CN102524275A - Flubendiamide and abamectin compounded suspending agent and preparation method thereof - Google Patents
Flubendiamide and abamectin compounded suspending agent and preparation method thereof Download PDFInfo
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- CN102524275A CN102524275A CN2012100185460A CN201210018546A CN102524275A CN 102524275 A CN102524275 A CN 102524275A CN 2012100185460 A CN2012100185460 A CN 2012100185460A CN 201210018546 A CN201210018546 A CN 201210018546A CN 102524275 A CN102524275 A CN 102524275A
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Abstract
The invention discloses a flubendiamide and abamectin compounded suspending agent and a preparation method thereof. The compounded suspending agent comprises the following components in percentage by weight: 0.2 to 40% of flubendiamide, 0.5 to 15% of abamectin, 1 to 5% of dispersing agent, 0.5 to 4% of wetting agent, 0.1 to 4% of thickening agent, 1 to 8% of anti-freezing agent, 0.1 to 0.6% of preservative, 0.1 to 0.5% of foam breaking agent, and 31.0 to 88.5% of water. The compounded suspending agent is prepared by shearing and dispersing the flubendiamide, the abamectin, the dispersing agent, the wetting agent, the thickening agent, the anti-freezing agent, the preservative, the foam breaking agent and the water uniformly according to the proportion, and then sanding and screening. The compounded suspending agent provided by the invention can control a wide range of pests, and the pests hardly generate drug-resistant strains; the preparation technology is simpler and the production cost is lower; and only less organic solvent is needed, so that not only is the cost reduced, but also irritation on operators and pollution to the environment by the organic solvent are reduced.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of agriculture chemical compounding insecticide, be specifically related to fipronil bisamide and abamectin compounded suspending agent and preparation method thereof.
Background technology
Contain a large amount of organic solvents in the chemical pesticide, when making huge contribution, also brought serious pollution to natural environment for agricultural foison.Along with environmental regulation becomes better and approaching perfection day by day, the cry that reduces pesticide pollution is strong day by day.Develop safely, environmental protection and cheap novel liquid formulation are to reduce or eliminate the trend of the times of organic solvent harm having become agricultural chemicals development.Wherein, Water-borne modification is exactly one of dominant direction of formulations of pesticide development.This type pesticides new formulation also can increase new characteristic to agricultural chemicals; More can give full play to the function Characteristics of former medicine self, overcome and remedy the deficiency of the original formulation of agricultural chemicals, all lower to people and animals' toxicity and excitant; And can alleviate poisoning to crop; Improve physico chemistry and biological property, expanding application scope, the service life of prolongation medicament.
Agricultural chemicals suspension agent belongs to one of Water-borne modification novel form, is pesticide active ingredient and dispersant, wetting agent, thickener, antifoaming agent, antifreezing agent etc. are dispersed in the matrix water and the high dispersive that forms, stable suspended substance.Agricultural chemicals suspension agent has the advantage of wetting powder and missible oil concurrently: aspect drug effect, the suspending agent herbicide effects is superior to wetting powder, and the insecticide effect is then close with missible oil; Because agricultural chemicals suspension agent is dispersion medium with water, make it have environmental protection, cheap characteristics, reduced in a large number with an organic solvent production process safety, pollution-free simultaneously; And suspending agent can mix with arbitrary proportion with water, and is easy to use, can reach bigger coverage rate after the dilution, can be processed to the formulation of high concentration.
The fipronil bisamide chemical name is 3-iodo-N '-(2-mesyl)-1,1-dimethyl ethyl group-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-0-tolyl } phthalic amide.Belong to novel phthalic amide insecticides, insect ryania (muscle) receptor activators, different fully with the mechanism of action of insecticide in the past, can make excessively to discharge calcium ion in the insect bodies, cause insect death.This insecticide does not produce cross resistance with existing insecticide, and efficient, safety, is rising novel pesticide.
AVM has insect and mite class tags and stomach poison function, and faint fumigation action is arranged, no systemic action; But blade is had very strong osmosis, can kill subepidermal insect, and the longevity of residure is long; What its mechanism of action was different with general insecticide is that it disturbs neurophysiology movable; Stimulate to discharge y-aminobutyric acid, and y-aminobutyric acid has inhibitory action to arthropodan nerve conduction, little to the damage of beneficial insect.Its formulation is main with missible oil mainly, and long-term use of AVM list agent is prone to cause pest resistance constantly to increase.
At present, do not see that fipronil bisamide and abamectin compounded for the report of suspending agent is arranged.
Summary of the invention
The objective of the invention is deficiency to prior art; A kind of control of insect spectrum is provided extensively; The action target spot of medicament is many, delays pest resistance to insecticide and suspending agent and has particle diameter is little, biologically active is high and using dosage is low fipronil bisamide and abamectin compounded suspending agent and preparation method thereof.Composite suspending agent preparation technology of the present invention is simple, production cost is lower.
Insect is serious day by day to the pesticide resistance that AVM produced; And the mechanism of action of fipronil bisamide is different from AVM fully; The two is composite for not only having enlarged the control of insect spectrum behind the suspending agent, and increased the action target spot of medicament, can delay pest resistance to insecticide.
The water-insoluble solid pesticide processing is become suspending agent, itself is a kind of thermodynamic unstable system between colloid and rough segmentation system.The present invention adds specific auxiliary agents such as wetting agent, dispersant and antifreezing agent in the preparation process of suspending agent, wherein the main effect of wetting agent and dispersant is: increase the dispersion medium viscosity, reduce the difference in specific gravity between dispersion medium and the disperse phase.Coordinate each other through auxiliary agent and active component, kept stability of formulation.The prepared suspending agent of the present invention has that particle diameter is little, biologically active is high and characteristics such as using dosage is low, and is medium with water, and it is environmentally friendly.
For reaching above purpose, the present invention has adopted following technical scheme:
Fipronil bisamide and abamectin compounded suspending agent are pressed the weight percent meter of each component at said composite suspending agent, and its component consists of: fipronil bisamide 0.2～40%; AVM 0.5～15%, dispersant 1～5%, wetting agent 0.5～4%; Thickener 0.1～4%, antifreezing agent 1～8%, preservative 0.1～0.6%; Antifoaming agent 0.1～0.5%, water 31.0～88.5%;
Said dispersant is one or both in calcium lignosulfonate, Negel and the AEO;
Said wetting agent is one or both in sodium alkyl sulfate, sodium alkyl sulfonate and the phenethyl phenol polyethenoxy ether sodium sulfate;
Said thickener is xanthans or polyvinyl alcohol;
Said antifreezing agent is ethylene glycol or urea;
Said preservative is sodium salicylate or Sodium Benzoate;
Said antifoaming agent is polyethers-silicone antifoam agent.
Further, said water is preferably distilled water or deionized water.
The percentage by weight that said fipronil bisamide accounts for composite suspending agent is preferably 5～30%.
The preparation method of described fipronil bisamide and abamectin compounded suspending agent: shear after by proportioning fipronil bisamide, AVM, dispersant, wetting agent, thickener, antifreezing agent, preservative, antifoaming agent and water being mixed and be dispersed to evenly, obtaining particle diameter through sand milling, screening again is fipronil bisamide and the abamectin compounded suspending agent of 0.5～5 μ m.
Further, the rotating speed of said dispersion is preferably 1100～3000r/min, and the time is preferably 30～60min.
The rotating speed of said sand milling is preferably 1400～1600r/min, and the time is preferably 1～3h.
Said row is sheared and is disperseed preferably to carry out through shearing dispersion emulsifying machine.
The present invention compared with prior art has following advantage:
(1) the composite suspending agent of the present invention is wide to the control of insect spectrum, and insect is difficult to develop immunity to drugs;
(2) preparation technology of the composite suspending agent of the present invention is simpler, and production cost is lower;
(3) do not use a large amount of organic solvents in the production process of the composite suspending agent of the present invention, safety and environmental protection, environmental pollution is little;
(4) the composite suspending agent of the present invention does not contain a large amount of organic solvents, meets the requirement of environmental type agricultural chemicals, is appropriate to the scale of chemical production.
Embodiment
Below in conjunction with embodiment the present invention is described further, but the scope that the present invention requires to protect is not limited thereto.
Embodiment 1
Take by weighing fipronil bisamide 0.2kg, AVM 15.0kg, calcium lignosulfonate 1.8kg, sodium alkyl sulfate 2.0kg, xanthans 1.5kg, ethylene glycol 5.0kg, sodium salicylate 0.15kg, polyethers-silicone antifoam agent 0.35kg and distilled water 74.0kg in high-shearing dispersion emulsifying machine; Under the 2500r/min rotating speed, disperse 30min; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 15.2% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 2500 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 12 days after the medication of cotton cotton bollworm is respectively 91.2% and 90.5%.
Embodiment 2
Take by weighing fipronil bisamide 40.0kg, AVM 0.5kg, Negel 1.2kg, sodium alkyl sulfonate 1.8kg, polyvinyl alcohol 0.1kg, urea 4.5kg, Sodium Benzoate 0.2kg, polyethers-silicone antifoam agent 0.3kg and deionized water 51.4kg in high-shearing dispersion emulsifying machine; Under the 2000r/min rotating speed, disperse 35min; Be the sand mill sand milling 2.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 40.5% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 5000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 5th day and 10 days after the medication of wild cabbage beet armyworm is respectively 91.2% and 93.5%.
Embodiment 3
Take by weighing fipronil bisamide 0.2kg, AVM 0.5kg, AEO 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 2.3kg, xanthans 1.0kg, ethylene glycol 5.5kg, sodium salicylate 0.5kg, polyethers-silicone antifoam agent 0.5kg and distilled water 88.5kg in high-shearing dispersion emulsifying machine; Under the 2600r/min rotating speed, disperse 45min; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 0.7% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 2000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 12 days after the medication of cotton beet armyworm is respectively 85.6% and 82.8%.
Embodiment 4
Take by weighing fipronil bisamide 40.0kg, AVM 15.0kg, calcium lignosulfonate 3.0kg, Negel 2.0kg, sodium alkyl sulfate 0.5kg, polyvinyl alcohol 2.0kg, urea 6.0kg, Sodium Benzoate 0.3kg, polyethers-silicone antifoam agent 0.2kg and deionized water 31.0kg in high-shearing dispersion emulsifying machine; Under the 2000r/min rotating speed, disperse 60min; Be the sand mill sand milling 1.0h of 1600r/min again through rotating speed, it is that 0.5～5 μ m, content are 55.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 3000 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 5th day and 10 days after the medication of cotton cotton bollworm is respectively 92.7% and 95.5%, and the control efficiency of the 6th day and 12 days after the medication of wild cabbage beet armyworm is respectively 93.6% and 95.7%.
Embodiment 5
Take by weighing fipronil bisamide 34.0kg, AVM 12.0kg, calcium lignosulfonate 1.5kg, AEO 1.5kg, sodium alkyl sulfonate 1.5kg, xanthans 2.5kg, ethylene glycol 5.6kg, sodium salicylate 0.15kg, polyethers-silicone antifoam agent 0.25kg and distilled water 41.0kg in high-shearing dispersion emulsifying machine; Under the 3000r/min rotating speed, disperse 30min; Be the sand mill sand milling 3h of 1400r/min again through rotating speed, it is that 0.5～5 μ m, content are 46.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 5000 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 7th day and 14 days after the medication of cotton cotton bollworm is respectively 91.8% and 87.6%, and the control efficiency of the 7th day and 10 days after the medication of cotton beet armyworm is respectively 92.1% and 94.8%.
Embodiment 6
Take by weighing fipronil bisamide 30.0kg, AVM 10.0kg, Negel 1.4kg, AEO 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 1.6kg, polyvinyl alcohol 1.2kg, urea 4.8kg, Sodium Benzoate 0.35kg, polyethers-silicone antifoam agent 0.15kg and deionized water 49.5kg in high-shearing dispersion emulsifying machine; Under the 2200r/min rotating speed, disperse 40min; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 40.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 3000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 10 days after the medication of wild cabbage beet armyworm is respectively 94.2% and 96.5%.
Embodiment 7
Take by weighing fipronil bisamide 24.0kg, AVM 8.0kg, calcium lignosulfonate 3.8kg, sodium alkyl sulfate 0.6kg, sodium alkyl sulfonate 0.6kg, xanthans 1.6kg, ethylene glycol 5.4kg, sodium salicylate 0.1kg, polyethers-silicone antifoam agent 0.4kg and distilled water 55.5kg in high-shearing dispersion emulsifying machine; Under the 1800r/min rotating speed, disperse 50min; Be the sand mill sand milling 2.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 32.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 2000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 5th day and 10 days after the medication of cotton beet armyworm is respectively 90.9% and 95.2%.
Embodiment 8
Take by weighing fipronil bisamide 20.0kg, AVM 6.0kg, Negel 2.6kg, sodium alkyl sulfate 1.0kg, phenethyl phenol polyethenoxy ether sodium sulfate 1.4kg, polyvinyl alcohol 0.8kg, urea 1.0kg, Sodium Benzoate 0.55kg, polyethers-silicone antifoam agent 0.45kg and deionized water 66.2kg in high-shearing dispersion emulsifying machine; Under the 2500r/min rotating speed, disperse 35min; Be the sand mill sand milling 2h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 26.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 4000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 8th day and 16 days after the medication of cotton cotton bollworm is respectively 90.1% and 81.3%.
Embodiment 9
Take by weighing fipronil bisamide 12.0kg, AVM 3.0kg, AEO 1.5kg, sodium alkyl sulfonate 1.5kg, phenethyl phenol polyethenoxy ether sodium sulfate 2.0kg, xanthans 3.0kg, ethylene glycol 3.2kg, sodium salicylate 0.4kg, polyethers-silicone antifoam agent 0.1kg and distilled water 73.3kg in high-shearing dispersion emulsifying machine; Under the 1500r/min rotating speed, disperse 55min; Be the sand mill sand milling 1.5h of 1600r/min again through rotating speed, it is that 0.5～5 μ m, content are 15.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion; Use 1500 times of liquid of said preparation to carry out field control effectiveness test; Control efficiency to the 6th day and 12 days after the medication of cotton beet armyworm is respectively 91.8% and 94.5%, and the control efficiency of the 4th day and 10 days after the medication of wild cabbage beet armyworm is respectively 90.3% and 95.9%.
Embodiment 10
Take by weighing fipronil bisamide 4.0kg, AVM 2.0kg, Negel 4.0kg, sodium alkyl sulfate 3.0kg, polyvinyl alcohol 3.5kg, urea 8.0kg, Sodium Benzoate 0.3kg, polyethers-silicone antifoam agent 0.2kg and deionized water 75.0kg in high-shearing dispersion emulsifying machine; Under the 1100r/min rotating speed, disperse 50min; Be the sand mill sand milling 1.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 6.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 1500 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 7th day and 10 days after the medication of wild cabbage prodenia litura is respectively 90.5% and 91.3%.
Embodiment 11
Take by weighing fipronil bisamide 0.8kg, AVM 1.2kg, calcium lignosulfonate 2.0kg, sodium alkyl sulfonate 4.0kg, xanthans 4.0kg, ethylene glycol 6.4kg, sodium salicylate 0.6kg, polyethers-silicone antifoam agent 0.4kg and distilled water 80.6kg in high-shearing dispersion emulsifying machine; Under the 2800r/min rotating speed, disperse 38min; Be the sand mill sand milling 2.5h of 1500r/min again through rotating speed, it is that 0.5～5 μ m, content are 2.0% fipronil bisamide and abamectin compounded suspending agent that screening obtains particle diameter.Carry out dispenser and biologically active statistics according to the pesticide field efficacy medicine test criterion, use 1000 times of liquid of said preparation to carry out field control effectiveness test, the control efficiency of the 6th day and 10 days after the medication of wild cabbage beet armyworm is respectively 89.7% and 91.2%.
Above embodiment shows that fipronil bisamide and abamectin compounded suspending agent disinfestation that the present invention prepares are effective.The composite suspending agent of the present invention is wide to the control of insect spectrum, and insect is difficult to develop immunity to drugs; Preparation technology is simpler, and production cost is lower; Do not need a large amount of organic solvents, both reduced cost, reduced organic solvent again to operator's stimulation with to the pollution of environment.
Claims (7)
1. fipronil bisamide and abamectin compounded suspending agent is characterized in that, press the weight percent meter of each component at said composite suspending agent; Its component consists of: fipronil bisamide 0.2～40%, AVM 0.5～15%, dispersant 1～5%; Wetting agent 0.5～4%, thickener 0.1～4%, antifreezing agent 1～8%; Preservative 0.1～0.6%, antifoaming agent 0.1～0.5%, water 31.0～88.5%;
Said dispersant is one or both in calcium lignosulfonate, Negel and the AEO;
Said wetting agent is one or both in sodium alkyl sulfate, sodium alkyl sulfonate and the phenethyl phenol polyethenoxy ether sodium sulfate;
Said thickener is xanthans or polyvinyl alcohol;
Said antifreezing agent is ethylene glycol or urea;
Said preservative is sodium salicylate or Sodium Benzoate;
Said antifoaming agent is polyethers-silicone antifoam agent.
2. fipronil bisamide according to claim 1 and abamectin compounded suspending agent is characterized in that: said water is distilled water or deionized water.
3. fipronil bisamide according to claim 1 and abamectin compounded suspending agent is characterized in that: the percentage by weight that said fipronil bisamide accounts for composite suspending agent is 5～30%.
4. the preparation method of each described fipronil bisamide of claim 1-3 and abamectin compounded suspending agent; It is characterized in that: shear after by proportioning fipronil bisamide, AVM, dispersant, wetting agent, thickener, antifreezing agent, preservative, antifoaming agent and water being mixed and be dispersed to evenly, obtaining particle diameter through sand milling, screening again is fipronil bisamide and the abamectin compounded suspending agent of 0.5～5 μ m.
5. preparation method according to claim 4 is characterized in that: the rotating speed of said dispersion is 1100～3000r/min, and the time is 30～60min.
6. preparation method according to claim 4 is characterized in that: the rotating speed of said sand milling is 1400～1600r/min, and the time is 1～3h.
7. preparation method according to claim 4 is characterized in that: it is to carry out through shearing dispersion emulsifying machine that said row is sheared dispersion.
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| CN2012100185460A CN102524275A (en) | 2012-01-18 | 2012-01-18 | Flubendiamide and abamectin compounded suspending agent and preparation method thereof |
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| CN2012100185460A CN102524275A (en) | 2012-01-18 | 2012-01-18 | Flubendiamide and abamectin compounded suspending agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104186505A (en) * | 2014-09-25 | 2014-12-10 | 江苏省绿盾植保农药实验有限公司 | Insecticidal composition containing abamectin and flubendiamide and application thereof |
| CN105454259A (en) * | 2015-12-16 | 2016-04-06 | 济南舜昊生物科技有限公司 | Insecticidal combination containing o-phenylenediamine insecticide and abamectin |
| CN106804606A (en) * | 2017-02-10 | 2017-06-09 | 北京明德立达农业科技有限公司 | A kind of microcapsule suspension suspending agent of AVM and fluorobenzene insect amide and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101601394A (en) * | 2009-07-14 | 2009-12-16 | 江苏龙灯化学有限公司 | A kind of insecticides with synergistic effect |
| CN101669493A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Synergistic pesticide combination |
-
2012
- 2012-01-18 CN CN2012100185460A patent/CN102524275A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101601394A (en) * | 2009-07-14 | 2009-12-16 | 江苏龙灯化学有限公司 | A kind of insecticides with synergistic effect |
| CN101669493A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Synergistic pesticide combination |
Non-Patent Citations (1)
| Title |
|---|
| 郭武棣 主编: "《液体制剂（第三版）》", 31 January 2004, article "第十二章 悬浮剂", pages: 199 - 208 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104186505A (en) * | 2014-09-25 | 2014-12-10 | 江苏省绿盾植保农药实验有限公司 | Insecticidal composition containing abamectin and flubendiamide and application thereof |
| CN105454259A (en) * | 2015-12-16 | 2016-04-06 | 济南舜昊生物科技有限公司 | Insecticidal combination containing o-phenylenediamine insecticide and abamectin |
| CN106804606A (en) * | 2017-02-10 | 2017-06-09 | 北京明德立达农业科技有限公司 | A kind of microcapsule suspension suspending agent of AVM and fluorobenzene insect amide and preparation method thereof |
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Application publication date: 20120704 |