CN108641479A - A kind of inkjet printing super white ceramic ink and preparation method thereof - Google Patents
A kind of inkjet printing super white ceramic ink and preparation method thereof Download PDFInfo
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- CN108641479A CN108641479A CN201810330698.1A CN201810330698A CN108641479A CN 108641479 A CN108641479 A CN 108641479A CN 201810330698 A CN201810330698 A CN 201810330698A CN 108641479 A CN108641479 A CN 108641479A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The present invention relates to ceramic ink technical fields, and in particular to a kind of inkjet printing super white ceramic ink and preparation method thereof is made of component below：One diaspore powder, calcining zinc oxide, auxiliary material inorganic particle, dispersant, antifoaming agent and solvent.Whitening effect is played jointly due to the main component using a diaspore powder as whiteware ink, and with calcining zinc oxide and auxiliary material inorganic particle, and then can reduce the use of zirconium silicate in overglaze, contributes to energy-saving and emission-reduction.During firing ceramic tile, a diaspore powder can slowly resolve into aluminium oxide under high temperature action, and aluminium oxide at this time is with respect to high temperature resistant, and in ceramic tile sintering process, and aluminium oxide and the calcining zinc oxide of generation synthesize heat safe ZnAl at high temperature2O4Spinelle, then whitening effect is played jointly with auxiliary material inorganic particle, and then ensure that whiteness, and ink whiteness is far above prior art products.The preparation method has advantage simple for process, and environmentally friendly.
Description
Technical field
The present invention relates to ceramic ink technical fields, and in particular to a kind of inkjet printing super white ceramic ink and its preparation
Method.
Background technology
Ceramic ink jet printing technology is a kind of newest contactless digital printing technologies, the more traditional stamp of the technology
Mode is more quick, and ceramic tile patterns are more rich and varied.Ceramic ink jet printing technology was developed so far from 2009, had been obtained a large amount of
Application, technical merit advances by leaps and bounds.Industry is mainly having the face such as blue, rufous, yellow and black with ceramic ink at present
Color, white ink also has a small amount of product this year, but ingredient is zirconium silicate, after ink is ground to submicron order, zirconium silicate
Covering power is greatly reduced, so that whiteness is low, and in there is white ink region in vain the phenomenon that yellowing, not using white ink
The dosage of zirconium silicate in overglaze can largely be reduced.Also, white ink is prepared using zirconium silicate, zirconium silicate granularity is at 1 μm or less
High temperature resistance weakens significantly afterwards, is dissolved in glaze, so whiteness is not high.
Existing home and overseas enterprise, which has, releases white ink product, and ink solid-phase component is all zirconium silicate, for example,
White ink patent is authorized to have《A kind of extra white aqueous ceramic jetted ink and preparation method thereof》With《A kind of ceramic ink jet printing use
White enamel ink and preparation method thereof》.Since the white ink of the prior art uses zirconium silicate as solid fraction, in glaze
Addition zirconium silicate is method that common glaze brightens, but zirconium silicate is levigate substantially weakens to high temperature resistance after submicron order,
In addition ink ejection amount is always not as good as traditional glaze pouring glaze volume, therefore, ink can become not milky white enough after burning, and it is white to influence product
Degree.When using existing white ink, it is desirable that needed in glaze containing more zirconium, this is significantly without the performance white ink work having
With.
In addition, the defect of the production technology of whiteware ink in the prior art there are complex process and not environmentally.Such as,
Patent name is《A kind of extra white aqueous ceramic jetted ink and preparation method thereof》Chinese patent application, the preparation method use
Sol-gal process prepares colloidal sol, then is prepared water-based ink, this method complex process with additive, solvent grinding, and used
The organic matters such as VOCs classes solvent such as glycol monoethyl ether, diethylene glycol monomethyl ether are unfavorable for environmental protection as solvent.Patent name is
《A kind of ceramic ink jet printing white enamel ink and preparation method thereof》Chinese patent application, the preparation method is by white glaze
Material is fired into after frit is processed into powder by frit again, then carries out that preparation white enamel ink is sanded, frit formula needs height
Levels of alumina and zirconium silicate improve the high temperature resistance of ink, and to ensure that ink whitens color, but there are frit bases for the program
Originally cannot levigate always cannot be with simple zirconium silicate certain degree to sub-micron and frit high temperature resistance the problems such as, although product
Whitening color, but it is not so good as existing white ink (zirconium silicate is solid phase) color development always.
Invention content
It is an object of the present invention in view of the deficiencies of the prior art, provide a kind of inkjet printing super white ceramic ink
Water, inkjet printing super white ceramic ink has the advantages that ultrawhite effect is good, and can reduce zirconium content in overglaze, helps to save
It can emission reduction.
The second object of the present invention is in view of the deficiencies of the prior art, to provide a kind of inkjet printing super white ceramic ink
Preparation method, the preparation method have it is simple for process, and environmental protection advantage.
One of to achieve the goals above, the present invention adopts the following technical scheme that：
A kind of inkjet printing super white ceramic ink is provided, is made of the component of following weight percent：
Preferably, a kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
More preferably, a kind of inkjet printing super white ceramic ink, by the component system of following weight percent
At：
The auxiliary material inorganic particle is one kind or two in ultra-fine yttrium stable zirconium oxide, calcined alumina or ultra-fine alumina
Kind or more composition.
The dispersant is one or two kinds of compositions of polyurethane-type dispersant or polymerization hydrogenation ricinoleic acid；
The antifoaming agent is organosilicon or the polymer-type antifoaming agent without organosilicon；
The anti-diffusion agent is polypropylene glycol 2000, glycerin polyoxyethylene ether HSH-330 or propylene glycol polyoxyethylene ether
The composition of one or more of HSH-215.
The solvent be mineral oil, isopropyl laurate, methyl oleate, the different monooctyl ester of coconut oil or one kind in laruyl alcohol or
Two or more compositions.
To achieve the goals above two, the present invention adopts the following technical scheme that：
A kind of preparation method of inkjet printing super white ceramic ink is provided, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill, then puts into a diaspore powder, calcining zinc oxide in sand mill
With auxiliary material inorganic particle, then proceed to grind the d until ink50Reach certain value, then add remaining solvent, continues to grind
It is milled to ink d50And d97Reach certain value；
Step 3: filtering：After filter element filtering, the inkjet printing super white ceramic ink is obtained.
In above-mentioned technical proposal, in the step 2, the rotating speed for adjusting sand mill is 2500r/min~4000r/min.
In above-mentioned technical proposal, in the step 2, a diaspore powder and auxiliary material inorganic powder are then put into sand mill
Body then proceedes to grind the d until ink50Reach 0.5 μm, then add remaining solvent, continues to be ground to ink d50For
0.4 μm~0.45 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 3~5:1.
In above-mentioned technical proposal, in the step 3, successively after 3 μm of filter cores and 1 μm of filter element filtering, the spray is obtained
Ink printing super white ceramic ink.
Compared with prior art, advantageous effect is the present invention：
(1) a kind of inkjet printing super white ceramic ink provided by the invention, due to making pottery using a diaspore powder as white
The main component of ceramic ink water, and whitening effect is played jointly with calcining zinc oxide and auxiliary material inorganic particle, and then overglaze can be reduced
The use of middle zirconium silicate, contributes to energy-saving and emission-reduction.Compared with the prior art prepares white ink using zirconium silicate as main component,
The white ink that the application is prepared using a diaspore powder as main component, during firing ceramic tile, under high temperature action
One diaspore powder can slowly resolve into aluminium oxide, and aluminium oxide at this time is with respect to high temperature resistant because the generation of aluminium oxide along with
The sintering process of ceramic tile, and in ceramic tile sintering process, aluminium oxide and the calcining zinc oxide of generation synthesize high temperature resistant at high temperature
ZnAl2O4Spinelle, then whitening effect is played jointly with auxiliary material inorganic particle, and then ensure that whiteness, and ink whiteness is far high
In prior art products.
(2) preparation method of a kind of inkjet printing super white ceramic ink provided by the invention has simple for process, production
It is at low cost, and can be suitable for industrialization large-scale production the characteristics of.And since solvent selects more environmentally friendly non-VOCs classes molten
Agent, and then avoid environmental pollution.
Specific implementation mode
In order to make the technical problems, technical solutions and beneficial effects solved by the present invention be more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain
The present invention is not intended to limit the present invention.
Embodiment 1.
A kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
Wherein, auxiliary material inorganic particle be ultra-fine yttrium stable zirconium oxide, calcined alumina or ultra-fine alumina in one kind or
Two or more compositions.
Wherein, dispersant is one or two kinds of compositions of polyurethane-type dispersant or polymerization hydrogenation ricinoleic acid；
Wherein, antifoaming agent is organosilicon or the polymer-type antifoaming agent without organosilicon, such as BYK-065, BYK-088 or
BYK-052；
Wherein, anti-diffusion agent is polypropylene glycol 2000, glycerin polyoxyethylene ether HSH-330 or propylene glycol polyoxyethylene ether
The composition of one or more of HSH-215.
Wherein, solvent is one kind in mineral oil, isopropyl laurate, methyl oleate, the different monooctyl ester of coconut oil or laruyl alcohol
Or two or more composition.
A kind of preparation method of above-mentioned inkjet printing super white ceramic ink, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill is 2500r/min~4000r/min, is then put into sand mill
One diaspore powder and auxiliary material inorganic particle then proceed to grind the d until ink50Reach 0.5 μm, then adds remaining molten
Agent continues to be ground to ink d50It is 0.4 μm~0.45 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 3~5:1.
Step 3: filtering：Successively after 3 μm of filter cores and 1 μm of filter element filtering, the inkjet printing super white ceramic is obtained
Ink.
Embodiment 2.
A kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
Wherein, auxiliary material inorganic particle is ultra-fine alumina.In the present embodiment, ultra-fine alumina is by Shandong state porcelain function material
Expect that limited liability company provides.
Wherein, dispersant is polymerization hydrogenation ricinoleic acid；
Wherein, antifoaming agent BYK-065；
Wherein, anti-diffusion agent is polypropylene glycol 2000.
Wherein, solvent is the composition of isopropyl laurate and methyl oleate.
A kind of preparation method of above-mentioned inkjet printing super white ceramic ink, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill is 3000r/min, and a diaspore powder is then put into sand mill
With auxiliary material inorganic particle, then proceed to grind the d until ink50Reach 0.5 μm, then add remaining solvent, continues to grind
It is milled to ink d50It is 0.43 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 4:1.
Step 3: filtering：Successively after 3 μm of filter cores and 1 μm of filter element filtering, the inkjet printing super white ceramic is obtained
Ink.
Embodiment 3.
A kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
Wherein, auxiliary material inorganic particle is the composition of ultra-fine yttrium stable zirconium oxide and calcined alumina.In the present embodiment, surpass
Thin yttrium stable zirconium oxide is provided by Shandong Sinocera Functional Materials Co., Ltd..
Wherein, dispersant is polyurethane-type dispersant；
Wherein, antifoaming agent BYK-088；
Wherein, anti-diffusion agent is glycerin polyoxyethylene ether HSH-330.
Wherein, solvent is the composition of mineral oil and isopropyl laurate.
A kind of preparation method of above-mentioned inkjet printing super white ceramic ink, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill is 2500r/min, and a diaspore powder is then put into sand mill
With auxiliary material inorganic particle, then proceed to grind the d until ink50Reach 0.5 μm, then add remaining solvent, continues to grind
It is milled to ink d50It is 0.4 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 3:1.
Step 3: filtering：Successively after 3 μm of filter cores and 1 μm of filter element filtering, the inkjet printing super white ceramic is obtained
Ink.
Embodiment 4.
A kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
Wherein, auxiliary material inorganic particle is calcined alumina.
Wherein, dispersant is polyurethane-type dispersant；
Wherein, antifoaming agent is the polymer-type antifoaming agent of organosilicon；
Wherein, anti-diffusion agent is propylene glycol polyoxyethylene ether HSH-215.
Wherein, solvent is the composition of coconut oil different monooctyl ester and laruyl alcohol.
A kind of preparation method of above-mentioned inkjet printing super white ceramic ink, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill is 4000r/min, and a diaspore powder is then put into sand mill
With auxiliary material inorganic particle, then proceed to grind the d until ink50Reach 0.5 μm, then add remaining solvent, continues to grind
It is milled to ink d50It is 0.45 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 5:1.
Step 3: filtering：Successively after 3 μm of filter cores and 1 μm of filter element filtering, the inkjet printing super white ceramic is obtained
Ink.
Embodiment 5.
A kind of inkjet printing super white ceramic ink, is made of the component of following weight percent：
Wherein, auxiliary material inorganic particle is ultra-fine yttrium stable zirconium oxide.In the present embodiment, ultra-fine yttrium stable zirconium oxide is by mountain
Dong Guoci functional materials limited liability company provides.
Wherein, dispersant is the composition of polyurethane-type dispersant and polymerization hydrogenation ricinoleic acid；
Wherein, antifoaming agent BYK-052；
Wherein, anti-diffusion agent is the composition of polypropylene glycol 2000 and glycerin polyoxyethylene ether HSH-330.
Wherein, solvent is the composition of mineral oil and isopropyl laurate.
A kind of preparation method of above-mentioned inkjet printing super white ceramic ink, it includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed
Conjunction stirs evenly, and is made into mixed solution, and mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：The rotating speed for adjusting sand mill is 3500r/min, and a diaspore powder is then put into sand mill
With auxiliary material inorganic particle, then proceed to grind the d until ink50Reach 0.5 μm, then add remaining solvent, continues to grind
It is milled to ink d50It is 0.44 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 4:1.
Step 3: filtering：Successively after 3 μm of filter cores and 1 μm of filter element filtering, the inkjet printing super white ceramic is obtained
Ink.
Performance test：
One, whiteness and glossiness are tested：
Inkjet printing super white ceramic ink obtained by above-described embodiment 2 to embodiment 5 and foreign well-known enterprise white
Ink is shown in Table 1 in the whiteness and glossiness test value on four kinds of different base surfaces.
Table 1
| Whiteness | Glossiness | Whiteness | Glossiness | Whiteness | Glossiness | Whiteness | Glossiness | ||||
| Black base | 30.0 | 2.0 | Openpore | 51.5 | 1.7 | Without zironium glaze | 57.0 | 3.1 | There is zironium glaze | 77.0 | 2.5 |
| Example 2 | 59.5 | 1.5 | Example 2 | 74.9 | 1.3 | Example 2 | 69.0 | 1.6 | Example 2 | 86.8 | 1.8 |
| Example 3 | 66.5 | 1.6 | Example 3 | 76.4 | 1.5 | Example 3 | 74.0 | 1.7 | Example 3 | 86.9 | 2.5 |
| Example 4 | 63.1 | 2.1 | Example 4 | 77.2 | 2.4 | Example 4 | 73.3 | 2.3 | Example 4 | 87.0 | 3.0 |
| Example 5 | 61.3 | 1.9 | Example 5 | 74.6 | 1.8 | Example 5 | 73.1 | 2.3 | Example 5 | 87.3 | 2.3 |
| Standard specimen | 46.0 | 2.2 | Standard specimen | 66.5 | 2.0 | Standard specimen | 65.0 | 2.4 | Standard specimen | 80.6 | 2.4 |
Two, it detects：
1, detection method：Directly detect the whiteness of ink using the green body of certain two kinds of whiteness of Ceramics Enterprises, in the application with
Black base is named with openpore, then applies no zironium glaze on black base surface and has zironium glaze comparison, the whiteness of ink on two kinds of different glazes.
No zironium glaze is formulated as shown in table 2 below with there is zironium glaze.
Table 2
| Oxide | Without zironium glaze | There is zironium glaze |
| Al2O3 | 34.5% | 29.3% |
| SiO2 | 53.4% | 50.3% |
| Fe2O3 | 0.3% | 0.26% |
| CaO | 1.2% | 1.0% |
| MgO | 0.9% | 0.7% |
| K2O | 0.9% | 0.7% |
| Na2O | 3.8% | 3.2% |
| TiO2 | 0.1% | 0.09% |
| ZrO2 | 0% | 10.1% |
| BaO | 0.8% | 0.7% |
| It burns and loses | 4.1% | 3.65% |
2, both the above glaze is added on the basis of raw material to carboxymethyl cellulose 0.1%, sodium tripolyphosphate according to the ratio
0.1%, according to material：Ball：Water is 1:3:0.4 ball milling certain time, at glaze slip, glaze slip was sprayed on green body, 100 DEG C of dryings
10min。
3, above example 2 is printed to embodiment 5 using new Jingtai CPM-70110 ink-jets experimental machine on different substrates
Ink and standard specimen ink, stamping ink amount are 3g/m2, and be burnt at 1200 DEG C, using SBDY-1 types digital display whiteness instrument and WGG60
Type mirror display glossness gauge distinguishes the whiteness and glossiness of test surfaces.
4, the inkjet printing obtained by embodiment 2 to embodiment 5 with super white ceramic ink billet surface whitening effect
Clearly, the close glaze whiteness for having glaze product of whiteness；Whitening effect is also fine on no zironium glaze, but on having zironium glaze, by
Higher in glaze whiteness, therefore, whitening effect is not as good as no zironium glaze, but the inkjet printing obtained by embodiment 2 to embodiment 5 is used and surpassed
White ceramic ink is all far above the effect of existing product in the whitening effect of four kinds of substrate surfaces, and ink is to substrate glossiness
Influence less.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art answer
Work as understanding, technical scheme of the present invention can be modified or replaced equivalently, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (10)
1. a kind of inkjet printing super white ceramic ink, it is characterised in that：It is made of the component of following weight percent：
2. a kind of inkjet printing super white ceramic ink according to claim 1, it is characterised in that：By following weight percent
The component of ratio is made：
3. a kind of inkjet printing super white ceramic ink according to claim 1, it is characterised in that：By following weight percent
The component of ratio is made：
4. a kind of inkjet printing super white ceramic ink according to claim 1, it is characterised in that：The auxiliary material inorganic powder
Body is the composition of one or more of ultra-fine yttrium stable zirconium oxide, calcined alumina or ultra-fine alumina.
5. a kind of inkjet printing super white ceramic ink according to claim 1, it is characterised in that：The dispersant is poly-
One or two kinds of compositions of urethane type dispersant or polymerization hydrogenation ricinoleic acid；
The antifoaming agent is organosilicon or the polymer-type antifoaming agent without organosilicon；
The anti-diffusion agent is polypropylene glycol 2000, glycerin polyoxyethylene ether HSH-330 or propylene glycol polyoxyethylene ether HSH-215
One or more of composition.
6. a kind of inkjet printing super white ceramic ink according to claim 1, it is characterised in that：The solvent is mineral
The composition of one or more of the different monooctyl ester of oil, isopropyl laurate, methyl oleate, coconut oil or laruyl alcohol.
7. a kind of preparation method of inkjet printing super white ceramic ink described in claim 1 to 6 any one, feature exist
In：It includes the following steps：
Step 1: preparing mixed solution：The dispersant of partial solvent and formula ratio, antifoaming agent and anti-diffusion agent are mixed and stirred
It mixes uniformly, is made into mixed solution, mixed solution is transferred in sand mill and continues to stir；
Step 2: grinding：Then the rotating speed for adjusting sand mill puts into a diaspore powder, calcining zinc oxide and auxiliary in sand mill
Expect inorganic particle, then proceedes to grind the d until ink50Reach certain value, then add remaining solvent, continues to be ground to
Ink d50And d97Reach certain value；
Step 3: filtering：After filter element filtering, the inkjet printing super white ceramic ink is obtained.
8. a kind of preparation method of inkjet printing super white ceramic ink according to claim 7, it is characterised in that：It is described
In step 2, the rotating speed for adjusting sand mill is 2500r/min~4000r/min.
9. a kind of preparation method of inkjet printing super white ceramic ink according to claim 7, it is characterised in that：It is described
In step 2, a diaspore powder and auxiliary material inorganic particle are then put into sand mill, then proceed to grind the d until ink50
Reach 0.5 μm, then add remaining solvent, continues to be ground to ink d50It is 0.4 μm~0.45 μm, d97It is≤1 μm；
Wherein, the mass ratio of the partial solvent of step 1 and the remaining solvent of step 2 is 3~5:1.
10. a kind of preparation method of inkjet printing super white ceramic ink according to claim 7, it is characterised in that：Institute
It states in step 3, successively after 3 μm of filter cores and 1 μm of filter element filtering, obtains the inkjet printing super white ceramic ink.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112479745A (en) * | 2020-11-10 | 2021-03-12 | 广西欧神诺陶瓷有限公司 | High-simulation ceramic tile and manufacturing process and application thereof |
| CN112812620A (en) * | 2021-01-22 | 2021-05-18 | 佛山森蒂泰珂科技有限公司 | Color development solvent digital ink and preparation method thereof |
| CN116814118A (en) * | 2023-07-21 | 2023-09-29 | 佛山市陶莹新型材料有限公司 | Ceramic ink capable of producing relief effect |
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| CN112812620A (en) * | 2021-01-22 | 2021-05-18 | 佛山森蒂泰珂科技有限公司 | Color development solvent digital ink and preparation method thereof |
| CN116814118A (en) * | 2023-07-21 | 2023-09-29 | 佛山市陶莹新型材料有限公司 | Ceramic ink capable of producing relief effect |
| CN116814118B (en) * | 2023-07-21 | 2024-02-20 | 佛山市陶莹新型材料有限公司 | Ceramic ink capable of producing relief effect |
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