CN101500969A - 沸石催化剂和沸石催化剂的制备方法与用途 - Google Patents
沸石催化剂和沸石催化剂的制备方法与用途 Download PDFInfo
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- CN101500969A CN101500969A CNA2006800315062A CN200680031506A CN101500969A CN 101500969 A CN101500969 A CN 101500969A CN A2006800315062 A CNA2006800315062 A CN A2006800315062A CN 200680031506 A CN200680031506 A CN 200680031506A CN 101500969 A CN101500969 A CN 101500969A
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- Prior art keywords
- zeolite
- phosphorus
- agglutinating
- temperature
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010457 zeolite Substances 0.000 title claims abstract description 153
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 150
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 148
- 239000003054 catalyst Substances 0.000 title claims abstract description 125
- 238000000034 method Methods 0.000 title claims description 55
- 239000000463 material Substances 0.000 claims abstract description 58
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 55
- 239000011574 phosphorus Substances 0.000 claims abstract description 53
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 16
- 238000005004 MAS NMR spectroscopy Methods 0.000 claims abstract description 14
- 230000029936 alkylation Effects 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 11
- 239000011230 binding agent Substances 0.000 claims abstract description 10
- -1 phosphorus compound Chemical class 0.000 claims abstract description 8
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 7
- 239000002168 alkylating agent Substances 0.000 claims abstract description 5
- 229940100198 alkylating agent Drugs 0.000 claims abstract description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 221
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 72
- 230000004523 agglutinating effect Effects 0.000 claims description 45
- 238000010438 heat treatment Methods 0.000 claims description 39
- 238000007069 methylation reaction Methods 0.000 claims description 35
- 239000002994 raw material Substances 0.000 claims description 32
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 31
- 239000000853 adhesive Substances 0.000 claims description 30
- 230000001070 adhesive effect Effects 0.000 claims description 30
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 28
- 230000011987 methylation Effects 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- 238000004738 31P MAS NMR Methods 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 239000004927 clay Substances 0.000 claims description 10
- 230000009466 transformation Effects 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 7
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 7
- 230000002152 alkylating effect Effects 0.000 claims description 6
- 238000005481 NMR spectroscopy Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000010555 transalkylation reaction Methods 0.000 claims 1
- 239000011148 porous material Substances 0.000 abstract description 6
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 230000004048 modification Effects 0.000 description 22
- 238000012986 modification Methods 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 239000004411 aluminium Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 238000012216 screening Methods 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000001035 methylating effect Effects 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 241000269350 Anura Species 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 230000002779 inactivation Effects 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000012690 zeolite precursor Substances 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910017119 AlPO Inorganic materials 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 240000007762 Ficus drupacea Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- RLPGUIZCGVYNLO-UHFFFAOYSA-N dimethylphosphanyl(dimethyl)phosphane Chemical compound CP(C)P(C)C RLPGUIZCGVYNLO-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- RYIOLWQRQXDECZ-UHFFFAOYSA-N phosphinous acid Chemical compound PO RYIOLWQRQXDECZ-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- NGHMEZWZOZEZOH-UHFFFAOYSA-N silicic acid;hydrate Chemical compound O.O[Si](O)(O)O NGHMEZWZOZEZOH-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/067—C8H10 hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
- C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/195,970 | 2005-08-03 | ||
| US11/195,970 US7368410B2 (en) | 2005-08-03 | 2005-08-03 | Zeolite catalyst and method of preparing and use of zeolite catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101500969A true CN101500969A (zh) | 2009-08-05 |
Family
ID=37718466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006800315062A Pending CN101500969A (zh) | 2005-08-03 | 2006-08-03 | 沸石催化剂和沸石催化剂的制备方法与用途 |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US7368410B2 (enExample) |
| EP (1) | EP1928809A4 (enExample) |
| JP (1) | JP5254789B2 (enExample) |
| KR (1) | KR101301890B1 (enExample) |
| CN (1) | CN101500969A (enExample) |
| MY (1) | MY144130A (enExample) |
| SG (2) | SG144161A1 (enExample) |
| TW (1) | TWI408006B (enExample) |
| WO (1) | WO2007019375A2 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103561868A (zh) * | 2011-03-15 | 2014-02-05 | 科莱恩产品（德国）有限公司 | 用于将含氧化合物转化成烯烃的改进的催化剂 |
| CN103945939A (zh) * | 2011-10-17 | 2014-07-23 | 埃克森美孚研究工程公司 | 磷改性沸石催化剂 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7368410B2 (en) * | 2005-08-03 | 2008-05-06 | Saudi Basic Industries Corporation | Zeolite catalyst and method of preparing and use of zeolite catalyst |
| US7662737B2 (en) * | 2005-12-22 | 2010-02-16 | Saudi Basic Industries Corporation | Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof |
| US8115041B2 (en) | 2008-04-02 | 2012-02-14 | Saudi Basic Industries Corporation | Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process |
| US20090326308A1 (en) * | 2008-06-30 | 2009-12-31 | Uop Llc | Binderless adsorbents comprising nano-size zeolite x and their use in the adsorptive separation of para-xylene |
| US7820869B2 (en) * | 2008-06-30 | 2010-10-26 | Uop Llc | Binderless adsorbents and their use in the adsorptive separation of para-xylene |
| US7812208B2 (en) * | 2008-09-22 | 2010-10-12 | Uop Llc | Binderless adsorbents with improved mass transfer properties and their use in the adsorptive separation of para-xylene |
| US8846559B2 (en) * | 2008-11-03 | 2014-09-30 | Saudi Basic Industries Corporation | Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing |
| US8062987B2 (en) | 2009-10-05 | 2011-11-22 | Saudi Basic Industries Corporation | Phosphorus-containing zeolite catalysts and their method of preparation |
| US20110137099A1 (en) * | 2009-12-08 | 2011-06-09 | Saudi Basic Industries Corporation | Aromatic alkylation process |
| DE102011013909A1 (de) | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine |
| DE102011013911A1 (de) | 2011-03-15 | 2012-09-20 | Süd-Chemie AG | Verbessertes Verfahren zur Herstellung eines Katalysators auf Zeolithbasis zur Umwandlung von Methanol in Olefine |
| US9278342B2 (en) | 2012-07-02 | 2016-03-08 | Saudi Basic Industries Corporation | Method of modifying a phosphorus-containing zeolite catalyst |
| US9314779B2 (en) | 2012-08-09 | 2016-04-19 | Saudi Basic Industries Corporation | Method of making a catalyst and catalyst made thereby |
| CN111437872A (zh) | 2013-01-23 | 2020-07-24 | 巴斯夫公司 | 通过改进的沸石和磷相互作用来增强zsm-5添加剂活性 |
| JP6021661B2 (ja) | 2013-01-30 | 2016-11-09 | 三菱重工業株式会社 | 燃料供給システム、スクラムジェットエンジン及びその動作方法 |
| US8969643B2 (en) | 2013-05-23 | 2015-03-03 | Saudi Basic Industries Corporation | Method for conversion of aromatic hydrocarbons |
| US9783462B2 (en) | 2013-09-10 | 2017-10-10 | Saudi Basic Industries Corporation | Toluene methylation with transalkylation of heavy aromatics |
| US9364815B2 (en) | 2013-11-07 | 2016-06-14 | Saudi Basic Industries Corporation | Method of preparing an alumina catalyst support and catalyst for dehydrogenation reactions, and its use |
| KR102262792B1 (ko) * | 2014-04-04 | 2021-06-09 | 에네오스 가부시키가이샤 | 알루미노실리케이트 촉매의 제조 방법, 알루미노실리케이트 촉매 및 단환 방향족 탄화수소의 제조 방법 |
| KR20160120529A (ko) | 2015-04-08 | 2016-10-18 | 조남희 | 분야별 분류 기반의 인터넷 기사 제공 시스템 및 방법 |
| WO2017066521A1 (en) * | 2015-10-16 | 2017-04-20 | Cool Planet Energy Systems, Inc. | Biofuel production using doped zeolite catalyst |
| CN108290801B (zh) | 2015-11-30 | 2021-04-09 | 托普索公司 | 包含磷的双功能催化剂 |
| US10532962B2 (en) | 2016-02-02 | 2020-01-14 | Sabic Global Technologies B.V. | Conversion of shale gas to aromatics |
| EA201891760A1 (ru) * | 2016-03-09 | 2019-06-28 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") | Способ совместного превращения углеводородных фракций и оксигенатов в высокооктановые компоненты топлив или ароматические углеводороды и катализатор для его осуществления |
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-
2005
- 2005-08-03 US US11/195,970 patent/US7368410B2/en active Active
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2006
- 2006-07-25 TW TW095127161A patent/TWI408006B/zh not_active IP Right Cessation
- 2006-08-02 MY MYPI20063743A patent/MY144130A/en unknown
- 2006-08-03 JP JP2008525253A patent/JP5254789B2/ja not_active Expired - Fee Related
- 2006-08-03 SG SG200804689-8A patent/SG144161A1/en unknown
- 2006-08-03 WO PCT/US2006/030582 patent/WO2007019375A2/en not_active Ceased
- 2006-08-03 KR KR1020087005247A patent/KR101301890B1/ko not_active Expired - Fee Related
- 2006-08-03 CN CNA2006800315062A patent/CN101500969A/zh active Pending
- 2006-08-03 EP EP06800818A patent/EP1928809A4/en not_active Ceased
- 2006-08-03 SG SG200804690-6A patent/SG144162A1/en unknown
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2008
- 2008-03-25 US US12/054,807 patent/US7507685B2/en not_active Expired - Lifetime
- 2008-03-25 US US12/054,788 patent/US7674942B2/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103561868A (zh) * | 2011-03-15 | 2014-02-05 | 科莱恩产品（德国）有限公司 | 用于将含氧化合物转化成烯烃的改进的催化剂 |
| CN103945939A (zh) * | 2011-10-17 | 2014-07-23 | 埃克森美孚研究工程公司 | 磷改性沸石催化剂 |
| CN103987456A (zh) * | 2011-10-17 | 2014-08-13 | 埃克森美孚研究工程公司 | 制备磷改性的沸石催化剂的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US7507685B2 (en) | 2009-03-24 |
| JP2009502501A (ja) | 2009-01-29 |
| US20080275280A1 (en) | 2008-11-06 |
| JP5254789B2 (ja) | 2013-08-07 |
| US7674942B2 (en) | 2010-03-09 |
| US20080176736A1 (en) | 2008-07-24 |
| SG144162A1 (en) | 2008-07-29 |
| SG144161A1 (en) | 2008-07-29 |
| KR20080039967A (ko) | 2008-05-07 |
| MY144130A (en) | 2011-08-15 |
| WO2007019375A2 (en) | 2007-02-15 |
| TW200806391A (en) | 2008-02-01 |
| US7368410B2 (en) | 2008-05-06 |
| WO2007019375A3 (en) | 2009-04-23 |
| EP1928809A2 (en) | 2008-06-11 |
| KR101301890B1 (ko) | 2013-08-29 |
| US20070032690A1 (en) | 2007-02-08 |
| EP1928809A4 (en) | 2009-11-18 |
| TWI408006B (zh) | 2013-09-11 |
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