CN101171921A - Bactericide agent composition containing active ingredient of metiram - Google Patents
Bactericide agent composition containing active ingredient of metiram Download PDFInfo
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- CN101171921A CN101171921A CNA2007100188627A CN200710018862A CN101171921A CN 101171921 A CN101171921 A CN 101171921A CN A2007100188627 A CNA2007100188627 A CN A2007100188627A CN 200710018862 A CN200710018862 A CN 200710018862A CN 101171921 A CN101171921 A CN 101171921A
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Abstract
The invention discloses a disinfectant component containing the effective ingredient of metiram. The disinfectant component comprises active ingredient component A and active ingredient component B; wherein, the active ingredient component A is the effective ingredient of the metiram, and the active ingredient component B comprises at least one of the following disinfectants: thiophanate-methyl, carbendazim, myclobutanil, difenoconazole, propiconazole, tebuconazole, hexaconazole, polyoxin or benomyl; according to the mass rate, the weight proportion of the active ingredient component A and the active ingredient component B is 50 : 1 to 1:50. The invention is characterized in that the binary sterilizing component can be used to prevent eyespot and anthracnose which are difficult to be prevented in agriculture, and to prevent the disease damages such as leaf spotted disease on fruit trees, and the prevention effect is respectively 87.9 percent, 89.4 percent, 90.5 percent, 92.3 percent, 93.8 percent, 89.7 percent, 90.6 percent, and 91.2 percent.
Description
Technical field
The agriculture chemicals fungicide composition that the present invention relates to, particularly a kind of microbicide compositions that contains the active ingredient of Carbatene.
Technical background
Existing agriculture chemicals fungicide is to form with single agent kind and additive combination mostly, and there is the relatively poor defective of prevention and elimination of disease and pests effect in this single agent kind, narrates the shortcoming of single agent kind below respectively:
Thiophanate-methyl, carbendazim, benomyl are three kinds of more common systemic fungicides, belong to benzimidazole; Its main mechanism is to disturb the formation of spindle in the mitosis of bacterium, thereby influences the cell division of bacterium, prevents and treats disease drug resistance in recent years separately and obviously strengthens, and causes its preventive effect very poor.
Nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, these five kinds all belong to triazole bactericidal agent, can prevent and treat the caused disease of sac fungi, basidiomycetes and imperfect fungus, it is sterol demethylation inhibitor, the content of these five kinds of compositions is more on the low side in the market, though all belong to broad-spectrum germicide, owing to use for many years, single use preventive effect obviously descends directly influences the high yield of grain.
Polyoxin: be the metabolite that streptomyces aureus produces, belong to the broad-spectrum antibiotics series bactericidal agent, have interior preferably absorption.Be a kind of efficient, the safety pesticide of low toxicity non-environmental-pollution, owing to belong to biologic product, and single use, preventive effect is slow.
Ring spot, anthracnose, spot defoliation are diseases more common on the various crop, usually cause crushing disaster.Particularly spot defoliation is prevented and treated difficulty, especially in zone, the north, and annual generation.In some serious zone, the conventional pesticide composition uses separately and be difficult to control, and effect is very poor.
Go up the germ that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But there is the cost height again in the exploitation of new active ingredient, the defective that the construction cycle is long.The composition of different cultivars is mixed, and is a kind of selection of the best.If reasonable proportioning is arranged, usually can produce synergistic effect.Make field control effect significantly be better than the effect of two kinds of single agent.Show the result of 1+1＞2.
Summary of the invention
The purpose of this invention is to provide a kind of composition of different cultivars that adopts and be mixed, produce synergistic effect, make field control effect significantly be better than a kind of microbicide compositions that contains the active ingredient of Carbatene of two kinds of single agent.
In order to overcome the defective that prior art exists, technical solution of the present invention is achieved in that a kind of microbicide compositions that contains the active ingredient of Carbatene, and substantive distinguishing features that it is outstanding and obvious improvement are that described microbicide compositions comprises that active ingredient components A and active ingredient components B form; Wherein active ingredient components A is the active ingredient of Carbatene, active ingredient components B is at least a following bactericide, and its bactericide is thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or benomyl; Is 50: 1～1: 50 by quality than the part by weight of active ingredient components A: active ingredient components B.
In order to prevent and treat more refractory ring spot, anthracnose, spot defoliation on the agricultural.Carried out mutual compositely with Carbatene A and different types of B composition, the ring spot on the crop, anthracnose, spot defoliation have been carried out Toxicity Determination and used prescription screening with different proportionings.
Carbatene: be a kind of non-internal-absorting bactericide, can stop the sprouting of germ spore, suppress the elongation of germ germ tube, make germ can't infect plant tissue; Can be widely used in ring spot, spot defoliation, anthracnose and the downy mildew etc. of preventing and treating various crop.Facts have proved that this composition is not only active high, toxicity is low but also pollution-free to surrounding environment.
The former medicine of test medicine provides for producer.This experiment adopts growth rate method to carry out, and be mixed into contrast with equivalent sterile water and medium, calculate virulence equation and lethal concentration of 50 LC50 with method of least squares, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC method) according to the abundant method of Sun Yun, two kinds of different proportioning synergies of medicament are antagonism than it (SR) SR＜0.5,0.5≤SR≤1.5 are summation action, SR＞1.5 are synergistic effect.Not only can prevent and treat the difficult ring spot that prevents on the agricultural, anthracnose, but also can prevent and treat diseases such as spot defoliation on the fruit tree.
Be mixed with active component Carbatene A and different activities composition B ring spot, anthracnose and spot fallen leaves and virulence test data are seen Table 1
Table 1
| Handle | LC50(PPM) | Co-toxicity coefficient | ||
| Ring spot | Anthracnose | Spot defoliation | ||
| Carbatene 10+ thiophanate-methyl 15 | 14.82 | 413.8 | 454.8 | 410.9 |
| Carbatene 15+ thiophanate-methyl 10 | 15.01 | 600.5 | 624.3 | 660.1 |
| Carbatene 30+ carbendazim 15 | 13.82 | 340.2 | 350.6 | 333.1 |
| Carbatene 25+ carbendazim 20 | 15.01 | 385.3 | 360.4 | 372.4 |
| Carbatene 30+ nitrile bacterium azoles 30 | 12.82 | 470.2 | 380.7 | 412.3 |
| Carbatene 8+ nitrile bacterium azoles 40 | 14.01 | 409.1 | 394.6 | 401.6 |
| Carbatene 40+ Difenoconazole 20 | 12.82 | 570.2 | 498.2 | 500.1 |
| Carbatene 10+ Difenoconazole 40 | 15.01 | 349.1 | 405.6 | 410.4 |
| Carbatene 30+ propiconazole 30 | 13.82 | 670.2 | 620.1 | 598.7 |
| Carbatene 10+ propiconazole 45 | 11.01 | 319.1 | 505.6 | 500.5 |
| Carbatene 45+ Tebuconazole 10 | 13.82 | 320.2 | 333.2 | 352.4 |
| Carbatene 20+ Tebuconazole 40 | 11.01 | 419.1 | 372.5 | 448.3 |
| The own azoles alcohol 45 of Carbatene 10+ | 14.82 | 320.2 | 350.2 | 355.2 |
| The own azoles alcohol 25 of Carbatene 25+ | 15.01 | 319.1 | 305.4 | 340.7 |
| Carbatene 30+ polyoxin 30 | 14.82 | 420.2 | 699.4 | 609.2 |
| Carbatene 45+ polyoxin 10 | 15.01 | 559.1 | 595.7 | 612.8 |
| Carbatene 28+ benomyl 47 | 14.82 | 510.2 | 580.5 | 590.9 |
| Carbatene 35+ benomyl 20 | 12.01 | 559.1 | 570.4 | 558.6 |
| Carbatene | 40.42 | - | - | - |
| Thiophanate-methyl | 52.10 | - | - | - |
| Carbendazim | 49.24 | - | - | - |
| Nitrile bacterium azoles | 56.3 | - | - | - |
| Difenoconazole | 57.2 | - | - | - |
| Propiconazole | 50.9 | - | - | - |
| Tebuconazole | 51.14 | - | - | - |
| Own azoles alcohol | 54.8 | - | - | - |
| Polyoxin | 58.9 | - | - | - |
| Benomyl | 55.6 | - | - | - |
From table, can obviously find out Carbatene and thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole.Propiconazole, Tebuconazole, own azoles alcohol, polyoxin or wherein any one combination of benomyl.To the ring spot of difficult control on the agricultural, anthracnose, and spot defoliation clearly synergistic effect is arranged.
Embodiment
Following examples specify content of the present invention, but the present invention is not limited to following examples.Each component percentage composition or proportioning are all in weight ratio among the embodiment.
A kind of microbicide compositions that contains the active ingredient of Carbatene, its described microbicide compositions comprise that active ingredient components A and active ingredient components B form; Wherein active ingredient components A is the active ingredient of Carbatene, active ingredient components B comprises at least a following bactericide, and its bactericide is thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or benomyl; Is 50: 1～1: 50 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 45: 5～10: 40 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 40: 10～15: 35 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 35: 15～20: 30 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described any composition can be made into different application forms, and its formulation can be suspending agent, aqueous dispersion pulvis, wetting powder.
The content percentage by weight of any one accumulation is between 1～99% in the Carbatene A of described any composition and the thiophanate-methyl of active ingredient components B, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or the benomyl.
Embodiment 1: ring spot.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 20%, with to be mixed respectively with a kind of in Different Weight proportioning thiophanate-methyl 20%, carbendazim 10%, nitrile bacterium azoles 25%, Difenoconazole 15% propiconazole 16%, Tebuconazole 22%, polyoxin 30%, the benomyl 9%, add wetting agent, diffusant and the filler of constant weight proportioning again and make wetting powder.All prescriptions are all sprayed by 1000～1500 times of dilutions, and to be respectively be 90.8%, 89.7%, 91.2%, 90.4%, 90.9%, 92.0%, 88.7%, 89.1% to 72 hours field control effects behind the medicine; If adopt 20% thiophanate-methyl list agent to be made into wetting powder or adopt 10% carbendazim list agent to be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder according to using with quadrat method with 9% benomyl list agent with 30% polyoxin list agent with 22% Tebuconazole list agent with 16% propiconazole list agent with 15% Difenoconazole list agent with 25% nitrile bacterium azoles list agent, 72 hours preventive effects are respectively 30.4% behind the medicine, 35.6%, 40.7%, 50.2%, 18.9%, 29.3%, 34.2%, 38.5%, be mixed and single agent use comparison by above-mentioned, be understood that its gained control efficiency differs 2～3 times.
Embodiment 2: anthracnose.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 35%, with with in Different Weight proportioning thiophanate-methyl 15%, carbendazim 30%, nitrile bacterium azoles 10%, Difenoconazole 30% propiconazole 34%, Tebuconazole 38%, polyoxin 10%, the benomyl 30% with one or both or two or morely be mixed respectively, add wetting agent, surfactant, emulsifier, cosolvent, antifreezing agent, thickener, defoamer, the water of constant weight proportioning again and do surplus, make suspending agent.All prescriptions are all sprayed by 1500～2500 times of dilutions, and to be respectively be 88.7%, 89.1%, 90.3%, 92.3%, 90.6%, 92.0%, 89.9%, 88.1%, 93.5% to 72 hours field control effects behind the medicine; Be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into suspending agent according to using if adopt with quadrat method with 30% benomyl list agent with 10% polyoxin list agent with 38% Tebuconazole list agent with 34% propiconazole list agent with 30% Difenoconazole list agent with 22% Tebuconazole list agent with 16% propiconazole list agent with 15% Difenoconazole list agent with 10% nitrile bacterium azoles list agent with 30% carbendazim list agent with 15% thiophanate-methyl list agent, 72 hours preventive effects are respectively 30.5% behind the medicine, 48.3%, 39.2%, 37.5%, 45.6%, 40.2%, 38.3%, 20.1%, be mixed and single agent use comparison by above-mentioned, be understood that its gained control efficiency differs 2～3 times.
Embodiment 3: spot defoliation.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 45%, with with Different Weight proportioning thiophanate-methyl 30%, carbendazim 20%, nitrile bacterium azoles 30%, Difenoconazole 20%, in propiconazole 20%, Tebuconazole 6%, polyoxin 20%, the benomyl 15% with one or both or two or morely be mixed respectively, add wetting agent, dispersant and the filler of constant weight proportioning again, make water dispersible granules.All by 2000～2500 times of dilution sprayings, 72 hours field control effects are respectively 87.9%, 89.4%, 90.5%, 92.3%, 93.8%, 89.7%, 90.6%, 91.2% to all prescriptions behind the medicine; Be made into the water dispersible granules agent or be made into water dispersible granules or be made into water dispersible granules or be made into water dispersible granules or be made into water dispersible granules or be made into the water dispersible granules agent or be made into water dispersible granules or be made into water dispersible granules according to using if adopt with quadrat method with 15% benomyl list agent with 20% polyoxin list agent with 6% Tebuconazole list agent with 20% propiconazole list agent with 20% Difenoconazole list agent with 30% nitrile bacterium azoles list agent with 20% carbendazim list agent with 20% methyl sulfur bacterium list agent, 72 hours preventive effects are respectively 20.8% behind the medicine, 19.7%, 30.5%, 32.3%, 20.7%, 32.8%, 29.7%, 12.5%, be mixed and single agent use comparison by above-mentioned, be understood that its gained control efficiency differs 2～3 times.
Additive described in the foregoing description comprises wetting agent, dispersant and filler; Wherein wetting agent is meant in sodium alkyl sulfate, alkylbenzenesulfonate, Fluhyzon formaldehyde condensation products, alkyl phenol polyether, fatty alcohol-polyoxyethylene ether, Tween-60, the Tween-80 any one or two or more combination; Dispersant is meant in polycarboxylate, lignosulfonates, Fluhyzon formaldehyde condensation products, sulfite cellulose solid dry substance, the oxirane propylene oxide block copolymer any one or two or more combination; Filler is meant kaolin.Wetting agent: diffusant: filler=5%～7%: 8%～15%: 15%～20%.
Claims (6)
1. a microbicide compositions that contains the active ingredient of Carbatene is characterized in that described microbicide compositions comprises active ingredient components (A) and active ingredient components (B) composition; Wherein active ingredient components (A) is the active ingredient of Carbatene, active ingredient components (B) comprises at least a following bactericide, and its bactericide is thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or benomyl; By quality than active ingredient components (A): the part by weight of active ingredient components (B) is 50: 1～1: 50.
2. a kind of microbicide compositions that contains the active ingredient of Carbatene according to claim 1, it is characterized in that described by quality than active ingredient components (A): the part by weight of active ingredient components (B) is 45: 5～10: 40.
3. a kind of microbicide compositions that contains the active ingredient of Carbatene according to claim 1, it is characterized in that described by quality than active ingredient components (A): the part by weight of active ingredient components (B) is 40: 10～15: 35.
4. a kind of microbicide compositions that contains the active ingredient of Carbatene according to claim 1, it is characterized in that described by quality than active ingredient components (A): the part by weight of active ingredient components (B) is 35: 15～20: 30.
5. according to the described a kind of microbicide compositions that contains the active ingredient of Carbatene of claim 1-4, it is characterized in that described any composition can be made into different application forms, its formulation can be suspending agent, aqueous dispersion pulvis, wetting powder.
6. according to the described a kind of microbicide compositions that contains the active ingredient of Carbatene of claim 1-4, the content percentage by weight that it is characterized in that any one accumulation in thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or the benomyl of the Carbatene (A) of described any composition and active ingredient components (B) is between 1～99%.
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| CN2007100188627A CN101171921B (en) | 2007-10-15 | 2007-10-15 | Bactericide agent composition containing active ingredient of metiram |
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| CN 201110060164 Division CN102308822B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing active ingredients of metiram |
| CN2011100601616A Division CN102308821B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
| CN201110060147A Division CN102308819A (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
| CN 201110060151 Division CN102308820B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
| CN 201110060139 Division CN102308818B (en) | 2007-10-15 | 2007-10-15 | Germicide composition containing active ingredient of polyram |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101971840A (en) * | 2010-11-22 | 2011-02-16 | 陕西美邦农药有限公司 | Bactericidal composition containing cyproconazole and metiram |
| CN101999380A (en) * | 2010-12-03 | 2011-04-06 | 陕西美邦农药有限公司 | Difenoconazole- and propineb-containing pesticidal composition |
| CN101530102B (en) * | 2008-09-11 | 2011-09-21 | 张少武 | Sterilization composition containing fenbuconazole and thiophonate-methyl and application thereof |
| CN101380011B (en) * | 2008-08-06 | 2012-03-07 | 张少武 | Composition containing thiophonate-methyl and hexaconazole with bactericidal action |
| CN101822264B (en) * | 2010-02-03 | 2013-03-13 | 陕西美邦农资贸易有限公司 | Bactericidal composition with pyriproxyfen and thiophanate-methyl |
| CN102308820B (en) * | 2007-10-15 | 2013-10-09 | 张少武 | Bactericide composition containing metiram active ingredient |
| CN104926449A (en) * | 2015-06-08 | 2015-09-23 | 柳州市宝杨种植专业合作社 | Organic-inorganic compound fertilizer capable of preventing block spot disease of dendrobium candidum |
| WO2016203154A1 (en) * | 2015-06-19 | 2016-12-22 | Phyteurop S.A. | Process for treating perennial plant wood diseases |
| CN108174859A (en) * | 2018-02-02 | 2018-06-19 | 北京科发伟业农药技术中心 | A kind of bactericidal composition containing Carbatene |
| CN108294032A (en) * | 2018-02-02 | 2018-07-20 | 北京科发伟业农药技术中心 | Bactericidal composition containing Carbatene |
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- 2007-10-15 CN CN2007100188627A patent/CN101171921B/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102308820B (en) * | 2007-10-15 | 2013-10-09 | 张少武 | Bactericide composition containing metiram active ingredient |
| CN101380011B (en) * | 2008-08-06 | 2012-03-07 | 张少武 | Composition containing thiophonate-methyl and hexaconazole with bactericidal action |
| CN101530102B (en) * | 2008-09-11 | 2011-09-21 | 张少武 | Sterilization composition containing fenbuconazole and thiophonate-methyl and application thereof |
| CN101822264B (en) * | 2010-02-03 | 2013-03-13 | 陕西美邦农资贸易有限公司 | Bactericidal composition with pyriproxyfen and thiophanate-methyl |
| CN101971840A (en) * | 2010-11-22 | 2011-02-16 | 陕西美邦农药有限公司 | Bactericidal composition containing cyproconazole and metiram |
| CN101999380A (en) * | 2010-12-03 | 2011-04-06 | 陕西美邦农药有限公司 | Difenoconazole- and propineb-containing pesticidal composition |
| CN101999380B (en) * | 2010-12-03 | 2013-10-09 | 陕西美邦农药有限公司 | Difenoconazole- and propineb-containing pesticidal composition |
| CN104926449A (en) * | 2015-06-08 | 2015-09-23 | 柳州市宝杨种植专业合作社 | Organic-inorganic compound fertilizer capable of preventing block spot disease of dendrobium candidum |
| WO2016203154A1 (en) * | 2015-06-19 | 2016-12-22 | Phyteurop S.A. | Process for treating perennial plant wood diseases |
| FR3037479A1 (en) * | 2015-06-19 | 2016-12-23 | Phyteurop S A | PROCESS FOR TREATING WOOD DISEASES OF PERENNIAL PLANTS |
| CN108174859A (en) * | 2018-02-02 | 2018-06-19 | 北京科发伟业农药技术中心 | A kind of bactericidal composition containing Carbatene |
| CN108294032A (en) * | 2018-02-02 | 2018-07-20 | 北京科发伟业农药技术中心 | Bactericidal composition containing Carbatene |
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