CN102308820B - Bactericide composition containing metiram active ingredient - Google Patents
Bactericide composition containing metiram active ingredient Download PDFInfo
- Publication number
- CN102308820B CN102308820B CN 201110060151 CN201110060151A CN102308820B CN 102308820 B CN102308820 B CN 102308820B CN 201110060151 CN201110060151 CN 201110060151 CN 201110060151 A CN201110060151 A CN 201110060151A CN 102308820 B CN102308820 B CN 102308820B
- Authority
- CN
- China
- Prior art keywords
- active ingredient
- agent
- carbatene
- metiram
- bactericide composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention discloses a bactericide composition containing metiram active ingredient. The bactericide composition comprises an active ingredient component A and an active ingredient component B, wherein the active ingredient component A is the metiram active ingredient, the active ingredient component B comprises at least one of the following bactericides: methyl thiophanate, carbendazim, myclobutanil, difenoconazole, propiconazole, tebuconazole, hexaconazole, polyoxin and benomyl, and the weight ratio of the active ingredient component A to the active ingredient component B is (50-1): (1-50). The invention has the characteristics that binary bactericide composition can be used for preventing and controlling ring spot and anthracnose in southern area in agriculture and also can be used for preventing and controlling alternaria leaf spot on fruit trees, and preventing and controlling effects are respectively 87.9%, 89.4%, 90.5%, 92.3%, 93.8%, 89.7%, 90.6% and 91.2%.
Description
The application is for dividing an application, and original application is the patent application " a kind of microbicide compositions that contains the active ingredient of Carbatene " of Zhang Shaowu, and the application number of original application is: 200710018862.7, and original application day is 2007.10.15.
Technical field
The agriculture chemicals fungicide composition that the present invention relates to, particularly a kind of microbicide compositions that contains the active ingredient of Carbatene.
Technical background
Existing agriculture chemicals fungicide is to form with single agent kind and additive combination mostly, and there is the relatively poor defective of prevention and elimination of disease and pests effect in this single agent kind, narrates the shortcoming of single agent kind below respectively:
Thiophanate-methyl, carbendazim, benomyl are three kinds of more common systemic fungicides, belong to benzimidazole; Its main mechanism is to disturb the formation of spindle in the mitosis of bacterium, thereby influences the cell division of bacterium, prevents and treats disease drug resistance in recent years separately and obviously strengthens, and causes its preventive effect very poor.
Nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, these five kinds all belong to triazole bactericidal agent, can prevent and treat the caused disease of sac fungi, basidiomycetes and imperfect fungus, it is sterol demethylation inhibitor, the content of these five kinds of compositions is more on the low side in the market, though all belong to broad-spectrum germicide, owing to use for many years, single use preventive effect obviously descends directly influences the high yield of grain.
Polyoxin: be the metabolite that streptomyces aureus produces, belong to the broad-spectrum antibiotics series bactericidal agent, have interior absorption preferably.Be a kind of efficient, the safety pesticide of low toxicity non-environmental-pollution, owing to belong to biologic product, and single use, preventive effect is slow.
Ring spot, anthracnose, spot defoliation are diseases more common on the various crop, usually cause crushing disaster.Particularly spot defoliation is prevented and treated difficulty, especially in zone, the north, and annual generation.In some serious zone, the conventional pesticide composition uses separately and be difficult to control, and effect is very poor.
Go up the germ that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But there is the cost height again in the exploitation of new active ingredient, the defective that the construction cycle is long.The composition of different cultivars is mixed, and is a kind of selection of the best.If reasonable proportioning is arranged, usually can produce synergistic effect.Make field control effect significantly be better than the effect of two kinds of single agent.Show the result of 1+1＞2.
Summary of the invention
The purpose of this invention is to provide a kind of composition of different cultivars that adopts and be mixed, produce synergistic effect, make field control effect significantly be better than a kind of microbicide compositions that contains the active ingredient of Carbatene of two kinds of single agent.
In order to overcome the defective that prior art exists, technical solution of the present invention is achieved in that a kind of microbicide compositions that contains the active ingredient of Carbatene, and the substantive distinguishing features that it is outstanding and obvious improvement are that described microbicide compositions comprises that active ingredient components A and active ingredient components B form; Wherein active ingredient components A is the active ingredient of Carbatene, active ingredient components B is at least a following bactericide, and its bactericide is thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or benomyl; Be 50: 1～1: 50 by quality than the part by weight of active ingredient components A: active ingredient components B.
In order to prevent and treat more refractory ring spot, anthracnose, spot defoliation on the agricultural.Carried out mutual compositely with Carbatene A and different types of B composition, the ring spot on the crop, anthracnose, spot defoliation have been carried out Toxicity Determination and used prescription screening with different proportionings.
Carbatene: be a kind of non-internal-absorting bactericide, can stop the sprouting of germ spore, suppress the elongation of germ germ tube, make germ can't infect plant tissue; Can be widely used in ring spot, spot defoliation, anthracnose and the downy mildew etc. of preventing and treating various crop.Facts have proved, this composition not only active high, toxicity is low but also pollution-free to surrounding environment.
The former medicine of test medicine provides for producer.This experiment adopts growth rate method to carry out, and be mixed into contrast with equivalent sterile water and medium, calculate virulence equation and lethal concentration of 50 LC50 with method of least squares, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC method) according to the abundant method of Sun Yun, two kinds of different proportioning synergies of medicament are antagonism than it (SR) SR＜0.5,0.5≤SR≤1.5 are summation action, SR＞1.5 are synergistic effect.Not only can prevent and treat the difficult ring spot that prevents on the agricultural, anthracnose, but also can prevent and treat diseases such as spot defoliation on the fruit tree.
Be mixed with active component Carbatene A and different activities composition B ring spot, anthracnose and spot fallen leaves and virulence test data are seen Table 1
Table 1
From table, can obviously find out Carbatene and thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or wherein any one combination of benomyl.Ring spot, anthracnose and the spot defoliation of difficult control on the agricultural there is clearly synergistic effect.
Embodiment
Following examples specify content of the present invention, but the present invention is not limited to following examples.Each component percentage composition or proportioning are all in weight ratio among the embodiment.
A kind of microbicide compositions that contains the active ingredient of Carbatene, its described microbicide compositions comprise that active ingredient components A and active ingredient components B form; Wherein active ingredient components A is the active ingredient of Carbatene, active ingredient components B comprises at least a following bactericide, and its bactericide is thiophanate-methyl, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or benomyl; Be 50: 1～1: 50 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 45: 5～10: 40 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 40: 10～15: 35 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described is 35: 15～20: 30 by quality than the part by weight of active ingredient components A: active ingredient components B.
Described any composition can be made into different application forms, and its formulation can be suspending agent, aqueous dispersion pulvis, wetting powder.
The content percentage by weight of any one accumulation is between 1～99% in the Carbatene A of described any composition and the thiophanate-methyl of active ingredient components B, carbendazim, nitrile bacterium azoles, Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, polyoxin or the benomyl.
Embodiment 1: ring spot.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 20%, with to be mixed respectively with a kind of in Different Weight proportioning thiophanate-methyl 20%, carbendazim 10%, nitrile bacterium azoles 25%, Difenoconazole, 15% propiconazole 16%, Tebuconazole 22%, polyoxin 30%, the benomyl 9%, add wetting agent, diffusant and the filler of constant weight proportioning again and make wetting powder.All prescriptions are all sprayed by 1000～1500 times of dilutions, and to be respectively be 90.8%, 89.7%, 91.2%, 90.4%, 90.9%, 92.0%, 88.7%, 89.1% to 72 hours field control effects behind the medicine; If adopt 20% thiophanate-methyl list agent to be made into wetting powder or adopt 10% carbendazim list agent to be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into wetting powder according to using with quadrat method with 9% benomyl list agent with 30% polyoxin list agent with 22% Tebuconazole list agent with 16% propiconazole list agent with 15% Difenoconazole list agent with 25% nitrile bacterium azoles list agent, 72 hours preventive effects are respectively 30.4% behind the medicine, 35.6%, 40.7%, 50.2%, 18.9%, 29.3%, 34.2%, 38.5%, used relatively with single agent by above-mentioned being mixed, be understood that its gained control efficiency differs 2～3 times.
Embodiment 2: anthracnose.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 35%, with with in Different Weight proportioning thiophanate-methyl 15%, carbendazim 30%, nitrile bacterium azoles 10%, Difenoconazole 30%, propiconazole 34%, Tebuconazole 38%, polyoxin 10%, the benomyl 30% with one or both or two or morely be mixed respectively, add wetting agent, surfactant, emulsifier, cosolvent, antifreezing agent, thickener, defoamer, the water of constant weight proportioning again and do surplus, make suspending agent.All prescriptions are all sprayed by 1500～2500 times of dilutions, and to be respectively be 88.7%, 89.1%, 90.3%, 92.3%, 90.6%, 92.0%, 89.9%, 88.1%, 93.5% to 72 hours field control effects behind the medicine; Be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into wetting powder or be made into wetting powder or be made into wetting powder or be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into suspending agent or be made into suspending agent according to using with quadrat method with 30% benomyl list agent with 10% polyoxin list agent with 38% Tebuconazole list agent with 34% propiconazole list agent with 30% Difenoconazole list agent with 22% Tebuconazole list agent with 16% propiconazole list agent with 15% Difenoconazole list agent with 10% nitrile bacterium azoles list agent with 30% carbendazim list agent if adopt with 15% thiophanate-methyl list agent, 72 hours preventive effects are respectively 30.5% behind the medicine, 48.3%, 39.2%, 37.5%, 45.6%, 40.2%, 38.3%, 20.1%, used relatively with single agent by above-mentioned being mixed, be understood that its gained control efficiency differs 2～3 times.
Embodiment 3: spot defoliation.
Common process is made, press the Carbatene weight proportion (unless stated otherwise, all refer to percentage by weight) 45%, with with Different Weight proportioning thiophanate-methyl 30%, carbendazim 20%, nitrile bacterium azoles 30%, Difenoconazole 20%, in propiconazole 20%, Tebuconazole 6%, polyoxin 20%, the benomyl 15% with one or both or two or morely be mixed respectively, add wetting agent, dispersant and the filler of constant weight proportioning again, make water dispersible granules.All prescriptions all doubly dilute spraying by 2000-2500, and 72 hours field control effects are respectively 87.9%, 89.4%, 90.5%, 92.3%, 93.8%, 89.7%, 90.6%, 91.2% behind the medicine; Be made into the water dispersible granules agent or be made into water dispersible granules or be made into water dispersible granules or be made into water dispersible granules or be made into water dispersible granules or be made into the water dispersible granules agent or be made into water dispersible granules or be made into water dispersible granules according to using with quadrat method with 15% benomyl list agent with 20% polyoxin list agent with 6% Tebuconazole list agent with 20% propiconazole list agent with 20% Difenoconazole list agent with 30% nitrile bacterium azoles list agent with 20% carbendazim list agent if adopt with 20% methyl sulfur bacterium list agent, 72 hours preventive effects are respectively 20.8% behind the medicine, 19.7%, 30.5%, 32.3%, 20.7%, 32.8%, 29.7%, 12.5%, used relatively with single agent by above-mentioned being mixed, be understood that its gained control efficiency differs 2～3 times.
Additive described in above-described embodiment comprises wetting agent, dispersant and filler; Wherein wetting agent refers in sodium alkyl sulfate, alkylbenzenesulfonate, Fluhyzon formaldehyde condensation products, alkyl phenol polyether, fatty alcohol-polyoxyethylene ether, Tween-60, the Tween-80 any one or two or more combination; Dispersant refers in polycarboxylate, lignosulfonates, Fluhyzon formaldehyde condensation products, sulfite cellulose solid dry substance, the oxirane propylene oxide block copolymer any one or two or more combination; Filler refers to kaolin.Wetting agent: diffusant: filler=5%～7%: 8%～15%: 15%～20%.
Claims (3)
1. microbicide compositions that contains the active ingredient of Carbatene, it is characterized in that: active ingredient comprises Carbatene and own azoles alcohol, and the weight ratio of Carbatene and own azoles alcohol is 1: 1～1: 4.5.
2. a kind of microbicide compositions that contains the active ingredient of Carbatene according to claim 1, it is characterized in that: composition is made different application forms, and its application forms is selected from: suspending agent, water dispersible granules, wetting powder.
3. a kind of microbicide compositions that contains the active ingredient of Carbatene according to claim 1 is characterized in that: Carbatene and own azoles alcohol accumulation content by weight percentage are between 1% to 99%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110060151 CN102308820B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110060151 CN102308820B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100188627A Division CN101171921B (en) | 2007-10-15 | 2007-10-15 | Bactericide agent composition containing active ingredient of metiram |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102308820A CN102308820A (en) | 2012-01-11 |
| CN102308820B true CN102308820B (en) | 2013-10-09 |
Family
ID=45422690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110060151 Expired - Fee Related CN102308820B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing metiram active ingredient |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102308820B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4490222A (en) * | 1982-04-30 | 1984-12-25 | Imperial Chemical Industries Plc | Preparation of selected epoxides |
| WO2007093535A1 (en) * | 2006-02-14 | 2007-08-23 | Basf Se | A method of using a micronutrient as safener for a triazole for controlling harmful fungi |
| CN101171921A (en) * | 2007-10-15 | 2008-05-07 | 张少武 | Bactericide agent composition containing active ingredient of metiram |
-
2007
- 2007-10-15 CN CN 201110060151 patent/CN102308820B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4490222A (en) * | 1982-04-30 | 1984-12-25 | Imperial Chemical Industries Plc | Preparation of selected epoxides |
| WO2007093535A1 (en) * | 2006-02-14 | 2007-08-23 | Basf Se | A method of using a micronutrient as safener for a triazole for controlling harmful fungi |
| CN101171921A (en) * | 2007-10-15 | 2008-05-07 | 张少武 | Bactericide agent composition containing active ingredient of metiram |
Non-Patent Citations (1)
| Title |
|---|
| 权利要求1,2,6. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102308820A (en) | 2012-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101171921B (en) | Bactericide agent composition containing active ingredient of metiram | |
| CN101171919B (en) | Bactericide agent composition containing active ingredient of epoxiconazole | |
| CN104322558A (en) | Sterilization composition and applications thereof | |
| CN104222116B (en) | Containing the agricultural bactericidal composition of the gloomy copper of thiophene | |
| CN105191946A (en) | Sterilization composition and application thereof | |
| CN106234380A (en) | A kind of microbicide compositions | |
| CN105638683A (en) | Agricultural bactericidal composition with saisentong | |
| CN102308822B (en) | Bactericide composition containing active ingredients of metiram | |
| CN106259366A (en) | A kind of microbicide compositions | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102308821B (en) | Bactericide composition containing metiram active ingredient | |
| CN106259433A (en) | A kind of microbicide compositions | |
| CN102308820B (en) | Bactericide composition containing metiram active ingredient | |
| CN102308818B (en) | Germicide composition containing active ingredient of polyram | |
| CN103749472A (en) | Sterilization composition containing trifloxystrobin and cyproconazole and application thereof | |
| CN106577680A (en) | Bactericide and application thereof | |
| CN107027778A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and Tebuconazole | |
| CN102308819A (en) | Bactericide composition containing metiram active ingredient | |
| CN112514912A (en) | Bactericidal composition containing triphenyltin acetate and propiconazole and preparation method thereof | |
| CN102224821B (en) | Bactericide composition containing effective Epoxiconazole ingredients | |
| CN102204558A (en) | Bactericide composite containing epoxiconazole used as active ingredient | |
| CN107232213A (en) | Microbicide compositions containing anthraquinone analog compound and polyoxin | |
| CN107087609A (en) | Microbicide compositions containing anthraquinone analog compound and S-Ethyl ethylthio sulfonate | |
| CN107094774A (en) | Synergistic composition containing benzothiostrobin | |
| CN105941440A (en) | Sterilization composition containing Bixafen and zineb and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161228 Address after: 714000 Weinan Shaanxi city Pucheng County agricultural base industrial park Patentee after: Shaanxi Meibang Pesticides Co., Ltd. Address before: 715500 Pucheng City, Shaanxi province grain street, No. 23 Patentee before: Zhang Shaowu |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131009 Termination date: 20171015 |