CN103798302A - Agriculture medicine taking plant as raw material - Google Patents
Agriculture medicine taking plant as raw material Download PDFInfo
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- CN103798302A CN103798302A CN201310622306.6A CN201310622306A CN103798302A CN 103798302 A CN103798302 A CN 103798302A CN 201310622306 A CN201310622306 A CN 201310622306A CN 103798302 A CN103798302 A CN 103798302A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses an agriculture medicine taking plants as raw materials. The medicine comprises the following components prepared according to weight unit: 5-10kg of carrot, 5-10kg of onion, 5-10kg of garlic, 5-10kg of pine tree leaves, 5-10kg of plant ash, 1-3kg of sodium chloride, 1-3kg of magnesium chloride and 1-3kg of carboxymethyl cellulose sodium. The agriculture medicine is prepared by mixing and stirring the following components in parts by mass: 24-26 parts of juice of carrot, onion and garlic, 13-15 parts of juice of hot pepper and Sichuan pepper, 6-7 parts of pine tree leaf alcohol extract, 10-12 parts of plant ash leach liquor, 4-5 parts of a sodium chloride solution, 5-7 parts of a magnesium chloride solution and 3 parts of a sodium carboxymethylcellulose solution. The agriculture medicine disclosed by the invention is prepared by taking non-toxic plant raw materials as main materials and compounding with mineral raw materials, has the functions of touch killing, stomach poisoning, stifling, internal sucking, trapping and killing, anesthesia, exciting, repelling, inhibition and sterilization, is harmless for people and livestock and free of environment pollution.
Description
Technical field:
What the present invention proposed is the agricultural chemicals of agriculture field, specifically a kind of agricultural medicine take plant as raw material.
Background technology:
Before the present invention proposes, useful microorganism extracts matter is used as agricultural chemicals, is used for to plant sterilization and desinsection.Also useful plant extracts plays killing action to sick worm.But due to the raw material difference, the extracting method difference that adopt, its effect is also desirable not to the utmost.For example, use root of langdu plant extracts as agricultural chemicals, can only be effective to insect, invalid to disease.Also as, with leaf tobacco extract as agricultural chemicals, also can only play the effect of desinsection, disease is not had to effect yet.Harmless owing to adopting agricultural medical instrument take plant as raw material to have, and the advantage of welding not, so be developing direction.
Summary of the invention:
For overcome the existing agricultural medicine raw material take plant as raw material single, act on single, the unsettled shortcoming of effect, the present invention proposes a kind of preparation method of the agricultural medicine take plant as raw material.This agricultural chemicals by adopt can be edible the mode that combines with mineral raw material of botanical extract, solve efficiently, can sterilization again can desinsection technical problem.
The scheme that technical solution problem of the present invention adopts is:
An agricultural medicine take plant as raw material, is characterized in that: comprise according to the following component of unit of weight configuration:
Get the raw materials ready: radish 5-10 kilogram, onion 5-10 kilogram, garlic 5-10 kilogram, pine needle 5-10 kilogram, ash 5-10 kilogram, sodium chloride 1-3 kilogram, magnesium chloride 1-3 kilogram, sodium cellulose glycolate 1-3 kilogram.
Configuration: get in mass ratio 24-26 parts of radish, onion, garlic juice, 13-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 10-12 parts of ash leaching liquors, sodium-chloride water solution 4-5 part, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions, mix and blend makes the agricultural medicine take plant as raw material.
By radish, onion, garlic juice, capsicum, Chinese prickly ash juice, pine tree leaf alcohol extract, ash leaching liquor, sodium-chloride water solution, magnesium chloride brine, sodium carboxymethyl cellulose solution is mixed.
Raw material preparation:
Get radish, onion, garlic raw material squeezing taking juice as radish, onion, garlic juice;
Get the infusion that adds water of capsicum, Chinese prickly ash raw material and get juice as capsicum, Chinese prickly ash juice;
Get pine needle lixiviate in 95% alcohol and get juice as pine tree leaf alcohol extract;
Get the ash extracting in water aqueous solution as ash leaching liquor;
After getting sodium chloride and being dissolved in water as sodium-chloride water solution;
After getting magnesium chloride and being dissolved in water as magnesium chloride brine;
After getting sodium carboxymethylcellulose and being dissolved in water as sodium carboxymethyl cellulose solution.
Prepare agricultural chemicals: get in mass ratio 24-26 parts of radish, onion, garlic juice, 13-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 10-12 parts of ash leaching liquors, sodium-chloride water solution 4-5 part, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions, mix and blend becomes refined biometric composite pesticide.
Good effect: agricultural chemicals of the present invention is mainly taken as the leading factor with nontoxic vegetable raw material, and with the mineral raw material compound composition that matches, have tag, the effect of stomach toxicity, stifling, interior suction, trapping, anesthesia, excitement, repellent and inhibition and sterilization, to person poultry harmless, and free from environmental pollution.The suitable control application for plant pest as agricultural chemicals.
Embodiment:
Preparation method:
A, raw material preparation:
Get each 5 kilograms of radish, onion, garlic raw material, elimination residue after squeezing adds water and adjusts to 15 kilograms as radish, onion, garlic juice in gained juice; Get each 5 kilograms of capsicum, Chinese prickly ash, be added to the water, infusion 30 minutes, elimination residue adds water and adjusts to 10 kilograms as capsicum, Chinese prickly ash juice in the juice of gained; Get 5 kilograms of pine needles, the volume percent that joins 20 kilograms is lixiviate in 95% alcohol, in the leaching liquor of gained, adds water, adjusts to 20 kilograms as pine tree leaf alcohol extract;
Get 10 kilograms of ash, join in 50 kg of water, stir, after precipitation, take out the upper strata stillness of night, refilter and remove residue, add water and adjust to 50 kilograms of ash leaching liquors; Get in the water that 1 kilogram, sodium chloride joins 10 kilograms, make the sodium-chloride water solution that 10 kg capacity percentages are 10%; Get 1 kilogram, magnesium chloride, join in the water of 10 kilograms, make the magnesium chloride brine that 10 kg capacity percentages are 10%; Get 1 kilogram of sodium carboxymethylcellulose, join in the water of 20 kilograms, make the sodium carboxymethyl cellulose solution that 20 kg capacity percentages are 5%.
B, prepare agricultural chemicals: get in mass ratio 24-26 parts of radish, onion, garlic juice, 13-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 10-12 parts of ash leaching liquors, 4-5 parts of sodium-chloride water solutions, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions, mix and blend becomes refined biometric composite pesticide.
The raw materials used mechanism of action of killing disease worm:
1, in radish, contain raphanin, mustard oil, there is very strong antibacterial action, have sterilization inhibitory action.Also contain isothiocyanic acid benzene fat, energy desinsection is harmless to human body.Phenyl isothiocyanate has stronger killing ability, effective to insects such as housefly, body louse, aphid, little beetle and cockroaches.
2, in onion, have sulfur compound mixture, can activate blood yield of fibrinolytic enzyme, for the stronger bioactivator such as vasodilator and sterilization.Allicin and the large alliin of multiple sulfur-containing compound, alkaloid can kill various bacteria and fungi energy desinsection within a short period of time.Blocker molecule polymerization, the crosslinked cellular damage that causes.Can kill and suppress various pathogens.
3, in garlic, containing allicin, is natural broad-spectrum antibiotic, and unique antibacterial pharmacologically active easily sees through immobilized artificial membrane and enters in cell.Oxygen atom in allicin molecule and bacterial growth breed that sulfydryl in necessary cysteine molecule combines and the Growth and reproduction that suppressed bacterium, multiple pathomycete is comprised to Candida albicans has and suppress or killing action.Garlic has stronger killing and anti-bacteria and viral effect.Garlic and water extraction liquid, effective monomer and catabolite thereof have multiple physiological action.Garlic can effectively have and suppress and killing action bacterium, virus, mould and protozoon simultaneously.
4, in capsicum, contain capsaicine, insect mucous membrane is had to excitant effect, can make insect spasm, tumble from plant, play killing action.In capsicum, also contain capsaicine, smell is pungent, and insect is had and avoids keeping away property.
5, in Chinese prickly ash, contain Geraniol, citrene, cumic alcohol, sterol, unsaturated organic acid etc.There is excitement, inhibitory action.Volatile oil all has certain inhibition and killing effect to tinea bacterium, fungi, itch mite.Contained Geraniol, can suppress spontaneous activity and gastrointestinal motor.
Animal dead is all due to due to respiratory paralysis.The rare alcohol liquid of Chinese prickly ash has local anaesthesia effect, has anthelmintic action.
6, in pine tree branches and leaves, contain abietic anhydride and abietic resin hydrocarbon, volatile oil material, rosin has viscosity, becomes water-fast free resin acid particulate and is attached on plant corpus, is conducive to reservation and the resistance to water of other medicines composition, extends drug effect.
7, in ash, contain potash, can be buffered in the organic acid producing in metabolism, mould is faced upward to make and use; Contained free potassium ion can promote the running of carbohydrate, can reduce the Transpiration Intensity of blade, strengthens the ability of drought resisting high temperature resistance, there is bactericidal action, the condition of breeding of germ in spoiled soil, suppresses germ activity, strengthens crop disease-resistant and ability resistant to lodging.Ash potassium element is in the content of cellulose increase making as object internal energy in stem of plant, and cell wall thickens, and impels straw stiffness to increase, and has strengthened the ability that crop is resistant to lodging, Resistant is encroached on.Can be used for preventing and treating the effect of the insects such as onion fly, root maggot, aphid, chafer, two spotted spider mite.Can avoid the generation that repeats of miscellaneous bacteria; The software insect pests such as fly, onion fly, maggot, bacterium maggot, mushroom mite of can committing genocide.Effectively prevent and treat the aphid on fruit tree, crops, and can augment potash fertilizer, strengthen the lodging tolerance of crop.Improve the kill capability to the insect such as aphid, two spotted spider mite.Ash 80%-90% is water-soluble potassium, easily absorbed by crop root, also contain the trace elements such as abundant nitrogen, phosphorus and calcium, magnesium, zinc, molybdenum, manganese, can reduce rapidly soil moisture content, reduce humidity, control pathogen transmission, the incidence of disease that reduces mildew, lays eggs adult nowhere, plays the effect of deinsectization, effectively potassium sweetening of the soil acidity, strengthens the resistant to lodging and insect protected sterilization multi-function action of crop disease-resistant.
8, the sodium chloride atom in salt has stronger Pesticidal and sterilizing effect, particularly prevents and treats bacterium, fungi, multiple parasite, killing egg, has significant effect.
9, magnesium chloride has the protein denaturation of making, and the effect losing vigor, has toxic action to damage by disease and insect, and magnesium ion wherein can also be for providing chlorophyll to synthesize indispensable magnesium ion in plant growth.
10, sodium carboxymethylcellulose mainly plays suspension, dispersion, thickening and huge legendary turtle cooperation and uses in agricultural chemicals of the present invention.
Agricultural chemicals of the present invention is to very strong the tagging and stomach toxicity, the multiple insecticidal action such as stifling of the various crop tools such as vegetables, apple and cotton; Ovum, larva are had to significant killing effect; Drug action is rapid, and the lasting period is long.Can effectively prevent and treat the various pests on the crop such as fruit tree and vegetables.
Preventive effect can be stabilized in more than 90% in 15 days.The speed of knocking down is fast, can in 24 hours, can make most insect death.Have stronger systemic action, the multiple sucking pest such as can prevent eliminating aphis.
To people and animals and environment and crops high safety, uniqueness, make the insect raw resistance of having difficult labour.Be improved the effect of crop products output.
Mainly kill disease worm mechanism:
(1), there is the conduction of blocking-up insect maincenter, disturb physiological metabolism balance, paralysis taste function, impact to digest and assimilate, block the multinomial mechanism such as insect grows and property is sterile.Act on rapidly the multiple positions in insect nerve system, make insect in several hours, occur rapidly fever, paralysis, food refusal, spasm, finally paralyse and death.Worm's ovum can not be hatched.
(2), there is the function of blocking-up kinesitherapy nerve information, it can enter in body by the pore of insect or palmula, can in insect bodies, conduct simultaneously, affects insect life by hindering neural normal function.For neural axon toxic agent, finally cause nerve conduction to be blocked completely, also can cause that other cellular tissure beyond nervous system produces pathology and death.Chlorion enters nerve cell can make cell function lose, and upsets nerve conduction, and stops feed, and irreversible paralysis occurs simultaneously, reaches high lethality rate, and pierce-suck type and rasping-sucking mouthparts insect are had to special efficacy.
Good dispersion, is uniformly dissolved, absorbs fast, and drug effect is high, adhesivity, permeability be than strong, is very easily absorbed by plant leaf blade and insect polypide.Take water as main solvent, can not pollute blade face, fruit face, be difficult for producing poisoning, safety and environmental protection.Desinsection is quick-acting, and after spray medicine, 3 hours killing rates reach more than 90%, and the drug effect duration can reach about 20 days.
(3), intractable insect and sucking pest are had tag, stomach toxicity, stifling and systemic action; liquid is the solution polypide wall protective barrier of getting rid of insects fast; enter insect inner chamber and central nervous system by insect epidermal area and epidermal cell rapidly, reach the effect of quick kill pests.Have strong interior absorption and permeability, infiltrate in plant parenchyma, positive spray medicine back side insect also can kill, and RT is long, and use cost is low.
Safe waterborne preparation, secure adhesion is in crop surface, resistance of rainwater washing against; Tag, stomach toxicity, systemic action be various, comprehensive kill pests, ovicidal action, all have good preventive effect to foliar pest and borer pest; And have in certain and ooze effect, can infiltrate and in plant parenchyma, kill rapidly the insect eating in plant corpus, and the lasting period is long.Very easily absorbed by crops and be penetrated into epidermis, make dispenser effect permanently effective, in environment, be difficult for accumulation, environmentally safe.There is superpower selectivity, high to crop safety, people and animals, without harm, to natural enemies security, are not injured.
This medicament can penetrate body wall and enter running and metabolic process in organism and in vivo, pointed.
There is neurotoxicity.To tag or stomach toxicity performance toxic effect, act on nervous system.When cholinesterase is subject to used time of doing of medicament, the physiological function that cannot bring into normal play, can cause acetylcholine in neural process to accumulate in a large number, thus neurolytic normal conduction, and poisoning insect there will be excitement, spasm etc. symptom, finally causes death.
The mode of action of desinsection for tagging, stomach toxicity, stifling, food refusal, repellent, ovicidal, lure.
1., stomach poison function.Medicament enters intestinal absorption in digestive tract quilt with food through insect oral cavity, arrives site of action cause that insect is poisoned to death by body fluid lymph.Be mainly used in preventing and treating biting mouth parts insect.
2., action of contace poison.After medicament contacts with insect epidermis or digitus, infiltration polypide epidermis enters in polypide, arrives site of action and causes that insect is poisoned to death.Take action of contace poison as main medicament, controlling object is more.
3., fumigation action.Medicament enters polypide with gaseous state through insect gas exchange system, causes that insect is poisoned to death.Its principle is in pest body, to have the exchange of a kind of and gas to have the pigment of direct relation, and the effect of this pigment is the same with the ferroheme in human body, and it can be combined with oxygen, and oxygen can be taken in body to each position for vital movement needs.When medicament enters after polypide, combine with these respiratory pigments rapidly, the effect of the transmission oxygen that makes it to recur.Insect is owing to can not get oxygen, thereby causes death.
4., systemics.Medicament absorbs through stem, leaf, flower, root or the seed of plant, and transporting in plant corpus just causes and is poisoned to death after insect takes food band poisonous plant.The effect of desinsection is the normal physiological processes that suppresses and destroy insect, makes it to be poisoned to death.Its Main Function mechanism is: 1) neural toxic action.Many insecticides have the normal delivery effect that destroys or upset insect nerve impulse.After insect touches medicament, suppress in pest body the activity of cholinesterase in nerve fiber, destroy the normal conduction of nerve impulse, cause a series of nervous system poisoning symptoms, until dead.2) respiration inhibition effect.Insect, by oxidation operation in body, obtains and maintains the needed energy of normal physiological processes.This medicament can suppress or destroy the breathing oxidizing process of insect, causes insect death.
The feature of agricultural chemicals of the present invention
One, environment protection type insecticidal
Immerse after polypide by spraying or soak medicament, the nerve and the respiratory system that suppress rapidly insect effectively decompose albumen in polypide simultaneously, cause insect death.Its anti-insecticidal mechanism is different from the mechanism of action of other chemical pesticide, galenical and alkaloid etc. on market completely.The insect pest of crossing through this chemicals treatment, cannot recover normal and fundamentally lose activity and taken food ability.
Two, lasting rapidly
General chemical pesticide need to be sprayed weekly one time medicine in insect pest peak period.This medicament desinsection broad-spectrum high efficacy, has special efficacy to class insect pests such as the two spotted spider mite on house plant, aphid, thrips, within 20 minutes, is visible insect death, tags lethality more than 85%.To the larva of Liriomyza etc., through infiltration in one night, its killing effect is remarkable.Once spray general sustainable 15-20 days.
Three, ovicidal insect protected
There is the effect of significant killing ova, pupa, larva and adult, fundamentally prevent from and suppressed damage by disease and insect repeating in a short time occurring, extended widely damage by disease and insect ground disease cycle.Save the work time, reduce muscle power work, increase work efficiency, reduced drug cost.Reach the object of killing anti-combination, treating both principal and secondary aspect of disease.
Four, secondary desinsection
This pharmacy application, on plant, does not develop immunity to drugs.In this medicament of use 1-7 days, when spraying a small amount of clear water or plant chance rainwater, fog on the dry backward plant of liquid, this medicament can play insecticidal action for the second time.
Five, bacteriostatic and disease prevention.The disease that fungi, bacterium, viral disease are caused has respectively obvious control and prevention effect, improves resistance against diseases.
Six, promote growth
Plant essence in this medicament provides required nutrition for plant, can be absorbed by plants, foliage fertilizer effect is remarkable, make that plant growth is vigorous, blade thickness, light, be bottle green, to fruit plant can ripen in advance 3-5 days, volume increase, can make leaf type plant increase 10-15%.Obviously improve quality, improve mouthfeel.
Claims (1)
1. the agricultural medicine take plant as raw material, is characterized in that: comprise according to the following component of unit of weight configuration:
Get the raw materials ready: radish 5-10 kilogram, onion 5-10 kilogram, garlic 5-10 kilogram, pine needle 5-10 kilogram, ash 5-10 kilogram, sodium chloride 1-3 kilogram, magnesium chloride 1-3 kilogram, sodium cellulose glycolate 1-3 kilogram;
Configuration: get in mass ratio 24-26 parts of radish, onion, garlic juice, 13-15 parts of capsicum, Chinese prickly ash juice, 6-7 parts of pine tree leaf alcohol extracts, 10-12 parts of ash leaching liquors, sodium-chloride water solution 4-5 part, 5-7 parts of magnesium chloride brines, 3 parts of sodium carboxymethyl cellulose solutions, mix and blend makes the agricultural medicine take plant as raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310622306.6A CN103798302A (en) | 2013-11-30 | 2013-11-30 | Agriculture medicine taking plant as raw material |
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| CN201310622306.6A CN103798302A (en) | 2013-11-30 | 2013-11-30 | Agriculture medicine taking plant as raw material |
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| CN103798302A true CN103798302A (en) | 2014-05-21 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016813A (en) * | 2014-06-06 | 2014-09-03 | 茹晖 | Ecological pesticide-added fertilizer and preparation method thereof |
| CN104429742A (en) * | 2014-12-15 | 2015-03-25 | 青岛田成原生态农产品专业合作社 | Method employing plant composition to prevent and cure asparagus pest and disease damages |
| CN104430636A (en) * | 2014-12-15 | 2015-03-25 | 青岛田成原生态农产品专业合作社 | Composition for preventing and treating diseases and insect pests of asparagus |
| CN104488994A (en) * | 2014-12-16 | 2015-04-08 | 于希萌 | Composition for preventing and controlling cucumber pest and disease damage |
| CN104542737A (en) * | 2014-12-15 | 2015-04-29 | 青岛田成原生态农产品专业合作社 | Preparation method of composition for preventing and controlling diseases and insect pests of asparagus |
| CN104621194A (en) * | 2015-02-02 | 2015-05-20 | 于希萌 | Composition for preventing and treating diseases and insect pests of cucumber and preparation method thereof |
| CN105211130A (en) * | 2015-09-23 | 2016-01-06 | 张本国 | For the ecological agricultural chemical of organic paddy rice plantation |
| CN105272741A (en) * | 2015-10-26 | 2016-01-27 | 广西农垦国有立新农场 | Biological organic pesticide-containing fertilizer and preparation method thereof |
| CN105794447A (en) * | 2016-03-09 | 2016-07-27 | 秀山县旺发农业专业合作社 | Method for transplanting chillies |
| CN107006535A (en) * | 2017-04-17 | 2017-08-04 | 广西大学 | Organic vegetable prevention and control of plant diseases, pest control medicine and preparation method thereof |
| CN107593792A (en) * | 2017-08-24 | 2018-01-19 | 成都圻坊生物科技有限公司 | A kind of vegetable insecticide of unpollution control methods fruit tree diseases and pests |
-
2013
- 2013-11-30 CN CN201310622306.6A patent/CN103798302A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104016813A (en) * | 2014-06-06 | 2014-09-03 | 茹晖 | Ecological pesticide-added fertilizer and preparation method thereof |
| CN104429742A (en) * | 2014-12-15 | 2015-03-25 | 青岛田成原生态农产品专业合作社 | Method employing plant composition to prevent and cure asparagus pest and disease damages |
| CN104430636A (en) * | 2014-12-15 | 2015-03-25 | 青岛田成原生态农产品专业合作社 | Composition for preventing and treating diseases and insect pests of asparagus |
| CN104542737A (en) * | 2014-12-15 | 2015-04-29 | 青岛田成原生态农产品专业合作社 | Preparation method of composition for preventing and controlling diseases and insect pests of asparagus |
| CN104488994A (en) * | 2014-12-16 | 2015-04-08 | 于希萌 | Composition for preventing and controlling cucumber pest and disease damage |
| CN104621194A (en) * | 2015-02-02 | 2015-05-20 | 于希萌 | Composition for preventing and treating diseases and insect pests of cucumber and preparation method thereof |
| CN105211130A (en) * | 2015-09-23 | 2016-01-06 | 张本国 | For the ecological agricultural chemical of organic paddy rice plantation |
| CN105272741A (en) * | 2015-10-26 | 2016-01-27 | 广西农垦国有立新农场 | Biological organic pesticide-containing fertilizer and preparation method thereof |
| CN105794447A (en) * | 2016-03-09 | 2016-07-27 | 秀山县旺发农业专业合作社 | Method for transplanting chillies |
| CN107006535A (en) * | 2017-04-17 | 2017-08-04 | 广西大学 | Organic vegetable prevention and control of plant diseases, pest control medicine and preparation method thereof |
| CN107593792A (en) * | 2017-08-24 | 2018-01-19 | 成都圻坊生物科技有限公司 | A kind of vegetable insecticide of unpollution control methods fruit tree diseases and pests |
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Application publication date: 20140521 |