CN1013363B - 制备双酚a的方法 - Google Patents
制备双酚a的方法Info
- Publication number
- CN1013363B CN1013363B CN88107757A CN88107757A CN1013363B CN 1013363 B CN1013363 B CN 1013363B CN 88107757 A CN88107757 A CN 88107757A CN 88107757 A CN88107757 A CN 88107757A CN 1013363 B CN1013363 B CN 1013363B
- Authority
- CN
- China
- Prior art keywords
- reaction
- phenol
- weight
- dihydroxyphenyl propane
- acetone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 74
- 238000006243 chemical reaction Methods 0.000 claims abstract description 70
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000011541 reaction mixture Substances 0.000 claims abstract description 37
- 239000006227 byproduct Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 27
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 46
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 10
- 239000003054 catalyst Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003729 cation exchange resin Substances 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005341 cation exchange Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000002349 favourable effect Effects 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical class CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL268,149 | 1987-10-07 | ||
| PL1987268149A PL153396B1 (en) | 1987-10-07 | 1987-10-07 | Method of obtaining bisphenol a |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1034197A CN1034197A (zh) | 1989-07-26 |
| CN1013363B true CN1013363B (zh) | 1991-07-31 |
Family
ID=20038430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN88107757A Expired CN1013363B (zh) | 1987-10-07 | 1988-09-29 | 制备双酚a的方法 |
Country Status (8)
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5059721A (en) * | 1990-07-31 | 1991-10-22 | Shell Oil Company | Process for preparing a bisphenol |
| PL164289B1 (pl) * | 1990-11-24 | 1994-07-29 | Inst Ciezkiej Syntezy Orga | Sposób otrzymywani blsfenolu A PL PL |
| DE4312039A1 (de) * | 1993-04-13 | 1994-10-20 | Bayer Ag | Optimierte Ionenaustauscherschüttungen für die Bis-phenol-A Synthese |
| US5783733A (en) * | 1996-06-13 | 1998-07-21 | General Electric Company | Process for manufacture of bisphenol |
| DE19720541A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dihydroxydiphenylalkanen |
| DE19720539A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Dihydroxydiarylalkanen |
| DE19720540A1 (de) | 1997-05-16 | 1998-11-19 | Bayer Ag | Verfahren zur Aufarbeitung von Mutterlaugen aus der Bisphenolsynthese |
| US20050075520A1 (en) * | 2002-03-13 | 2005-04-07 | O'young Drow Lionel | System and method of producing bisphenol-A (BPA) using two stage crystallization |
| US6960697B2 (en) * | 2002-03-13 | 2005-11-01 | Mitsubishi Chemical Corporation | System and method of producing bisphenol-A (BPA) |
| US20100121111A1 (en) * | 2006-05-31 | 2010-05-13 | Baker Hughes Incorporated | Alkoxylations of High Melting Point Substrates in Ketone Solvents |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3049569A (en) * | 1958-10-20 | 1962-08-14 | Union Carbide Corp | Production of 2, 2-bis(4-hydroxyphenyl) propane |
| US3221061A (en) * | 1961-08-01 | 1965-11-30 | Union Carbide Corp | Process for the production of 2,2-bis-(4-hydroxyphenyl) propane |
| DE2537027C2 (de) * | 1975-08-20 | 1982-06-03 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von 4,4'-Dihydroxy-3,3',5,5'-tetraalkyl- diphenylalkanen |
| US4308405A (en) * | 1978-07-05 | 1981-12-29 | Shell Oil Company | Preparation of bisphenols |
| PL124542B1 (en) * | 1978-12-30 | 1983-01-31 | Instytut Ciezkiej Syntezy Organicznej "Blachownia" | Method of manufacture of bisphenol a |
| US4391997A (en) * | 1981-10-23 | 1983-07-05 | General Electric Company | Ion exchange catalyzed bisphenol process |
-
1987
- 1987-10-07 PL PL1987268149A patent/PL153396B1/pl unknown
-
1988
- 1988-09-26 UA UA4356529A patent/UA13478A1/uk unknown
- 1988-09-26 RU SU884356529A patent/RU1799376C/ru active
- 1988-09-28 US US07/250,393 patent/US4906789A/en not_active Expired - Fee Related
- 1988-09-29 CN CN88107757A patent/CN1013363B/zh not_active Expired
- 1988-10-05 DE DE3833900A patent/DE3833900A1/de active Granted
- 1988-10-07 KR KR1019880013167A patent/KR910008367B1/ko not_active Expired
-
1989
- 1989-01-12 IN IN36/CAL/89A patent/IN171653B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN171653B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-12-05 |
| PL153396B1 (en) | 1991-04-30 |
| KR910008367B1 (ko) | 1991-10-12 |
| US4906789A (en) | 1990-03-06 |
| DE3833900A1 (de) | 1989-04-27 |
| DE3833900C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-08-14 |
| RU1799376C (ru) | 1993-02-28 |
| UA13478A1 (uk) | 1997-04-25 |
| PL268149A1 (en) | 1989-04-17 |
| CN1034197A (zh) | 1989-07-26 |
| KR890006553A (ko) | 1989-06-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |