxypyr suspending agent and 20% chlorine Tebufenozide suspending agent, co-toxicity coefficient is 126.19 ~ 182.73, and wherein the proportioning medicament co-toxicity coefficient of 1/10 is the highest, and result shows to have significant synergies.
Embodiment six
30% Rynaxypyr emamectin benzoate granule
Raw material forms: 20 parts of former medicines of Rynaxypyr, 10 parts of emamection benaoates; 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 5 parts of sodium lignin sulfonates, 4 parts of calcium lignosulfonates, 2 parts of dodecyl sodium sulfates, 10 parts of ammonium sulfate, 8 parts of carboxyrnethyl starch sodiums, supply 100 parts with corn starch, and extruder grain mode is prepared routinely.
Toxicity test, rat acute LD50 of passing through mouth > 10000mg/kg, rabbit is acute is greater than 10000mg/kg through skin LD50, has no stimulation, has no stimulation to eye, show that compound drug belongs to low-toxin farm chemicals to skin.
Using dosage: control cotton bollworm, is watered dilution 3000 ~ 5000 times, spray medicine 3-5 days, successful, preventive effect more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2, the ratio of 1/5,1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 5% emamectin-benzoate, co-toxicity coefficient is 164.32 ~ 212.45, and result shows to have significant synergies, wherein the most obvious with 2/1 synergistic effect.
Embodiment seven
3% Rynaxypyr emamectin-benzoate aqueous emulsion
Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of Methylaminoemamectin benzoate, 7 parts of dimethylbenzene, 10 parts of cyclohexanone, 5 parts of acetone, 1 part of phenethyl phenolformaldehyde resin APEO, 0.3 part of calcium dodecyl benzene sulfonate, 1 part of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, supply 100 parts with water, prepare in the usual way.
Toxicity test, rat acute LD50 of passing through mouth > 1000mg/kg, chmice acute LD50 of passing through mouth LD50 > 1000mg/kg, rabbit is acute is greater than 1000mg/kg through skin LD50, rat acute is greater than 1000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: control diamond-back moth, is watered dilution 1000 ~ 1500 times, spray medicine 2 ~ 5 days, successful, preventive effect more than 90%.
Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5, the ratio of 1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, result shows: each medicament is 185.43 ~ 223.74 to the co-toxicity coefficient of diamond-back moth.Show that there is significant synergistic effect, wherein the most outstanding with 2/1 effect.
Embodiment eight
72% Rynaxypyr furan tebufenozide wetting powder
Raw material consists of 8 parts of former medicines of Rynaxypyr, 64 parts of former medicines of worm hydrazides, and 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of lauryl sodium sulfate, 7 parts of calcium lignosulfonates, supply 100 parts with ammonium sulfate.Prepare in the usual way.
Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: control beet armyworm, is watered dilution 3000 ~ 5000 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 92%.
Former for Rynaxypyr medicine and the former medicine of furan tebufenozide are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 60% furan tebufenozide wetting powder, carry out the survey of beet armyworm indoor virulence, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 2837.57.
Claims (3)
1. the binary complex pesticide composition containing Rynaxypyr, is characterized in that: active ingredient weight percent content is 3%, and Rynaxypyr accounts for 2/3 of active ingredient; Second component is emamectin-benzoate.
2. the binary complex pesticide composition containing Rynaxypyr, is characterized in that: active ingredient weight percent content is 80%, and Rynaxypyr accounts for 8/9 of active ingredient; Second component is worm hydrazides.
3. claim 1 or 2 relate to any one contain the binary complex pesticide composition of Rynaxypyr, it is characterized in that: formulation is the one in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, water-dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910019508.5A CN101669488B (en) | 2009-09-29 | 2009-09-29 | Binary complex pesticide composition containing chlorantraniliprole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910019508.5A CN101669488B (en) | 2009-09-29 | 2009-09-29 | Binary complex pesticide composition containing chlorantraniliprole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101669488A CN101669488A (en) | 2010-03-17 |
| CN101669488B true CN101669488B (en) | 2015-04-29 |
Family
ID=42017069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910019508.5A Active CN101669488B (en) | 2009-09-29 | 2009-09-29 | Binary complex pesticide composition containing chlorantraniliprole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101669488B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614608A (en) * | 2016-11-23 | 2017-05-10 | 盐城市大丰区小海镇农业技术推广综合服务中心 | Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101971866B (en) * | 2010-10-20 | 2013-11-13 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound insecticidal microemulsion and preparation method thereof |
| CN103651428A (en) * | 2011-05-17 | 2014-03-26 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and antibiotic compound |
| CN102246762A (en) * | 2011-05-23 | 2011-11-23 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing furan tebufenozide and amide compounds |
| CN102578161B (en) * | 2012-01-18 | 2014-04-02 | 华南理工大学 | Chlorantraniliprole and natural pyrethrin compound suspension and preparation method thereof |
| CN103518730B (en) * | 2012-07-04 | 2015-08-19 | 陕西美邦农药有限公司 | The Pesticidal combination of a kind of brominated worm benzamide and bishydrazide |
| CN104604876B (en) * | 2012-07-04 | 2016-12-07 | 陕西美邦农药有限公司 | A kind of brominated worm Benzoylamide and the Pesticidal combination of bishydrazide |
| CN105613509A (en) * | 2014-10-30 | 2016-06-01 | 陕西美邦农药有限公司 | Pesticidal composition containing ZJ3757 |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| AU2018279253B2 (en) * | 2017-06-09 | 2024-02-29 | Upl Ltd | Novel pesticidal combinations |
| CN108174853A (en) * | 2018-02-05 | 2018-06-19 | 广东真格生物科技有限公司 | A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class |
| CN109845740B (en) * | 2019-01-22 | 2024-01-30 | 海利尔药业集团股份有限公司 | Insecticidal composition containing flucloxapyroxad and bishydrazide insecticide |
| CN110896955B (en) * | 2019-10-25 | 2021-08-03 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548680A (en) * | 2009-04-23 | 2009-10-07 | 惠州市中迅化工有限公司 | Pesticidal composition containing emamectin benzoate and chlorantraniliprole |
-
2009
- 2009-09-29 CN CN200910019508.5A patent/CN101669488B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548680A (en) * | 2009-04-23 | 2009-10-07 | 惠州市中迅化工有限公司 | Pesticidal composition containing emamectin benzoate and chlorantraniliprole |
Non-Patent Citations (2)
| Title |
|---|
| ACS.RN:873330-39-3.《STN-Registry》.2006,第7-8页. * |
| RN:873330-26-8;ACS;《STN-Registry》;20060202;第11-12页 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614608A (en) * | 2016-11-23 | 2017-05-10 | 盐城市大丰区小海镇农业技术推广综合服务中心 | Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101669488A (en) | 2010-03-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101669488B (en) | Binary complex pesticide composition containing chlorantraniliprole | |
| EP2667719B1 (en) | Pesticide composition comprising sulphur, an insecticide and an agrochemical excipient. | |
| CN104782630A (en) | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide | |
| CN105076185A (en) | Insecticide composition with chlorfenapyr and neonicotinoid insecticides, and preparation and application of insecticide composition | |
| CN102302035B (en) | Pesticide composition containing methoxyfenozide | |
| CN102084862B (en) | Insecticidal composition containing ethiprole | |
| CN101836643B (en) | Pesticide preparation for controlling vegetable pests of diamondback moth and the like | |
| CN102960354A (en) | Chlorantraniliprole-lufenuron insecticidal composition | |
| CN106818798A (en) | A kind of compounded pesticides containing anabasine compound | |
| CN109938030A (en) | A kind of fluridone complex weedicide and preparation method thereof | |
| CN102754657A (en) | Indoxacarb and tebufenozide compound insecticidal composition | |
| CN104542615B (en) | A kind of compositionss preventing and kill off dodders in garden platymiscium, preparation and its application | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN105557739A (en) | Pest killing composition | |
| CN104604896B (en) | A kind of composition, preparation and its application for preventing and kill off semen cuscatue spp parasitic plant | |
| CN105325415A (en) | Insecticidal composition containing cyhalodiamide and dimehypo | |
| CN103053600B (en) | Insecticidal composition of indoxacarb and efficient cyfluthrin | |
| CN103404531A (en) | Biological compound insecticide containing toosedarin and imidacloprid and preparation method and application thereof | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN102696651A (en) | Spirodiclofen-containing compound pesticidal composition and preparation thereof | |
| CN103300037A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN102415408A (en) | Composite insecticidal composition containing dinotefuran and chlopyrifos and purpose thereof | |
| CN102415395A (en) | Composite pesticidal composition containing dinotefuran and imidacloprid and application of composite pesticidal composition | |
| CN106212463B (en) | A kind of composition pesticide containing propylene glycol alginate and methoxyfenozide | |
| CN101228873A (en) | Combination acarus-killing compound containing hexythiazox |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANDONG CHAMBROAD HOLDING CO., LTD. Free format text: FORMER OWNER: SHANDONG JINGBO HOLDING DEVELOPMENT CO., LTD. Effective date: 20110822 Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD AGROCHEMICAL CO., LTD. |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20110822 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Applicant after: SHANDONG CHAMBROAD HOLDING Co.,Ltd. Co-applicant after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Applicant before: SHANDONG JINGBO HOLDING DEVELOPMENT Co.,Ltd. Co-applicant before: Shandong Jingbo Agrochemicals Co.,Ltd. |
|
| ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Effective date: 20130426 Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD HOLDING CO., LTD. Effective date: 20130426 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20130426 Address after: 256500 Boxing Economic Development Zone, Binzhou, Shandong Applicant after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Applicant before: SHANDONG CHAMBROAD HOLDING Co.,Ltd. Applicant before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Address before: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |