CN101518273A - Biological compound pesticide and preparation method thereof - Google Patents

Biological compound pesticide and preparation method thereof Download PDF

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Publication number
CN101518273A
CN101518273A CN200910010740A CN200910010740A CN101518273A CN 101518273 A CN101518273 A CN 101518273A CN 200910010740 A CN200910010740 A CN 200910010740A CN 200910010740 A CN200910010740 A CN 200910010740A CN 101518273 A CN101518273 A CN 101518273A
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kilograms
juice
water
portions
sodium
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王基兴
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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Abstract

The invention provides a biological compound pesticide and a preparation method thereof. The pesticide is prepared from the following raw materials by weight portion: 24 to 25 portions of radish/onion/garlic juice, 14 to 15 portions of chili/zanthoxylum juice, 6 to 7 portions of pine-leaf alcohol extract, 11 to 12 portions of plant-ash leaching liquor, 4 to 5 portions of sodium chloride aqueous solution, 5 to 7 portions of magnesium chloride aqueous solution and 3 portions of carboxymethyl sodium cellulose aqueous solution which are mixed and stirred. Through a process A of preparing raw materials and a process B of preparing pesticide, the raw materials are mixed, stirred and turned into the biological compound pesticide. The pesticide is formed by mainly taking nontoxic botanical raw materials as a leading part, matching and compounding the main part with mineral raw materials, has the functions of contact-poisoning, stomach-poisoning, fumigating, sucking, trapping-killing, anaesthetizing, exciting and repelling pests, inhibiting and killing bacteria, is harmless to people and animals, causes no environmental pollution, and is applicable to the control on plant diseases and insect pests.

Description

A kind of biological compound pesticide and preparation method
Technical field
What the present invention proposed is the agricultural chemicals of agriculture field, specifically a kind of biological compound pesticide and preparation method.
Background technology
Before the present invention proposed, useful microorganism extracts matter was used as agricultural chemicals, is used for to plant sterilization and desinsection.Also useful plant extracts plays killing action to sick worm.But because the raw material difference, the extracting method difference that adopt, its effect is also desirable not to the utmost.For example, use root of langdu plant extracts as agricultural chemicals, can only be effective to insect, then invalid to disease.Also as, with leaf tobacco extract as agricultural chemicals, also can only play the effect of desinsection, disease is not had effect yet.Because it is harmless to adopt biopesticide to have, and does not destroy the advantage of environment, so be developing direction.
Summary of the invention
Existing biopesticide raw material is single in order to overcome, single, the unsettled shortcoming of effect of effect, and the present invention proposes a kind of biological compound pesticide and preparation method.The mode of this agricultural chemicals by adopting the botanical extract that can eat to combine with the mineral raw material, solve efficiently, can sterilization again can desinsection technical problem.
The scheme that technical solution problem of the present invention is adopted is:
By radish, onion, garlic juice, capsicum, Chinese prickly ash juice, the pine tree leaf alcohol extract, the ash leaching liquor, sodium-chloride water solution, magnesium chloride brine, sodium carboxymethyl cellulose solution is mixed and made into.
Feedstock production:
Get radish, onion, garlic raw material squeezing taking juice as radish, onion, garlic juice;
Get capsicum, the Chinese prickly ash raw material adds the water infusion and gets juice as capsicum, Chinese prickly ash juice;
Get pine needle lixiviate in 95% alcohol and get juice as the pine tree leaf alcohol extract;
Get the ash extracting in water aqueous solution as the ash leaching liquor;
Get sodium chloride and be dissolved in water the back as sodium-chloride water solution;
Get magnesium chloride and be dissolved in water the back as magnesium chloride brine;
Get sodium carboxymethylcellulose and be dissolved in water the back as sodium carboxymethyl cellulose solution.
Preparation agricultural chemicals: get 24-25 parts of radish, onion, garlic juice by mass ratio, 14-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 11-12 parts of ash leaching liquors, sodium-chloride water solution 4-5 part, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions are mixed into and are the refined biometric composite pesticide.
Good effect: agricultural chemicals of the present invention is mainly taken as the leading factor with nontoxic vegetable raw material, and with the mineral raw material compound composition that matches, have tag, the effect of stomach toxicity, stifling, interior suction, trapping, anesthesia, excitement, repellent and inhibition and sterilization, to the person poultry harmless, and free from environmental pollution.The suitable control application that is used for plant pest as agricultural chemicals.
Embodiment
The compound bio agricultural chemicals is formed: by radish, onion, garlic juice, and capsicum, Chinese prickly ash juice, the pine tree leaf alcohol extract, the ash leaching liquor, sodium-chloride water solution, magnesium chloride brine, sodium carboxymethyl cellulose solution is mixed and made into.
The preparation method:
A, feedstock production:
Get respectively 10 kilograms of radish, onion, garlic raw materials, squeezing back elimination residue adds water and adjusts to 30 kilograms as radish, onion, garlic juice in gained juice;
Get each 3 kilograms in capsicum, Chinese prickly ash, be added to the water, infusion 30 minutes, the elimination residue adds water and adjusts to 6 kilograms as capsicum, Chinese prickly ash juice in the juice of gained;
Get 5 kilograms of pine needles, the volume percent that joins 20 kilograms is lixiviate in 95% alcohol, adds entry in the leaching liquor of gained, adjusts to 20 kilograms as the pine tree leaf alcohol extract;
Get 10 kilograms of ash, join in 50 kg of water, stir, post precipitation takes out the upper strata stillness of night, refilters and removes residue, adds water and adjusts to 50 kilograms of ash leaching liquors;
Get in the water that 1 kilogram in sodium chloride joins 10 kilograms, make 10 kg capacity percentages and be 10% sodium-chloride water solution;
Get 1 kilogram in magnesium chloride, join in 10 kilograms the water, make 10 kg capacity percentages and be 10% magnesium chloride brine;
Get 1 kilogram of sodium carboxymethylcellulose, join in 20 kilograms the water, make 20 kg capacity percentages and be 5% sodium carboxymethyl cellulose solution.
B, preparation agricultural chemicals: get 24-25 parts of radish, onion, garlic juice by mass ratio, 14-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 11-12 parts of ash leaching liquors, 4-5 parts of sodium-chloride water solutions, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions are mixed into and are the refined biometric composite pesticide.
The raw materials used mechanism of action of killing the disease worm:
1, contain in the radish raphanin, mustard oil, have very strong antibacterial action, the sterilization inhibitory action is arranged.Also contain isothiocyanic acid benzene fat, the energy desinsection is harmless to human body.Phenyl isothiocyanate has stronger killing ability, and is effective to insects such as housefly, body louse, aphid, little beetle and cockroaches.
2, have in the onion sulfur compound mixture, can activate the molten fibrin activity of blood, be bioactivators such as stronger vasodilator and sterilization.Allicin and the big alliin of multiple sulfur-containing compound, alkaloid can kill various bacteria and fungi and energy desinsection within a short period of time.Blocker molecule polymerization, the crosslinked cellular damage that causes.Can kill and suppress various pathogens.
3, contain allicin in the garlic, be natural broad-spectrum antibiotic, unique antibiotic pharmacologically active sees through immobilized artificial membrane easily and enters in the cell.Oxygen atom in the allicin molecule and bacterial growth breed that sulfydryl in the necessary cysteine molecule combines and the growth and the breeding that have suppressed bacterium, multiple pathomycete is comprised that Candida albicans has suppress or killing action.Garlic has the stronger effect of killing and suppress bacterium and virus.Garlic and water extract, effective monomer and catabolite thereof have multiple physiological action.Garlic can effectively all have inhibition and killing action to bacterium, virus, mould and protozoon simultaneously.
4, contain capsaicine in the capsicum, the insect mucous membrane is had the excitant effect, can make the insect spasm, tumble, play killing action from plant.Also contain capsaicine in the capsicum, smell is pungent, insect is had avoid keeping away property.
5, contain Mang geraniol, citrene, cumic alcohol, sterol, unsaturated organic acid etc. in the Chinese prickly ash.Have excitement, inhibitory action.Volatile oil all has certain inhibition and killing effect to tinea bacterium, fungi, itch mite.Contained Mang geraniol can suppress spontaneous activity and gastrointestinal motor.Animal dead is all because due to the respiratory paralysis.The rare pure liquid of Chinese prickly ash has the local anaesthesia effect, has anthelmintic action.
6, contain abietic anhydride and abietic resin hydrocarbon in the pine tree branches and leaves, the volatile oil material, rosin has viscosity, becomes water-fast free resin acid particulate attached on the plant corpus, helps the reservation and the resistance to water of other medicines composition, prolongs drug effect.
7, contain potash in the ash, the organic acid that can be buffered in the metabolism to be produced is faced upward to make to mould and is used; Contained free potassium ion can promote the running of carbohydrate, can reduce the rising intensity of blade, strengthens the ability of drought resisting high temperature resistance, has bactericidal action, destroy the condition of breeding of germ in the soil, suppress the germ activity, strengthen crop disease-resistant and ability resistant to lodging.The ash potassium element can make the content of cellulose in the stem of plant increase in making object, and cell wall thickens, and impels straw stiffness to increase, and has strengthened the ability of crop worm infringement resistant to lodging, disease-resistant.Can be used for preventing and treating the effect of insects such as onion fly, root maggot, aphid, chafer, two spotted spider mite.Can avoid the generation that repeats of assorted bacterium; The software insect pests such as fly, onion fly, maggot, bacterium maggot, mushroom mite of can committing genocide.Prevent and treat the aphid on fruit tree, the crops effectively, and can augment potash fertilizer, strengthen the lodging tolerance of crop.Raising is to the kill capability of insects such as aphid, two spotted spider mite.Ash 80%-90% is a water-soluble potassium, easily absorbed by crop root, also contain trace elements such as abundant nitrogen, phosphorus and calcium, magnesium, zinc, molybdenum, manganese, can reduce soil moisture content rapidly, reduce humidity, the control pathogen transmission, reduce the incidence of disease of mildew, adult is laid eggs nowhere, play the effect of deinsectization, effectively potassium sweetening of the soil acidity strengthens the resistant to lodging and insect protected sterilization multi-function action of crop disease-resistant.
8, the sodium chloride atom in the salt has stronger Pesticidal and sterilizing effect, particularly prevents and treats bacterium, fungi, multiple parasite, killing egg, and significant effect is arranged.
9, magnesium chloride has the protein denaturation of making, and the effect that loses vigor has toxic action to damage by disease and insect, and magnesium ion wherein can also synthesize indispensable magnesium ion for chlorophyll is provided in the plant growing.
10, sodium carboxymethylcellulose mainly plays suspension, dispersion, thickening and huge legendary turtle cooperation and uses in agricultural chemicals of the present invention.
Agricultural chemicals of the present invention is to very strong the tagging and stomach toxicity, multiple insecticidal action such as stifling of various crop tools such as vegetables, apple and cotton; Ovum, larva there is significant killing effect; Drug action is rapid, and the lasting period is long.Can effectively prevent and treat the various pests on the crops such as fruit tree and vegetables.
Preventive effect can be stabilized in more than 90% in 15 days.The speed of knocking down is fast, can make most insect death in 24 hours.Stronger systemic action is arranged, and multiple sucking pest such as can prevent eliminating aphis.
To people and animals and environment and crops high safety, uniqueness, make insect difficult labour give birth to resistance.The effect that improves crop products output is arranged.
Mainly kill disease worm mechanism:
(1), have the conduction of blocking-up insect maincenter, disturb physiological metabolism balance, paralysis taste function, influence to digest and assimilate, block multinomial mechanism such as insect grows and property is sterile.Act on a plurality of positions in the insect nervous system rapidly, make insect in several hours, occur fever, paralysis, food refusal, spasm rapidly, paralyse and death at last.Make worm's ovum not hatch.
(2), have the function of blocking-up kinesitherapy nerve information, it can enter in the body by pore or the palmula of insect, can conduct in insect bodies simultaneously, influences insect life by hindering neural normal function.Be the neural axon toxic agent, finally cause nerve conduction to be blocked fully, can cause that also other cellular tissure beyond the nervous system produces pathology and death.Chlorion enters nerve cell can make the cell function forfeiture, upsets nerve conduction, and stops feed, and irreversible paralysis takes place simultaneously, reaches high lethality rate, and pierce-suck type and rasping-sucking mouthparts insect are had special efficacy.
Good dispersion, dissolving is even, absorption is fast, and drug effect height, adhesivity, permeability are than strong, very easily by plant leaf blade and the absorption of insect polypide.With water is main solvent, can not pollute blade face, fruit face, is difficult for producing poisoning, safety and environmental protection.Desinsection is quick-acting, and 3 hours killing rates reach more than 90% behind the spray medicine, and the drug effect duration can reach about 20 days.
(3), intractable insect and sucking pest are had tag, stomach toxicity, stifling and systemic action; soup can be separated the polypide wall protection barrier of getting rid of insects fast; enter insect inner chamber and central nervous system by insect epidermal area and epidermal cell rapidly, reach the effect of quick kill pests.Have strong interior absorption and permeability, infiltrate in the plant parenchyma, positive spray medicine back side insect also can kill, and RT is long, and use cost is low.
Safe waterborne preparation, secure adhesion be in crop surface, resistance of rainwater washing against; Tag, stomach toxicity, systemic action be various, comprehensive kill pests, ovicidal action all have good preventive effect to blade face insect and borer pest; And have and ooze effect in certain, can infiltrate and kill moth in the plant parenchyma rapidly and go into insect in the plant corpus, and the lasting period is long.Very easily absorbed and be penetrated into epidermis, make the dispenser effect permanently effective, in environment, be difficult for accumulation by crop, environmentally safe.Have superpower selectivity,, people and animals are not had harm the crop safety height, to natural enemies security, not injury.
This medicament can penetrate body wall and enter in the organism and running in vivo and metabolic process, and is pointed.
Has neurotoxicity.To tag or stomach toxicity performance toxic effect, act on nervous system.When cholinesterase is subjected to time spent of doing of medicament, the physiological function that can't bring into normal play can cause that acetylcholine accumulates in a large number in the neural process, thus neurolytic normal conduction, and excitement, spasm or the like symptom can appear in the insect of poisoning, finally causes death.
The mode of action of desinsection is for tagging, stomach toxicity, stifling, food refusal, repellent, killing ovum, lure.
1., stomach poison function.Medicament enters intestinal absorption in the digestive tract quilt with food through the insect oral cavity, arrives site of action by the body fluid lymph and causes that insect is poisoned to death.Be mainly used in control biting mouth parts insect.
2., action of contace poison.Medicament is with after insect epidermis or digitus contact, and infiltration polypide epidermis enters in the polypide, arrives site of action and causes that insect is poisoned to death.Based on the medicament of action of contace poison, controlling object is more.
3., fumigation action.Medicament enters polypide with gaseous state through insect gas exchange system, causes that insect is poisoned to death.Its principle is to have a kind of and gas exchange that the pigment of direct relation is arranged in the pest body, and the effect of this pigment is the same with ferroheme in the human body, and it can combine with oxygen, and can take in the body oxygen to each position for vital movement needs.After medicament enters polypide, promptly combine rapidly the effect of the transmission oxygen that makes it to recur with these respiratory pigments.Insect is owing to can not get oxygen, thereby causes death.
4., systemics.Medicament absorbs through stem, leaf, flower, root or the seed of plant, and transporting in plant corpus just causes after insect is got zone of eclipse poisonous plant and is poisoned to death.The effect of desinsection is the normal physiological processes that suppresses and destroy insect, makes it to be poisoned to death.Its main mechanism of action is: 1) neural toxic action.Many insecticides have the normal delivery effect that destroys or upset insect nerve impulse.After insect touches medicament, promptly suppress in the pest body activity of cholinesterase in the nerve fiber, destroy the normal conduction of nerve impulse, cause a series of nervous system poisoning symptoms, until death.2) respiration inhibition effect.Insect obtains to keep the normal physiological processes energy needed by oxidation operation in the body.This medicament can suppress or destroy the breathing oxidizing process of insect, causes insect death.
The characteristics of agricultural chemicals of the present invention
One, environment protection type insecticidal
After spraying or soak medicament immersion polypide, the nerve and the respiratory system that suppress insect rapidly effectively decompose albumen in the polypide simultaneously, cause insect death.Its anti-insecticidal mechanism is different from the mechanism of action of other chemical pesticide, galenical and alkaloid etc. on the market fully.Through the insect pest that this chemicals treatment is crossed, can't recover normal and also fundamentally lose activity and got the food ability.
Two, lasting rapidly
General chemical pesticide need be sprayed one time medicine weekly in the insect pest peak period.This medicament desinsection broad-spectrum high efficacy has special efficacy to class insect pests such as the two spotted spider mite on the house plant, aphid, thrips, and 20 minutes is visible insect death, tags lethality more than 85%.Through in one night infiltration, its killing effect is remarkable to the larva of Liriomyza etc.Once sprayed general sustainable 15-20 days.
Three, kill the ovum insect protected
Effect with significant killing ova, pupa, larva and adult fundamentally prevents from and has suppressed damage by disease and insect repeating in a short time to take place, and has prolonged damage by disease and insect ground disease cycle widely.Save the work time, reduce the muscle power work, increase work efficiency, reduced drug cost.Reached the purpose of killing anti-combination, treating both principal and secondary aspect of disease.
Four, secondary desinsection
This pharmacy application does not develop immunity to drugs on plant.In this medicament of use 1-7 days, after doing, on plant, sprays soup a small amount of clear water or plant chance rainwater, fog, and this medicament can play insecticidal action for the second time.
Five, bacteriostatic and disease prevention.The disease that fungi, bacterium, viral disease are caused has tangible control and prevention effect respectively, improves resistance against diseases.
Six, promote growth
Plant essence in this medicament provides required nutrition for plant, can be by plant absorbing, the foliage fertilizer effect is remarkable, but make that plant growing is vigorous, blade thickness, light, be bottle green, to fruit plant ripen in advance 3-5 days, volume increase, can make leaf type plant increase 10-15%.Obviously improve quality, improve mouthfeel.

Claims (1)

1, a kind of biological compound pesticide and preparation method's compound bio is characterized in that: by radish, onion, garlic juice, and capsicum, Chinese prickly ash juice, the pine tree leaf alcohol extract, ash leaching liquor, sodium-chloride water solution, magnesium chloride brine, sodium carboxymethyl cellulose solution is formed;
The preparation method:
A, feedstock production:
Get respectively 10 kilograms of radish, onion, garlic raw materials, squeezing back elimination residue adds water and adjusts to 30 kilograms as radish, onion, garlic juice in gained juice;
Get each 3 kilograms in capsicum, Chinese prickly ash, be added to the water, infusion 30 minutes, the elimination residue adds water and adjusts to 6 kilograms as capsicum, Chinese prickly ash juice in the juice of gained;
Get 5 kilograms of pine needles, the volume percent that joins 20 kilograms is lixiviate in 95% alcohol, adds entry in the leaching liquor of gained, adjusts to 20 kilograms as the pine tree leaf alcohol extract;
Get 10 kilograms of ash, join in 50 kg of water, stir, post precipitation takes out the upper strata stillness of night, refilters and removes residue, adds water and adjusts to 50 kilograms of ash leaching liquors;
Get in the water that 1 kilogram in sodium chloride joins 10 kilograms, make 10 kg capacity percentages and be 10% sodium-chloride water solution;
Get 1 kilogram in magnesium chloride, join in 10 kilograms the water, make 10 kg capacity percentages and be 10% magnesium chloride brine;
Get 1 kilogram of sodium carboxymethylcellulose, join in 20 kilograms the water, make 20 kg capacity percentages and be 5% sodium carboxymethyl cellulose solution;
B, preparation agricultural chemicals: get 24-25 parts of radish, onion, garlic juice by mass ratio, 14-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 11-12 parts of ash leaching liquors, sodium-chloride water solution 4-5 part, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions are mixed into and are the refined biometric composite pesticide.
CN200910010740A 2009-03-19 2009-03-19 Biological compound pesticide and preparation method thereof Pending CN101518273A (en)

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CN101897349A (en) * 2010-08-23 2010-12-01 刘志亮 Botanical pesticide for preventing and controlling borer of fruit trees
CN102273493A (en) * 2011-06-30 2011-12-14 刘天平 Attractant for coccinella septempunctata
CN102320894A (en) * 2011-06-21 2012-01-18 吕金波 The many mixture of a kind of biological pesticide
CN101715793B (en) * 2009-10-30 2012-10-03 茹晖 Ecological pesticide and preparation method thereof
CN103355362A (en) * 2012-04-11 2013-10-23 南通市双隆农业发展有限公司 Pesticide for preventing and treating gree wheat mites as well as using method of pesticide
CN103609623A (en) * 2013-11-25 2014-03-05 青岛东颐锦禾农业科技有限公司 Pesticidal bactericidal compound for organic vegetable planting and manufacturing method thereof
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* Cited by examiner, † Cited by third party
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CN101715793B (en) * 2009-10-30 2012-10-03 茹晖 Ecological pesticide and preparation method thereof
CN101897349A (en) * 2010-08-23 2010-12-01 刘志亮 Botanical pesticide for preventing and controlling borer of fruit trees
CN102320894A (en) * 2011-06-21 2012-01-18 吕金波 The many mixture of a kind of biological pesticide
CN102320894B (en) * 2011-06-21 2013-07-17 吕金波 Biopesticide mixture
CN102273493A (en) * 2011-06-30 2011-12-14 刘天平 Attractant for coccinella septempunctata
CN102273493B (en) * 2011-06-30 2013-05-15 刘天平 Attractant for coccinella septempunctata
CN103355362A (en) * 2012-04-11 2013-10-23 南通市双隆农业发展有限公司 Pesticide for preventing and treating gree wheat mites as well as using method of pesticide
CN103609623A (en) * 2013-11-25 2014-03-05 青岛东颐锦禾农业科技有限公司 Pesticidal bactericidal compound for organic vegetable planting and manufacturing method thereof
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CN104522060A (en) * 2014-12-31 2015-04-22 江苏健神生物农化有限公司 Environment-friendly plant pesticide and preparation method thereof
CN105053077A (en) * 2015-07-25 2015-11-18 安徽博发文化生态园有限公司 Agent for preventing and treating plant diseases and insect pests of large cherries
CN105053069A (en) * 2015-07-25 2015-11-18 安徽博发文化生态园有限公司 Agent for preventing and treating plant diseases and insect pests of hickories
CN105145683A (en) * 2015-08-25 2015-12-16 蚌埠海上明珠农业科技发展有限公司 Efficient natural biological pesticide and preparation method thereof
CN105165919A (en) * 2015-08-29 2015-12-23 固镇县传红家庭农场 Agent for preventing and treating plant diseases and insect pests of snow pears
CN105028516A (en) * 2015-08-29 2015-11-11 固镇县传红家庭农场 Medicament capable of preventing and treating Chinese cabbage downy mildew
CN105211130A (en) * 2015-09-23 2016-01-06 张本国 For the ecological agricultural chemical of organic paddy rice plantation
CN105379769A (en) * 2015-10-16 2016-03-09 全椒县荣昌葡萄种植专业合作社 Chemical agent for preventing and controlling grape diseases and pests
CN105815349A (en) * 2016-04-13 2016-08-03 储志强 Improved insecticidal pesticide
CN106613593A (en) * 2016-12-30 2017-05-10 四川俊成生态农业开发有限公司 Selenium-enriched rice planting method
CN106857712A (en) * 2017-01-20 2017-06-20 珠海横琴宝中宝科技开发有限公司 A kind of nontoxic fruits and vegetables disease-resistant, insect-prevention agent
CN107006535A (en) * 2017-04-17 2017-08-04 广西大学 Organic vegetable prevention and control of plant diseases, pest control medicine and preparation method thereof
CN109315445A (en) * 2017-07-31 2019-02-12 安树义 A kind of fruits and vegetables gray mold sterilization aqua and its production technology
CN107593792A (en) * 2017-08-24 2018-01-19 成都圻坊生物科技有限公司 A kind of vegetable insecticide of unpollution control methods fruit tree diseases and pests
CN107926523A (en) * 2017-11-18 2018-04-20 安徽双圆农业科技有限公司 A kind of organic hot pepper implantation methods
CN108244156A (en) * 2017-12-19 2018-07-06 佛山杰致信息科技有限公司 Ornamental plant insecticide
CN108902206A (en) * 2018-05-03 2018-11-30 南安市创培电子科技有限公司 A kind of environment-friendlyplant plant pesticide preparation method
CN108935086A (en) * 2018-08-14 2018-12-07 吉林农业科技学院 A kind of chemical seed-soaking liquid and preparation method thereof for corn doubling monoploids
CN110692658A (en) * 2019-11-12 2020-01-17 贵州土司农业发展有限公司 Botanical pesticide for preventing and treating pepper root rot and preparation method thereof

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Application publication date: 20090902