CN102524276A - Chlorantraniliprole and emamectin benzoate compounded suspending agent and preparation method thereof - Google Patents
Chlorantraniliprole and emamectin benzoate compounded suspending agent and preparation method thereof Download PDFInfo
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- CN102524276A CN102524276A CN2012100209060A CN201210020906A CN102524276A CN 102524276 A CN102524276 A CN 102524276A CN 2012100209060 A CN2012100209060 A CN 2012100209060A CN 201210020906 A CN201210020906 A CN 201210020906A CN 102524276 A CN102524276 A CN 102524276A
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Abstract
The invention discloses a chlorantraniliprole and emamectin benzoate compounded suspending agent and a preparation method thereof. The compounded suspending agent is composed of chlorantraniliprole, emamectin benzoate, dispersing agents, wetting agents, thickening agents, antifreezing agents, preservatives, antifoaming agents and water. The preparation method of the compounded suspending agent comprises adding chlorantraniliprole, emamectin benzoate, the dispersing agents, the wetting agents, the thickening agents, the antifreezing agents, the preservatives, the antifoaming agents and the water into a high-shearing dispersing mulser, and after dispersing evenly, performing sanding and screening to obtain the chlorantraniliprole and emamectin benzoate compounded suspending agent with the grain size to be 0.5-5mum. The compounded suspending agent is wide in pest control spectrum, prevents pests from easily generating chemical resistance, is simple in manufacturing process and low in production cost, does not need plenty of organic solvents, reduces costs, and reduces irritation of the organic solvents on operators and pollution to the environment.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of agriculture chemical compounding insecticide, be specifically related to composite suspending agent of Rynaxypyr and first dimension salt and preparation method thereof.
Background technology
Contain a large amount of organic solvents in the chemical pesticide, when making huge contribution, also brought serious pollution to natural environment for agricultural foison.Along with environmental regulation becomes better and approaching perfection day by day, the cry that reduces pesticide pollution is strong day by day.Develop safely, environmental protection and cheap novel liquid formulation are to reduce or eliminate the trend of the times of organic solvent harm having become agricultural chemicals development.Wherein, Water-borne modification is exactly one of dominant direction of formulations of pesticide development.This type pesticides new formulation also can increase new characteristic to agricultural chemicals; More can give full play to the function Characteristics of former medicine self, overcome and remedy the deficiency of the original formulation of agricultural chemicals, all lower to people and animals' toxicity and excitant; And can alleviate poisoning to crop; Improve physico chemistry and biological property, expanding application scope, the service life of prolongation medicament.
Agricultural chemicals suspension agent belongs to one of Water-borne modification novel form, is pesticide active ingredient and dispersant, wetting agent, thickener, antifoaming agent, antifreezing agent etc. are dispersed in the matrix water and the high dispersive that forms, stable suspended substance.Agricultural chemicals suspension agent has the advantage of wetting powder and missible oil concurrently: aspect drug effect, the suspending agent herbicide effects is superior to wetting powder, and the insecticide effect is then close with missible oil; Because agricultural chemicals suspension agent is dispersion medium with water, make it have environmental protection, cheap characteristics, reduced the use of a large amount of organic solvents simultaneously, production process safety, pollution-free; And suspending agent can mix with arbitrary proportion with water, and is easy to use, can reach bigger coverage rate after the dilution, can be processed to the formulation of high concentration.
The Rynaxypyr chemical name is 3-bromo-N-{4-chloro-2-methyl-6-[(methylamino) carbonyl] phenyl }-1-(3-chloro-2-pyridine radicals)-1H-pyrazoles-5-acid amides.Rynaxypyr is a kind of brand-new high-efficient low toxicity insecticide, and insecticidal mechanism is different with traditional insecticide.Rynaxypyr can efficiently activate ryania (muscle) acceptor of insect, makes it excessively discharge the calcium ion in the intracellular calcium store, causes the insect paralysis dead.Rynaxypyr has tags and stomach poison function; Show efficient, wide spectrum, hold and imitate and characteristics such as mechanism of action novelty, can be used for preventing and treating multiple lepidoptera pest, other commercialization insecticide varieties that its control efficiency obviously is superior to using in the current production; There is not cross resistance in other insecticides; And, can be used for the comprehensive regulation and the resistance management of insect, the various pests that is used to prevent and treat crops such as vegetables, beet, cotton to natural enemy insect safety; Like beet armyworm, tomato moth, diamond-back moth, imported cabbageworm, cotton bollworm, pink bollworm etc., each instar larvae all there is good control efficiency.
The full name of first dimension salt is an emamectin-benzoate, is farm antibiotics AVM B
1Structure modified outcome, its main mode of action is stomach poison function, and certain action of contace poison is arranged.The mechanism of action is the effect that strengthens neurotransmitter such as glutamate and GABA; Thereby make a large amount of chlorions get into nerve cell, make the cell function forfeiture, upset nerve conduction; Larva stops to get food very soon behind the contact medicament, irreversible paralysis takes place.Medicament can be penetrated into the epidermis of target crop, forms an effective storage layers, and long-term drug effect is arranged.Simultaneously, be prone to degraded because consumption is little, thereby environmentally safe, noresidue.Development test shows that first dimension salt has good effect under low-down dosage, and in the process of pest control, beneficial insect is not injured, to plant height safety.First dimension salt is a kind of efficient, high selection, green, environment-friendly type, biological source insecticide.
At present, do not see that having Rynaxypyr and first to tie up salt composite is the report of suspending agent.
Summary of the invention
The objective of the invention is the deficiency to prior art, provide a kind of wide to the control of insect spectrum, insect is difficult to develop immunity to drugs, and the Rynaxypyr of safety and environmental protection and the composite suspending agent of first dimension salt and preparation method thereof.Composite suspending agent preparation technology of the present invention is simple, production cost is lower.
Rynaxypyr insecticidal action mechanism is different from first dimension salt, the two has compositely not only been enlarged the control of insect spectrum for behind the suspending agent, and increased the action target spot of medicament, can delay pest resistance to insecticide.
The water-insoluble solid pesticide processing is become suspending agent, itself is a kind of thermodynamic unstable system between colloid and rough segmentation system.The present invention is added with auxiliary agents such as wetting agent, dispersant and antifreezing agent in the preparation process of suspending agent, the main effect of wetting agent and dispersant is: increase the dispersion medium viscosity, reduce the difference in specific gravity between dispersion medium and the disperse phase.Coordinate each other through auxiliary agent and active component, kept stability of formulation.The prepared suspending agent of the present invention has that particle diameter is little, biologically active is high and characteristics such as using dosage is low, and is medium with water, and it is environmentally friendly.
For reaching above purpose, the present invention has adopted following technical scheme:
Rynaxypyr and the composite suspending agent of first dimension salt, by weight percentage, the each component proportioning consists of in its raw material: Rynaxypyr 0.5～28%; First dimension salt 0.1～22%, dispersant 0.5～6%, wetting agent 0.5～5%; Thickener 0.1～4.5%, antifreezing agent 2～8%, preservative 0.1～0.6%; Antifoaming agent 0.1～1%, water 38.0～90.0%;
Said dispersant is one or both in sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate or the AEO;
Said wetting agent is one or both in isopropyl naphthalene sodium sulfonate, alkyl sulfonic acid calcium or the phenethyl phenol polyethenoxy ether sodium sulfate;
Said thickener is bentonite or gum Arabic;
Said antifreezing agent is ethylene glycol or glycerine;
Said preservative is Sodium Benzoate or potassium sorbate;
Said antifoaming agent is polyethers-silicone antifoam agent.
Further, said water is preferably distilled water or deionized water.
Said Rynaxypyr preferably accounts for 5～20% of component raw material gross weight, and first dimension salt preferably accounts for 1～15% of component raw material gross weight.
The preparation method of described Rynaxypyr and the composite suspending agent of first dimension salt; Press the material component proportioning Rynaxypyr, first dimension salt, dispersant, wetting agent, thickener, antifreezing agent, preservative, antifoaming agent and water are added in the high-shearing dispersion emulsifying machine, obtain Rynaxypyr and the composite suspending agent of first dimension salt that particle diameter is 0.5～5 μ m through sand milling, screening again.
Further, the rotating speed of said high-shearing dispersion emulsifying machine is preferably 1000～3000r/min, and the time is 25～60min.
The rotating speed of said sand milling is preferably 1400～1600r/min, and the time is 0.5～2.5h.
The present invention compared with prior art has following advantage:
(1) the composite suspending agent of the present invention is wide to the control of insect spectrum, and insect is difficult to develop immunity to drugs;
(2) preparation technology of the composite suspending agent of the present invention is simpler, and production cost is lower;
(3) do not use a large amount of organic solvents in the production process of the composite suspending agent of the present invention, safety and environmental protection, environmental pollution is little;
(4) the composite suspending agent of the present invention does not contain a large amount of organic solvents, meets the requirement of environmental type agricultural chemicals, is appropriate to the scale of chemical production.
Embodiment
Below in conjunction with embodiment the present invention is described further, but the scope that the present invention requires to protect is not limited thereto.
Embodiment 1
Take by weighing Rynaxypyr 0.5kg, first dimension salt 22.0kg, sodium lignin sulfonate 2.5kg, isopropyl naphthalene sodium sulfonate 1.5kg, bentonite 1.8kg, ethylene glycol 5.2kg, potassium sorbate 0.1kg, polyethers-silicone antifoam agent 0.4kg and distilled water 66.0kg in high-shearing dispersion emulsifying machine; 30min under the 2500r/min rotating speed; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 22.5% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 2000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 12 days after the medication of wild cabbage prodenia litura is respectively 94.3% and 92.7%.
Embodiment 2
Take by weighing Rynaxypyr 28.0kg, first dimension salt 0.1kg, sodium metnylene bis-naphthalene sulfonate 0.5kg, alkyl sulfonic acid calcium 3.5kg, gum Arabic 1.2kg, glycerine 4.8kg, Sodium Benzoate 0.4kg, polyethers-silicone antifoam agent 0.5kg and deionized water 61.0kg in high-shearing dispersion emulsifying machine; 35min under the 2000r/min rotating speed; Be the sand mill sand milling 2.5h of 1400r/min again through rotating speed, it is that 0.5～5 μ m, content are 28.1% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 3000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 5th day and 10 days after the medication of cotton cotton bollworm is respectively 94.2% and 96.7%.
Embodiment 3
Take by weighing Rynaxypyr 0.5kg, first dimension salt 0.1kg, AEO 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 0.5kg, bentonite 1.4kg, ethylene glycol 6.0kg, potassium sorbate 0.2kg, polyethers-silicone antifoam agent 0.3kg and distilled water 90.0kg in high-shearing dispersion emulsifying machine; At 1800r/min rotating speed down cut 45min; Be the sand mill sand milling 1.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 0.6% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 2000 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 5th day and 10 days after the medication of wild cabbage prodenia litura is respectively 86.1% and 85.5%, and the control efficiency of the 6th day and 12 days after the medication of cotton cotton bollworm is respectively 88.4% and 84.3%.
Embodiment 4
Take by weighing Rynaxypyr 28.0kg, first dimension salt 22.0kg, sodium lignin sulfonate 3.0kg, sodium metnylene bis-naphthalene sulfonate 3.0k, isopropyl naphthalene sodium sulfonate 2.0kg, gum Arabic 1.0kg, glycerine 2.0kg, Sodium Benzoate 0.2kg, polyethers-silicone antifoam agent 0.8kg and deionized water 38.0kg in high-shearing dispersion emulsifying machine; At 1000r/min rotating speed down cut 60min; Be the sand mill sand milling 1.0h of 1600r/min again through rotating speed, it is that 0.5～5 μ m, content are 50.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 4500 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 12 days after the medication of soybean prodenia litura is respectively 94.8% and 92.5%.
Embodiment 5
Take by weighing Rynaxypyr 25.0kg, first dimension salt 20.0kg, sodium lignin sulfonate 1.0kg, AEO 1.0kg, alkyl sulfonic acid calcium 1.0kg, bentonite 0.1kg, ethylene glycol 4.2kg, potassium sorbate 0.6kg, polyethers-silicone antifoam agent 0.4kg and distilled water 46.7kg in high-shearing dispersion emulsifying machine; 25min under the 3000r/min rotating speed; Be the sand mill sand milling 2.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 45.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 4000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 7th day and 14 days after the medication of Chinese cabbage prodenia litura is respectively 94.9% and 90.3%.
Embodiment 6
Take by weighing Rynaxypyr 20.2kg, first dimension salt 15.8kg, sodium metnylene bis-naphthalene sulfonate 0.5kg, AEO 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 1.6kg, gum Arabic 2.0kg, glycerine 8.0kg, Sodium Benzoate 0.1kg, polyethers-silicone antifoam agent 1.0kg and deionized water 49.8kg in high-shearing dispersion emulsifying machine; 40min under the 2200r/min rotating speed; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 36.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 2000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 10 days after the medication of cotton cotton bollworm is respectively 93.8% and 96.3%.
Embodiment 7
Take by weighing Rynaxypyr 16.5kg, first dimension salt 12.5kg, sodium lignin sulfonate 1.8kg, isopropyl naphthalene sodium sulfonate 1.0kg, alkyl sulfonic acid calcium 3.2kg, bentonite 2.5kg, ethylene glycol 5.5kg, potassium sorbate 0.3kg, polyethers-silicone antifoam agent 0.7kg and distilled water 49.8kg in high-shearing dispersion emulsifying machine; 50min under the 1500r/min rotating speed; Be the sand mill sand milling 1.0h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 29.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 3000 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 6th day and 12 days after the medication of soybean prodenia litura is respectively 92.5% and 93.8%, and the control efficiency of the 5th day and 10 days after the medication of cotton cotton bollworm is respectively 92.1% and 94.3%.
Embodiment 8
Take by weighing Rynaxypyr 14.0kg, first dimension salt 10.0kg, sodium metnylene bis-naphthalene sulfonate 2.6kg, isopropyl naphthalene sodium sulfonate 2.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 0.4kg, gum Arabic 3.0kg, glycerine 4.5kg, Sodium Benzoate 0.15kg, polyethers-silicone antifoam agent 0.35kg and deionized water 63.0kg in high-shearing dispersion emulsifying machine; 55min under the 2500r/min rotating speed; Be the sand mill sand milling 0.5h of 1600r/min again through rotating speed, it is that 0.5～5 μ m, content are 24.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 4000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 7th day and 14 days after the medication of cotton cotton bollworm is respectively 91.9% and 86.1%.
Embodiment 9
Take by weighing Rynaxypyr 10.0kg, first dimension salt 5.0kg, AEO 3.2kg, alkyl sulfonic acid calcium 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 0.8kg, bentonite 4.5kg, ethylene glycol 2.5kg, potassium sorbate 0.2kg, polyethers-silicone antifoam agent 0.6kg and distilled water 72.2kg in high-shearing dispersion emulsifying machine; 55min under the 1200r/min rotating speed; Be the sand mill sand milling 1.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 15.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 1500 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 6th day and 10 days after the medication of wild cabbage prodenia litura is respectively 91.6% and 93.4%, and the control efficiency of the 7th day and 12 days after the medication of cotton cotton bollworm is respectively 90.5% and 92.3%.
Embodiment 10
Take by weighing Rynaxypyr 0.8kg, first dimension salt 1.2kg, sodium metnylene bis-naphthalene sulfonate 4.0kg, isopropyl naphthalene sodium sulfonate 5.0kg, gum Arabic 0.5kg, glycerine 6.5kg, Sodium Benzoate 0.5kg, polyethers-silicone antifoam agent 0.5kg and deionized water 81.0kg in high-shearing dispersion emulsifying machine; 40min under the 2600r/min rotating speed; Be the sand mill sand milling 2.0h of 1400r/min again through rotating speed, it is that 0.5～5 μ m, content are 2.0% Rynaxypyr and the composite suspending agent of first dimension salt that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 2500 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 5th day and 10 days after the medication of wild cabbage prodenia litura is respectively 83.2% and 85.7%, and the control efficiency of the 7th day and 15 days after the medication of Chinese cabbage prodenia litura is respectively 85.1% and 80.3%.
Above embodiment shows that Rynaxypyr and the composite suspending agent disinfestation of first dimension salt that the present invention prepares are effective.The composite suspending agent of the present invention is wide to the control of insect spectrum, and insect is difficult to develop immunity to drugs; Preparation technology is simpler, and production cost is lower; Do not need a large amount of organic solvents, both reduced cost, reduced organic solvent again to operator's stimulation with to the pollution of environment.
Claims (6)
1. the composite suspending agent of Rynaxypyr and first dimension salt is characterized in that, by weight percentage; The each component proportioning consists of in its raw material: Rynaxypyr 0.5～28%, first dimension salt 0.1～22%, dispersant 0.5～6%; Wetting agent 0.5～5%, thickener 0.1～4.5%, antifreezing agent 2～8%; Preservative 0.1～0.6%, antifoaming agent 0.1～1%, water 38.0～90.0%;
Said dispersant is one or both in sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate or the AEO;
Said wetting agent is one or both in isopropyl naphthalene sodium sulfonate, alkyl sulfonic acid calcium or the phenethyl phenol polyethenoxy ether sodium sulfate;
Said thickener is bentonite or gum Arabic;
Said antifreezing agent is ethylene glycol or glycerine;
Said preservative is Sodium Benzoate or potassium sorbate;
Said antifoaming agent is polyethers-silicone antifoam agent.
2. the composite suspending agent of described Rynaxypyr of claim 1 and first dimension salt is characterized in that said water is distilled water or deionized water.
3. the composite suspending agent of described Rynaxypyr of claim 1 and first dimension salt is characterized in that said Rynaxypyr accounts for 5～20% of component raw material gross weight, and first dimension salt accounts for 1～15% of component raw material gross weight.
4. each described Rynaxypyr of claim 1-3 and first are tieed up the preparation method of the composite suspending agent of salt; It is characterized in that; Press the material component proportioning Rynaxypyr, first dimension salt, dispersant, wetting agent, thickener, antifreezing agent, preservative, antifoaming agent and water are added in the high-shearing dispersion emulsifying machine, obtain Rynaxypyr and the composite suspending agent of first dimension salt that particle diameter is 0.5～5 μ m through sand milling, screening again.
5. preparation method according to claim 4 is characterized in that, the rotating speed of said high-shearing dispersion emulsifying machine is 1000～3000r/min, and the time is 25～60min.
6. preparation method according to claim 4 is characterized in that, the rotating speed of said sand milling is 1400～1600r/min, and the time is 0.5～2.5h.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
| CN114052036A (en) * | 2021-12-31 | 2022-02-18 | 山东耘歌生物科技有限公司 | Insecticide containing chlorantraniliprole and emamectin benzoate as well as preparation method and application thereof |
| CN114431248A (en) * | 2022-02-07 | 2022-05-06 | 陕西先农生物科技有限公司 | Suspending agent containing abamectin and chlorantraniliprole |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548680A (en) * | 2009-04-23 | 2009-10-07 | 惠州市中迅化工有限公司 | Pesticidal composition containing emamectin benzoate and chlorantraniliprole |
| CN101554170A (en) * | 2009-05-15 | 2009-10-14 | 陕西标正作物科学有限公司 | Chlorantraniliprole and emamectin benzoate insecticidal composition |
-
2012
- 2012-01-30 CN CN2012100209060A patent/CN102524276A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548680A (en) * | 2009-04-23 | 2009-10-07 | 惠州市中迅化工有限公司 | Pesticidal composition containing emamectin benzoate and chlorantraniliprole |
| CN101554170A (en) * | 2009-05-15 | 2009-10-14 | 陕西标正作物科学有限公司 | Chlorantraniliprole and emamectin benzoate insecticidal composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
| CN114052036A (en) * | 2021-12-31 | 2022-02-18 | 山东耘歌生物科技有限公司 | Insecticide containing chlorantraniliprole and emamectin benzoate as well as preparation method and application thereof |
| CN114431248A (en) * | 2022-02-07 | 2022-05-06 | 陕西先农生物科技有限公司 | Suspending agent containing abamectin and chlorantraniliprole |
| CN114431248B (en) * | 2022-02-07 | 2023-09-01 | 陕西先农生物科技有限公司 | Suspending agent containing avermectin and chlorantraniliprole |
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Application publication date: 20120704 |