CN105440796A - Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof - Google Patents
Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof Download PDFInfo
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- CN105440796A CN105440796A CN201510920292.5A CN201510920292A CN105440796A CN 105440796 A CN105440796 A CN 105440796A CN 201510920292 A CN201510920292 A CN 201510920292A CN 105440796 A CN105440796 A CN 105440796A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a low-temperature metal glaze printing ink for ink-jet printing of ceramics and a preparation method thereof. The printing ink comprises, by mass, 40 to 60% of metal glaze, 1 to 3% of resin and 2 to 4% of a dispersant, with the balance being a solvent, wherein the metal glaze comprises the following raw materials: SiO2, Al2O3, Na2O, CaO, Fe2O3 and P2O5. The metal glaze printing ink prepared in the invention has low viscosity and a uniformly-distributed particle size; the preparation method is simple and highly efficient; and the prepared printing ink has good quality stability, can be stored for a long time and shows good ink-jet printing performance. The low-temperature metal glaze printing ink for ink-jet printing of ceramics successfully realizes nationalization of novel low-temperature metal glaze in China, fills a gap in development and production of low-temperature metal glaze printing ink in China, changes the situation that imported glaze products of a same kind dominate the market and substantially reduces production cost of building ceramic enterprises.
Description
Technical field
The invention belongs to ceramic ink jet technical field, relate to a kind of low-temp ceramics spray ink Printing metal glaze ink and preparation method thereof.
Background technology
Metal glaze is the special artistic glaze of one in china industry glaze, mainly imposes on Antique Imitation Tiles ceramic tile, can not only produce appearance effect graceful, magnificent as metal, and can strengthen the chemical stability of Ceramic glaze and the tolerance to soda acid.Metal enamelled bricks was once the leading product of domestic market, and each Ceramics Enterprises is fallen over each other to release metal enamelled bricks product and seized market.The domestic sintering temperature being applicable to the metal glaze ink of building ceramic tiles is higher at present, Chinese invention patent application number is 201310119276.7 disclose a kind of ceramic ink jet printing metal glaze ink and preparation method thereof, is also the jetted ink prepared based on metal glaze.In the metal glaze ink preparation related in this patent, its metal glaze is in 800 ~ 1100 DEG C of sintering.And rarely found in the preparation of metal glaze ink of lower temperature sintering, up to the present domesticly also not appear in the newspapers.
Summary of the invention
For deficiency existing in prior art, the object of the present invention is to provide a kind of low-temp ceramics spray ink Printing metal glaze ink and preparation method thereof.
The technical solution used in the present invention is:
A kind of low-temp ceramics spray ink Printing metal glaze ink, the component containing, for example lower mass percent: metal glaze 40 ~ 60%, resin 1 ~ 3%, dispersion agent 2 ~ 4%, surplus is solvent;
Described metal glaze, its raw material is containing, for example lower content of component: SiO
27 ~ 15 parts, Al
2o
30 ~ 3 part, Na
2o30 ~ 40 part, CaO0 ~ 3 part, Fe
2o
320 ~ 30 parts, P
2o
527 ~ 35 parts.
As preferably, described resin comprises at least one in Synolac, acrylic resin.
As preferably, described dispersion agent is high molecular polyurethane-type dispersion agent.
As preferably, described solvent comprises at least one in diethylene glycol dimethyl ether, ethylene glycol ether acetate, 1-Methoxy-2-propyl acetate.
As preferably: the preparation method of described metal glaze is: weighed by proportioning by each feed composition, in 600 ~ 700 DEG C of sintering after mixing, pulverizing is also levigate to 250 ~ 400 orders afterwards.
The preparation method of above-described spray ink Printing metal glaze ink, comprises the following steps:
1) resin, dispersion agent, metal glaze and partial solvent are mixed, be uniformly dispersed, make glaze fully wetting;
2) ground by scattered material, the median size controlling metal glaze is 200 ~ 400nm, and maximum particle diameter is less than 1 μm, obtains metal glaze slip;
3) in metal glaze slip, add solvent, filter, obtain spray ink Printing metal glaze ink.
The invention has the beneficial effects as follows:
A kind of low-temp ceramics spray ink Printing metal glaze ink quality stability of the present invention is good, can preserve for a long time, and there is good Ink Jet Printing Performance, and the viscosity of metal glaze ink is low, even particle size distribution, the viscosity of metal glaze ink is between 15.0 ~ 30.0mPas and controllable, and surface tension is 20 ~ 30mN/m, median size is 250 ~ 400nm, and maximum particle diameter is less than 1 μm.The preparation method of a kind of low-temp ceramics spray ink Printing metal glaze ink of the present invention, simply efficient, through a single metal glaze slip process of lapping and metal glaze ink performance regulate process, greatly save production cost.
Accompanying drawing explanation
Fig. 1 is the product photo after the low-temp ceramics spray ink Printing metal glaze ink of embodiment 2 preparation burns till;
Fig. 2 is the product photo after the low-temp ceramics spray ink Printing metal glaze ink of embodiment 4 preparation burns till.
Embodiment
A kind of low-temp ceramics spray ink Printing metal glaze ink, the component containing, for example lower mass percent: metal glaze 40 ~ 60%, resin 1 ~ 3%, dispersion agent 2 ~ 4%, surplus is solvent;
Described metal glaze, its raw material is containing, for example lower content of component: SiO
27 ~ 15 parts, Al
2o
30 ~ 3 part, Na
2o30 ~ 40 part, CaO0 ~ 3 part, Fe
2o
320 ~ 30 parts, P
2o
527 ~ 35 parts.
As preferably, described resin comprises at least one in Synolac, acrylic resin.
As preferably, described dispersion agent is high molecular polyurethane-type dispersion agent.
As preferably, described solvent comprises at least one in diethylene glycol dimethyl ether, ethylene glycol ether acetate, 1-Methoxy-2-propyl acetate.
As preferably: the preparation method of described metal glaze is: weighed by proportioning by each feed composition, in 600 ~ 700 DEG C of sintering after mixing, pulverizing is also levigate to 250 ~ 400 orders afterwards.
The preparation method of above-described spray ink Printing metal glaze ink, comprises the following steps:
1) resin, dispersion agent, metal glaze and partial solvent are mixed, be uniformly dispersed, make glaze fully wetting;
2) ground by scattered material, the median size controlling metal glaze is 200 ~ 400nm, and maximum particle diameter is less than 1 μm, obtains metal glaze slip;
3) in metal glaze slip, add solvent, filter, obtain spray ink Printing metal glaze ink.
Below in conjunction with embodiment, the present invention is further illustrated, but be not limited thereto.
embodiment 1
A kind of low-temp ceramics spray ink Printing metal glaze ink, by mass percentage, composed of the following components: metal glaze 40%, resin 1%, dispersion agent 3%, surplus is solvent.
Wherein, metal glaze, its raw material is made up of following content of component: SiO
27 parts, Al
2o
32 parts, Na
2o35 part, CaO1 part, Fe
2o
325 parts, P
2o
527 parts; Its preparation method, comprises the following steps: weighed by proportioning by each feed composition, and in 650 DEG C of sintering 0.5h after mixing, pulverizing is afterwards also levigate to 200 ~ 400 orders, obtains metal glaze.
embodiment 2
A kind of low-temp ceramics spray ink Printing metal glaze ink, by mass percentage, composed of the following components: metal glaze 45%, resin 2%, dispersion agent 3%, surplus is solvent.
Wherein, metal glaze, its raw material is made up of the component of following mass parts: SiO
210 parts, Al
2o
32 parts, Na
2o30 part, CaO1 part, Fe
2o
327 parts, P
2o
529 parts; Its preparation method, comprises the following steps: weighed by proportioning by each feed composition, and in 700 DEG C of sintering 0.5h after mixing, pulverizing is afterwards also levigate to 200 ~ 400 orders, obtains metal glaze.
embodiment 3
A kind of low-temp ceramics spray ink Printing metal glaze ink, by mass percentage, composed of the following components: metal glaze 50%, resin 3%, dispersion agent 2%, surplus is solvent.
Wherein, metal glaze, its raw material is made up of following content of component: SiO
215 parts, Na
2o40 part, CaO2 part, Fe
2o
330 parts, P
2o
535 parts; Its preparation method, comprises the following steps: weighed by proportioning by each feed composition, and in 600 DEG C of sintering 0.5h after mixing, pulverizing is afterwards also levigate to 200 ~ 400 orders, obtains metal glaze.
embodiment 4
A kind of low-temp ceramics spray ink Printing metal glaze ink, by mass percentage, composed of the following components: metal glaze 56%, resin 1%, dispersion agent 4%, surplus is solvent.
Wherein, metal glaze, its raw material is made up of following content of component: SiO
212%, Al
2o
32%, Na
2o37 part, Fe
2o
320 parts, P
2o
532 parts; Its preparation method, comprises the following steps: weighed by proportioning by each feed composition, and in 670 DEG C of sintering 0.5h after mixing, pulverizing is afterwards also levigate to 200 ~ 400 orders, obtains metal glaze.
embodiment 5
A kind of low-temp ceramics spray ink Printing metal glaze ink, by mass percentage, composed of the following components: metal glaze 60%, resin 1%, dispersion agent 3%, surplus is solvent.
Wherein, metal glaze, its raw material is made up of following content of component: SiO
215%, Na
2o40 part, CaO3 part, Fe
2o
320 parts, P
2o
533 parts; Its preparation method, comprises the following steps: weighed by proportioning by each feed composition, and in 630 DEG C of sintering 0.5h after mixing, pulverizing is afterwards also levigate to 200 ~ 400 orders, obtains metal glaze.
The preparation method of a kind of low-temp ceramics spray ink Printing metal glaze ink of above embodiment, comprises the steps: that partial solvent, resin, dispersion agent, metal glaze carry out pre-dispersed through high speed dispersor by (1), metal glaze is fully soaked; (2) be transferred in shredder by pre-dispersed good material and carry out grinding 1.5 ~ 3.5h, make the median size of metal glaze be 250 ~ 400nm, maximum particle diameter is less than 1 μm, obtains metal glaze slip; (3) in metal glaze slip, add residual solvent, with 1 micron of filter element filtering, obtain ceramic ink jet printing metal glaze ink.
Ceramic ink jet printing metal glaze ink prepared by embodiment 1 ~ 5 is carried out performance test, and test result is in table 1.
The performance test results of ceramic ink jet printing metal glaze ink prepared by table 1 embodiment 1 ~ 5
Ink viscosity prepared by the embodiment of the present invention 1 ~ 5 is 15.0 ~ 30.0mPas, surface tension at 20 ~ 30mN/m, even particle size distribution, median size is between 250 ~ 400nm, maximum particle diameter is less than 1 μm, and good stability, has the smooth performance of good spray ink Printing.Do not occur the phenomenons such as broken string, streak, can not wear and tear and block shower nozzle, the pattern in detail of printing is clear.
Claims (6)
1. a low-temp ceramics spray ink Printing metal glaze ink, the component containing, for example lower mass percent: metal glaze 40 ~ 60%, resin 1 ~ 3%, dispersion agent 2 ~ 4%, surplus is solvent;
Described metal glaze, its raw material is containing, for example lower content of component: SiO
27 ~ 15 parts, Al
2o
30 ~ 3 part, Na
2o30 ~ 40 part, CaO0 ~ 3 part, Fe
2o
320 ~ 30 parts, P
2o
527 ~ 35 parts.
2. low-temp ceramics spray ink Printing metal glaze ink according to claim 1, it is characterized in that, described resin comprises at least one in Synolac, acrylic resin.
3. low-temp ceramics spray ink Printing metal glaze ink according to claim 1, is characterized in that, described dispersion agent is high molecular polyurethane-type dispersion agent.
4. low-temp ceramics spray ink Printing metal glaze ink according to claim 1, it is characterized in that, described solvent comprises at least one in diethylene glycol dimethyl ether, ethylene glycol ether acetate, 1-Methoxy-2-propyl acetate.
5. the metal glaze ink of the spray ink Printing according to any one of Claims 1 to 4, it is characterized in that: the preparation method of described metal glaze is: weighed by proportioning by each feed composition, in 600 ~ 700 DEG C of sintering after mixing, pulverizing is afterwards also levigate to 250 ~ 400 orders.
6. the preparation method of metal glaze ink of the spray ink Printing described in any one of Claims 1 to 5, comprises the following steps:
1) resin, dispersion agent, metal glaze and partial solvent are mixed, be uniformly dispersed, make glaze fully wetting;
2) ground by scattered material, the median size controlling metal glaze is 200 ~ 400nm, and maximum particle diameter is less than 1 μm, obtains metal glaze slip;
3) in metal glaze slip, add solvent, filter, obtain spray ink Printing metal glaze ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510920292.5A CN105440796A (en) | 2015-12-10 | 2015-12-10 | Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510920292.5A CN105440796A (en) | 2015-12-10 | 2015-12-10 | Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof |
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|---|---|
| CN105440796A true CN105440796A (en) | 2016-03-30 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473592A (en) * | 2017-08-18 | 2017-12-15 | 佛山市石湾裕龙陶瓷有限公司 | A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof |
| CN114163872A (en) * | 2022-01-14 | 2022-03-11 | 英辉（大厂）自动化技术有限公司 | Low-viscosity automobile glass printing ink and preparation method thereof |
| CN115893843A (en) * | 2022-10-26 | 2023-04-04 | 山东国瓷康立泰新材料科技有限公司 | Silver-white metal ink for ceramic ink-jet printing and preparation method and application thereof |
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| CN1765836A (en) * | 2005-09-07 | 2006-05-03 | 毛海燕 | Ceramic glaze with metal sense of reality |
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| CN101148369A (en) * | 2006-09-20 | 2008-03-26 | 毛海燕 | Glaze material with metal texture for ceramic, preparation method thereof and ceramic prepared from the same |
| CN101244949A (en) * | 2008-03-27 | 2008-08-20 | 湖南华联瓷业有限公司 | Method for manufacturing middle-temperature metal glaze and glaze material thereof |
| CN101314549A (en) * | 2007-05-29 | 2008-12-03 | 卡塔罗尼安-阿拉贡斯矿业公司 | Metallic glaze composition |
| CN102964920A (en) * | 2012-11-27 | 2013-03-13 | 广东道氏技术股份有限公司 | Ink for ceramic ink-jet printing and method for preparing same |
| CN103224724A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Metal glaze printing ink for ceramic ink-jet printing and preparation method thereof |
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2015
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Patent Citations (8)
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| CN1765836A (en) * | 2005-09-07 | 2006-05-03 | 毛海燕 | Ceramic glaze with metal sense of reality |
| CN1907907A (en) * | 2006-08-17 | 2007-02-07 | 钟旭东 | Method of producing archaistic brick by low-temperature sintering |
| CN101148369A (en) * | 2006-09-20 | 2008-03-26 | 毛海燕 | Glaze material with metal texture for ceramic, preparation method thereof and ceramic prepared from the same |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107473592A (en) * | 2017-08-18 | 2017-12-15 | 佛山市石湾裕龙陶瓷有限公司 | A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof |
| CN114163872A (en) * | 2022-01-14 | 2022-03-11 | 英辉（大厂）自动化技术有限公司 | Low-viscosity automobile glass printing ink and preparation method thereof |
| CN115893843A (en) * | 2022-10-26 | 2023-04-04 | 山东国瓷康立泰新材料科技有限公司 | Silver-white metal ink for ceramic ink-jet printing and preparation method and application thereof |
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Application publication date: 20160330 |
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