CN101273074B - 使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 - Google Patents
使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 Download PDFInfo
- Publication number
- CN101273074B CN101273074B CN2006800342110A CN200680034211A CN101273074B CN 101273074 B CN101273074 B CN 101273074B CN 2006800342110 A CN2006800342110 A CN 2006800342110A CN 200680034211 A CN200680034211 A CN 200680034211A CN 101273074 B CN101273074 B CN 101273074B
- Authority
- CN
- China
- Prior art keywords
- bismuth
- isocyanato
- blocking
- polyurethane prepolymer
- base end
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/227,919 US8232362B2 (en) | 2005-09-15 | 2005-09-15 | Preparation of amino-silane terminated polymer by using organic bismuth catalyst and cured polymer therefrom by using non-tin catalyst |
| US11/227,919 | 2005-09-15 | ||
| PCT/US2006/034138 WO2007037915A2 (en) | 2005-09-15 | 2006-08-31 | Preparation of amino-silane terminated polymer by using organic bismuth catalyst and cured polymer therefrom by using non-tin catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101273074A CN101273074A (zh) | 2008-09-24 |
| CN101273074B true CN101273074B (zh) | 2013-06-26 |
Family
ID=37622190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800342110A Expired - Fee Related CN101273074B (zh) | 2005-09-15 | 2006-08-31 | 使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8232362B2 (https=) |
| EP (2) | EP2518094B1 (https=) |
| JP (1) | JP5603007B2 (https=) |
| KR (1) | KR101350769B1 (https=) |
| CN (1) | CN101273074B (https=) |
| AU (1) | AU2006295277A1 (https=) |
| BR (1) | BRPI0616214A2 (https=) |
| CA (1) | CA2622156A1 (https=) |
| NO (1) | NO20081347L (https=) |
| RU (1) | RU2008114489A (https=) |
| TW (1) | TW200720308A (https=) |
| WO (1) | WO2007037915A2 (https=) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007231030A (ja) * | 2006-02-27 | 2007-09-13 | Shin Etsu Chem Co Ltd | 皮膜形成シリコーンエマルジョン組成物 |
| DE102006055739A1 (de) * | 2006-11-25 | 2008-05-29 | Bayer Materialscience Ag | Abformmassen |
| JP5154187B2 (ja) * | 2007-10-03 | 2013-02-27 | アイカ工業株式会社 | 上水道用表面ウレタン樹脂組成物 |
| DE102008021221A1 (de) * | 2008-04-28 | 2009-10-29 | Henkel Ag & Co. Kgaa | Härtbare Zusammensetzung auf Basis silylierter Polyurethane |
| DE102008047362A1 (de) | 2008-09-15 | 2010-04-15 | Henkel Ag & Co. Kgaa | Zusammensetzung zur Hautaufhellung |
| US8138297B2 (en) * | 2009-02-09 | 2012-03-20 | Momentive Performance Materials Inc. | Moisture-curable silylated polymer possessing improved storage stability |
| DE102009026679A1 (de) * | 2009-06-03 | 2010-12-16 | Henkel Ag & Co. Kgaa | Kleb- und Dichtstoffe auf Basis silanterminierter Bindemittel zum Verkleben und Abdichten von flexiblen Solarfolien / Photovoltaikmodulen |
| BR112012005909A2 (pt) * | 2009-09-15 | 2020-08-25 | Basf Se | compostos do catalisador de quelato de ti, formulação de catalisador de quelato de ti, uso do composto de catalisador de quelato de ti, ou da formulação de catalisador de quelato de ti, composição polimerizável, processo para a polimerização de compostos, uso da composição polimerizável, substrato revestido, e, composição polimerizada ou reticulada |
| DE102009046269A1 (de) | 2009-10-30 | 2011-05-05 | Henkel Ag & Co. Kgaa | Harnstoffgebundende Alkoxysilane zum Einsatz in Dicht- und Klebstoffen |
| DE102009057584A1 (de) * | 2009-12-09 | 2011-06-16 | Bayer Materialscience Ag | Polyurethane-Prepolymere |
| KR101130317B1 (ko) * | 2010-01-12 | 2012-03-26 | 도레이첨단소재 주식회사 | 연성회로기판 보강판용 접착제 조성물 및 이를 이용한 접착제 시트 |
| JP5769929B2 (ja) * | 2010-03-17 | 2015-08-26 | サンスター技研株式会社 | ポリウレタン樹脂 |
| AU2011260263B2 (en) | 2010-06-01 | 2014-04-24 | Edilon) (Sedra B.V. | Polymer composition, method for applying such composition and use of such composition in railway track structures |
| KR101123558B1 (ko) | 2011-03-14 | 2012-03-12 | 코오롱인더스트리 주식회사 | 친환경 소재를 적용한 폴리우레탄 조성물 및 이로부터 제조된 폴리우레탄 방수?바닥재 |
| JP5771048B2 (ja) * | 2011-04-05 | 2015-08-26 | コニシ株式会社 | 硬化性シリル化ウレタン系樹脂及びその製造方法 |
| JP5972990B2 (ja) * | 2011-11-10 | 2016-08-17 | モーメンティブ・パフォーマンス・マテリアルズ・インク | 湿気硬化性オルガノポリシロキサン組成物 |
| JP5679352B2 (ja) * | 2012-05-23 | 2015-03-04 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | 室温硬化性ケイ素基含有ポリマー組成物 |
| US20140058030A1 (en) * | 2012-08-23 | 2014-02-27 | Bayer Materialscience Llc | Silane-terminated polyurethane and rubber composite materials |
| DE102012223422A1 (de) | 2012-12-17 | 2014-06-18 | Henkel Ag & Co. Kgaa | Niedermodulige silanterminierte PU-Präpolymere |
| EP2774673A1 (de) | 2013-03-04 | 2014-09-10 | Nitrochemie Aschau GmbH | Katalysator für die Vernetzung von Siliconkautschukmassen |
| CN103146336B (zh) * | 2013-04-08 | 2014-08-06 | 株洲时代新材料科技股份有限公司 | 一种单组份硅烷改性聚氨酯密封胶及其制备方法 |
| EP2796493A1 (en) * | 2013-04-25 | 2014-10-29 | Huntsman International Llc | Composition comprising silylated polymers and polyhedral oligomeric metallo silsesquioxane |
| US9321878B2 (en) * | 2013-12-16 | 2016-04-26 | Momentive Performance Materials Inc. | Process for the preparation of silylated polyurethane polymers using titanium-containing and zirconium-containing catalysts |
| EP3108076B1 (en) | 2014-02-18 | 2025-03-26 | 3M Innovative Properties Company | Easy to apply air and water barrier articles |
| US9822263B2 (en) | 2014-04-28 | 2017-11-21 | Nitto Kasei Co., Ltd. | Electrodeposition coating material composition and catalyst for electrodeposition coating material |
| JP6615783B2 (ja) * | 2014-06-19 | 2019-12-04 | ハンツマン・インターナショナル・エルエルシー | シリル化ポリウレタン |
| CN107109152B (zh) | 2014-12-22 | 2020-11-03 | 3M创新有限公司 | 空气和水阻挡制品 |
| JP6536147B2 (ja) * | 2015-04-17 | 2019-07-03 | 東ソー株式会社 | ウレタンプレポリマー、及びそれを用いた2液型ウレタン粘着剤 |
| WO2017031275A1 (en) | 2015-08-18 | 2017-02-23 | 3M Innovative Properties Company | Self-sealing articles including elastic porous layer |
| JP2018536045A (ja) | 2015-11-18 | 2018-12-06 | ダウ グローバル テクノロジーズ エルエルシー | 加水分解性ポリエーテルモノシランで可塑化された単一成分湿気硬化型シランシーラント |
| WO2017112756A1 (en) | 2015-12-22 | 2017-06-29 | 3M Innovative Properties Company | Roll including air and water barrier article and method of using the same |
| KR101790486B1 (ko) * | 2016-03-30 | 2017-10-25 | 주식회사 빅스 | 텍스타일 코팅용 친수성 수분산 폴리우레탄 수지 및 그 제조방법 |
| WO2018156631A1 (en) | 2017-02-23 | 2018-08-30 | 3M Innovative Properties Company | Air and water barrier article including inelastic porous layer |
| JP2020527640A (ja) * | 2017-07-21 | 2020-09-10 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA | シリル化ポリウレタンおよびその製造方法 |
| EP3480234A1 (de) | 2017-11-03 | 2019-05-08 | Evonik Degussa GmbH | Block-copolymere, enthaltend polyester- und polyolefin-struktureinheiten, und deren verwendung |
| KR20200136456A (ko) * | 2018-08-17 | 2020-12-07 | 와커 헤미 아게 | 실란-종결 중합체를 생성하는 방법 |
| CN114206605A (zh) | 2019-08-07 | 2022-03-18 | 3M创新有限公司 | 带材、包括带材和复合层的制品及相关方法 |
| CN113736367B (zh) * | 2019-09-29 | 2022-03-18 | 江苏凯伦建材股份有限公司 | 一种适用于水泥基层的沥青聚氨酯防水涂料的制备方法 |
| CN110872373B (zh) * | 2019-11-29 | 2022-03-18 | 江西省纳米技术研究院 | 一种聚氨酯增粘剂及其制备方法与应用 |
| JP7799989B2 (ja) * | 2020-03-17 | 2026-01-16 | 三菱ケミカル株式会社 | ウレタン結合含有化合物の製造方法 |
| KR102132179B1 (ko) * | 2020-04-16 | 2020-07-09 | 광진산업(주) | 비스무스계 촉매가 함유된 폴리우레탄 제조용 조성물 |
| KR102157018B1 (ko) * | 2020-04-16 | 2020-09-16 | 김영기 | 폴리우레탄 조성물 및 이로부터 제조된 친환경 폴리우레탄 포장재 |
| WO2022064931A1 (ja) * | 2020-09-25 | 2022-03-31 | 株式会社スリーボンド | 湿気硬化性樹脂組成物および硬化物 |
| CN113292958A (zh) * | 2021-05-20 | 2021-08-24 | 山东沃赛新材料科技有限公司 | 一种高透明度环保型硅烷改性聚醚密封胶及其制备方法 |
| CN116606415B (zh) * | 2023-05-31 | 2026-02-27 | 湖北回天新材料股份有限公司 | 梳型硅烷封端聚氨酯聚合物树脂及其制备方法和应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3627722A (en) * | 1970-05-28 | 1971-12-14 | Minnesota Mining & Mfg | Polyurethane sealant containing trialkyloxysilane end groups |
| US5095045A (en) * | 1989-07-22 | 1992-03-10 | Bayer Aktiengesellschaft | Plastics which cure in a series of steps having urethane, urea, siloxane and acrylate groups |
| CN1245507A (zh) * | 1997-01-29 | 2000-02-23 | 爱赛克斯特种产品公司 | 聚氨酯密封剂组合物 |
| CN1637043A (zh) * | 2003-11-27 | 2005-07-13 | 瓦克化学有限公司 | 有机基氧基甲硅烷基终止的聚合物的制备方法 |
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|---|---|---|---|---|
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| JPS55164270A (en) | 1979-06-07 | 1980-12-20 | Kuraray Co Ltd | Laminate |
| US4242490A (en) | 1979-07-20 | 1980-12-30 | The General Tire & Rubber Company | Thermoset polyurethane prepared from a polypropylene ether triol obtained using a double metal cyanide complex catalyst, ethylene glycol and tolylene diisocyanate |
| US4345053A (en) * | 1981-07-17 | 1982-08-17 | Essex Chemical Corp. | Silicon-terminated polyurethane polymer |
| US4687851A (en) | 1985-08-15 | 1987-08-18 | The Dow Chemical Company | Polyurethane elastomers prepared from high equivalent weight polyahls |
| US5106874A (en) | 1989-06-16 | 1992-04-21 | The Dow Chemical Company | Process for preparing elastomeric polyurethane or polyurethane-urea polymers, and polyurethanes so prepared |
| US4985491A (en) | 1989-10-05 | 1991-01-15 | Olin Corporation | Polyurethane sealants made using high molecular weight polyols prepared with double metal cyanide catalysts |
| US5100997A (en) | 1990-05-29 | 1992-03-31 | Olin Corporation | Preparation of elastomers using high molecular weight polyols or polyamines, said polyols prepared using a double metal cyanide complex catalyst |
| US5136010A (en) | 1990-09-28 | 1992-08-04 | Olin Corporation | Polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts |
| US5116931A (en) | 1990-09-28 | 1992-05-26 | Olin Corporation | Thermoset polyurethane elastomers and polyurea elastomers made using high functionality, low unsaturation level polyols prepared with double metal cyanide catalysts |
| US5096993A (en) | 1990-11-02 | 1992-03-17 | Olin Corporation | Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts |
| US5185420A (en) | 1990-11-02 | 1993-02-09 | Olin Corporation | Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts |
| US5266681A (en) | 1992-08-03 | 1993-11-30 | Olin Corporation | Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity |
| JP3296982B2 (ja) * | 1996-12-11 | 2002-07-02 | サンスター技研株式会社 | 一液型湿気硬化性組成物 |
| US5976669A (en) * | 1996-12-20 | 1999-11-02 | 3M Innovative Properties Company | Retroreflective article having launderably durable bead-bond |
| US5990257A (en) * | 1998-01-22 | 1999-11-23 | Witco Corporation | Process for producing prepolymers which cure to improved sealants, and products formed thereby |
| US6121354A (en) * | 1998-11-19 | 2000-09-19 | Bostik, Inc. | High performance single-component sealant |
| JP3477120B2 (ja) * | 1999-09-20 | 2003-12-10 | サンスター技研株式会社 | 2成分形硬化性組成物 |
| US7115696B2 (en) * | 2002-05-31 | 2006-10-03 | Bayer Materialscience Llc | Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings |
| US20030225237A1 (en) * | 2002-05-31 | 2003-12-04 | Roesler Richard R. | Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings |
| US6844413B2 (en) * | 2002-06-18 | 2005-01-18 | Bayer Materialscience Llc | Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings |
| US6749943B1 (en) * | 2002-07-02 | 2004-06-15 | 3M Innovative Properties Company | Silane based moisture curing hot-melt adhesives |
| US7009022B2 (en) * | 2003-12-15 | 2006-03-07 | Henkel Corporation | Moisture curable high strength, flexible RTV organic copolymer compositions and methods of preparation |
| JP4535764B2 (ja) * | 2004-04-09 | 2010-09-01 | サンスター技研株式会社 | ガラス面用プライマー組成物 |
| US7365145B2 (en) * | 2005-09-14 | 2008-04-29 | Momentive Performance Materials Inc. | Moisture curable silylated polymer containing free polyols for coating, adhesive and sealant application |
-
2005
- 2005-09-15 US US11/227,919 patent/US8232362B2/en active Active
-
2006
- 2006-08-31 KR KR1020087006199A patent/KR101350769B1/ko not_active Expired - Fee Related
- 2006-08-31 AU AU2006295277A patent/AU2006295277A1/en not_active Abandoned
- 2006-08-31 CA CA002622156A patent/CA2622156A1/en not_active Abandoned
- 2006-08-31 JP JP2008531157A patent/JP5603007B2/ja not_active Expired - Fee Related
- 2006-08-31 CN CN2006800342110A patent/CN101273074B/zh not_active Expired - Fee Related
- 2006-08-31 BR BRPI0616214-2A patent/BRPI0616214A2/pt active IP Right Grant
- 2006-08-31 EP EP12002245.4A patent/EP2518094B1/en active Active
- 2006-08-31 WO PCT/US2006/034138 patent/WO2007037915A2/en not_active Ceased
- 2006-08-31 RU RU2008114489/04A patent/RU2008114489A/ru not_active Application Discontinuation
- 2006-08-31 EP EP06802760.6A patent/EP1943282B1/en active Active
- 2006-09-13 TW TW095133905A patent/TW200720308A/zh unknown
-
2008
- 2008-03-14 NO NO20081347A patent/NO20081347L/no not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3627722A (en) * | 1970-05-28 | 1971-12-14 | Minnesota Mining & Mfg | Polyurethane sealant containing trialkyloxysilane end groups |
| US5095045A (en) * | 1989-07-22 | 1992-03-10 | Bayer Aktiengesellschaft | Plastics which cure in a series of steps having urethane, urea, siloxane and acrylate groups |
| CN1245507A (zh) * | 1997-01-29 | 2000-02-23 | 爱赛克斯特种产品公司 | 聚氨酯密封剂组合物 |
| CN1637043A (zh) * | 2003-11-27 | 2005-07-13 | 瓦克化学有限公司 | 有机基氧基甲硅烷基终止的聚合物的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US8232362B2 (en) | 2012-07-31 |
| EP2518094B1 (en) | 2017-12-27 |
| EP1943282A2 (en) | 2008-07-16 |
| JP5603007B2 (ja) | 2014-10-08 |
| WO2007037915A3 (en) | 2007-06-14 |
| TW200720308A (en) | 2007-06-01 |
| WO2007037915A2 (en) | 2007-04-05 |
| RU2008114489A (ru) | 2009-10-20 |
| EP2518094A1 (en) | 2012-10-31 |
| AU2006295277A1 (en) | 2007-04-05 |
| CN101273074A (zh) | 2008-09-24 |
| JP2009508985A (ja) | 2009-03-05 |
| KR101350769B1 (ko) | 2014-02-17 |
| BRPI0616214A2 (pt) | 2011-06-14 |
| CA2622156A1 (en) | 2007-04-05 |
| NO20081347L (no) | 2008-06-09 |
| EP1943282B1 (en) | 2020-03-04 |
| KR20080055831A (ko) | 2008-06-19 |
| US20070060732A1 (en) | 2007-03-15 |
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