CN107473592A - A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof - Google Patents

A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof Download PDF

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Publication number
CN107473592A
CN107473592A CN201710714236.5A CN201710714236A CN107473592A CN 107473592 A CN107473592 A CN 107473592A CN 201710714236 A CN201710714236 A CN 201710714236A CN 107473592 A CN107473592 A CN 107473592A
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CN
China
Prior art keywords
parts
jet printing
ink jet
glaze
raw material
Prior art date
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Pending
Application number
CN201710714236.5A
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Chinese (zh)
Inventor
梁裕恩
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Foshan Shiwan Yulong Ceramic Co Ltd
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Foshan Shiwan Yulong Ceramic Co Ltd
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Priority to CN201710714236.5A priority Critical patent/CN107473592A/en
Publication of CN107473592A publication Critical patent/CN107473592A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cosmetics (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof, wherein, raw material component meter, including following components by weight:38 52 parts of feldspar powder, 14 20 parts of calcite, 8 15 parts of talcum powder, 38 parts of quartz, 10 20 parts of glass dust, 11 18 parts of titanium dioxide, 0.1 0.5 parts of cobalt oxide, 0.1 1 parts of methylcellulose, 0.2 0.8 parts of sodium tripolyphosphate, 28 parts of hyper-dispersant, 50 80 parts of cyan, 25 parts of brown ink, cream-coloured 8 12 parts of chromatic ink, 49 parts of black ink.Its preparation method comprises the following steps:Each raw material is added in ball mill by number, adds solvent, the water that quality is 0.6 0.9 times of raw material gross mass is added and carries out ball milling, the fineness to glaze slip is 300 550 mesh, and glaze is made.The present invention is used for stability height during ceramic ink jet printing, and hair color effect is fabulous, has great promotional value.

Description

A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof
Technical field
The present invention relates to ceramic glaze technical field, more particularly to a kind of ceramic ink jet printing furnace transmutation glaze and its preparation side Method.
Background technology
Ceramic decoration is to mix glaze with multi-color ink with inkjet printing, by mixing ink droplet with the speed of thousands of drops per second Spray, it is directly printed on ceramic surface by way of inkjet printing, burns till the trailing of rear colour generation.With it is existing Ceramic decoration means are compared, and have breakthrough advantage:First, raw material is almost lossless, greatly reduces the pollution to environment, symbol Close the theme of green economy.2nd, using computer resource, exploitation and the production efficiency of new product are improved, while is also favorably made Make complex figure, such as imitative bark, imitation wood line, high-grade stone effect.
But in the prior art, the cost of glaze component is higher, and hair color effect is bad, and stability is low, causes obtained pottery Porcelain is second-rate.
Therefore, prior art has yet to be improved and developed.
The content of the invention
In view of above-mentioned the deficiencies in the prior art, a kind of ceramic ink jet printing furnace transmutation glaze and its preparation side are provided in of the invention Method, it is intended to solve using the low technical problem of ceramic tile hair color effect difference made from traditional glaze and stability.
Technical scheme is as follows:
A kind of ceramic ink jet printing furnace transmutation glaze, wherein, raw material component meter, including following components by weight:Feldspar powder 38- 52 parts, calcite 14-20 parts, talcum powder 8-15 parts, quartzy 3-8 parts, glass dust 10-20 parts, titanium dioxide 11-18 parts, cobalt oxide 0.1-0.5 parts, methylcellulose 0.1-1 parts, sodium tripolyphosphate 0.2-0.8 parts, hyper-dispersant 2-8 parts, cyan 50-80 Part, brown ink 2-5 parts, cream-coloured chromatic ink 8-12 parts, black ink 4-9 parts.
It was verified that the titanium dioxide added in material component of the present invention, cobalt oxide and methylcellulose, coordinate other former Expect the effect of component, can be greatly improved the retention of color of glaze during for ceramic ink jet printing, hair color effect might as well, The buying cost of raw material is low, and operating method is simple and convenient, greatly reduces production cost, improves the matter of inkjet printing ceramics Amount.
Described ceramic ink jet printing furnace transmutation glaze, wherein, 10-17 part solvents are also included in raw material.
The solvent added in the present invention is advantageous to accelerate the dissolving of each raw material components to combine, and mixes color inks and colouring agent Close the stability for uniformly, further improving glaze color.
Described ceramic ink jet printing furnace transmutation glaze, wherein, the solvent be in ether solvent or esters solvent at least It is a kind of.
Described ceramic ink jet printing furnace transmutation glaze, wherein, the hyper-dispersant is polyester type ultra-dispersant agent, polyether-type surpasses Any one or more in dispersant and poly- propionic acid type hyper-dispersant.
The preparation method of described ceramic ink jet printing furnace transmutation glaze, wherein, comprise the following steps:Each raw material is pressed into number Add in ball mill, add solvent, add the water progress ball milling that quality is 0.6-0.9 times of raw material gross mass, it is thin to glaze slip Spend for 300-550 mesh, obtained glaze.
Beneficial effect:The present invention provides a kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof, changes traditional glaze The component formula of material, stability is high during for ceramic ink jet printing, and hair color effect is fabulous, and production method is simple, and drops significantly Low cost of manufacture, has great promotional value.
Embodiment
The present invention provides a kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof, to make the purpose of the present invention, technology Scheme and effect are clearer, clear and definite, and the present invention is described in more detail below.It is it should be appreciated that described herein specific Embodiment only to explain the present invention, is not intended to limit the present invention.
Embodiment 1
A kind of ceramic ink jet printing furnace transmutation glaze, wherein, raw material component meter, including following components by weight:Feldspar powder 52 Part, 20 parts of calcite, 15 parts of talcum powder, 8 parts of quartz, 20 parts of glass dust, 18 parts of titanium dioxide, 0.5 part of cobalt oxide, methylcellulose 1 part, 0.8 part of sodium tripolyphosphate, 8 parts of hyper-dispersant, 80 parts of cyan, 5 parts of brown ink, cream-coloured 12 parts of chromatic ink, black 9 parts of ink.
In practical application, 17 parts of solvents are also included in raw material.
Further, solvent is ether solvent.
Further, hyper-dispersant is polyester type ultra-dispersant agent.
The preparation method of ceramic ink jet printing furnace transmutation glaze, wherein, comprise the following steps:Each raw material is added into ball by number In grinding machine, solvent is added, the water that quality is 0.9 times of raw material gross mass is added and carries out ball milling, the fineness to glaze slip is 550 mesh, Glaze is made.
The present embodiment is optimum embodiment.
Embodiment 2
A kind of ceramic ink jet printing furnace transmutation glaze, wherein, raw material component meter, including following components by weight:Feldspar powder 40 Part, 16 parts of calcite, 10 parts of talcum powder, 5 parts of quartz, 12 parts of glass dust, 13 parts of titanium dioxide, 0.3 part of cobalt oxide, methylcellulose 0.3 part, 0.4 part of sodium tripolyphosphate, 4 parts of hyper-dispersant, 55 parts of cyan, 3 parts of brown ink, cream-coloured 9 parts of chromatic ink, black 5 parts of ink.
In practical application, cover-coat enamel also includes 12 parts of solvents.
Further, solvent is esters solvent.
Further, hyper-dispersant is polyether-type hyper-dispersant.
The preparation method of ceramic ink jet printing furnace transmutation glaze, wherein, comprise the following steps:Each raw material is added into ball by number In grinding machine, solvent is added, the water that quality is 0.7 times of raw material gross mass is added and carries out ball milling, the fineness to glaze slip is 350 mesh, Glaze is made.
Embodiment 3
A kind of ceramic ink jet printing furnace transmutation glaze, wherein, raw material component meter, including following components by weight:Feldspar powder 45 Part, 18 parts of calcite, 13 parts of talcum powder, 6 parts of quartz, 18 parts of glass dust, 16 parts of titanium dioxide, 0.4 part of cobalt oxide, methylcellulose 0.8 part, 0.7 part of sodium tripolyphosphate, 6 parts of hyper-dispersant, 70 parts of cyan, 4 parts of brown ink, cream-coloured 11 parts of chromatic ink is black 8 parts of chromatic ink.
In practical application, cover-coat enamel also includes 15 parts of solvents.
Further, solvent is ether solvent.
Further, hyper-dispersant is poly- propionic acid type hyper-dispersant.
The preparation method of described ceramic ink jet printing furnace transmutation glaze, wherein, comprise the following steps:Each raw material is pressed into number Add in ball mill, add solvent, add the water that quality is 0.8 times of raw material gross mass and carry out ball milling, the fineness to glaze slip is 450 mesh, glaze is made.
Embodiment 4
A kind of ceramic ink jet printing furnace transmutation glaze, wherein, raw material component meter, including following components by weight:Feldspar powder 38 Part, 14 parts of calcite, 8 parts of talcum powder, 3 parts of quartz, 10 parts of glass dust, 11 parts of titanium dioxide, 0.1 part of cobalt oxide, methylcellulose 0.1 part, 0.2 part of sodium tripolyphosphate, 2 parts of hyper-dispersant, 50 parts of cyan, 2 parts of brown ink, cream-coloured 8 parts of chromatic ink, black 4 parts of ink.
In practical application, cover-coat enamel also includes 10 parts of solvents.
Further, solvent is esters solvent.
Further, hyper-dispersant is polyester type ultra-dispersant agent.
The preparation method of ceramic ink jet printing furnace transmutation glaze, wherein, comprise the following steps:Each raw material is added into ball by number In grinding machine, solvent is added, the water that quality is 0.6 times of raw material gross mass is added and carries out ball milling, the fineness to glaze slip is 300 mesh, Glaze is made.
The present invention provides a kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof, changes the group distribution of traditional glaze Stability is high when just, for ceramic ink jet printing, and hair color effect is fabulous, and production method is simple, and greatly reduces and be fabricated to This, has great promotional value.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention Protect scope.

Claims (5)

  1. A kind of 1. ceramic ink jet printing furnace transmutation glaze, it is characterised in that raw material component meter, including following components by weight: Feldspar powder 38-52 parts, calcite 14-20 parts, talcum powder 8-15 parts, quartzy 3-8 parts, glass dust 10-20 parts, titanium dioxide 11-18 Part, cobalt oxide 0.1-0.5 parts, methylcellulose 0.1-1 parts, sodium tripolyphosphate 0.2-0.8 parts, hyper-dispersant 2-8 parts, cyan ink Water 50-80 parts, brown ink 2-5 parts, cream-coloured chromatic ink 8-12 parts, black ink 4-9 parts.
  2. 2. ceramic ink jet printing furnace transmutation glaze according to claim 1, it is characterised in that also include 10-17 parts in raw material Solvent.
  3. 3. ceramic ink jet printing furnace transmutation glaze according to claim 2, it is characterised in that the solvent be ether solvent or At least one of esters solvent.
  4. 4. ceramic ink jet printing furnace transmutation glaze according to claim 1, it is characterised in that the hyper-dispersant is polyester-type Any one or more in hyper-dispersant, polyether-type hyper-dispersant and poly- propionic acid type hyper-dispersant.
  5. 5. a kind of preparation method of ceramic ink jet printing furnace transmutation glaze as described in claim 1-4 any one, its feature exist In comprising the following steps:Each raw material is added in ball mill by number, adds solvent, it is raw material gross mass to add quality 0.6-0.9 times of water carries out ball milling, and the fineness to glaze slip is 300-550 mesh, and glaze is made.
CN201710714236.5A 2017-08-18 2017-08-18 A kind of ceramic ink jet printing furnace transmutation glaze and preparation method thereof Pending CN107473592A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114933411A (en) * 2022-04-23 2022-08-23 绵竹市红森玻璃制品有限责任公司 Cobalt blue porcelain-like glass bottle and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114933411A (en) * 2022-04-23 2022-08-23 绵竹市红森玻璃制品有限责任公司 Cobalt blue porcelain-like glass bottle and preparation method thereof
CN114933411B (en) * 2022-04-23 2023-11-14 绵竹市红森玻璃制品有限责任公司 Cobalt blue porcelain-imitating glass bottle and preparation method thereof

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