CN104782630A - Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide - Google Patents
Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide Download PDFInfo
- Publication number
- CN104782630A CN104782630A CN201510180709.9A CN201510180709A CN104782630A CN 104782630 A CN104782630 A CN 104782630A CN 201510180709 A CN201510180709 A CN 201510180709A CN 104782630 A CN104782630 A CN 104782630A
- Authority
- CN
- China
- Prior art keywords
- insecticide
- chlorantraniliprole
- diacylhydrazine
- bishydrazide
- methoxyfenozide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a mixed pesticide preparation comprising a diacylhydrazine insecticide. The mixed pesticide preparation comprises the following effective constituents: chlorantraniliprole and the diacylhydrazine insecticide, wherein the diacylhydrazine insecticide can be one of tebufenozide, methoxyfenozide, fufenozide, chromafenozide and halofenozide; the halofenozide accounts for 1-40% according to weight and the diacylhydrazine insecticide accounts for 1-60% according to weight; the mixed pesticide preparation can be prepared into an emulsifiable concentrate, a microemulsion, an emulsion in water, water-dispersible granules, wettable powder or a suspending agent. The pesticide composition has the advantages that a higher synergetic effect is realized; resistance development of the diacylhydrazine insecticide is delayed; the service life of the pesticide is prolonged, and a control effect on resistant lepidopteran pests is improved; compared with a diacylhydrazine insect growth regulator, the pesticide composition has the advantage that the fast-acting property is improved obviously.
Description
One, technical field
The present invention relates to be active ingredient a kind of composition pesticide and the application thereof of chlorantraniliprole and bishydrazide insecticide.
Two, background technology
The bromo-N-of chlorantraniliprole (chlorantraniliprole) chemical name 3-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-base)-1H-pyrazoles-5-formamide, trade name health wide (Ryanxypyr).It is a kind of Novel ortho formamido benzamide insecticides that du pont company develops, and belongs to insect ryanodine receptor inhibitor, shows insecticidal action mainly through the intracellular calcium ion release of induction insect ryanodine receptor regulation and control.Have and tag and stomach poison function, show the features such as efficient, wide spectrum, holding effect and the mechanism of action are novel, can be used for preventing and treating each Species of Lepidopterous Insect Pests, its control efficiency is obviously better than other commercialization insecticide variety used in current production, cross resistance is not existed to other insecticide, and to natural enemy insect safety, can be used for the various insects such as crop control beet armyworm, tomato moth, diamond-back moth, imported cabbageworm, cotton bollworm such as vegetables, beet, cotton, have good control efficiency to each instar larvae.But this medicament is not very good to the control efficiency of rice leaf roller, striped rice borer, paddy stem borer because of resistance problem.Chlorantraniliprole is as efficient pesticides of new generation, and due to complex synthetic route, high in cost of production reason greatly limit it and promotes the use of.Based on the unique features of chlorantraniliprole on agricultural insect pests control, the scientists of pesticides application and field of pest control carries out the composition research of this insecticide and other insecticide, to expand insecticidal spectrum, improve drug effect and reduce resistance risk, the composition pesticide especially with synergistic effect also can obviously reduce agricultural cost.
Bishydrazide insect growth regulator, IGR is a class high-efficiency low-toxicity, selectivity is strong, to environment-friendly insecticide, its commercial varieties comprises worm hydrazides, methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides, furan tebufenozide etc.This insecticides is mainly through the moulting hormone 20-hydroxyecdysone as moulting hormone antagonist or simulation insect, and cause insect to cast off a skin in advance, cause casting off a skin and can not complete, insect can not continue to take food, dead after several days.This type of selectivity is strong, has good control efficiency to lepidoptera pests such as cotton bollworm, cabbage caterpillar, diamond-back moths, safe for human and animal and environment, is applicable to prevent and treat the Lepidoptera class pest on the crops such as vegetables, fruit tree, tea tree, ornamental plants and paddy rice.But this insecticides has quick-acting difference, be used alone insect and easily produce the shortcomings such as resistance.This limits bishydrazide utilization of pesticides to a certain extent, affects the general control to insect, especially poor to explosive pest controling effect.
Research and development composition pesticide is about to two kinds of different structures, the composition of the different mechanism of action carries out to be the focus of agriculture and forestry sustainable development, to reduce especially, delay pest resistance, improve the effective way of drug effect and protecting ecology composite.Up to now still less than the relevant report of the composition pesticide about chlorantraniliprole and bishydrazide insecticide.
Three, summary of the invention
1, goal of the invention
The object of the invention is to provide a kind of mixed insecticide preparation containing bishydrazide insecticide, is the mixed insecticide preparation that is main active with chlorantraniliprole and bishydrazide insect growth regulator, IGR.
2, technical scheme
The technical scheme that the present invention solves the problems of the technologies described above is as follows:
A kind of containing bishydrazide insecticide mixture pesticidal preparations, active ingredient is chlorantraniliprole and bishydrazide insecticide, chlorantraniliprole by weight 1 ~ 40%, bishydrazide insecticide by weight 1 ~ 60%, and all the other are auxiliary agents, and each component total amount is 100%; Wherein bishydrazide insecticide can be one of worm hydrazides, methoxyfenozide, furan tebufenozide, ring worm hydrazides, chlorine worm hydrazides.
Above-mentioned one contains bishydrazide insecticide mixture pesticidal preparations, can be made into missible oil, microemulsion, aqueous emulsion, water dispersible granules, wetting powder or suspending agent.
In order to make technical solution of the present invention more short and sweet, the following concrete preparation embodiment of the present invention is described, but the present invention is only limitted to absolutely not these prepares embodiment.The following stated is only the present invention and prepares embodiment preferably, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.Described in preparation embodiment, content is all weight percentage.
Preparation embodiment 1: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 10% chlorantraniliprole methoxyfenozide microemulsion, each components by weight is:
Chlorantraniliprole is 4%,
Methoxyfenozide is 6%,
Methyl alcohol is 10%,
Phenethyl phenol polyethenoxy ether is 2%,
Water is 78%.
Preparation embodiment 2: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 15% chlorantraniliprole furan tebufenozide aqueous emulsion, each composition weight proportioning is:
Chlorantraniliprole is 5%,
Furan tebufenozide is 10%,
Cyclohexanone is 10%,
Methyl alcohol is 10%,
Oleic acid polyoxyethylene groups ester is 5%,
Dimethyl silicone polymer is 1%,
Water is 59%.
Preparation embodiment 3: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 20% chlorantraniliprole chlorine worm hydrazides water dispersible granules, each composition weight proportioning is:
Chlorantraniliprole is 5%,
Chlorine worm hydrazides is 15%,
Sodium lignin sulfonate is 4%,
Dodecyl sodium sulfate is 2%,
Ammonium sulfate is 4%,
Bentonite is 70%.
Preparation embodiment 4: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole worm hydrazides missible oil, each composition weight proportioning is:
Chlorantraniliprole is 5%,
Worm hydrazides is 25%,
Calcium dodecyl benzene sulfonate is 5%,
Phenethyl phenol polyethenoxy ether is 5%,
Dimethylbenzene is 60%.
Preparation embodiment 5: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole chlorine worm hydrazides wetting powder, each composition weight proportioning is:
Chlorantraniliprole is 10%,
Chlorine worm hydrazides is 20%,
Dodecyl sodium sulfate is 2%,
Sodium lignin sulfonate is 3%,
Kaolin is 65%.
Preparation embodiment 6: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole Tebufenozide suspending agent, each composition weight proportioning is:
Chlorantraniliprole is 8%,
Worm hydrazides is 22%,
Sodium lignin sulfonate is 6%,
Methyl naphthalene sulfonate formaldehyde condensate is 2%,
Xanthans is 1%,
Glycerine is 3%.
Water is 58%.
Preparation embodiment 7: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 10% chlorantraniliprole ring worm hydrazides missible oil, each composition weight proportioning is:
Chlorantraniliprole is 4%,
Ring worm hydrazides is 6%,
Dimethyl formamide is 5%,
Dodecyl sodium sulfonate calcium is 5%,
Dimethylbenzene 80%.
3, beneficial effect
Mixed insecticide preparation of the present invention beneficial effect compared with prior art:
1. because two kinds of pharmacy effect mechanism are different, the application of composition contributes to the resistance development delaying bishydrazide insect growth regulator, IGR, extends the service life of medicament;
2. after mixture, significantly improve the control efficiency to the lepidoptera pest producing resistance, in particular improve the control efficiency of the rice leaf roller to single dose chlorantraniliprole generation resistance, striped rice borer, paddy stem borer.
3., compared with single dose bishydrazide insect growth regulator, IGR pesticide species, quick-acting is significantly improved.
Four, embodiment
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage.On this basis, then carry out field trial.
In order to make object of the present invention, formulation prepares scheme, mixture pharmacodynamic results and advantage are clearly understood, the present invention is described with following specific embodiment further, but the present invention is limited to absolutely not these examples.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.
Test medicine is developed by TanJin Agricultural College basic science institute and only for for the present invention.Contrast medicament: 10% chlorantraniliprole suspending agent (autogamy), 5% methoxyfenozide missible oil (commercial).
Toxicity Determination embodiment one,
Toxicity Determination test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, the blade of the same size not contacting any medicament soaked in the liquid configured taking-up afterwards in 5 seconds, naturally dry, put into insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process repetition 3 times, often repeating examination borer population used is 50, establishes blank simultaneously.If contrast lethality is greater than 10%, be then considered as invalid test.Be disposed and be placed in observation ward, make regular check on record examination worm situation anyway, calculate lethality and lethal concentration of 50 LC
50value.The co-toxicity coefficient (CTC) that synergy evaluation adopts Sun & Johnson (1960) to propose is weighed.Usually, when co-toxicity coefficient is obviously greater than 100, represent that there is synergistic effect, co-toxicity coefficient close to 100 time represent that there is summation action, spend together when coefficient is significantly less than 100 and be expressed as antagonism.
Chlorantraniliprole and the toxicity test of methoxyfenozide mixture to mythimna separata (Mythimna separate) and rice leaf roller (Cnaphalocrocis medinalis) the results are shown in Table 1.Visible chlorantraniliprole and methoxyfenozide all show as obvious synergistic effect with the ratio mixture of 1: 1,1: 10,1: 20,1: 50,1: 80,1: 100,100: 1,80: 1,50: 1,20: 1,10: 1 to mythimna separata and rice leaf roller, and its co-toxicity coefficient is all obviously greater than 100.
Table 1 chlorantraniliprole and methoxyfenozide mixture are to the Toxicity Determination result (72h) of mythimna separata and rice leaf roller
Field control effectiveness test embodiment two: 10% chlorantraniliprole methoxyfenozide microemulsion
Chlorantraniliprole 4 grams, methoxyfenozide 6 grams, methyl alcohol 10 grams, phenethyl phenol polyethenoxy ether 2 grams, water complement to 100 grams.Former medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase, under high velocity agitation, oil phase is mixed with water, obtained 10% chlorantraniliprole methoxyfenozide microemulsion.
Field control effectiveness test: the present embodiment mixed agent is by following concentration spraying control wild cabbage diamond-back moth, and test site is positioned at Linyi County, Shanxi Province, and the time is in April, 2014, in Eggs of Diamondback Moth hatching Sheng phase dispenser, adopts spray-on process.Investigation wild cabbage diamond-back moth insect index before medicine, 1 day, 3 days, 5 days investigation insect pest indexes after dispenser also calculate preventive effect.Control efficiency is in table 2.
Table 2 chlorantraniliprole and methoxyfenozide mixture prevent and treat wild cabbage diamond-back moth field control effectiveness test result
From table 2, after built agent medicine, 1 day preventive effect is far away higher than methoxyfenozide single dose, illustrates that composite rear quick-acting significantly improves; After built agent medicine, preventive effect exceeds chlorantraniliprole and methoxyfenozide single dose more than 10%, illustrate composite after have building performance; And the consumption of chlorantraniliprole is less than single dose chlorantraniliprole in built agent, illustrate that built agent can reduce the field rate of chlorantraniliprole.The overall preventive effect of built agent, apparently higher than methoxyfenozide, illustrates that built agent can prevent and treat insect methoxyfenozide being produced to resistance well.
Embodiment three, 10% chlorantraniliprole methoxyfenozide missible oil
Chlorantraniliprole 4 grams, methoxyfenozide 6 grams, dimethyl formamide 5 grams, dodecyl sodium sulfonate calcium 5 grams, dimethylbenzene complement to 100 grams.Active component, emulsifier and the soluble additive ratio in formula is added in mixing kettle successively, stirs, obtained 10% chlorantraniliprole methoxyfenozide missible oil.
Embodiment four, 20% chlorantraniliprole methoxyfenozide suspending agent
Chlorantraniliprole 8 grams, methoxyfenozide 12 grams, sodium lignin sulfonate 6 grams, methyl naphthalene sulfonate formaldehyde condensate 2 grams, xanthans 1 gram, glycerine 3 grams, water complement to 100 grams.The ratio of each components such as active component, dispersant, wetting agent and water in formula is mixed, obtains 20% chlorantraniliprole methoxyfenozide suspending agent through grinding.
Embodiment five, 30% chlorantraniliprole methoxyfenozide wetting powder
Chlorantraniliprole 10 grams, methoxyfenozide 20 grams, dodecyl sodium sulfate 2 grams, sodium lignin sulfonate 3 grams, kaolin complement to 100 grams.The ratio in formula such as active component, various auxiliary agent and filler is fully mixed, after ultra-fine pulverizer disintegrating, obtains 30% chlorantraniliprole methoxyfenozide wetting powder.
Embodiment six, 20% chlorantraniliprole methoxyfenozide water dispersible granules
Chlorantraniliprole 5 grams, methoxyfenozide 15 grams, dodecyl sodium sulfate 2 grams, sodium lignin sulfonate 4 grams, ammonium sulfate are 4 grams, bentonite complements to 100 grams.Active component, dispersant, wetting agent, disintegrant and filler are mixed by formula rate, wetting powder is become through air-flow crushing, add a certain amount of water mixing extruder grain again, after drying screening, obtain 20% chlorantraniliprole methoxyfenozide water dispersible granules.
Claims (4)
1. the mixed insecticide preparation containing bishydrazide insecticide, it is characterized in that, active ingredient is chlorantraniliprole and bishydrazide insecticide, chlorantraniliprole by weight 1 ~ 40%, bishydrazide insecticide by weight 1 ~ 60%, all the other are auxiliary agents, and each component total amount is 100%.
2. Pesticidal combination according to claim 1, wherein bishydrazide insecticide is one of worm hydrazides, methoxyfenozide, furan tebufenozide, ring worm hydrazides, chlorine worm hydrazides.
3. a kind of mixed insecticide preparation containing bishydrazide insecticide according to claim 1, is characterized in that making missible oil, microemulsion, aqueous emulsion, water dispersible granules, wetting powder or suspending agent.
4. the purposes of Pesticidal combination according to right 1,2 and 3, is characterized in that having synergistic effect to the virulence of insect; Can effectively prevent and treat the pest, the particularly control of antagonism insect diamond-back moth such as aleyrodid, liriomyza bryoniae, thrips, beet armyworm, striped flea-beetle, aphid, diamond-back moth, prodenia litura, cabbage caterpillar, apple leaf miner, peach fruit borer, rice leaf roller, striped rice borer, paddy stem borer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510180709.9A CN104782630A (en) | 2015-04-15 | 2015-04-15 | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510180709.9A CN104782630A (en) | 2015-04-15 | 2015-04-15 | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104782630A true CN104782630A (en) | 2015-07-22 |
Family
ID=53548187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510180709.9A Pending CN104782630A (en) | 2015-04-15 | 2015-04-15 | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104782630A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN106614608A (en) * | 2016-11-23 | 2017-05-10 | 盐城市大丰区小海镇农业技术推广综合服务中心 | Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide |
| CN106889067A (en) * | 2017-02-27 | 2017-06-27 | 南京华洲药业有限公司 | A kind of compound pesticide compositions of containing chromafenozide and chlorine tebufenozide and application thereof |
| CN108174853A (en) * | 2018-02-05 | 2018-06-19 | 广东真格生物科技有限公司 | A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class |
| CN108378034A (en) * | 2018-05-08 | 2018-08-10 | 江西正邦生物化工有限责任公司 | A kind of Pesticidal combination containing bromine worm fluorobenzene bisamide and furan tebufenozide |
| CN109845740A (en) * | 2019-01-22 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination of fluorine-containing chlorine worm bisamide and bishydrazide insecticide |
| EP3634131A4 (en) * | 2017-06-09 | 2021-03-10 | UPL Ltd | Novel pesticidal combinations |
-
2015
- 2015-04-15 CN CN201510180709.9A patent/CN104782630A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN105685051A (en) * | 2016-04-20 | 2016-06-22 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension agent with methoxyfenozide |
| CN106614608A (en) * | 2016-11-23 | 2017-05-10 | 盐城市大丰区小海镇农业技术推广综合服务中心 | Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide |
| CN106889067A (en) * | 2017-02-27 | 2017-06-27 | 南京华洲药业有限公司 | A kind of compound pesticide compositions of containing chromafenozide and chlorine tebufenozide and application thereof |
| EP3634131A4 (en) * | 2017-06-09 | 2021-03-10 | UPL Ltd | Novel pesticidal combinations |
| CN108174853A (en) * | 2018-02-05 | 2018-06-19 | 广东真格生物科技有限公司 | A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class |
| CN108378034A (en) * | 2018-05-08 | 2018-08-10 | 江西正邦生物化工有限责任公司 | A kind of Pesticidal combination containing bromine worm fluorobenzene bisamide and furan tebufenozide |
| CN109845740A (en) * | 2019-01-22 | 2019-06-07 | 海利尔药业集团股份有限公司 | A kind of Pesticidal combination of fluorine-containing chlorine worm bisamide and bishydrazide insecticide |
| CN109845740B (en) * | 2019-01-22 | 2024-01-30 | 海利尔药业集团股份有限公司 | Insecticidal composition containing flucloxapyroxad and bishydrazide insecticide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104782630A (en) | Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide | |
| CN101669488B (en) | Binary complex pesticide composition containing chlorantraniliprole | |
| CN101836641B (en) | Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate | |
| CN103300000A (en) | Insecticidal composition containing chromafenozide and amide | |
| CN103355319A (en) | Insecticidal composition containing pyridalyl and biological source | |
| CN102084862B (en) | Insecticidal composition containing ethiprole | |
| CN104705329A (en) | Pesticide composition of chlorantraniliprole and benzoyl urea insecticides | |
| CN101406192A (en) | Compositional acaricide and uses thereof | |
| CN101385461A (en) | Compound pesticide for preventing and treating ricestem borer, rice leaf roller | |
| CN102415401A (en) | Synergistic insecticidal composition containing dinotefuran and acetamiprid and application thereof | |
| CN102415398A (en) | Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof | |
| CN103098816A (en) | Indoxacarb and spinetoram insecticidal composition | |
| CN102696651B (en) | Spirodiclofen-containing compound pesticidal composition and preparation thereof | |
| CN105028461A (en) | Insecticidal composition containing diflubenzuron and deltamethrin and application thereof | |
| CN103053600B (en) | Insecticidal composition of indoxacarb and efficient cyfluthrin | |
| CN106561657A (en) | Insecticide composite containing celastrus angulatus and spinetoram | |
| CN103300006A (en) | Chromafenozide-containing insecticidal composition | |
| CN103355320A (en) | Efficient environment-friendly pesticide compound composition | |
| CN102415396A (en) | Compound insecticidal composition containing dinotefuran and carbosulfan and purpose thereof | |
| CN103300037A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN103053585A (en) | Synergistic insecticidal composition containing dinotefuran and clothianidin, and application thereof | |
| CN102047906A (en) | Chlorantraniliprole and profenofos compound pesticide | |
| CN102017948A (en) | Synergistic pesticide combination containing nitenpyram and pyridalyl and application of combination | |
| CN104522007B (en) | A kind of Pesticidal combination for preventing and treating lepidoptera pest | |
| CN105475339A (en) | Synergistic insecticidal composition containing propargite and cycloprothrin and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150722 |
|
| WD01 | Invention patent application deemed withdrawn after publication |