CN104782630A - Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide - Google Patents

Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide Download PDF

Info

Publication number
CN104782630A
CN104782630A CN201510180709.9A CN201510180709A CN104782630A CN 104782630 A CN104782630 A CN 104782630A CN 201510180709 A CN201510180709 A CN 201510180709A CN 104782630 A CN104782630 A CN 104782630A
Authority
CN
China
Prior art keywords
insecticide
chlorantraniliprole
diacylhydrazine
bishydrazide
methoxyfenozide
Prior art date
Application number
CN201510180709.9A
Other languages
Chinese (zh)
Inventor
赵毓
黄治强
童军
王丹婷
张婧
Original Assignee
南开大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 南开大学 filed Critical 南开大学
Priority to CN201510180709.9A priority Critical patent/CN104782630A/en
Publication of CN104782630A publication Critical patent/CN104782630A/en

Links

Abstract

The invention relates to a mixed pesticide preparation comprising a diacylhydrazine insecticide. The mixed pesticide preparation comprises the following effective constituents: chlorantraniliprole and the diacylhydrazine insecticide, wherein the diacylhydrazine insecticide can be one of tebufenozide, methoxyfenozide, fufenozide, chromafenozide and halofenozide; the halofenozide accounts for 1-40% according to weight and the diacylhydrazine insecticide accounts for 1-60% according to weight; the mixed pesticide preparation can be prepared into an emulsifiable concentrate, a microemulsion, an emulsion in water, water-dispersible granules, wettable powder or a suspending agent. The pesticide composition has the advantages that a higher synergetic effect is realized; resistance development of the diacylhydrazine insecticide is delayed; the service life of the pesticide is prolonged, and a control effect on resistant lepidopteran pests is improved; compared with a diacylhydrazine insect growth regulator, the pesticide composition has the advantage that the fast-acting property is improved obviously.

Description

The composition pesticide of chlorantraniliprole and bishydrazide insecticide

One, technical field

The present invention relates to be active ingredient a kind of composition pesticide and the application thereof of chlorantraniliprole and bishydrazide insecticide.

Two, background technology

The bromo-N-of chlorantraniliprole (chlorantraniliprole) chemical name 3-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-base)-1H-pyrazoles-5-formamide, trade name health wide (Ryanxypyr).It is a kind of Novel ortho formamido benzamide insecticides that du pont company develops, and belongs to insect ryanodine receptor inhibitor, shows insecticidal action mainly through the intracellular calcium ion release of induction insect ryanodine receptor regulation and control.Have and tag and stomach poison function, show the features such as efficient, wide spectrum, holding effect and the mechanism of action are novel, can be used for preventing and treating each Species of Lepidopterous Insect Pests, its control efficiency is obviously better than other commercialization insecticide variety used in current production, cross resistance is not existed to other insecticide, and to natural enemy insect safety, can be used for the various insects such as crop control beet armyworm, tomato moth, diamond-back moth, imported cabbageworm, cotton bollworm such as vegetables, beet, cotton, have good control efficiency to each instar larvae.But this medicament is not very good to the control efficiency of rice leaf roller, striped rice borer, paddy stem borer because of resistance problem.Chlorantraniliprole is as efficient pesticides of new generation, and due to complex synthetic route, high in cost of production reason greatly limit it and promotes the use of.Based on the unique features of chlorantraniliprole on agricultural insect pests control, the scientists of pesticides application and field of pest control carries out the composition research of this insecticide and other insecticide, to expand insecticidal spectrum, improve drug effect and reduce resistance risk, the composition pesticide especially with synergistic effect also can obviously reduce agricultural cost.

Bishydrazide insect growth regulator, IGR is a class high-efficiency low-toxicity, selectivity is strong, to environment-friendly insecticide, its commercial varieties comprises worm hydrazides, methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides, furan tebufenozide etc.This insecticides is mainly through the moulting hormone 20-hydroxyecdysone as moulting hormone antagonist or simulation insect, and cause insect to cast off a skin in advance, cause casting off a skin and can not complete, insect can not continue to take food, dead after several days.This type of selectivity is strong, has good control efficiency to lepidoptera pests such as cotton bollworm, cabbage caterpillar, diamond-back moths, safe for human and animal and environment, is applicable to prevent and treat the Lepidoptera class pest on the crops such as vegetables, fruit tree, tea tree, ornamental plants and paddy rice.But this insecticides has quick-acting difference, be used alone insect and easily produce the shortcomings such as resistance.This limits bishydrazide utilization of pesticides to a certain extent, affects the general control to insect, especially poor to explosive pest controling effect.

Research and development composition pesticide is about to two kinds of different structures, the composition of the different mechanism of action carries out to be the focus of agriculture and forestry sustainable development, to reduce especially, delay pest resistance, improve the effective way of drug effect and protecting ecology composite.Up to now still less than the relevant report of the composition pesticide about chlorantraniliprole and bishydrazide insecticide.

Three, summary of the invention

1, goal of the invention

The object of the invention is to provide a kind of mixed insecticide preparation containing bishydrazide insecticide, is the mixed insecticide preparation that is main active with chlorantraniliprole and bishydrazide insect growth regulator, IGR.

2, technical scheme

The technical scheme that the present invention solves the problems of the technologies described above is as follows:

A kind of containing bishydrazide insecticide mixture pesticidal preparations, active ingredient is chlorantraniliprole and bishydrazide insecticide, chlorantraniliprole by weight 1 ~ 40%, bishydrazide insecticide by weight 1 ~ 60%, and all the other are auxiliary agents, and each component total amount is 100%; Wherein bishydrazide insecticide can be one of worm hydrazides, methoxyfenozide, furan tebufenozide, ring worm hydrazides, chlorine worm hydrazides.

Above-mentioned one contains bishydrazide insecticide mixture pesticidal preparations, can be made into missible oil, microemulsion, aqueous emulsion, water dispersible granules, wetting powder or suspending agent.

In order to make technical solution of the present invention more short and sweet, the following concrete preparation embodiment of the present invention is described, but the present invention is only limitted to absolutely not these prepares embodiment.The following stated is only the present invention and prepares embodiment preferably, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.Described in preparation embodiment, content is all weight percentage.

Preparation embodiment 1: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 10% chlorantraniliprole methoxyfenozide microemulsion, each components by weight is:

Chlorantraniliprole is 4%,

Methoxyfenozide is 6%,

Methyl alcohol is 10%,

Phenethyl phenol polyethenoxy ether is 2%,

Water is 78%.

Preparation embodiment 2: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 15% chlorantraniliprole furan tebufenozide aqueous emulsion, each composition weight proportioning is:

Chlorantraniliprole is 5%,

Furan tebufenozide is 10%,

Cyclohexanone is 10%,

Methyl alcohol is 10%,

Oleic acid polyoxyethylene groups ester is 5%,

Dimethyl silicone polymer is 1%,

Water is 59%.

Preparation embodiment 3: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 20% chlorantraniliprole chlorine worm hydrazides water dispersible granules, each composition weight proportioning is:

Chlorantraniliprole is 5%,

Chlorine worm hydrazides is 15%,

Sodium lignin sulfonate is 4%,

Dodecyl sodium sulfate is 2%,

Ammonium sulfate is 4%,

Bentonite is 70%.

Preparation embodiment 4: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole worm hydrazides missible oil, each composition weight proportioning is:

Chlorantraniliprole is 5%,

Worm hydrazides is 25%,

Calcium dodecyl benzene sulfonate is 5%,

Phenethyl phenol polyethenoxy ether is 5%,

Dimethylbenzene is 60%.

Preparation embodiment 5: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole chlorine worm hydrazides wetting powder, each composition weight proportioning is:

Chlorantraniliprole is 10%,

Chlorine worm hydrazides is 20%,

Dodecyl sodium sulfate is 2%,

Sodium lignin sulfonate is 3%,

Kaolin is 65%.

Preparation embodiment 6: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 30% chlorantraniliprole Tebufenozide suspending agent, each composition weight proportioning is:

Chlorantraniliprole is 8%,

Worm hydrazides is 22%,

Sodium lignin sulfonate is 6%,

Methyl naphthalene sulfonate formaldehyde condensate is 2%,

Xanthans is 1%,

Glycerine is 3%.

Water is 58%.

Preparation embodiment 7: above-mentioned a kind of mixed insecticide preparation containing bishydrazide insecticide, make 10% chlorantraniliprole ring worm hydrazides missible oil, each composition weight proportioning is:

Chlorantraniliprole is 4%,

Ring worm hydrazides is 6%,

Dimethyl formamide is 5%,

Dodecyl sodium sulfonate calcium is 5%,

Dimethylbenzene 80%.

3, beneficial effect

Mixed insecticide preparation of the present invention beneficial effect compared with prior art:

1. because two kinds of pharmacy effect mechanism are different, the application of composition contributes to the resistance development delaying bishydrazide insect growth regulator, IGR, extends the service life of medicament;

2. after mixture, significantly improve the control efficiency to the lepidoptera pest producing resistance, in particular improve the control efficiency of the rice leaf roller to single dose chlorantraniliprole generation resistance, striped rice borer, paddy stem borer.

3., compared with single dose bishydrazide insect growth regulator, IGR pesticide species, quick-acting is significantly improved.

Four, embodiment

The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage.On this basis, then carry out field trial.

In order to make object of the present invention, formulation prepares scheme, mixture pharmacodynamic results and advantage are clearly understood, the present invention is described with following specific embodiment further, but the present invention is limited to absolutely not these examples.If no special instructions, the ratio (comprising percentage) below mentioned is all mass ratio.

Test medicine is developed by TanJin Agricultural College basic science institute and only for for the present invention.Contrast medicament: 10% chlorantraniliprole suspending agent (autogamy), 5% methoxyfenozide missible oil (commercial).

Toxicity Determination embodiment one,

Toxicity Determination test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, the blade of the same size not contacting any medicament soaked in the liquid configured taking-up afterwards in 5 seconds, naturally dry, put into insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process repetition 3 times, often repeating examination borer population used is 50, establishes blank simultaneously.If contrast lethality is greater than 10%, be then considered as invalid test.Be disposed and be placed in observation ward, make regular check on record examination worm situation anyway, calculate lethality and lethal concentration of 50 LC 50value.The co-toxicity coefficient (CTC) that synergy evaluation adopts Sun & Johnson (1960) to propose is weighed.Usually, when co-toxicity coefficient is obviously greater than 100, represent that there is synergistic effect, co-toxicity coefficient close to 100 time represent that there is summation action, spend together when coefficient is significantly less than 100 and be expressed as antagonism.

Chlorantraniliprole and the toxicity test of methoxyfenozide mixture to mythimna separata (Mythimna separate) and rice leaf roller (Cnaphalocrocis medinalis) the results are shown in Table 1.Visible chlorantraniliprole and methoxyfenozide all show as obvious synergistic effect with the ratio mixture of 1: 1,1: 10,1: 20,1: 50,1: 80,1: 100,100: 1,80: 1,50: 1,20: 1,10: 1 to mythimna separata and rice leaf roller, and its co-toxicity coefficient is all obviously greater than 100.

Table 1 chlorantraniliprole and methoxyfenozide mixture are to the Toxicity Determination result (72h) of mythimna separata and rice leaf roller

Field control effectiveness test embodiment two: 10% chlorantraniliprole methoxyfenozide microemulsion

Chlorantraniliprole 4 grams, methoxyfenozide 6 grams, methyl alcohol 10 grams, phenethyl phenol polyethenoxy ether 2 grams, water complement to 100 grams.Former medicine, solvent, emulsifier are added together, make to be dissolved into homogeneous oil phase, under high velocity agitation, oil phase is mixed with water, obtained 10% chlorantraniliprole methoxyfenozide microemulsion.

Field control effectiveness test: the present embodiment mixed agent is by following concentration spraying control wild cabbage diamond-back moth, and test site is positioned at Linyi County, Shanxi Province, and the time is in April, 2014, in Eggs of Diamondback Moth hatching Sheng phase dispenser, adopts spray-on process.Investigation wild cabbage diamond-back moth insect index before medicine, 1 day, 3 days, 5 days investigation insect pest indexes after dispenser also calculate preventive effect.Control efficiency is in table 2.

Table 2 chlorantraniliprole and methoxyfenozide mixture prevent and treat wild cabbage diamond-back moth field control effectiveness test result

From table 2, after built agent medicine, 1 day preventive effect is far away higher than methoxyfenozide single dose, illustrates that composite rear quick-acting significantly improves; After built agent medicine, preventive effect exceeds chlorantraniliprole and methoxyfenozide single dose more than 10%, illustrate composite after have building performance; And the consumption of chlorantraniliprole is less than single dose chlorantraniliprole in built agent, illustrate that built agent can reduce the field rate of chlorantraniliprole.The overall preventive effect of built agent, apparently higher than methoxyfenozide, illustrates that built agent can prevent and treat insect methoxyfenozide being produced to resistance well.

Embodiment three, 10% chlorantraniliprole methoxyfenozide missible oil

Chlorantraniliprole 4 grams, methoxyfenozide 6 grams, dimethyl formamide 5 grams, dodecyl sodium sulfonate calcium 5 grams, dimethylbenzene complement to 100 grams.Active component, emulsifier and the soluble additive ratio in formula is added in mixing kettle successively, stirs, obtained 10% chlorantraniliprole methoxyfenozide missible oil.

Embodiment four, 20% chlorantraniliprole methoxyfenozide suspending agent

Chlorantraniliprole 8 grams, methoxyfenozide 12 grams, sodium lignin sulfonate 6 grams, methyl naphthalene sulfonate formaldehyde condensate 2 grams, xanthans 1 gram, glycerine 3 grams, water complement to 100 grams.The ratio of each components such as active component, dispersant, wetting agent and water in formula is mixed, obtains 20% chlorantraniliprole methoxyfenozide suspending agent through grinding.

Embodiment five, 30% chlorantraniliprole methoxyfenozide wetting powder

Chlorantraniliprole 10 grams, methoxyfenozide 20 grams, dodecyl sodium sulfate 2 grams, sodium lignin sulfonate 3 grams, kaolin complement to 100 grams.The ratio in formula such as active component, various auxiliary agent and filler is fully mixed, after ultra-fine pulverizer disintegrating, obtains 30% chlorantraniliprole methoxyfenozide wetting powder.

Embodiment six, 20% chlorantraniliprole methoxyfenozide water dispersible granules

Chlorantraniliprole 5 grams, methoxyfenozide 15 grams, dodecyl sodium sulfate 2 grams, sodium lignin sulfonate 4 grams, ammonium sulfate are 4 grams, bentonite complements to 100 grams.Active component, dispersant, wetting agent, disintegrant and filler are mixed by formula rate, wetting powder is become through air-flow crushing, add a certain amount of water mixing extruder grain again, after drying screening, obtain 20% chlorantraniliprole methoxyfenozide water dispersible granules.

Claims (4)

1. the mixed insecticide preparation containing bishydrazide insecticide, it is characterized in that, active ingredient is chlorantraniliprole and bishydrazide insecticide, chlorantraniliprole by weight 1 ~ 40%, bishydrazide insecticide by weight 1 ~ 60%, all the other are auxiliary agents, and each component total amount is 100%.
2. Pesticidal combination according to claim 1, wherein bishydrazide insecticide is one of worm hydrazides, methoxyfenozide, furan tebufenozide, ring worm hydrazides, chlorine worm hydrazides.
3. a kind of mixed insecticide preparation containing bishydrazide insecticide according to claim 1, is characterized in that making missible oil, microemulsion, aqueous emulsion, water dispersible granules, wetting powder or suspending agent.
4. the purposes of Pesticidal combination according to right 1,2 and 3, is characterized in that having synergistic effect to the virulence of insect; Can effectively prevent and treat the pest, the particularly control of antagonism insect diamond-back moth such as aleyrodid, liriomyza bryoniae, thrips, beet armyworm, striped flea-beetle, aphid, diamond-back moth, prodenia litura, cabbage caterpillar, apple leaf miner, peach fruit borer, rice leaf roller, striped rice borer, paddy stem borer.
CN201510180709.9A 2015-04-15 2015-04-15 Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide CN104782630A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510180709.9A CN104782630A (en) 2015-04-15 2015-04-15 Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510180709.9A CN104782630A (en) 2015-04-15 2015-04-15 Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide

Publications (1)

Publication Number Publication Date
CN104782630A true CN104782630A (en) 2015-07-22

Family

ID=53548187

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510180709.9A CN104782630A (en) 2015-04-15 2015-04-15 Pesticide composition comprising chlorantraniliprole and diacylhydrazine insecticide

Country Status (1)

Country Link
CN (1) CN104782630A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105685051A (en) * 2016-04-20 2016-06-22 陕西上格之路生物科学有限公司 Dispersible oil suspension agent with methoxyfenozide
CN105724389A (en) * 2016-04-19 2016-07-06 陕西上格之路生物科学有限公司 Dispersible oil suspension containing chlorantraniliprole
CN106614608A (en) * 2016-11-23 2017-05-10 盐城市大丰区小海镇农业技术推广综合服务中心 Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide
CN106889067A (en) * 2017-02-27 2017-06-27 南京华洲药业有限公司 A kind of compound pesticide compositions of containing chromafenozide and chlorine tebufenozide and application thereof
CN108174853A (en) * 2018-02-05 2018-06-19 广东真格生物科技有限公司 A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class
CN108378034A (en) * 2018-05-08 2018-08-10 江西正邦生物化工有限责任公司 A kind of Pesticidal combination containing bromine worm fluorobenzene bisamide and furan tebufenozide

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105724389A (en) * 2016-04-19 2016-07-06 陕西上格之路生物科学有限公司 Dispersible oil suspension containing chlorantraniliprole
CN105685051A (en) * 2016-04-20 2016-06-22 陕西上格之路生物科学有限公司 Dispersible oil suspension agent with methoxyfenozide
CN106614608A (en) * 2016-11-23 2017-05-10 盐城市大丰区小海镇农业技术推广综合服务中心 Pesticide for preventing and controlling vegetable leafminer in bengal waterdropwort herb and prevention and control method of pesticide
CN106889067A (en) * 2017-02-27 2017-06-27 南京华洲药业有限公司 A kind of compound pesticide compositions of containing chromafenozide and chlorine tebufenozide and application thereof
CN108174853A (en) * 2018-02-05 2018-06-19 广东真格生物科技有限公司 A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and molting hormone class
CN108378034A (en) * 2018-05-08 2018-08-10 江西正邦生物化工有限责任公司 A kind of Pesticidal combination containing bromine worm fluorobenzene bisamide and furan tebufenozide

Similar Documents

Publication Publication Date Title
CN102113516B (en) Insect killing compound containing chlorantraniliprole
CN100586282C (en) Insecticidal composition containing chlorantraniliprole and monosultap
CN102379282A (en) Ultralow volume liquid containing benzoylurea insecticide
CN102273444A (en) Ultralow volume liquid containing thiamethoxam
CN101669488B (en) Binary complex pesticide composition containing chlorantraniliprole
CN103609621B (en) Traditional Chinese medicine insecticidal composition
CN101703051A (en) Insecticidal composition containing cyanogen insect amide and molosultap and application thereof
CN102396475A (en) Pesticide composition containing cyantraniliprole and abamectin
CN103300000B (en) A kind of Pesticidal combination containing ring worm hydrazides and amide-type
CN101480191B (en) Insecticidal composition
CN104585190A (en) Nematicide composition containing abamectin and fluopyram
CN103931643A (en) Insecticidal composition containing tetrachloro insect amide
CN104488921A (en) Nematicidal composition containing fluensulfone and abamectin
CN101380008A (en) Disinsection composition with synergistic action
CN103380778A (en) Pesticide composition of thiamethoxam and azoxystrobin
CN102217615A (en) Pesticide composition containing Spirotetramat and amide insecticides
CN104522049A (en) Nematicidal composition containing fluensulfone and fosthiazate
CN101836641B (en) Oil-suspending agent disinfestation composition containing spinosyns and emamectin benzoate
CN103355319A (en) Insecticidal composition containing pyridalyl and biological source
CN101836643B (en) Pesticide preparation for controlling vegetable pests of diamondback moth and the like
CN104186514A (en) Pesticide composition containing cyhalodiamide
CN102084862B (en) Insecticidal composition containing ethiprole
CN102204548A (en) High-efficient environmentally-friendly type avermectin emulsifiable solution and preparation method thereof
CN103385251A (en) Insecticidal composition comprising pyriproxyfen
CN101773141B (en) Compound pesticide of chlorantraniliprole and chlorpyrifos

Legal Events

Date Code Title Description
PB01 Publication
C06 Publication
SE01 Entry into force of request for substantive examination
EXSB Decision made by sipo to initiate substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150722

WD01 Invention patent application deemed withdrawn after publication