CN101203474A - 羟基化芳族化合物的c-烷基化方法 - Google Patents

羟基化芳族化合物的c-烷基化方法 Download PDF

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Publication number
CN101203474A
CN101203474A CN 200680022161 CN200680022161A CN101203474A CN 101203474 A CN101203474 A CN 101203474A CN 200680022161 CN200680022161 CN 200680022161 CN 200680022161 A CN200680022161 A CN 200680022161A CN 101203474 A CN101203474 A CN 101203474A
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CN
China
Prior art keywords
group
acid catalyst
atom
ring
hydroxyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200680022161
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English (en)
Chinese (zh)
Inventor
J-P·西莫纳托
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Publication of CN101203474A publication Critical patent/CN101203474A/zh
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0222—Sulfur-containing compounds comprising sulfonyl groups
    • B01J31/0224—Sulfur-containing compounds comprising sulfonyl groups being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by condensation involving hydroxy groups of phenols or alcohols or the ether or mineral ester group derived therefrom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN 200680022161 2005-08-04 2006-08-03 羟基化芳族化合物的c-烷基化方法 Pending CN101203474A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0508344A FR2889519B1 (fr) 2005-08-04 2005-08-04 Procede de c-alkylation de composes aromatiques hydroxyles avec un catalyseur de type tfsih
FR0508344 2005-08-04

Publications (1)

Publication Number Publication Date
CN101203474A true CN101203474A (zh) 2008-06-18

Family

ID=36581630

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200680022161 Pending CN101203474A (zh) 2005-08-04 2006-08-03 羟基化芳族化合物的c-烷基化方法

Country Status (5)

Country Link
EP (1) EP1910256A2 (fr)
JP (1) JP2009503038A (fr)
CN (1) CN101203474A (fr)
FR (1) FR2889519B1 (fr)
WO (1) WO2007015015A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643170A (zh) * 2012-05-09 2012-08-22 河北工业大学 一种用含离子液体的混酸催化体系合成对叔丁基邻苯二酚的方法
CN109721473A (zh) * 2017-10-30 2019-05-07 中国石油化工股份有限公司 一种制备邻甲酚的方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5716291B2 (ja) * 2009-04-27 2015-05-13 セントラル硝子株式会社 含フッ素レジスト用モノマー類の製造方法
JP6083643B2 (ja) * 2013-05-13 2017-02-22 国立大学法人 鹿児島大学 シルセスキオキサン構造を有するイオン液体及びその製造方法
JP6034750B2 (ja) * 2013-05-31 2016-11-30 三井化学株式会社 パラデシルフェノール
CN112079690B (zh) * 2020-08-24 2023-03-10 西安石油大学 一种用于2,4/2,5-二甲酚的烷基化反应装置及方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908939A (en) * 1996-11-11 1999-06-01 Roche Vitamins Inc. Method of making D,L-A-tocopherol
US6664380B1 (en) * 1999-08-18 2003-12-16 The Institute Of Applied Catalysis Perfluorosulfonylmethide compounds; use thereof for carbon-carbon bond formation
EP1414568B1 (fr) * 2001-03-12 2007-08-22 The Queen's University of Belfast Utilisation de composes de bis-triflimides metalliques

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643170A (zh) * 2012-05-09 2012-08-22 河北工业大学 一种用含离子液体的混酸催化体系合成对叔丁基邻苯二酚的方法
CN109721473A (zh) * 2017-10-30 2019-05-07 中国石油化工股份有限公司 一种制备邻甲酚的方法
CN109721473B (zh) * 2017-10-30 2022-02-08 中国石油化工股份有限公司 一种制备邻甲酚的方法

Also Published As

Publication number Publication date
FR2889519A1 (fr) 2007-02-09
JP2009503038A (ja) 2009-01-29
WO2007015015A2 (fr) 2007-02-08
WO2007015015A3 (fr) 2007-04-12
EP1910256A2 (fr) 2008-04-16
FR2889519B1 (fr) 2008-07-11

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Open date: 20080618