CN101148369A - Glaze material with metal texture for ceramic, preparation method thereof and ceramic prepared from the same - Google Patents
Glaze material with metal texture for ceramic, preparation method thereof and ceramic prepared from the same Download PDFInfo
- Publication number
- CN101148369A CN101148369A CNA2006101222654A CN200610122265A CN101148369A CN 101148369 A CN101148369 A CN 101148369A CN A2006101222654 A CNA2006101222654 A CN A2006101222654A CN 200610122265 A CN200610122265 A CN 200610122265A CN 101148369 A CN101148369 A CN 101148369A
- Authority
- CN
- China
- Prior art keywords
- oxide
- glaze
- metal
- ceramic
- screen printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The present invention discloses one kind of ceramic glaze material with metal texture. The ceramic glaze material includes one kind of base metal facing glaze material of metal oxide mixture and one kind of covering printed glaze material. The ceramic product with the ceramic glaze has metal luster and metal texture as well as improved physical and chemical performances, and raised mechanical strength, abrasive strength and other mechanical performance, and is beautiful and durable. In addition, the ceramic glaze material has relatively simple preparation process and is suitable for industrial production. The present invention also discloses the preparation process of the ceramic glaze material and the ceramic product.
Description
Technical field
The present invention relates to pottery, glass enamel material technical field, refer to a kind of ceramic glaze especially with metal-like.
Background technology
Pottery be by clay or based on the mixture of clay, feldspar, quartz etc. through moulding, drying, fire the goods that form.Traditional pottery often has characteristics such as color and luster is low and deep, opaque, suction owing to do not do any surface treatment, and the color of pottery is subjected to the kind restriction of the metal ingredient in the mineral substance and limits to.For color that enriches pottery and the physical and chemical performance that improves pottery, people more and more pay attention to the research of bristol glaze.
For this reason, people develop various glaze with difference in functionality, as luminous class glaze, application number: 99123083, the applying date: on December 15th, 1999, denomination of invention: luminescent glaze, this light-accumulating luminescent glaze is made up of different kinds of ions activated long after glow luminous material and base solvent, luminescent ceramic, luminescent enamel and fluorescent glass goods with this luminescent glaze manufacturing have illumination effect, but lack metallic character and texture.
Therefore, demand providing a kind of glaze that is used to be coated on ceramic surface urgently,, and make it have certain metal-like with the mechanical property and the chemical stability on the surface of further enhancing ceramic.
Summary of the invention
Based on the deficiencies in the prior art, main purpose of the present invention has been to provide a kind of glaze that can further strengthen the physical and chemical performance of ceramic, makes it have the glaze of certain metal-like and characteristic.
A kind of ceramic glaze of the present invention with metal-like, it contains at least a metal oxide, is made up of underlying metal cover-coat enamel and covering screen printing glaze, and it comprises following component, and weight percent content is as follows:
| The underlying metal glaze | Cover screen printing glaze | ||
| Composition | Per-cent | Composition | Per-cent |
| Aluminum oxide (Al 2O 3) | 5-25％ | Aluminum oxide (Al 2O 3) | 5-25％ |
| Silicon oxide (SiO 2) | 10-45％ | Silicon oxide (SiO 2) | 10-45％ |
| Ferric oxide (Fe 2O 3) | 5-40％ | Cerium oxide (CeO) | 0-40％ |
| Calcium oxide (CaO) | 0-20％ | Calcium oxide (CaO) | 0-20％ |
| Magnesium oxide (MgO) | 0-10％ | Magnesium oxide (MgO) | 0-10％ |
| Potassium oxide (K 2O) | 0-5％ | Potassium oxide (K 2O) | 0-5％ |
| Sodium oxide (Na 2O) | 0-15％ | Sodium oxide (Na 2O) | 0-15％ |
| Titanium oxide (TiO) | 0-20％ | Titanium oxide (TiO) | 0-20％ |
| Zirconium white (ZrO 2) | 1-25％ | Zirconium white (ZrO 2) | 1-25％ |
| Vanadium Pentoxide in FLAKES (P 2O 5) | 0-40％ | Vanadium Pentoxide in FLAKES (P 2O 5) | 0-40％ |
| Plumbous oxide (PbO) | 0-25％ | Plumbous oxide (PbO) | 0-25％ |
A kind of manufacture method with ceramic glaze of metal-like may further comprise the steps:
(1) at first, choose suitable proportion raw material according to required color;
(2) secondly, adopt micro mist equipment respectively above-mentioned raw materials to be carried out grinding and processing, the size of the pellet after the control processing is no more than 400 orders;
(3) the various raw materials after will pulverizing are according to should needing the proportioning uniform mixing and carry out siccative and handle, and the siccative process is controlled at 1000-1250 ℃ with temperature range;
(4) last, put it into ball mill and add water and grind and make the underlying metal glaze respectively and cover screen printing glaze, the size range of control glaze grain is 0.8-1g/325 eye mesh screen/100ml, and proportion is 1.25-1.5g/ml, and glazing heavily is 90-260g/60 * 60cm
2
In step (4), the Xylo-Mucine (CMC) that also can add 0.5-1% carries out ball milling, to increase the viscosity of glaze.
Compared with prior art, ceramic glaze of the present invention sprayed on the work in-process of pottery, fire the ceramic that forms again, because this kind glaze contains various metal oxides, make the ceramic product that is prepared from not only present various metallic luster, the surface has certain metal-like, and, improved its physical and chemical performance greatly, mechanical propertys such as physical strength and fastness to rubbing have been improved, make product not only attractive in appearance but also durable in use, fill up the blank of ceramic decoration field metal glaze, promoted the development of the ceramic of colorful metal glaze.In addition, comparatively simple on the preparation technology of glaze and glazing process, easy control of process conditions is fit to large-scale technology production.
For making the present invention easier to understand, further set forth a kind of specific embodiment of the present invention with ceramic glaze of metal-like below in conjunction with accompanying drawing.
Embodiment
Below further set forth a kind of prescription of the present invention with ceramic glaze of metal-like.
Glaze of the present invention is by the underlying metal cover-coat enamel and cover screen printing glaze and forms, its be mineral substance by containing various metal ingredients such as phosphorus, calcium, strontium, zinc, lead as raw material, or the following compound of employing carries out mixing match according to different deals and makes respectively.According to the underlying metal cover-coat enamel of allotment with cover the different of metal content in the screen printing glaze, present different metallic luster, as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc., can trace adding 1% chromic oxide (Cr).Following table illustrates the underlying metal cover-coat enamel when presenting the different metal color and luster by several embodiment and covers the different proportionings of screen printing glaze.
| Underlying metal glaze (weight ratio) | ||||
| Embodiment one | Embodiment two | Embodiment three | Embodiment four | |
| Aluminum oxide (Al 2O 3) | 5 | 7 | 23 | 10 |
| Silicon oxide (SiO 2) | 12 | 10 | 29 | 8 |
| Ferric oxide (Fe 2O 3) | 5 | 10 | 8 | 40 |
| Calcium oxide (CaO) | 13 | 20 | 2 | 6 |
| Magnesium oxide (MgO) | 6 | 10 | 1 | 5 |
| Potassium oxide (K 2O) | 3 | 5 | 1 | 2 |
| Sodium oxide (Na 2O) | 10 | 9 | 3 | 6 |
| Titanium oxide (TiO) | 12 | 10 | 4 | 2 |
| Zirconium white (ZrO 2) | 4 | 6 | 8 | 15 |
| Vanadium Pentoxide in FLAKES (P 2O 5) | 18 | 8 | 5 | 2 |
| Plumbous oxide (PbO) | 12 | 5 | 16 | 4 |
| Cover screen printing glaze (weight ratio) | ||||
| Aluminum oxide (Al 2O 3) | 5 | 15 | 25 | 8 |
| Silicon oxide (SiO 2) | 20 | 10 | 11 | 15 |
| Cerium oxide (CeO) | 15 | 4 | 5 | 8 |
| Calcium oxide (CaO) | 3 | 20 | 8 | 10 |
| Magnesium oxide (MgO) | 4 | 2 | 2 | 8 |
| Potassium oxide (K 20) | 5 | 1 | 2 | 2 |
| Sodium oxide (Na 2O) | 8 | 15 | 1 | 3 |
| Titanium oxide (TiO) | 16 | 4 | 1 | 20 |
| Zirconium white (ZrO 2) | 4 | 20 | 3 | 3 |
| Vanadium Pentoxide in FLAKES (P 2O 5) | 8 | 3 | 40 | 15 |
| Plumbous oxide (PbO) | 12 | 6 | 2 | 8 |
Below sketch a kind of manufacture method of the present invention with ceramic glaze of metal-like:
(1) at first, choose suitable proportion raw material according to required color;
(2) secondly, adopt micro mist equipment respectively above-mentioned raw materials to be carried out grinding and processing, the size of the pellet after the control processing is no more than 400 orders;
(3) the various raw materials after will pulverizing are according to should needing the proportioning uniform mixing and carry out siccative and handle, and the siccative process is controlled at 1000-1250 ℃ with temperature range;
(4) last, put it into ball mill and add water and grind and make the underlying metal glaze respectively and cover screen printing glaze, the size range of control glaze grain is 0.8-1g/325 eye mesh screen/100ml, and proportion is 1.25-1.5g/ml, and glazing heavily is 90-260g/60 * 60cm
2
In step (4), the Xylo-Mucine (CMC) that also can add 0.5-1% carries out ball milling, to increase the viscosity of glaze.
During use, underlying metal cover-coat enamel and the covering screen printing glaze of making successively sprayed on the surface of ceramic semi-finished product equably, after vegetarian noodles or printing treatment, directly advance klining and become to get final product.
The not only color variation of ceramic after the glazing, glaze quality is good, and mechanical property and chemical stability are all had been further upgraded, and general glaze fastness to rubbing is greater than 2.5cc, if after adding wear-resisting ceramic glaze printing, fastness to rubbing can be promoted to more than the 3.5cc, has improved the mechanical property of ceramic greatly, meets the paving requirement in popular place, simultaneously, the acid and alkali-resistance degree also reaches the A grade standard after testing, and the corrosion resistance excellence is suitable for the laying of exterior wall.
Five colours metal glaze only need be sprayed onto the ornamental brick surface through burning till with the glaze spraying cabinet, just can obtain glistening metal effect, just as glistening sandy beach under the setting sun, be sprayed on brick face modelled after an antique, just like placing oneself in the midst of among the nature, true to nature, naturally reach back to nature, return Piao and return genuine effect, and every tile only needs a little to get final product, and because of it is series product, can only use on brick modelled after an antique in the past, use on can changeing in micro mist, polishing now, changeing on exterior wall, square again, have wide range of applications.
Above disclosed only is a kind of preferred embodiment with ceramic glaze of metal-like of the present invention, certainly can not limit the present invention's interest field with this, therefore the equivalent variations of being done according to the present patent application claim still belongs to the scope that the present invention is contained.
Claims (4)
1. ceramic glaze with metal-like is characterized in that: contain at least a metal oxide, it is by the underlying metal cover-coat enamel and cover screen printing glaze and form, and comprises following component, and weight percent content is as follows:
2. manufacturing as claimed in claim 1 has the manufacture method of the ceramic glaze of metal-like, it is characterized in that may further comprise the steps:
(1) at first, choose suitable proportion raw material according to required color;
(2) secondly, adopt micro mist equipment respectively above-mentioned raw materials to be carried out grinding and processing, the size of the pellet after the control processing is no more than 400 orders;
(3) the various raw materials after will pulverizing are according to should needing the proportioning uniform mixing and carry out siccative and handle, and the siccative process is controlled at 1000-1250 ℃ with temperature range;
(4) last, put it into ball mill and add water and grind and make the underlying metal glaze respectively and cover screen printing glaze, the size range of control glaze grain is 0.8-1g/325 eye mesh screen/100ml, and proportion is 1.25-1.5g/ml, and glazing heavily is 90-260g/60 * 60cm
2
3. the manufacture method with ceramic glaze of metal-like as claimed in claim 2 is characterized in that: in step (4), the Xylo-Mucine (CMC) that also can add 0.5-1% carries out ball milling, to increase the viscosity of glaze.
4. pottery with ceramic glaze preparation with metal-like; it is characterized in that: described ceramic surface is coated with the protective layer that contains metal oxide; this protective layer comprises underlying metal cover-coat enamel and covering screen printing glaze, and it comprises following component, and weight percent content is as follows:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101222654A CN101148369B (en) | 2006-09-20 | 2006-09-20 | Glaze material with metal texture for ceramic and ceramic prepared from the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101222654A CN101148369B (en) | 2006-09-20 | 2006-09-20 | Glaze material with metal texture for ceramic and ceramic prepared from the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101148369A true CN101148369A (en) | 2008-03-26 |
| CN101148369B CN101148369B (en) | 2010-06-23 |
Family
ID=39249084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006101222654A Expired - Fee Related CN101148369B (en) | 2006-09-20 | 2006-09-20 | Glaze material with metal texture for ceramic and ceramic prepared from the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101148369B (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515859A (en) * | 2011-12-14 | 2012-06-27 | 广东四通集团股份有限公司 | Formula of sanitary ceramic glaze |
| CN102515860A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | High-luster daily ceramic glaze and preparation method thereof |
| CN102731151A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Leadless color ceramic glaze |
| CN102731150A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with good oil rub resistance |
| CN102731161A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Assistant agent for improving weather resistance of glaze surface |
| CN102731165A (en) * | 2012-06-27 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Lead-free blue glaze for preparing ceramic |
| CN102731160A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with characteristic of unease breaking during cutting |
| CN103910539A (en) * | 2014-04-04 | 2014-07-09 | 辉煌水暖集团有限公司 | Ceramic metal glaze |
| CN105440796A (en) * | 2015-12-10 | 2016-03-30 | 广东道氏技术股份有限公司 | Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof |
| CN106348606A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Red water-soluble Jun porcelain glaze material and preparation method thereof |
| CN106348607A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Black water-soluble Jun porcelain glaze material |
| CN106477884A (en) * | 2016-09-20 | 2017-03-08 | 崔松伟 | A kind of rust red glaze and preparation method thereof |
| CN106517778A (en) * | 2016-09-20 | 2017-03-22 | 崔松伟 | Green glaze and preparation method thereof |
| CN107555795A (en) * | 2017-10-13 | 2018-01-09 | 沈阳建筑大学 | A kind of cobalt oxide high temperature purple ceramic glaze and preparation method thereof |
| CN109390112A (en) * | 2018-11-19 | 2019-02-26 | 醴陵市东方电瓷电器有限公司 | A kind of coloured glaze is for needle type ceramic insulators and preparation method thereof |
| CN109534801A (en) * | 2018-11-12 | 2019-03-29 | 苏州工业园区职业技术学院 | A kind of ceramic metal ornament materials |
| CN110357429A (en) * | 2019-08-09 | 2019-10-22 | 信益陶瓷(中国)有限公司 | A kind of metal-like Imitation Rock Porcelain Tiles and preparation method thereof |
| CN110484027A (en) * | 2019-06-27 | 2019-11-22 | 浙江大学 | It is a kind of for improving the active inorganic corrosion-inhibiting coating and its coating method of adhesion strength between reinforcing bar and concrete |
| CN114213008A (en) * | 2021-12-16 | 2022-03-22 | 新明珠集团股份有限公司 | Ceramic metal glaze powder, metal glaze and metal glazed tile |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU910544A1 (en) * | 1980-08-11 | 1982-03-07 | Грузинский Ордена Ленина И Ордена Трудового Красного Знамени Политехнический Институт Им. В.И.Ленина | Glazing composition |
| ES2161193B1 (en) * | 2000-03-30 | 2002-06-16 | Vidres S A Vidresa | FORMULATION AND PROCEDURE FOR OBTAINING METAL EFFECTS IN CERAMIC TILES AND THEIR APPLICATIONS. |
| CN1765836B (en) * | 2005-09-07 | 2010-05-12 | 毛海燕 | Ceramic glaze with metal sense of reality |
-
2006
- 2006-09-20 CN CN2006101222654A patent/CN101148369B/en not_active Expired - Fee Related
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515859A (en) * | 2011-12-14 | 2012-06-27 | 广东四通集团股份有限公司 | Formula of sanitary ceramic glaze |
| CN102515860A (en) * | 2011-12-14 | 2012-06-27 | 广东松发陶瓷股份有限公司 | High-luster daily ceramic glaze and preparation method thereof |
| CN102515860B (en) * | 2011-12-14 | 2014-03-19 | 广东松发陶瓷股份有限公司 | High-luster daily ceramic glaze and preparation method thereof |
| CN102731151A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Leadless color ceramic glaze |
| CN102731150A (en) * | 2012-06-14 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with good oil rub resistance |
| CN102731161A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Assistant agent for improving weather resistance of glaze surface |
| CN102731160A (en) * | 2012-06-19 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Ceramic glaze with characteristic of unease breaking during cutting |
| CN102731165A (en) * | 2012-06-27 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Lead-free blue glaze for preparing ceramic |
| CN103910539A (en) * | 2014-04-04 | 2014-07-09 | 辉煌水暖集团有限公司 | Ceramic metal glaze |
| CN105440796A (en) * | 2015-12-10 | 2016-03-30 | 广东道氏技术股份有限公司 | Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof |
| CN106348606A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Red water-soluble Jun porcelain glaze material and preparation method thereof |
| CN106348607A (en) * | 2016-09-20 | 2017-01-25 | 崔松伟 | Black water-soluble Jun porcelain glaze material |
| CN106477884A (en) * | 2016-09-20 | 2017-03-08 | 崔松伟 | A kind of rust red glaze and preparation method thereof |
| CN106517778A (en) * | 2016-09-20 | 2017-03-22 | 崔松伟 | Green glaze and preparation method thereof |
| CN107555795A (en) * | 2017-10-13 | 2018-01-09 | 沈阳建筑大学 | A kind of cobalt oxide high temperature purple ceramic glaze and preparation method thereof |
| CN109534801A (en) * | 2018-11-12 | 2019-03-29 | 苏州工业园区职业技术学院 | A kind of ceramic metal ornament materials |
| CN109390112A (en) * | 2018-11-19 | 2019-02-26 | 醴陵市东方电瓷电器有限公司 | A kind of coloured glaze is for needle type ceramic insulators and preparation method thereof |
| CN110484027A (en) * | 2019-06-27 | 2019-11-22 | 浙江大学 | It is a kind of for improving the active inorganic corrosion-inhibiting coating and its coating method of adhesion strength between reinforcing bar and concrete |
| CN110357429A (en) * | 2019-08-09 | 2019-10-22 | 信益陶瓷(中国)有限公司 | A kind of metal-like Imitation Rock Porcelain Tiles and preparation method thereof |
| CN114213008A (en) * | 2021-12-16 | 2022-03-22 | 新明珠集团股份有限公司 | Ceramic metal glaze powder, metal glaze and metal glazed tile |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101148369B (en) | 2010-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101148369A (en) | Glaze material with metal texture for ceramic, preparation method thereof and ceramic prepared from the same | |
| CN101786904B (en) | Color-changing glaze for metallic luster ceramics and preparation method thereof | |
| CN1765836B (en) | Ceramic glaze with metal sense of reality | |
| CN102515875B (en) | Full polished glaze porcelain tile capable of self-exciting to produce negative ions, and preparation method for full polished glaze porcelain tile | |
| CN110357668A (en) | A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments | |
| CN107759090B (en) | Glaze material with effect of imitating black gold sand marble and application thereof | |
| CN105884197A (en) | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze | |
| CN101786795A (en) | Enamel glaze and preparation process thereof | |
| CN103693994A (en) | Color-changing glaze tile and production method thereof | |
| CN103332968B (en) | Full-polishing glaze production process and prepared product | |
| CN103964900A (en) | formula and preparation method of Sky blue transmutation glaze | |
| CN106699146A (en) | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof | |
| CN110981553B (en) | Transparent amber-like ceramic tile and preparation method thereof | |
| CN102515864B (en) | Gold crystal glaze domestic ceramic glaze material | |
| CN103833420A (en) | Manufacturing method of antique black colored glaze and formula thereof | |
| CN108484123A (en) | A kind of Ceramic Tiles and preparation method thereof of high additive metallurgical steel slag waste material | |
| CN103224331B (en) | Frit dry granules with characteristics of one-time sintering and golden brown color, and preparation method thereof | |
| CN115448598A (en) | Dry particle protective glaze, soft marble tile and preparation method thereof | |
| CN100528812C (en) | Method for formulating moderate temperature bright red glaze | |
| CN110845252B (en) | Special blank large-particle combined digital cloth archaized brick and preparation method thereof | |
| CN105218162B (en) | A kind of ceramet glaze and preparation method thereof | |
| CN103183528B (en) | Shaping glaze and firing technology of bone china containing high-permeability pigment | |
| CN1583658A (en) | Underglazed color porcelain and its production | |
| CN101591962A (en) | Fambe glaze-polished brick and production method thereof | |
| CN105254275A (en) | Ge kiln porcelain formula and manufacturing process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Foshan Mingzhao Technology Development Co., Ltd. Assignor: Mao Haiyan Contract record no.: 2011440000562 Denomination of invention: Glaze material with metal texture for ceramic and ceramic prepared from the same Granted publication date: 20100623 License type: Common License Open date: 20080326 Record date: 20110628 |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100623 Termination date: 20130920 |