CN105941451A - Insecticide composition containing chromafenozide and neonicotinoid - Google Patents

Insecticide composition containing chromafenozide and neonicotinoid Download PDF

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Publication number
CN105941451A
CN105941451A CN201610367679.7A CN201610367679A CN105941451A CN 105941451 A CN105941451 A CN 105941451A CN 201610367679 A CN201610367679 A CN 201610367679A CN 105941451 A CN105941451 A CN 105941451A
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ring tebufenozide
thiacloprid
acetamiprid
clothianidin
nitenpyram
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张伟
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Shaanxi Welch Crop Protection Co Ltd
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Shaanxi Welch Crop Protection Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an insecticide composition containing chromafenozide and neonicotinoid. The composition contains an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from chromafenozide, the active ingredient B is selected from any one of the following compounds: thiacloprid, thiamethoxam, clothianidin, imidacloprid, acetamiprid, nitenpyram and dinotefuran, and the weight ratio of the active ingredient A to the active ingredient B is (1-60):(60-1). The composition of the invention can be used for preventing and curing various pests, has an obvious synergistic action, enlarges an insecticidal spectrum, has high activity on various pests, reduces a pesticide dosage, lowers a residual quantity of the pesticide on the crop, lightens environment pollution, is safe to people and livestock and has good environmental compatibility, and pests are unlikely to generate the drug resistance.

Description

A kind of containing chromafenozide and the Pesticidal combination of anabasine
The application is divisional application, and original application is the special of Shaanxi Welch Crop Protection Co., Ltd. Profit application " a kind of containing chromafenozide and the Pesticidal combination of anabasine ", the application number of original application For 201210070850X, original application day is 2012.03.16.
Technical field
The invention belongs to technical field of pesticide, relate to killing of a kind of containing chromafenozide and anabasine Worm compositions
Background technology
Ring tebufenozide (chromafenozide) chemical name: 2-tert-butyl group-5-methyl-2- (3,5-dimethylbenzoyl) color alkane-6-formylhydrazine, molecular formula: C24H30N2O3, it is Nippon Kayaku K. K and Sankyo Co., Ltd's (being now three common agricultural Co., Ltd.) open jointly Send out and practical novel pesticide.Ring tebufenozide is bishydrazide insecticide, after pests In several hours, suppression feed, causes insect to cast off a skin in advance simultaneously and causes death.Ring tebufenozide is not only To mammal, birds, aquatic organism low toxicity, and to arthropod class, predatism acarian, Aranea, Semiptera, coleoptera (beetle), parasite and environment are without impact.Therefore, it It it is a preferable medicament in comprehensive pest improvement system.
Diacloden (Thiamethoxam) chemical name: 3-(2-chloro-1,3-thiazole-5-ylmethyl)-5- Methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine, molecular formula: C8H10ClN5O3S, Diacloden is The second filial generation nicotinoids high-efficient low toxicity insecticide of a kind of brand new, has stomach toxicity, touches insect Kill and systemic activity, for foliar spray and soil root irrigation.Rapidly by interior suction after its dispenser, And it is transmitted to each position of plant, sucking pest such as aphid, plant hopper, leafhopper, aleyrodid etc. are had Good preventive effect.
Thiacloprid (Thiacloprid) chemical name: (3-((6-chloro-3-pyridyl base) methyl)-1,3-thiophene Oxazoline-2-subunit) cyanamide, molecular formula: C13H5N4SCl, the former medicine of thiacloprid is by Bayer Bitterfeld GmbH agriculture Change company and Japan's Bayer agro-chemical companies cooperative development, be novel chloro nicotinic insecticide；Thiophene The mechanism of action of worm quinoline is different with other conventional pesticides.It is neural that it mainly acts on insecticide Engaging caudacoria, by being combined with nAChR, interference insect nervous system normally passes Lead, cause the obstruction of neural channel, cause a large amount of accumulation of acetylcholine, so that insecticide is different Chang Xingfen, general spasticity, paralysis and dead.There is stronger interior suction, tag and stomach poison function, Resist the most alternately with common insecticides such as pyrethroid, organic phosphates and carbamates Property, thus can be used for resistance management.
Clothianidin (clothianidin) chemical name: (E)-1-(2-chloro-1,3-thiazole-5-ylmethyl)-3- Methyl-2-2-nitroguanidine, molecular formula: C10H19O6PS2, clothianidin is the one in anabasine Insecticide, is a class highly effective and safe, high selective novel pesticide, its effect and nicotine second Acetylcholine receptor is similar to, have tag, stomach toxicity and systemic activity.Be mainly used in Oryza sativa L., vegetable, Anti-on fruit tree and other crops eliminate aphis, leafhopper, thrips, the Semiptera such as plant hopper, coleoptera, The insecticide of Diptera and some Lepidoptera class pest, have efficiently, wide spectrum, consumption few, malicious Property low, drug effect lasting period length, to crop without poisoning, use safety and conventional pesticide no interactions The advantages such as resistance, have interior suction and the osmosis of brilliance, are to substitute high-toxic organic phosphorus pesticide again One kind.Its novel structure, special, performance is the most excellent compared with tradition nicotinic insecticide, It is likely to become global large-scale insecticide variety.
Imidacloprid (imidacloprid) chemical name: 1-(6-chloropyridine-3-pyridylmethyl)-N- Nitroimidazoline-2-base amine, molecular formula: C9H10ClN5O2, imidacloprid is that nicotinoids surpasses Efficient pesticides, has wide spectrum, efficient, low toxicity, low-residual, and insect is not likely to produce resistance, To features such as people, animal, plant and natural enemies securities, and have tag, many recasts such as stomach toxicity and interior suction With.After contacting pests medicament, nervus centralis normal conduction is obstructed so that it is paralysis death.Product Quick-acting is good, within after medicine 1 day, i.e. has higher preventive effect, and residual period is up to about 25 days.Drug effect Being proportionate with temperature, temperature is high, good disinsection effect.It is mainly used in preventing and treating sucking mouth parts Insect.
Acetamiprid (acetamiprid) chemical name: N-(N-cyano group-ethyliminum base)-N-methyl-2- Chloropyridine-5-methylamine, molecular formula: C10H11ClN4, Acetamiprid is a kind of New-type wide-spectrum and has The insecticide of certain acaricidal activity, its model of action is the systemic insecticide of soil and branch and leaf.Extensively General for Oryza sativa L., especially vegetable, fruit tree, the aphid of Folium Camelliae sinensis, plant hopper, thrips, part squama wing The preventing and treating of mesh insect etc..
Nitenpyram (Nitenpyram) chemical name: (E)-N-(6-chloro-3-pyridylmethyl)-N- Ethyl-N '-methyl-2-nitro ethylene diamine, molecular formula: C11H15ClN4O2, Nitenpyram Nicotimine insecticides, be Japan develop after imidacloprid, pyridine worm miaow another is new Type product.Have that the interior absorption of brilliance, osmosis, insecticidal spectrum be wide, safety is without poisoning.It is Preventing and treating sucking pest such as trialeurodes vaporariorum, aphid, pear sucker, leafhopper, the replacement of thrips are produced Product.
MTI-446 (dinotefuran) chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furan Methyl) guanidine；(EZ)-(RS)-1-methyl-2-nitro-3-(tetrahydrochysene-3-furylmethyl) guanidine；N-methyl-N'- Nitro-N "-[(tetrahydrochysene-3-furan) methyl] guanidine, molecular formula: C7H14N4O3, MTI-446 is Japan The third generation nicotinic insecticide of Mitsui Chemicals, Inc.'s exploitation.It is with existing nicotinic insecticide Chemical constitution be far from each other, its tetrahydrofuran base instead of former chloro-pyridine Base, chloro-thiazole base, without halogen.Meanwhile, at aspect of performance also with nicotine Difference, so, current people are referred to as " furan nicotine ".
But, in the real process of agricultural production, pest control is easiest to generate the problem that The generation of pest resistance to insecticide.Different cultivars composition compounds, and is that preventing and treating resistant insect is the most common Method.Heterogeneity compounds, and according to practical application effect, judging that certain compounds is Potentiation, add and or antagonism.In most cases, the compounding effect of pesticide all adds And effect, really there are the compounding little of potentiation, especially potentiation clearly, altogether Compounding that poison coefficient is the highest is the most less.Study through inventor, find ring tebufenozide and thiophene After worm quinoline, Diacloden, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, MTI-446 are compounding Good potentiation can be produced, and about ring tebufenozide and thiacloprid, Diacloden, thiophene worm The relevant report that amine, imidacloprid, Acetamiprid, Nitenpyram, MTI-446 compound is the openest.
Summary of the invention
Resistance that ring tebufenozide single dose life-time service may bring occurs, degradation problem under drug effect, The Pesticidal combination that the present invention proposes contains active components A, active component B, and appropriate Surfactant and carrier.
A kind of containing chromafenozide and the Pesticidal combination of anabasine, compositions contains active component A and active component B, active components A and active component B weight ratio are 1 60～60 1, Described active components A be selected from ring tebufenozide, active component B selected from thiacloprid, Diacloden, One in clothianidin, imidacloprid, Acetamiprid, Nitenpyram, MTI-446.
Described containing chromafenozide and the Pesticidal combination of anabasine, it is characterised in that: activity becomes Dividing A, the weight ratio of active component B is 1 40～40 1.
Described containing chromafenozide and the Pesticidal combination of anabasine, it is characterised in that: ring worm acyl Hydrazine is 20:1～1:20 with the weight ratio of thiacloprid；
Ring tebufenozide is 20 1～1 10 with the weight ratio of Diacloden；
Ring tebufenozide is 20 1～1 10 with the weight ratio of clothianidin；
Ring tebufenozide is 30:1～1:10 with the weight ratio of imidacloprid；
Ring tebufenozide is 30:1～1:10 with the weight ratio of Acetamiprid；
Ring tebufenozide is 20 1～1 10 with the weight ratio of Nitenpyram；
Ring tebufenozide is 20 1～1 10 with the weight ratio of MTI-446.
Described containing chromafenozide and the Pesticidal combination of anabasine, it is characterised in that: combination Thing make wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, Microcapsule suspending agent, microcapsule suspending agent-suspending agent.
Described containing chromafenozide is used for preventing and treating crop pest with the Pesticidal combination of anabasine Purposes, described crop includes cereal crops, fruit tree, fibre crops, vegetable, flowers, bean Class crop, specifically include Semen Tritici aestivi, Oryza sativa L., Semen Maydis, Camellia sinensis, apple tree, pear tree, mandarin tree, Banana tree, rubber tree, Cotton Gossypii, Fructus Cucumidis sativi, Fructus Capsici, Caulis et Folium Brassicae capitatae, Flos Chrysanthemi, Flos Rosae Rugosae, Semen sojae atricolor etc.； Described insect includes: aphid, flea beetle, thrips, striped rice borer, yellow rice borer, rice leaf roller, Planthopper, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, bean Pod snout moth's larva, melon aphid, Bemisia tabaci, beet armyworm, bollworm, 2 committee noctuids.
Generally in compositions weight percentage is gross weight 1%～the 90% of active component, relatively Good for 5%～85%.According to different preparation types, active component content scope is different. Generally, liquid preparation contains the active substance of by weight 1%～70%, preferably 5%～ 50%；Solid preparation contains the active substance of by weight 5%～85%, preferably 10%～ 70%.
The Pesticidal combination of the present invention at least contains a kind of surfactant, when being beneficial to use Active component dispersion in water.Surface-active contents is the 10%～40% of total formulation weight amount, Surplus is solid or liquid diluent.
The compositions of the present invention through dilution or directly can be used before use by user.It is joined System can be prepared by common processing method known in those skilled in the art, will active substance After mixing with liquid flux or solid carrier, add surfactant such as dispersant, stabilizer, One or more in wetting agent, emulsifying agent, binding agent, defoamer etc..
The Pesticidal combination of the present invention, can be processed on any pesticide acceptable dose on demand Type, the most excellent relatively selects the dosage form to be: wettable powder, suspending agent, suspension emulsion, water dispersible granules, Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspending agent-suspending agent.
Compositions comprises following constituent content when making wettable powder: ring tebufenozide 1%～80%, Active component B 1%～60%, dispersant 1.5%～10%, wetting agent 1%～10%, filler surplus.
Compositions includes following constituent content when making suspending agent: ring tebufenozide 1%～50%, live Property composition B 1%～50%, dispersant 1%～10%, wetting agent 1%～10%, defoamer 0.01%～1%, thickening agent 0.05%～2%, antifreeze 0%～8%, deionized water add to 100%.
Compositions includes following constituent content when making suspension emulsion: ring tebufenozide 1%～50%, live Property composition B 1%～50%, solvent 0～15%, emulsifying agent 2%～12%, dispersant 2%～10%, Defoamer 0.01%～2%, thickening agent 0.05%～2%, antifreeze 0%～8%, stabilizer 0%～3%, Deionized water adds to 100%.
Compositions comprises following constituent content when making aqueous emulsion: ring tebufenozide 1%～50%, live Property composition B 1%～50%, solvent 1%～30%, emulsifying agent 1%～20%, co-emulsifier 1%～8%, Antifreeze 0%～8%, thickening agent 0.05%～2%, defoamer 0%～2%, deionized water are supplied remaining Amount.
Compositions comprises following constituent content when making microemulsion: ring tebufenozide 1%～50%, live Property composition B 1%～50%, solvent 1%～30%, emulsifying agent 3%～20%, antifreeze 0%～8%, Thickening agent 0.05%～2%, defoamer 0.01%～2%, stabilizer 0%～4%, deionized water is mended Foot surplus.
Compositions includes following constituent content when making microcapsule suspending agent: ring tebufenozide 1%～50%, Active component B 1%～50%, macromolecule cyst material 3%～10%, dispersant 2%～10%, Organic solvent 0%～10%, emulsifying agent 2%～7%, pH adjusting agent 0.1%～5%, deionized water Add to 100%.
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 1%～40%, active component B 1%～60%, macromolecule cyst material 2%～12%, surface activity Agent 3%～15%, organic solvent 1%～5%, emulsifying agent 1%～6%, defoamer 0.2%～5%, Thickening agent 0.05%～1%, pH adjusting agent 1%～5%, water add to 100%.
Compositions includes following constituent content when making water dispersible granules: activity become A 1%～80%, Active component B 1%～70%, dispersant 3%～12%, wetting agent 1%～8%, disintegrating agent 1%～10%, Binding agent 0%～8%, filler surplus.
The suspending agent the key technical indexes of the present invention:
The wettable powder the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) ring tebufenozide and thiacloprid, Diacloden, clothianidin, imidacloprid, Acetamiprid, alkene After pyridine worm amine, MTI-446 are compounding, there is notable synergistic and lasting effect；
(2) expand insecticidal spectrum, a lot of insects are had greater activity；
(3) decrease the dosage of pesticide, reduce pesticide residual quantity on crop, alleviate Environmental pollution；
(4) to person poultry safety, Environmental compatibility is good, and insect is not likely to produce Drug resistance.
Detailed description of the invention
Below in conjunction with embodiment, further instruction of the present invention, the percentage ratio in embodiment are Percentage by weight, but the invention is not limited in this.
Application Example one
Example 1 10% ring tebufenozide thiacloprid suspending agent
Ring tebufenozide 5%, thiacloprid 5%, alkylnaphthalene sulfonate 2.5%, wetting agent T 4%, Organic silicon defoamer 0.3%, sodium acrylate 0.1%, glycerol 3%, deionized water adds to 100%, It is mixed to prepare 10% ring tebufenozide thiacloprid suspending agent.
Thiacloprid is changed into Diacloden, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 2 15% ring tebufenozide Diacloden suspending agent
Ring tebufenozide 10%, Diacloden 5%, aryl phenol polyoxyethylene succinate sulfonate 3%, Sodium lauryl sulphate 4%, silicone 0.2%, polyvinyl alcohol 0.09%, Polyethylene Glycol 4%, Deionized water adds to 100%, is mixed to prepare 15% ring tebufenozide Diacloden suspending agent.
Diacloden is changed into thiacloprid, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 3 20% ring tebufenozide clothianidin suspending agent
Ring tebufenozide 12%, clothianidin 8%, lignosulfonates 2.5%, sodium laurylsulfate 3.5%, C8～10Aliphatic alcohols 0.9%, arabic gum 0.05%, ethylene glycol 2.5%, deionization Water adds to 100%, is mixed to prepare 20% ring tebufenozide clothianidin suspending agent.
Clothianidin is changed into thiacloprid, Diacloden, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 4 40% ring tebufenozide imidacloprid suspending agent
Ring tebufenozide 30%, imidacloprid 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, Laurel Alcohol sodium sulfate 4%, propylene glycol 4.5%, organic silicon defoamer 0.4%, sodium acrylate 0.14%, Deionized water adds to 100%, is mixed to prepare 40% ring tebufenozide imidacloprid suspending agent.
Imidacloprid is changed into thiacloprid, Diacloden, clothianidin, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 5 35% ring tebufenozide acetamiprid suspending agent
Ring tebufenozide 25%, Acetamiprid 10%, naphthalene sulfonic acid-formaldehyde condensation product 5.3%, moistening infiltration Agent F 6%, organic silicon defoamer 0.6%, sodium acrylate 0.07%, ethylene glycol 4%, deionization Water adds to 100%, is mixed to prepare 35% ring tebufenozide acetamiprid suspending agent.
Acetamiprid is changed into thiacloprid, Diacloden, clothianidin, imidacloprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 6 30% ring tebufenozide Nitenpyram suspending agent
Ring tebufenozide 10%, Nitenpyram 20%, double (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, C10～20Saturated fat acids 1.4%, polyvinyl alcohol 0.16%, wetting and penetrating agent F5%, Polyethylene Glycol 2.5%, deionized water adds to 100%, is mixed to prepare 30% ring tebufenozide alkene pyridine Worm amine suspending agent.
Nitenpyram will be changed into thiacloprid, Diacloden, clothianidin, imidacloprid, Acetamiprid, The embodiment that MTI-446 is the newest.
Example 7 25% ring tebufenozide MTI-446 suspending agent
Ring tebufenozide 15%, MTI-446 10%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulphuric acid Salt 4%, tea seed cake 3%, silicone oil 0.3%, xanthan gum 0.06%, ethylene glycol 6%, deionized water Add to 100%, prepare 25% ring tebufenozide MTI-446 suspending agent.
MTI-446 is changed into thiacloprid, Diacloden, clothianidin, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 8 30% ring tebufenozide thiacloprid suspending agent
Ring tebufenozide 15%, thiacloprid 15%, ethyl acetate 7%, alkyl benzene calcium sulfonate 8%, Alkylaryl polyoxyethylene poly-oxygen propylene aether 6%, methylcellulose 0.09%, C10～20Saturated fat Fat acids 1.3%, propylene glycol 1%, deionized water adds to 100%, prepares 30% ring tebufenozide thiophene Worm quinoline suspension emulsion.
Thiacloprid is changed into Diacloden, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 9 45% ring tebufenozide Diacloden suspension emulsion
Ring tebufenozide 30%, Diacloden 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, 12 Alkyl sodium sulfate 6%, C8～10Aliphatic alcohols 0.4%, aluminium-magnesium silicate 0.13%, glycerol 0.7%, Alkyl biphenyl ether disulfonic acid magnesium salt 5%, ethyl acetate 2%, deionized water adds to 100%, system Obtain 45% ring tebufenozide Diacloden suspension emulsion.
Diacloden is changed into clothianidin, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 10 10% ring tebufenozide imidacloprid suspension emulsion
Ring tebufenozide 8%, imidacloprid 2%, polyoxyethylene carboxylate 3.6%, C10～20Saturated Fatty acid 0.5%, arabic gum 0.06%, NPE 5.3%, Polyethylene Glycol 2%, propylene glycol 3%, deionized water adds to 100%, prepares 10% ring tebufenozide imidacloprid and hangs Emulsion.
Imidacloprid is changed into Diacloden, thiacloprid, clothianidin, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 11 20% ring tebufenozide Acetamiprid suspension emulsion
Ring tebufenozide 15%, Acetamiprid 5%, aryl phenol polyoxyethylene succinate sulfonate 5.3%, Alkyl biphenyl ether disulfonic acid magnesium salt 6.7%, sodium alginate 0.07%, ethylene glycol 4.3%, silicone 0.7%, dimethylbenzene 4%, deionized water adds to 100%, prepares 20% ring tebufenozide Acetamiprid Suspension emulsion.
Acetamiprid is changed into Diacloden, thiacloprid, clothianidin, imidacloprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 12 40% ring tebufenozide Nitenpyram suspension emulsion
Ring tebufenozide 1%, Nitenpyram 39%, 2,4 toluene diisocyanate 8%, fatty alcohol Polyoxyethylene ether 7%, carboxymethyl cellulose 0.08%, Polyethylene Glycol 0.17%, C8～10Fatty alcohol Class 0.18%, deionized water adds to 100%, prepares 40% ring tebufenozide Nitenpyram suspension emulsion.
Nitenpyram is changed into Diacloden, thiacloprid, clothianidin, imidacloprid, Acetamiprid, furan The embodiment that worm amine is the newest.
Example 13 50% ring tebufenozide clothianidin suspension emulsion
Ring tebufenozide 30%, clothianidin 20%, Ketohexamethylene 1.3%, sorbitan fatty acid ester Polyoxyethylene ether 5.6%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3.5%, sodium acrylate 0.02%, C10～20 Saturated fat acids 1.5%, deionized water adds to 100%, prepares 50% ring tebufenozide thiophene worm Amine suspension emulsion.
Clothianidin is changed into Diacloden, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 14 35% ring tebufenozide MTI-446 suspension emulsion
Ring tebufenozide 20%, MTI-446 15%, alkylnaphthalene sulfonate 6.4%, lauryl sulphate acid Sodium 4.4%, methylcellulose 0.13%, Polyethylene Glycol 1.7%, C10～20Saturated fat acids 0.4%, Ketohexamethylene 2.5%, deionized water adds to 100%, prepares the outstanding breast of 35% ring tebufenozide MTI-446 Agent.
MTI-446 is changed into Diacloden, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, thiophene The embodiment that worm amine is the newest.
Example 15 60% ring tebufenozide Diacloden wettable powder
Ring tebufenozide 20%, Diacloden 40%, octylphenol polyethylene oxyethylene group ether sulfate 5%, Wetting and penetrating agent F 6.5%, bentonite add to 100%, and mixture carries out comminution by gas stream, prepare 60% ring tebufenozide Diacloden wettable powder.
Diacloden is changed into thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, clothianidin, furan The embodiment that worm amine is the newest.
Example 16 20% ring tebufenozide clothianidin wettable powder
Ring tebufenozide 18%, clothianidin 2%, aryl phenol polyoxyethylene succinate sulfonate 4%, Sodium laurylsulfate 4.5%, Kaolin add to 100%, and mixture carries out comminution by gas stream, prepare 20% ring tebufenozide clothianidin wettable powder.
Clothianidin is changed into thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, Diacloden, furan The embodiment that worm amine is the newest.
Example 17 30% ring tebufenozide thiacloprid wettable powder
Ring tebufenozide 20%, thiacloprid 10%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulphuric acid Salt 5.5%, dodecylbenzene sodium sulfonate 5.9%, white carbon add to 100%, and mixture carries out gas Stream is pulverized, and prepares 30% ring tebufenozide thiacloprid wettable powder.
Thiacloprid is changed into Diacloden, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 18 50% ring tebufenozide imidacloprid wettable powder
Ring tebufenozide 35%, imidacloprid 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6.7%, tea seed cake 5.9%, attapulgite adds to 100%, and mixture carries out comminution by gas stream, prepares 50% ring worm acyl Hydrazine imidacloprid wettable powder.
Imidacloprid is changed into Diacloden, clothianidin, thiacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 19 45% ring tebufenozide acetamiprid wettable powder
Ring tebufenozide 2%, Acetamiprid 43%, aryl phenol polyoxyethylene succinate sulfonate 6.5%, Bombyx mori L. 4.5%, bentonite add to 100%, are mixed to prepare 45% ring tebufenozide Acetamiprid wettable Property powder.
Acetamiprid is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 20 70% ring tebufenozide Nitenpyram wettable powder
Ring tebufenozide 10%, Nitenpyram 60%, polycarboxylate 4.5%, spaonin powder 4.6%, Kaolin adds to 100%, is mixed to prepare 70% ring tebufenozide Nitenpyram wettable powder.
Nitenpyram is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Acetamiprid, furan The embodiment that worm amine is the newest.
Example 21 80% ring tebufenozide MTI-446 wettable powder
Ring tebufenozide 2%, MTI-446 78%, ester polyoxyethylene are phonetic 7%, DBSA Sodium 6%, white carbon add to 100%, and mixture carries out comminution by gas stream, are mixed to prepare 80% ring worm Hydrazides MTI-446 wettable powder.
MTI-446 is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 22 80% ring tebufenozide Diacloden water dispersible granules
Ring tebufenozide 20%, Diacloden 60%, lignosulfonates 6.3%, wetting and penetrating agent F 5.1%, aluminum chloride 2.9%, sodium alginate 0.05%, precipitated calcium carbonate add to 100%, through mixed Close and prepare 80% ring tebufenozide Diacloden water dispersible granules.
Diacloden is changed into clothianidin, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 23 60% ring tebufenozide clothianidin water dispersible granules
Ring tebufenozide 59%, clothianidin 1%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, Bombyx mori L. 6%, Glucose 5%, arabic gum 0.14%, precipitated calcium carbonate add to 100%, blended prepared 60% Ring tebufenozide clothianidin water dispersible granules.
Clothianidin is changed into Diacloden, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 24 40% ring tebufenozide thiacloprid water dispersible granules
Ring tebufenozide 20%, thiacloprid 20%, aryl phenol polyoxyethylene succinate sulfonate salt 4%, sodium laurylsulfate 4.5%, ammonium sulfate 6%, starch add to 100%, blended prepare 40% ring tebufenozide thiacloprid water dispersible granules.
Thiacloprid is changed into Diacloden, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 25 20% ring tebufenozide imidacloprid water dispersible granule
Ring tebufenozide 15%, imidacloprid 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, Bombyx mori L. 3.5%, Bentonite 4.5%, sodium acrylate 0.11%, kieselguhr add to 100%, blended prepared 20% Ring tebufenozide imidacloprid water dispersible granule.
Imidacloprid is changed into Diacloden, clothianidin, thiacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 26 70% ring tebufenozide acetamiprid water dispersible granules
Ring tebufenozide 20%, Acetamiprid 50%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulphuric acid Salt 2.9%, sodium lauryl sulphate 4.9%, aluminum chloride 3.5%, aluminium-magnesium silicate 0.11%, light Matter calcium carbonate adds to 100%, blended prepared 70% ring tebufenozide acetamiprid water dispersible granules.
Acetamiprid is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 27 50% ring tebufenozide Nitenpyram water dispersible granules
Ring tebufenozide 30%, Nitenpyram 20%, aryl phenol polyoxyethylene succinate sulfonate 6%, dodecylbenzene sodium sulfonate 4.6%, carbamide 3.4%, hydroxypropyl cellulose 0.09%, light Matter calcium carbonate adds to 100%, blended prepared 50% ring tebufenozide Nitenpyram water dispersible granules.
Nitenpyram is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Acetamiprid, furan The embodiment that worm amine is the newest.
Example 28 75% ring tebufenozide MTI-446 water dispersible granules
Ring tebufenozide 25%, MTI-446 50%, octylphenol polyethylene oxyethylene group ether sulfate 6.4%, Wetting and penetrating agent F 6.8%, aluminum chloride 4.5%, xanthan gum 0.06%, precipitated calcium carbonate add to 100%, Blended prepared 75% ring tebufenozide MTI-446 water dispersible granules.
MTI-446 is changed into Diacloden, clothianidin, thiacloprid, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 29 10% ring tebufenozide Diacloden aqueous emulsion
Ring tebufenozide 8%, Diacloden 2%, 2,4 toluene diisocyanate 15%, alkyl phenol first Urea formaldehyde polyoxyethyl ether 4.5%, isobutanol 4%, ethylene glycol 3.5%, arabic gum 0.05%, C8～10Aliphatic alcohols 0.5%, deionized water add to 100%, blended prepared 10% ring tebufenozide thiophene Worm piperazine aqueous emulsion.
Diacloden is changed into MTI-446, clothianidin, thiacloprid, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 30 40% ring tebufenozide clothianidin aqueous emulsion
Ring tebufenozide 10%, clothianidin 30%, ketopyrrolidine 5%, epoxy ethane-epoxy propane Block copolymer 14%, propylene glycol 5%, isobutanol 6%, arabic gum 0.08%, C8～10Fat Fat alcohols 1.3%, deionized water add to 100%, blended prepared 40% ring tebufenozide thiophene worm Aqueous amine Emulsion.
Clothianidin is changed into MTI-446, Diacloden, thiacloprid, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 31 15% ring tebufenozide thiacloprid aqueous emulsion
Ring tebufenozide 5%, thiacloprid 10%, dichloromethane 16%, triethanolamine salt 6%, different Butanol 3%, Polyethylene Glycol 7%, sodium alginate 0.08%, C10～20Saturated fat acids 0.6%, Deionized water adds to 100%, blended prepared 15% ring tebufenozide thiacloprid aqueous emulsion.
Thiacloprid is changed into MTI-446, Diacloden, clothianidin, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 32 20% ring tebufenozide imidacloprid aqueous emulsion
Ring tebufenozide 1%, imidacloprid 19%, Ketohexamethylene 13%, NPE 6%, Butanol 6.5%, glycerol 5%, polyvinyl alcohol 0.11%, silicone 1.5%, deionized water add To 100%, blended prepared 20% ring tebufenozide imidacloprid aqueous emulsion.
Imidacloprid is changed into MTI-446, Diacloden, thiacloprid, clothianidin, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 33 45% ring tebufenozide Acetamiprid aqueous emulsion
Ring tebufenozide 15%, Acetamiprid 30%, solvent naphtha 7%, fat alcohol polyoxyethylenated alcohol 8%, Butanol 6%, Polyethylene Glycol 4%, C10～20Saturated fat acids 1%, aluminium-magnesium silicate 0.08%, Deionized water adds to 100%, blended prepared 45% ring tebufenozide Acetamiprid aqueous emulsion.
Acetamiprid is changed into MTI-446, Diacloden, thiacloprid, clothianidin, imidacloprid, alkene pyridine The embodiment that worm amine is the newest.
Example 34 30% ring tebufenozide Nitenpyram aqueous emulsion
The acid of ring tebufenozide 10%, Nitenpyram 20%, isobutanol 8.5%, sorbitan fatty Ester polyoxyethylene ether 5%, isobutanol 9%, Polyethylene Glycol 1.3%, C10～20Saturated fat acids 0.8%, sodium polyacrylate 0.13%, deionized water adds to 100%, blended prepared 30% ring worm Hydrazides Nitenpyram aqueous emulsion.
Nitenpyram is changed into MTI-446, Diacloden, thiacloprid, clothianidin, imidacloprid, pyridine The embodiment that worm amidine is the newest.
Example 35 20% ring tebufenozide MTI-446 aqueous emulsion
Ring tebufenozide 5%, MTI-446 15%, butanol 18%, castor oil polyoxyethylene ether 5%, Isobutanol 4%, Polyethylene Glycol 2%, C10～20Saturated fat acids 0.5%, hydroxypropyl cellulose 0.06%, deionized water adds to 100%, blended prepared 20% ring tebufenozide MTI-446 microemulsion Agent.
MTI-446 is changed into Diacloden, thiacloprid, clothianidin, imidacloprid, Acetamiprid, alkene pyridine The embodiment that worm amine is the newest.
Example 36 20% ring tebufenozide thiamethoxam micro-emulsion
Ring tebufenozide 10%, Diacloden 10%, dimethylbenzene 17%, alkylaryl polyoxypropylene are poly- Oxygen vinyl Ether 4.6%, ethylene glycol 2.3%, C8～10Saturated fat acids 0.7%, crosslinked polyethylene Ketopyrrolidine 0.08%, deionized water adds to 100%, blended prepared 20% ring tebufenozide thiophene Worm piperazine microemulsion.
Diacloden is changed into thiacloprid, clothianidin, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 37 30% ring tebufenozide clothianidin microemulsion
Ring tebufenozide 15%, clothianidin 15%, vegetable oil 9%, alkyl biphenyl ether disulfonic acid magnesium Salt 8%, glycerol 4%, arabic gum 0.11%, C10～20Saturated fat acids 1.2%, goes Ionized water adds to 100%, blended prepared 30% ring tebufenozide clothianidin microemulsion.
Clothianidin is changed into thiacloprid, Diacloden, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 38 30% ring tebufenozide thiacloprid microcapsule suspending agent
Ring tebufenozide 1%, thiacloprid 29%, polyfunctional group acyl halide polyamines 6.5%, fatty amine Polyoxyethylene is phonetic 6.3%, dimethylbenzene 10%, benzyl dimethyl phenol polyoxyethyl ether 5.5%, hydrogen Sodium oxide 2%, hydrochloric acid 2%, deionized water adds to 100%, blended prepared 30% ring worm acyl Hydrazine thiacloprid microcapsule suspending agent.
Thiacloprid is changed into clothianidin, Diacloden, imidacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 39 35% ring tebufenozide imidacloprid microcapsule suspending agent
Ring tebufenozide 34%, imidacloprid 1%, polyisocyanate 7%, aliphatic amine polyoxyethylene are phonetic 7.5%, ketopyrrolidine 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 2%, sodium hydroxide 1.5%, Sorbic acid 1%, deionized water adds to 100%, blended prepared 35% ring tebufenozide imidacloprid Microcapsule suspending agent.
Imidacloprid is changed into clothianidin, Diacloden, thiacloprid, Acetamiprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 40 40% ring tebufenozide Acetamiprid microcapsule suspending agent-suspending agent
Ring tebufenozide 12%, Acetamiprid 28%, polyisocyanate 5.5%, tristyryl phenol first Urea formaldehyde polyoxyethylene ether phosphate salt 7.5%, Polyethylene Glycol 4.2%, alkyl biphenyl ether disulfonic acid Magnesium salt 4%, C10～20Saturated fat acids 2.6%, sodium hydroxide 1.5%, hydrochloric acid 2%, go from Sub-water adds to 100%, blended prepared 40% ring tebufenozide Acetamiprid microcapsule suspending agent-suspension Agent.
Acetamiprid is changed into clothianidin, Diacloden, thiacloprid, imidacloprid, Nitenpyram, furan The embodiment that worm amine is the newest.
Example 41 30% ring tebufenozide Nitenpyram microcapsule suspending agent-suspending agent
Ring tebufenozide 29%, Nitenpyram 1%, deformation lactoprotein 6%, di-2-ethylhexylphosphine oxide methyl naphthalene Sulfonate 7%, solvent N-chain alkyl ketopyrrolidine 4.6%, phenyl phenol polyoxyethyl ether 4%, C8～10Aliphatic alcohols 4.3%, sodium hydroxide 1%, citric acid 2.5%, deionized water adds to 100%, Blended prepared 30% ring tebufenozide Nitenpyram microcapsule suspending agent-suspending agent.
Nitenpyram is changed into clothianidin, Diacloden, thiacloprid, imidacloprid, Acetamiprid, furan The embodiment that worm amine is the newest.
The embodiment of the present invention is the method using Toxicity Determination and field test to combine.First Co-toxicity coefficient by Toxicity Determination, after clear and definite two kinds of medicaments are compounding by a certain percentage (CTC), CTC ＜ 80 is antagonism, and 80≤CTC≤120 are summation action, CTC ＞ 120 is potentiation, on this basis, then carries out field test.
Test method: respectively the mother solution of each mixed agent is diluted to during test five series concentration, It is respectively placed in beaker standby.Use the method that first leaching leaf is followed by worm, will be not in contact with any medicament Blade of the same size in the medicinal liquid configured, soak 5s after take out, naturally dry, put into In insect box, then connect for examination larva, raise under the conditions of 25 DEG C, often process 3 times and repeat, Often repeating examination borer population used is 50, sets blank simultaneously, checks dead borer population, meter in 72h Calculate mortality rate and corrected mortality, try to achieve virulence regression equation and calculate LC50Value.If comparison is dead Rate of dying is more than 10%, then be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) is converted into Logarithm value (x), draws virulence regression equation with method of least square, and thus calculates every kind of medicine The value of agent.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (with Ring tebufenozide is standard agent, and its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=ring tebufenozide of MRing tebufenozide+ effective active becomes Divide the TI × P of BEffective active composition B
In formula: M is the mixture of different ratio
PEffective active composition BFor the ratio that effective active composition B is shared in the composition
PRing tebufenozideFor the ratio that ring tebufenozide is shared in the composition
A is selected from ring tebufenozide；
B be selected from any one compound following: Diacloden, thiacloprid, clothianidin, imidacloprid, One of Acetamiprid, Nitenpyram, MTI-446 are planted.
Application Example two:
For examination insect: Pieris rapae.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, Diacloden and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result one
Table 1 ring tebufenozide and the Diacloden different ratio toxicity test to Pieris rapae
As shown in Table 1, ring tebufenozide and the proportioning of Thiamethoxam compound preventing and treating Pieris rapae are 60 1 During to 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are in 60:1 to 1:60 scope Interior mixture all shows potentiation, especially when the proportioning of ring tebufenozide and Diacloden is 20: During 1 to 1:10, potentiation becomes apparent from highlighting, wherein when ring tebufenozide and Diacloden weight Amount is more maximum than co-toxicity coefficient when being 21, and potentiation is the most obvious, finds, ring worm acyl simultaneously Hydrazine and Diacloden proportioning 20:1,19:1,18:1,17:1,16:1,15:1,14: 1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6:1,5:1, 4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1: 8,1:9,1:10 recurrence of disease at the same time next year pairing aphid, flea beetle, thrips, striped rice borer, yellow rice borer, rice are indulged Leaf roll snout moth's larva, planthopper, diamondback moth, tea lesser leafhopper, Prodenia litura, Americal rice leaf miner, bean Pod snout moth's larva, melon aphid, Bemisia tabaci, beet armyworm, bollworm, 2 committee noctuids also have well Potentiation, co-toxicity coefficient is all higher than 120.
Application Example three:
For examination insect: planthopper.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, clothianidin and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result two
Table 2 ring tebufenozide and the clothianidin different ratio toxicity test to planthopper
As shown in Table 2, ring tebufenozide and clothianidin compound the proportioning of preventing and treating planthopper 60 1 During to 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are in 60:1 to 1 60 scope Interior mixture all shows potentiation, especially obtains proportioning 20 when ring tebufenozide and clothianidin: During 1 to 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide When being 21 with clothianidin weight ratio, co-toxicity coefficient is maximum, and potentiation is the most obvious.Send out simultaneously Existing, ring tebufenozide and clothianidin proportioning 20:1,19:1,18:1,17:1,16:1, 15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6: 1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6, 1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing aphid, flea beetle, thrips, striped rice borer, three Change snout moth's larva, rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, America Liriomyza bryoniae, bean-pod borer, melon aphid, Bemisia tabaci, beet armyworm, bollworm, 2 committee noctuids are also Having good potentiation, co-toxicity coefficient is all higher than 120.
Application Example four:
For examination insect: Bemisia tabaci.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, thiacloprid and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result three
Table 3 ring tebufenozide and the thiacloprid different ratio toxicity test to Bemisia tabaci
As shown in Table 3, ring tebufenozide and thiacloprid compound the proportioning preventing and treating Bemisia tabaci 60 1 During to 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are in 60:1 to 1 60 scope Interior mixture all shows potentiation, especially obtains proportioning 20 when ring tebufenozide and thiacloprid: During 1 to 1:20, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide When being 11 with thiacloprid weight ratio, co-toxicity coefficient is maximum, and potentiation is the most obvious.Send out simultaneously Existing, ring tebufenozide and thiacloprid proportioning 20:1,19:1,18:1,17:1,16:1, 15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6: 1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6, 1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1: 16,1:17,1:18,1:19,1:20 recurrence of disease at the same time next year pairing aphid, flea beetle, thrips, two changes Snout moth's larva, yellow rice borer, rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, bean-pod borer, melon aphid, beet armyworm, bollworm, 2 committee noctuids also have Well potentiation, co-toxicity coefficient is all higher than 120.
Application Example five:
For examination insect: aphid.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, imidacloprid and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result four
Table 4 ring tebufenozide and the imidacloprid different ratio toxicity test to aphid
As shown in Table 4, ring tebufenozide and imidacloprid compound the anti-proportioning eliminated aphis 60 1 to During 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are mixed in the range of 60:1 is to 1 60 Join and all show potentiation, especially obtain proportioning at 30:1 extremely when ring tebufenozide and imidacloprid During 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide and pyrrole When worm quinoline weight ratio is 31, co-toxicity coefficient is maximum, and potentiation is the most obvious.Find simultaneously, Ring tebufenozide and imidacloprid proportioning 30:1,29:1,28:1,27:1,26:1,25: 1,24:1,23:1,22:1,21:1,20:1,19:1,18:1,17:1,16: 1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1, 6:1,5:1,4:1,3:1,4:1,1:1,1:2,1:3,1:4,1:5,1: 6,1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing flea beetle, thrips, striped rice borer, yellow rice borer, Rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, Bean-pod borer, melon aphid, beet armyworm, bollworm, 2 committee noctuids also have good potentiation and make With, co-toxicity coefficient is all higher than 120.
Application Example six:
For examination insect: flea beetle.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, Acetamiprid and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result five
Table 5 ring tebufenozide and the Acetamiprid different ratio toxicity test to flea beetle
As shown in Table 5, ring tebufenozide and Acetamiprid compound the proportioning of preventing and treating flea beetle 60 1 to During 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are mixed in the range of 60:1 is to 1 60 Join and all show potentiation, especially obtain proportioning at 30:1 extremely when ring tebufenozide and Acetamiprid During 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide and pyridine When worm amidine weight ratio is 31, co-toxicity coefficient is maximum, and potentiation is the most obvious.Find simultaneously, Ring tebufenozide and Acetamiprid proportioning 30:1,29:1,28:1,27:1,26:1,25: 1,24:1,23:1,22:1,21:1,20:1,19:1,18:1,17:1,16: 1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1, 6:1,5:1,4:1,3:1,4:1,1:1,1:2,1:3,1:4,1:5,1: 6,1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing aphid, thrips, striped rice borer, yellow rice borer, Rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, Bean-pod borer, melon aphid, beet armyworm, bollworm, 2 committee noctuids also have good potentiation and make With, co-toxicity coefficient is all higher than 120.
Application Example seven:
For examination insect: striped rice borer.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: through pilot study determine the former medicine of ring tebufenozide, Nitenpyram and the two not Effective lethasl concentration scope with proportioning mixture.
Toxicity test result six
Table 6 ring tebufenozide and the Nitenpyram different ratio toxicity test to striped rice borer
As shown in Table 6, ring tebufenozide and Nitenpyram compound the proportioning of preventing and treating striped rice borer 60 During 1 to 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are in 60:1 to 1 60 scope Interior mixture all shows potentiation, especially obtains proportioning 20 when ring tebufenozide and Nitenpyram: During 1 to 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide When being 21 with Nitenpyram weight ratio, co-toxicity coefficient is maximum, and potentiation is the most obvious.Simultaneously Find, ring tebufenozide and Nitenpyram proportioning 20:1,19:1,18:1,17:1,16: 1,15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1, 6:1,5:1,4:1,3:1,4:1,1:1,1:2,1:3,1:4,1:5,1: 6,1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing aphid, flea beetle, thrips, yellow rice borer, Rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, Bean-pod borer, melon aphid, beet armyworm, bollworm, 2 committee noctuids also have good potentiation and make With, co-toxicity coefficient is all higher than 120.
Application Example eight:
For examination insect: bollworm.
Test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd..
EXPERIMENTAL DESIGN: determine the former medicine of ring tebufenozide, MTI-446 and the two difference through pilot study Effective lethasl concentration scope of proportioning mixture.
Toxicity test result seven
Table 7 ring tebufenozide and the MTI-446 different ratio toxicity test to bollworm
As shown in Table 7, ring tebufenozide and MTI-446 compound the proportioning of preventing and treating bollworm 60 1 During to 1:60, co-toxicity coefficient is all higher than 120, illustrates that both are in 60:1 to 1 60 scope Interior mixture all shows potentiation, especially obtains proportioning 20 when ring tebufenozide and MTI-446: During 1 to 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when ring tebufenozide When being 21 with MTI-446 weight ratio, co-toxicity coefficient is maximum, and potentiation is the most obvious.Send out simultaneously Existing, ring tebufenozide and MTI-446 proportioning 20:1,19:1,18:1,17:1,16:1, 15:1,14:1,13:1,12:1,11:1,10:1,9:1,8:1,7:1,6: 1,5:1,4:1,3:1,4:1,1:1,1:2,1:3,1:4,1:5,1:6, 1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing flea beetle, thrips, striped rice borer, yellow rice borer, Rice leaf roller, diamondback moth, tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, Bean-pod borer, melon aphid, beet armyworm, 2 committee noctuids also have good potentiation, poison altogether Coefficient is all higher than 120.
Application Example nine ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid, And compounding preventing and treating Semen Maydis 2 the committee noctuid test of pesticide effectiveness
This experimental establishment is in Xue Hu town one, city of Henan Yong Cheng peasant household, and test medicine is by Shaanxi Wei Erqi The research and development of crop protection company limited, offer, comparison medicament 200g/L chromafenozide suspending agent (from Join), 25% Diacloden water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% clothianidin water dispersible granules (autogamy), 10% imidacloprid wettable powder (commercial).
Semen Maydis 2 committee noctuid insect pest index is investigated, in insect pest early period of origination dispenser, dispenser before medicine Within latter 1 day, 15 days, 30 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 8 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and compounding preventing and treating Semen Maydis 2 committee noctuid medicine thereof Effect test
As can be seen from Table 8, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid, Semen Maydis 2 committee noctuid, preventing and treating can be effectively prevented and treated after Acetamiprid, Nitenpyram, MTI-446 are compounding Effect is superior to the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target is made Thing has no adverse effects.
Application Example bull's eye tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding The preventing and treating soybean pod snout moth's larva test of pesticide effectiveness
This experimental establishment is in Mang Shan town one, city of Henan Yong Cheng peasant household, and test medicine is by Shaanxi Wei Erqi The research and development of crop protection company limited, offer, comparison medicament 200g/L chromafenozide suspending agent (from Join), 20% Acetamiprid soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 20% MTI-446 wettable powder (autogamy).
Soybean pod snout moths larva evil index is investigated, in insect pest early period of origination dispenser, after dispenser 1 before medicine My god, 15 days, 30 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 9 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and the compounding preventing and treating soybean pod snout moth's larva test of pesticide effectiveness thereof
As can be seen from Table 9, after ring tebufenozide compounds with Acetamiprid, Nitenpyram, MTI-446 Can effectively prevent and treat soybean pod snout moth's larva, prevention effect is superior to the preventive effect of single dose, and the preventive effect time is long. In test scope of medication, target crop is had no adverse effects.
Application Example 11 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and multiple Join the preventing and treating Caulis et Folium Brassicae capitatae diamondback moth test of pesticide effectiveness
This experimental establishment is in Yangling Shaanxi town one peasant household booth, and test medicine is by Shaanxi Wei Erqi The research and development of crop protection company limited, offer, comparison medicament 200g/L chromafenozide suspending agent (from Join), 25% Diacloden water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% clothianidin water dispersible granules (autogamy), 10% imidacloprid wettable powder (commercial).
Caulis et Folium Brassicae capitatae diamondback moth insect pest index is investigated, in insect pest early period of origination dispenser, after dispenser 1 before medicine My god, 3 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 10 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and The compounding preventing and treating Caulis et Folium Brassicae capitatae diamondback moth test of pesticide effectiveness
As can be seen from Table 10, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid, Can effectively prevent and treat Caulis et Folium Brassicae capitatae diamondback moth after Fu Pei, prevention effect is superior to the preventive effect of single dose, and preventive effect Time is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten bicyclo-tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating thereof The Brassica campestris L striped flea-beetle test of pesticide effectiveness
This experimental establishment is in acrobatic skill town, Shaanxi, and test medicine is limited by Shaanxi Wei Erqi crop protection Company's research and development, offer, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 20% pyridine Worm amidine soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 20% MTI-446 are wettable Property powder (autogamy).
Before medicine investigate striped flea-beetle insect pest index, in insect pest early period of origination dispenser, after dispenser 1 day, Within 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 11 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating striped flea-beetle effect test thereof
As can be seen from Table 11, after ring tebufenozide compounds with Acetamiprid, Nitenpyram, MTI-446 Can effectively prevent and treat Brassica campestris L striped flea-beetle, prevention effect is superior to the preventive effect of single dose, and preventive effect time Long.In test scope of medication, target crop is had no adverse effects.
Application Example 13 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and multiple Join and prevent and treat the rice hoppers test of pesticide effectiveness
This experimental establishment is at Hanzhong suburban area, and test medicine is by Shaanxi Wei Erqi crop protection Company limited research and development, provide, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 25% Diacloden water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% thiophene Worm aqueous amine dispersible granule (autogamy), 10% imidacloprid wettable powder (commercial).
Rice hoppers insect pest index is investigated, in insect pest early period of origination dispenser, after dispenser 1 before medicine My god, 15 days, 30 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 10 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and compounding prevent and treat the rice hoppers test of pesticide effectiveness
As can be seen from Table 10, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid Can effectively prevent and treat rice hoppers after Fu Pei, prevention effect is superior to the preventive effect of single dose, and preventive effect Time is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten Fourth Ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating thereof View and admire the Flos Chrysanthemi Bemisia tabaci test of pesticide effectiveness
This experimental establishment is in suburb, Xi'an, Shaanxi, and test medicine is by Shaanxi Wei Erqi crop protection Company limited research and development, provide, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 20% Acetamiprid soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 20% MTI-446 can WP (autogamy).
Before medicine, investigation views and admires Flos Chrysanthemi Bemisia tabaci insect pest index, in insect pest early period of origination dispenser, dispenser Within latter 1 day, 15 days, 30 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 13 ring tebufenozide views and admires the Flos Chrysanthemi Bemisia tabaci test of pesticide effectiveness with Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating thereof
As can be seen from Table 13, after ring tebufenozide compounds with Acetamiprid, Nitenpyram, MTI-446 Can effectively prevent and treat and view and admire Flos Chrysanthemi Bemisia tabaci, prevention effect is superior to the preventive effect of single dose, and during preventive effect Between long.In test scope of medication, target crop is had no adverse effects.
Application Example ten five rings tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and multiple Join the preventing and treating Oryza sativa L. rice leaf roller test of pesticide effectiveness
This experimental establishment is in Hanzhong City suburb, Shaanxi Province, and test medicine is protected by Shaanxi Wei Erqi crop Protect company limited's research and development, provide, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 25% Diacloden water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% Clothianidin water dispersible granules (autogamy), 10% imidacloprid wettable powder (commercial).
Oryza sativa L. rice leaf roller insect pest index is investigated, in insect pest early period of origination dispenser, dispenser before medicine Within latter 1 day, 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 14 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and compounding preventing and treating Oryza sativa L. rice leaf roller drug effect thereof Test
As can be seen from Table 14, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid Can effectively prevent and treat Oryza sativa L. rice leaf roller after Fu Pei, prevention effect is superior to the preventive effect of single dose, and The preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example 16 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating thereof The rice-stem borer test of pesticide effectiveness
This experimental establishment is in Hanzhong City suburb, Shaanxi Province, and test medicine is protected by Shaanxi Wei Erqi crop Protect company limited's research and development, provide, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 20% Acetamiprid soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 20% furan worm Amine wettable powder (autogamy).
Rice-stem borer insect pest index is investigated, in insect pest early period of origination dispenser, after dispenser 1 before medicine My god, 3 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 15 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and the compounding preventing and treating rice-stem borer test of pesticide effectiveness thereof
As can be seen from Table 15, after ring tebufenozide compounds with Acetamiprid, Nitenpyram, MTI-446 Can effectively prevent and treat rice-stem borer, prevention effect is superior to the preventive effect of single dose, and the preventive effect time is long. In test scope of medication, target crop is had no adverse effects.
Application Example 17 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and multiple Join and prevent and treat the Camellia sinensis tea lesser leafhopper test of pesticide effectiveness
This experimental establishment is at Hanzhong suburban area, and test medicine is by Shaanxi Wei Erqi crop protection Company limited research and development, provide, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 25% Diacloden water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% thiophene Worm aqueous amine dispersible granule (autogamy), 10% imidacloprid wettable powder (commercial).
Tea lesser leafhopper insect pest index is investigated, in insect pest early period of origination dispenser, after dispenser 1 before medicine My god, 3 days, 7 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 16 ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid and the compounding preventing and treating tea lesser leafhopper test of pesticide effectiveness thereof
As can be seen from Table 16, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid Can effectively prevent and treat tea lesser leafhopper after Fu Pei, prevention effect is superior to the preventive effect of single dose, and preventive effect Time is long.In test scope of medication, target crop is had no adverse effects.
Application Example 18 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and compounding preventing and treating thereof The Fructus Cucumidis sativi melon aphid test of pesticide effectiveness
This experimental establishment is at Hanzhong suburban area, and test medicine is by Shaanxi Wei Erqi crop protection Company limited's research and development, offer, comparison medicament 200g/L chromafenozide suspending agent (autogamy) 20% Acetamiprid soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 20% MTI-446 can WP (autogamy).
Before medicine investigate Fructus Cucumidis sativi melon aphid insect damage index, in insect pest early period of origination dispenser, after dispenser 1 day, Within 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 17 ring tebufenozide and Acetamiprid, Nitenpyram, MTI-446 and the compounding preventing and treating Fructus Cucumidis sativi melon aphid test of pesticide effectiveness thereof
As can be seen from Table 17, after ring tebufenozide compounds with Acetamiprid, Nitenpyram, MTI-446 Can effectively prevent and treat Fructus Cucumidis sativi melon aphid, prevention effect is superior to the preventive effect of single dose, and the preventive effect time is long. In test scope of medication, target crop is had no adverse effects.
Application Example 19 ring tebufenozide and Diacloden, clothianidin, thiacloprid and compounding preventing and treating thereof The Cotton Gossypii cotten aphid test of pesticide effectiveness.
This experimental establishment is in Yang County, Shaanxi, and test medicine is by the limited public affairs of Shaanxi Wei Erqi crop protection Department's research and development, offer, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 25% thiophene worm Piperazine water dispersible granules (commercial), 480 grams per liters thiacloprid suspending agent (autogamy), 50% clothianidin Water dispersible granules (autogamy).
Before medicine investigate cotten aphid insect pest index, in insect pest early period of origination dispenser, after dispenser 1 day, 15 My god, 30 days investigation insect pest indexes calculate preventive effect.Experimental result is as follows:
Table 18 ring tebufenozide and Diacloden, clothianidin, thiacloprid and the compounding preventing and treating Cotton Gossypii cotten aphid test of pesticide effectiveness thereof
As can be seen from Table 18, ring tebufenozide and Diacloden, clothianidin, thiacloprid, imidacloprid, Can effectively prevent and treat Cotton Gossypii cotten aphid after Acetamiprid, Nitenpyram, MTI-446 are compounding, prevention effect is equal It is better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication to target crop invariably Good impact.
Application Example two bull's eye tebufenozide and imidacloprid, Acetamiprid, Nitenpyram and compounding anti- Control the cotton boll worm test of pesticide effectiveness.
This experimental establishment is in Heyang County, Shaanxi, and test medicine is limited by Shaanxi Wei Erqi crop protection Company's research and development, offer, comparison medicament 200g/L chromafenozide suspending agent (autogamy), 20% pyridine Worm amidine soluble powder (commercial), 10% Nitenpyram water preparation (commercial), 10% imidacloprid are wettable Property powder (commercial).
Before medicine investigate bollworm insect pest index, in insect pest early period of origination dispenser, after dispenser 1 day, Within 15 days, 30 days, investigate insect pest indexes and calculate preventive effect.Experimental result is as follows:
Table 19 ring tebufenozide and Diacloden, clothianidin, thiacloprid and the compounding preventing and treating cotton boll worm test of pesticide effectiveness thereof
As can be seen from Table 19, after ring tebufenozide compounds with imidacloprid, Acetamiprid, Nitenpyram Can effectively prevent and treat cotton boll worm, prevention effect is superior to the preventive effect of single dose, and the preventive effect time is long. In test scope of medication, target crop is had no adverse effects.

Claims (6)

1. a containing chromafenozide and the Pesticidal combination of anabasine, it is characterised in that: group Compound effective active composition is active components A and active component B, active components A and activity Composition B weight ratio is 1 60～60 1；Described active components A is ring tebufenozide, lives Property composition B in thiacloprid, clothianidin, Acetamiprid, Nitenpyram, the MTI-446 one Kind.
Containing chromafenozide the most according to claim 1 and the Pesticidal combination of anabasine, It is characterized in that: active components A, the weight ratio of active component B are 1 40～40 1.
Containing chromafenozide the most according to claim 2 and the Pesticidal combination of anabasine, It is characterized in that: ring tebufenozide is 20:1～1:20 with the weight ratio of thiacloprid；
Ring tebufenozide is 20 1～1 10 with the weight ratio of clothianidin；
Ring tebufenozide is 30:1～1:10 with the weight ratio of Acetamiprid；
Ring tebufenozide is 20 1～1 10 with the weight ratio of Nitenpyram；
Ring tebufenozide is 20 1～1 10 with the weight ratio of MTI-446.
Containing chromafenozide the most according to claim 3 and the Pesticidal combination of anabasine, It is characterized in that: compositions make wettable powder, water dispersible granules, suspending agent, suspension emulsion, Aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspending agent-suspending agent.
5. according to any one containing chromafenozide described in Claims 1-4 and anabasine Pesticidal combination is for preventing and treating the purposes of crop pest.
Purposes the most according to claim 5, it is characterised in that described insect includes: Aphid, flea beetle, thrips, striped rice borer, yellow rice borer, rice leaf roller, planthopper, diamondback moth, Tea lesser leafhopper, Pieris rapae, Prodenia litura, Americal rice leaf miner, bean-pod borer, melon aphid, tobacco powder Louse, beet armyworm, bollworm, 2 committee noctuids.
CN201610367679.7A 2012-03-16 2012-03-16 Insecticide composition containing chromafenozide and neonicotinoid Pending CN105941451A (en)

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