CN101669488B - Binary complex pesticide composition containing chlorantraniliprole - Google Patents

Binary complex pesticide composition containing chlorantraniliprole Download PDF

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Publication number
CN101669488B
CN101669488B CN200910019508.5A CN200910019508A CN101669488B CN 101669488 B CN101669488 B CN 101669488B CN 200910019508 A CN200910019508 A CN 200910019508A CN 101669488 B CN101669488 B CN 101669488B
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rynaxypyr
parts
pesticide composition
chlorantraniliprole
binary complex
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CN200910019508.5A
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CN101669488A (en
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王成
史庆苓
郑亭路
郝春艳
宋妍
魏双勇
刘彦
邓晓杰
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京博农化科技股份有限公司
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Abstract

The invention relates to a binary complex pesticide composition containing chlorantraniliprole, which comprises active ingredients with the content of 3-80 percent by weight and chlorantraniliprole with the content accounting for 10-90 percent by weight of the active ingredients. Complex components mainly comprise emamectin benzoate or a bishydrazide type pesticide, and can be any possible preparation formulations. The binary complex pesticide composition containing chlorantraniliprole has high efficiency, low toxicity, low residuals, broad pesticidal spectrum, remarkable synergy, can markedly lower the use cost, can be processed into the preparation formulations containing suspending agents, wettable powder, granular formulations, water-dispersible granular formulations, missible oil, microemulsion and aqueous emulsion, is suitable for controlling multiple pests on vegetables and crops including cabbages, rice, brassicaceous vegetables, cotton, potatoes and the like, has remarkable action effect on multiple plant pests including asparagus caterpillars, cabbage butterflies, prodenia litura, striped rice borers, paddy borers, cotton bollworms, fall webworms and the like, and is particularly suitable for the production of green foods.

Description

Binary complex pesticide composition containing Rynaxypyr

One, technical field

The present invention relates to technical field of pesticide, relate to pesticide combination technology, particularly the compounded technology of Rynaxypyr.

Two, background technology

Rynaxypyr is a kind of efficient pesticides.The bromo-N-of chemical name: 3-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-base)-1-hydrogen-pyridine-5-formamide, molecular formula: C 18h 14n 5o 2brCl 2, relative molecular weight: 481, structural formula is:

Rynaxypyr is a kind of brand-new insecticide, and the chemical constitution due to Rynaxypyr has the brand-new desinsection principle that other any insecticides do not possess, and efficiently can activate insect ryania (muscle) acceptor.Calcium ion in excessive release cells in calcium storehouse, cause insect to be paralysed dead, high to the larva activity of lepidoptera pest, insecticidal spectrum is wide, lasting effect good.Very safe to crop under different temperature condition, to person poultry safety, low toxicity.

Three, summary of the invention

The object of the present invention is to provide a kind of take Rynaxypyr as a kind of insecticides of host component, reaches the object of synergy, wide spectrum, reduction use cost.

The object of the present invention is achieved like this, based on Rynaxypyr, carries out compositely obtaining having synergy, wide spectrum, binary built preparation that use cost is low with other pesticide.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, active ingredient weight percent content is 3% ~ 80%, and Rynaxypyr accounts for 10% ~ 90% of active ingredient.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the second component composite with Rynaxypyr is emamection benaoate.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the second component composite with Rynaxypyr is bishydrazide insecticide.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, the one that the bishydrazide insecticide composite with Rynaxypyr is selected from methoxyfenozide, worm hydrazides, chlorine worm hydrazides, furan tebufenozide combines.

The formulation of the binary complex pesticide composition containing Rynaxypyr that the present invention relates to is the one in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, water-dispersible granules.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, auxiliary element comprises acceptable organic solvent, emulsifier, surfactant, inert filler etc.

The present invention relates to containing the binary complex pesticide composition of Rynaxypyr, use solvent to comprise fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohol organic solvent, lipid organic solvent or organic solvent of ketone etc.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, use surfactant, comprise alkylbenzenesulfonate, lignin sulfonate, alkyl sulfate, Alkyl ethoxy carboxylate acid salt, phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, the anion surfactants such as sulfonate and formaldehyde condensation product, amine salt, quaternary amine, the cationic surfactants such as amine oxide, betain, imidazoline type, Amino acid, the amphoteric surfactantes such as phosphine ester, fatty alcohol ether, alkyl phenol ether, alkyl ether amine, the non-ionic surface active agents such as alkoxide such as polyethers, also has aliphatic alcohol ester, fatty acid alkane ester, alkylamide, the mixed surfactants such as alcohol ether type.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, other auxiliary element used also comprises xanthans, the thickeners such as sodium carboxymethyl starch, the antifreezing agents such as ethylene glycol, glycerine, urea; The fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium, and the acceptable stabilizing agent of other pesticidal preparations, safener, colouring agent etc.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, has efficiently, low toxicity, low-residual, insecticidal spectrum is wide, synergistic effect is remarkable, significantly can reduce use cost.

The binary complex pesticide composition containing Rynaxypyr that the present invention relates to, be used for preventing and treating the various pests on the vegetables such as wild cabbage, paddy rice, brassicaceous vegetable, cotton, potato and crop, remarkable to various plants insect action effects such as such as beet armyworm, cabbage caterpillar, prodenia litura, striped rice borer, paddy stem borer, cotton bollworm, fall webworm, be specially adapted to the production of pollution-free food.

Four, embodiment

Be further described, to contribute to understanding of the present invention, but not as the restriction to technical scheme inventing the technical scheme related to below in conjunction with embodiment.

Except mentioning especially, in embodiment use component ratio to be weight portion.

Embodiment one

20% Rynaxypyr methoxyfenozide suspending agent

Raw material consists of 4 parts of former medicines of Rynaxypyr, 16 parts of former medicines of methoxyfenozide, 1.2 parts are pulled open powder, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.3 parts of calcium dodecyl benzene sulfonates, 3 parts of triphenoethyl benzene phenol polyethenoxy ethers, 1.5 parts of white carbons, 0.15 part of xanthans, supplies 100 parts with water, suspending agent mode of production preparation routinely.

Toxicity test, rat (female/male) acute oral LD50 > 5000mg/kg, to the no skin irritation of rabbit, has no stimulation to the eyes of rabbit.Show that Recompounded pesticide belongs to low-toxin farm chemicals.

Using dosage: control Laphygma exigua Hubner, is watered dilution 1000 ~ 2000 times, spray medicine 3 ~ 7 days, successful, preventive effect more than 95%.

Rynaxypyr and methoxyfenozide are pressed 1/10 respectively, 1/8,1/4,1/1,4/1,8/1,10/1 ratio is composite, floats agent and contrasts, carry out the Toxicity Determination of Laphygma exigua Hubner with 20% Tebufenozide suspending agent and 5% Rynaxypyr, it is 141.58 ~ 198.82 that result shows the co-toxicity coefficient (Sun Yun abundant co-toxicity coefficient computational methods under same) of each medicament to beet armyworm, wherein the most obvious with 1/4 synergistic effect.

Embodiment two

3% Rynaxypyr emamectin benzoate microemulsion

Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of Methylaminoemamectin benzoate, 5 parts of N, N-dimethylformamide, 10 parts of cyclohexanone, 5 parts of acetone, 3 parts of phenethyl phenolformaldehyde resin APEOs, 2 parts of calcium dodecyl benzene sulfonates, 3 parts of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, supply 100 parts with water, prepare in the usual way.

Toxicity test, rat acute LD50 of passing through mouth > 1000mg/kg, chmice acute LD50 of passing through mouth LD50 > 1000mg/kg, rabbit is acute is greater than 1000mg/kg through skin LD50, rat acute is greater than 1000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.

Using dosage: control diamond-back moth, is watered dilution 1000 ~ 1500 times, spray medicine 2 ~ 5 days, successful, preventive effect more than 90%.

Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5, the ratio of 1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, result shows: each medicament is 185.43 ~ 223.74 to the co-toxicity coefficient of diamond-back moth.Show that there is significant synergistic effect, wherein the most outstanding with 2/1 effect.

Embodiment three

80% Rynaxypyr worm hydrazides wetting powder

Raw material consists of 9 parts of former medicines of Rynaxypyr, 72 parts of former medicines of worm hydrazides, and 14 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 2 parts of lauryl sodium sulfate, 5 parts of calcium lignosulfonates, supply 100 parts with ammonium sulfate.Prepare in the usual way.

Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.

Using dosage: control beet armyworm, is watered dilution 3000 ~ 5000 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 90%.

Former for Rynaxypyr medicine and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out the survey of beet armyworm indoor virulence, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 245.36.

Embodiment four

9% Rynaxypyr worm hydrazides missible oil

Raw material forms: 1 part of former medicine of Rynaxypyr, 8 parts of former medicines of worm hydrazides, 8 parts of N, N-dimethylformamide, 10 parts of methyl alcohol, 4 parts of calcium dodecyl benzene sulfonates, 4 parts of triphenoethyl benzene phenol polyethenoxy ethers, 3 parts of phenethyl phenolformaldehyde resin APEOs, supply 100 parts with toluene.Prepare in the usual way.

Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.

Using dosage: control beet armyworm, is watered dilution 1000 ~ 1500 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 90%.

Former for Rynaxypyr medicine and the former medicine of worm hydrazides are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 30% worm hydrazides wetting powder, carry out beet armyworm Toxicity Determination, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 238.56.

Embodiment five

60% Rynaxypyr chlorine worm hydrazides water-dispersible granules

Raw material forms: 10 parts of former medicines of Rynaxypyr, 50 parts of former medicines of chlorine worm hydrazides; 1 part of calcium dodecyl benzene sulfonate, 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of naphthalenesulfonate formaldehyde condensation compounds, 5 parts of calcium lignosulfonates, 5 parts of sodium carboxymethyl starches, supply 100 parts with ammonium sulfate, and extruder grain mode is prepared routinely.

Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 5000mg/kg through skin LD50, has no stimulation, has no stimulation to eye, show that compound drug belongs to low-toxin farm chemicals to skin.

Using dosage: control prodenia litura, is watered dilution 3000 ~ 5000 times, spray medicine 4-6 days, successful, preventive effect more than 90%.

Rynaxypyr and chlorine worm hydrazides are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5,1/10, the ratio of 1/20 is composite, contrast with 5% Rynaxypyr suspending agent and 20% chlorine Tebufenozide suspending agent, co-toxicity coefficient is 126.19 ~ 182.73, and wherein the proportioning medicament co-toxicity coefficient of 1/10 is the highest, and result shows to have significant synergies.

Embodiment six

30% Rynaxypyr emamectin benzoate granule

Raw material forms: 20 parts of former medicines of Rynaxypyr, 10 parts of emamection benaoates; 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 5 parts of sodium lignin sulfonates, 4 parts of calcium lignosulfonates, 2 parts of dodecyl sodium sulfates, 10 parts of ammonium sulfate, 8 parts of carboxyrnethyl starch sodiums, supply 100 parts with corn starch, and extruder grain mode is prepared routinely.

Toxicity test, rat acute LD50 of passing through mouth > 10000mg/kg, rabbit is acute is greater than 10000mg/kg through skin LD50, has no stimulation, has no stimulation to eye, show that compound drug belongs to low-toxin farm chemicals to skin.

Using dosage: control cotton bollworm, is watered dilution 3000 ~ 5000 times, spray medicine 3-5 days, successful, preventive effect more than 90%.

Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2, the ratio of 1/5,1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 5% emamectin-benzoate, co-toxicity coefficient is 164.32 ~ 212.45, and result shows to have significant synergies, wherein the most obvious with 2/1 synergistic effect.

Embodiment seven

3% Rynaxypyr emamectin-benzoate aqueous emulsion

Raw material consists of 2 parts of former medicines of Rynaxypyr, 1 part of Methylaminoemamectin benzoate, 7 parts of dimethylbenzene, 10 parts of cyclohexanone, 5 parts of acetone, 1 part of phenethyl phenolformaldehyde resin APEO, 0.3 part of calcium dodecyl benzene sulfonate, 1 part of alkylphenol polyoxyethylene, 3 parts of ethylene glycol, supply 100 parts with water, prepare in the usual way.

Toxicity test, rat acute LD50 of passing through mouth > 1000mg/kg, chmice acute LD50 of passing through mouth LD50 > 1000mg/kg, rabbit is acute is greater than 1000mg/kg through skin LD50, rat acute is greater than 1000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.

Using dosage: control diamond-back moth, is watered dilution 1000 ~ 1500 times, spray medicine 2 ~ 5 days, successful, preventive effect more than 90%.

Rynaxypyr and emamectin-benzoate are pressed 10/1 respectively, 5/1,2/1,1/1,1/2,1/5, the ratio of 1/10 is composite, contrast with 5% Rynaxypyr suspending agent and 2.2% emamectin benzoate microemulsion, carry out the Toxicity Determination of diamond-back moth, result shows: each medicament is 185.43 ~ 223.74 to the co-toxicity coefficient of diamond-back moth.Show that there is significant synergistic effect, wherein the most outstanding with 2/1 effect.

Embodiment eight

72% Rynaxypyr furan tebufenozide wetting powder

Raw material consists of 8 parts of former medicines of Rynaxypyr, 64 parts of former medicines of worm hydrazides, and 15 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts of lauryl sodium sulfate, 7 parts of calcium lignosulfonates, supply 100 parts with ammonium sulfate.Prepare in the usual way.

Toxicity test, rat acute LD50 of passing through mouth > 5000mg/kg, chmice acute LD50 of passing through mouth > 5000mg/kg, rabbit is acute is greater than 3000mg/kg through skin LD50, rat acute is greater than > 3000mg/kg through skin LD50, skin is had no stimulation, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.

Using dosage: control beet armyworm, is watered dilution 3000 ~ 5000 times, spray medicine 4 ~ 7 days, successful, preventive effect more than 92%.

Former for Rynaxypyr medicine and the former medicine of furan tebufenozide are pressed 10/1,8/1,5/1 respectively, 2/1,1/1,1/2,1/5, the ratio of 1/8,1/10 is composite, contrasts with 5% Rynaxypyr suspending agent and 60% furan tebufenozide wetting powder, carry out the survey of beet armyworm indoor virulence, result shows to have significant synergistic effect, and wherein the proportioning medicament synergy of 8/1 is the most obvious, co-toxicity coefficient 2837.57.

Claims (3)

1. the binary complex pesticide composition containing Rynaxypyr, is characterized in that: active ingredient weight percent content is 3%, and Rynaxypyr accounts for 2/3 of active ingredient; Second component is emamectin-benzoate.
2. the binary complex pesticide composition containing Rynaxypyr, is characterized in that: active ingredient weight percent content is 80%, and Rynaxypyr accounts for 8/9 of active ingredient; Second component is worm hydrazides.
3. claim 1 or 2 relate to any one contain the binary complex pesticide composition of Rynaxypyr, it is characterized in that: formulation is the one in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, water-dispersible granules.
CN200910019508.5A 2009-09-29 2009-09-29 Binary complex pesticide composition containing chlorantraniliprole CN101669488B (en)

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CN106614608A (en) * 2016-11-23 2017-05-10 盐城市大丰区小海镇农业技术推广综合服务中心 Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide

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CN103651428A (en) * 2011-05-17 2014-03-26 陕西韦尔奇作物保护有限公司 Insecticidal composition containing furan tebufenozide and antibiotic compound
CN102246762A (en) * 2011-05-23 2011-11-23 陕西韦尔奇作物保护有限公司 Insecticidal composition containing furan tebufenozide and amide compounds
CN102578161B (en) * 2012-01-18 2014-04-02 华南理工大学 Chlorantraniliprole and natural pyrethrin compound suspension and preparation method thereof
CN104604876B (en) * 2012-07-04 2016-12-07 陕西美邦农药有限公司 A kind of brominated worm Benzoylamide and the Pesticidal combination of bishydrazide
CN103518730B (en) * 2012-07-04 2015-08-19 陕西美邦农药有限公司 The Pesticidal combination of a kind of brominated worm benzamide and bishydrazide
CN105613509A (en) * 2014-10-30 2016-06-01 陕西美邦农药有限公司 Pesticidal composition containing ZJ3757
CN105724389A (en) * 2016-04-19 2016-07-06 陕西上格之路生物科学有限公司 Dispersible oil suspension containing chlorantraniliprole
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CN108174853A (en) * 2018-02-05 2018-06-19 广东真格生物科技有限公司 A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class

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