CN112812620A - Color development solvent digital ink and preparation method thereof - Google Patents
Color development solvent digital ink and preparation method thereof Download PDFInfo
- Publication number
- CN112812620A CN112812620A CN202110087520.0A CN202110087520A CN112812620A CN 112812620 A CN112812620 A CN 112812620A CN 202110087520 A CN202110087520 A CN 202110087520A CN 112812620 A CN112812620 A CN 112812620A
- Authority
- CN
- China
- Prior art keywords
- parts
- digital ink
- ether
- ink
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Abstract
The invention discloses a chromophoric solvent digital ink and a preparation method thereof, wherein the ink is prepared from the following raw materials in parts by weight: 45-50 parts of high-temperature transparent frit, 20-30 parts of inorganic coloring accelerant, 10-15 parts of fused silica, 5-10 parts of gas-phase silica, 3-6 parts of 10N nano zinc oxide, 1-3 parts of 10N aluminum oxide, 3-6 parts of high-molecular dispersant, 20-30 parts of ether compound, 30-40 parts of alcohol compound and 3-6 parts of oil-water amphoteric silicone oil, the prepared color development solvent digital ink has good fluidity and stability, reduces the high-temperature viscosity of glaze, widens the high-temperature melting range of the glaze, effectively overcomes the defect that the glaze surface is easy to absorb dirt, colors all color systems fully, and leads the texture of ink-jet printing patterns to be clearer, especially when the high-gray-scale printing of the dark color pattern is needed, the printing gray scale can be reduced, the ink jet amount can be reduced, the ink can be saved, and the production cost of enterprises can be reduced.
Description
Technical Field
The invention relates to ink, in particular to color development solvent digital ink and a preparation method thereof.
Background
With the cross-industry development and application of ceramic rock boards, users have higher requirements on pattern definition and texture, and the rock board manufacturing needs more natural and vivid imitation natural stone and wood patterns and also needs more intelligent ceramic ink-jet printing and color matching technology to manufacture products with higher pattern definition. Aiming at the requirements of users, manufacturers need to produce rock plates with pure color development of all color systems, and color development solvent digital ink with high technological content, standardization, strong stability and full coloring is needed, so that the development of high-end manufacturing industry is promoted, and high value-added products and novel materials for manufacturing sophisticated building materials are created for enterprises.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides color development solvent digital ink and a preparation method thereof.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a color development solvent digital ink is prepared from the following raw materials in parts by weight: 45-50 parts of high-temperature transparent frit, 20-30 parts of inorganic coloring accelerant, 10-15 parts of fused silica, 5-10 parts of gas-phase silica, 3-6 parts of 10N nano zinc oxide, 1-3 parts of 10N aluminum oxide, 3-6 parts of high molecular dispersing agent, 20-30 parts of ether compound, 30-40 parts of alcohol compound and 3-6 parts of oil-water amphoteric silicone oil.
Preferably, the inorganic colouring promoter is calcium phosphate.
Preferably, the alcohol compound is at least one of polyol, diethylene glycol and polypropylene glycol.
Preferably, the polymeric dispersant is octyl phenol polyoxyethylene ether, the molecular weight of the octyl phenol polyoxyethylene ether is 600-700, and the pH value is 5.0-7.0.
Preferably, the ether compound includes at least one of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monobutyl ether.
Preferably, the unsaturated acid is at least one of ricinoleic acid, cocoic acid, palmitoleic acid.
Preferably, the mixture of the high-temperature transparent frit, the inorganic coloring accelerator, the fused silica, the fumed silica, the 10N nano zinc oxide and the 10N aluminum oxide in parts by weight is neutral in acid-base property and has the conductivity of 10-50 mu s/cm.
The method for preparing the digital ink comprises the following steps:
(1) and raw material pretreatment: respectively crushing the high-temperature transparent frit and the fused silica in parts by weight to 2400-;
(2) preparing digital ink: mixing the inorganic coloring accelerant, the fumed silica, the 10N nano zinc oxide, the 10N aluminum oxide, the polymeric dispersant, the ether compound, the alcohol compound and the oil-water amphoteric silicone oil in parts by weight with the high-temperature transparent frit pretreated in the step (1) and the fused silica, and adding the mixture into a sand mill for grinding to obtain the digital ink;
(3) detecting digital ink: detecting the digital ink prepared in the step (2), wherein the step (4) is carried out when the granularity of the digital ink is less than 1 mu m and the viscosity of the digital ink is 14-16mPa & s, and the step (2) is carried out continuously if the granularity of the digital ink is greater than 1 mu m or the viscosity of the digital ink is not 14-16mPa & s;
(4) and ink filtering: and (4) filtering the digital ink with the granularity smaller than 1 mu m and the viscosity of 14-16mPa & s, which is detected in the step (3), and collecting the filtrate, wherein the obtained filtrate is the finished product of the color development solvent digital ink.
Preferably, when the digital ink with the granularity of less than 1 μm and the viscosity of 15mPa · s is detected in the filtering step (3) in the step (4), a filter element with the filtering precision of 3 μm is firstly used to obtain a filtrate, the filtrate is collected, then the filter element with the filtering precision of 2 μm is used to collect the filtrate, and finally the filter element with the filtering precision of 1 μm is used to obtain a finished product of the color-developing solvent digital ink.
Preferably, the particle size of the chromophoric solvent digital ink is D50: 300-350nm, D90: 500-550nm, D99 is less than or equal to 700 nm.
The invention has the beneficial effects that: the color development solvent digital ink prepared by the invention has good fluidity and stability, reduces the high-temperature viscosity of glaze, widens the high-temperature melting range of the glaze, effectively overcomes the defect that the glaze surface is easy to absorb dirt, colors all color systems are fully colored, the texture of an ink-jet printing pattern is clearer, and the printing gray scale can be reduced, the ink-jet amount is reduced, the ink is saved and the production cost of enterprises is reduced when high-gray scale printing of deep-color patterns is particularly needed.
Detailed Description
The following examples further illustrate the practice and advantages of the present invention, and should not be construed as limiting the scope of the invention.
A color development solvent digital ink is prepared from the following raw materials in parts by weight: 45-50 parts of high-temperature transparent frit, 20-30 parts of inorganic coloring accelerant, 10-15 parts of fused silica, 5-10 parts of gas-phase silica, 3-6 parts of 10N nano zinc oxide, 1-3 parts of 10N aluminum oxide, 3-6 parts of high molecular dispersing agent, 20-30 parts of ether compound, 30-40 parts of alcohol compound and 3-6 parts of oil-water amphoteric silicone oil.
The high-temperature transparent frit prepared by high-temperature melting hardly generates gas burning loss, and is beneficial to the stability of the formula. Preferably, the inorganic coloring accelerant is calcium phosphate, the 10N nano zinc oxide and the 10N aluminum oxide are white powder, the nano particles can generate reflection and scattering effect on light, but when the particles with different sizes and particle diameters are uniformly mixed, the effect is equivalent to the effect of the composite particles and the light, so that the composite particles have the performance of two particles, and the reflection and scattering effect on the light can be enhanced. The masking effect is enhanced.
In addition, the existence of the two types of nanoparticles can influence each other, weaken the mutual attraction among the same type of particles and enhance the dispersibility of the particles.
Preferably, the alcohol compound is at least one of polyol, diethylene glycol and polypropylene glycol.
Preferably, the polymeric dispersant is octyl phenol polyoxyethylene ether, preferably, the molecular weight of the octyl phenol polyoxyethylene ether is 646.34, the pH value is 5.0-7.0, and the octyl phenol polyoxyethylene ether is a polyoxyethylene type nonionic surfactant, has stable property, acid and alkali resistance, and has good lipophilic and hydrophilic properties.
Preferably, the ether compound includes at least one of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, and tripropylene glycol monobutyl ether, which can enhance dispersibility.
Preferably, the unsaturated acid is at least one of ricinoleic acid, cocoic acid, and palmitoleic acid, and the viscosity of the color developing solvent digital ink may be adjusted.
Preferably, the mixture of the high-temperature transparent frit, the inorganic coloring accelerator, the fused silica, the fumed silica, the 10N nano zinc oxide and the 10N aluminum oxide in parts by weight is neutral in acid-base property and has the conductivity of 10-50 mu s/cm.
The method for preparing the digital ink comprises the following steps:
(1) and raw material pretreatment: respectively crushing the high-temperature transparent frit and the fused silica in parts by weight to 2400-;
(2) preparing digital ink: mixing the inorganic coloring accelerant, the fumed silica, the 10N nano zinc oxide, the 10N aluminum oxide, the polymeric dispersant, the ether compound, the alcohol compound and the oil-water amphoteric silicone oil in parts by weight with the high-temperature transparent frit pretreated in the step (1) and the fused silica, and adding the mixture into a sand mill for grinding to obtain the digital ink;
(3) detecting digital ink: detecting the digital ink prepared in the step (2), wherein the step (4) is carried out when the granularity of the digital ink is less than 1 mu m and the viscosity of the digital ink is 14-16mPa & s, and the step (2) is carried out continuously if the granularity of the digital ink is greater than 1 mu m or the viscosity of the digital ink is not 14-16mPa & s;
(4) and ink filtering: and (4) filtering the digital ink with the granularity of less than 1 mu m and the viscosity of 14-16mPa & s, which is detected in the step (3), collecting filtrate, and repeating the filtering step twice to obtain the filtrate, namely the finished product of the color development solvent digital ink.
Preferably, when the digital ink with the granularity of less than 1 μm and the viscosity of 14-16mPa · s is detected in the filtering step (3) in the step (4), a filter element with the filtering precision of 3 μm is firstly used to obtain the filtrate, the filtrate is collected, then the filter element with the filtering precision of 2 μm is used to collect the filtrate, and finally the filter element with the filtering precision of 1 μm is used to obtain the finished product of the color developing solvent digital ink.
Preferably, the particle size of the chromophoric solvent digital ink is D50: 300-350nm, D90: 500-550nm, D99 is less than or equal to 700nm, the maximum grain diameter of the ink is less than or equal to 1 mu m, and the average grain diameter is less than or equal to 0.5 mu m, so as to avoid blocking the collision head.
In the present invention, the portions where the temperature and pressure are not particularly emphasized are both normal temperature and normal pressure.
For the chromophoric solvent digital ink of the above formulation, the inventors designed and tested a number of examples and produced them according to the above method:
example 1: a color development solvent digital ink is prepared from the following raw materials in parts by weight: 45 parts of high-temperature transparent frit, 20 parts of inorganic coloring accelerant, 10 parts of fused silica, 5 parts of fumed silica, 3 parts of 10N nano zinc oxide, 1 part of 10N aluminum oxide, 3 parts of high-molecular dispersant, 20 parts of ether compound, 30 parts of alcohol compound and 3 parts of oil-water amphoteric silicone oil.
Wherein the alcohol compound is a mixture of polyhydric alcohol, diethylene glycol and polypropylene glycol in a ratio of 1:1: 1; the ether compound is a mixture of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether and tripropylene glycol monobutyl ether in a ratio of 1:1:1: 1; the unsaturated acid is a mixture of ricinoleic acid, coconut oil acid and palmitoleic acid in a ratio of 1:1:1, and the viscosity of the digital ink is detected to be 15mPa & s.
In the step (1), the high-temperature transparent frit and the fused silica in parts by weight are respectively pulverized into 2500 meshes by airflow.
Example 2: a color development solvent digital ink is prepared from the following raw materials in parts by weight: 50 parts of high-temperature transparent frit, 30 parts of inorganic coloring accelerant, 15 parts of fused silica, 10 parts of fumed silica, 6 parts of 10N nano zinc oxide, 3 parts of 10N aluminum oxide, 6 parts of high-molecular dispersant, 30 parts of ether compound, 40 parts of alcohol compound and 6 parts of oil-water amphoteric silicone oil.
Wherein the alcohol compound is a mixture of polyhydric alcohol, diethylene glycol and polypropylene glycol in a ratio of 1:1: 1; the ether compound comprises a mixture of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether and tripropylene glycol monobutyl ether in a ratio of 1:1:1: 1; the unsaturated acid is a mixture of ricinoleic acid, coconut oil acid and palmitoleic acid in a ratio of 1:1:1, and the viscosity of the digital ink is 14mPa & s through detection.
In the step (1), the high-temperature transparent frit and the fused silica in parts by weight are respectively pulverized into 2400 meshes by airflow.
Example 3: a color development solvent digital ink is prepared from the following raw materials in parts by weight: 47 parts of high-temperature transparent frit, 25 parts of inorganic coloring accelerant, 13 parts of fused silica, 7 parts of fumed silica, 4 parts of 10N nano zinc oxide, 2 parts of 10N aluminum oxide, 5 parts of high-molecular dispersant, 25 parts of ether compound, 35 parts of alcohol compound and 4 parts of oil-water amphoteric silicone oil.
Wherein the alcohol compound is a mixture of polyhydric alcohol, diethylene glycol and polypropylene glycol in a ratio of 1:1: 1; the ether compound comprises a mixture of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether and tripropylene glycol monobutyl ether in a ratio of 1:1:1: 1; the unsaturated acid is a mixture of ricinoleic acid, coconut oil acid and palmitoleic acid in a ratio of 1:1:1, and the viscosity of the digital ink is detected to be 16mPa & s.
In the step (1), the high-temperature transparent frit and the fused silica in parts by weight are respectively pulverized into 2600 meshes by air flow.
Example 4: a color development solvent digital ink is prepared from the following raw materials in parts by weight: 47 parts of high-temperature transparent frit, 25 parts of inorganic coloring accelerant, 13 parts of fused silica, 7 parts of fumed silica, 4 parts of 10N nano zinc oxide, 2 parts of 10N aluminum oxide, 5 parts of high-molecular dispersant, 25 parts of ether compound, 35 parts of alcohol compound and 4 parts of oil-water amphoteric silicone oil.
Wherein the alcohol compound is a mixture of polyhydric alcohol, diethylene glycol and polypropylene glycol in a ratio of 2:1: 1; the ether compound comprises a mixture of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether and tripropylene glycol monobutyl ether in a ratio of 2:1:2: 3; the unsaturated acid is a mixture of ricinoleic acid, coconut oil acid and palmitoleic acid in a ratio of 3:1:1, and the viscosity of the digital ink is detected to be 15mPa & s.
In the step (1), the high-temperature transparent frit and the fused silica in parts by weight are respectively pulverized into 2550 meshes by airflow.
All ranges in this application, including ranges for parts by weight of the starting materials and ranges for production parameters, etc., include both end values.
The above embodiments do not limit the scope of the present invention, and those skilled in the art can make equivalent modifications and variations without departing from the overall concept of the present invention.
Claims (10)
1. The color development solvent digital ink is characterized by being prepared from the following raw materials in parts by weight: 45-50 parts of high-temperature transparent frit, 20-30 parts of inorganic coloring accelerant, 10-15 parts of fused silica, 5-10 parts of gas-phase silica, 3-6 parts of 10N nano zinc oxide, 1-3 parts of 10N aluminum oxide, 3-6 parts of high molecular dispersing agent, 20-30 parts of ether compound, 30-40 parts of alcohol compound and 3-6 parts of oil-water amphoteric silicone oil.
2. The digital ink according to claim 1, wherein said inorganic coloring accelerator is calcium phosphate.
3. The digital ink according to claim 1, wherein the alcohol compound is at least one of polyol, diethylene glycol, and polypropylene glycol.
4. The digital ink according to claim 1, wherein the polymeric dispersant is octyl phenol polyoxyethylene ether.
5. The digital ink according to claim 1, wherein the ether-based compound comprises at least one of diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, tripropylene glycol monomethyl ether, and tripropylene glycol monobutyl ether.
6. The digital ink according to claim 1, wherein the unsaturated acid is at least one of ricinoleic acid, cocoic acid, and palmitoleic acid.
7. The digital ink according to claim 1, wherein the mixture of the high-temperature transparent frit, the inorganic coloring accelerator, the electro-fused silica, the fumed silica, the 10N nano-zinc oxide, and the 10N aluminum oxide is neutral in acidity and alkalinity, and has a conductivity of 10 to 50 μ s/cm.
8. A method of preparing the digital ink according to any one of claims 1 to 7, characterized by the steps of:
(1) and raw material pretreatment: respectively crushing the high-temperature transparent frit and the fused silica in parts by weight to 2400-;
(2) preparing digital ink: mixing the inorganic coloring accelerant, the fumed silica, the 10N nano zinc oxide, the 10N aluminum oxide, the polymeric dispersant, the ether compound, the alcohol compound and the oil-water amphoteric silicone oil in parts by weight with the high-temperature transparent frit pretreated in the step (1) and the fused silica, and grinding to obtain the digital ink;
(3) detecting digital ink: detecting the digital ink prepared in the step (2), wherein the step (4) is carried out when the granularity of the digital ink is less than 1 mu m and the viscosity of the digital ink is 14-16mPa & s, and the step (2) is carried out continuously if the granularity of the digital ink is greater than 1 mu m or the viscosity of the digital ink is not 14-16mPa & s;
(4) and ink filtering: and (4) filtering the digital ink with the granularity smaller than 1 mu m and the viscosity of 14-16mPa & s, which is detected in the step (3), and collecting the filtrate, wherein the obtained filtrate is the finished product of the color development solvent digital ink.
9. The method for preparing digital ink according to claim 8, wherein when the digital ink with particle size less than 1 μm and viscosity of 14-16mPa · s is detected in the filtering step (3) in the step (4), the color developing solvent digital ink is obtained by first passing through a filter element with filtering precision of 3 μm, collecting the filtrate, passing through a filter element with filtering precision of 2 μm, collecting the filtrate, and finally passing through a filter element with filtering precision of 1 μm.
10. The method of claim 8, wherein the particle size of the color-developing solvent digital ink is D50: 300-350nm, D90: 500-550nm, and D99 is less than or equal to 700 nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110087520.0A CN112812620A (en) | 2021-01-22 | 2021-01-22 | Color development solvent digital ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110087520.0A CN112812620A (en) | 2021-01-22 | 2021-01-22 | Color development solvent digital ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112812620A true CN112812620A (en) | 2021-05-18 |
Family
ID=75858789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110087520.0A Pending CN112812620A (en) | 2021-01-22 | 2021-01-22 | Color development solvent digital ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112812620A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107840574A (en) * | 2017-11-30 | 2018-03-27 | 佛山市华力达材料科技有限公司 | It is a kind of suitable for white glaze ink of digital printing and preparation method thereof |
| CN108641479A (en) * | 2018-04-13 | 2018-10-12 | 山东国瓷康立泰新材料科技有限公司 | A kind of inkjet printing super white ceramic ink and preparation method thereof |
-
2021
- 2021-01-22 CN CN202110087520.0A patent/CN112812620A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107840574A (en) * | 2017-11-30 | 2018-03-27 | 佛山市华力达材料科技有限公司 | It is a kind of suitable for white glaze ink of digital printing and preparation method thereof |
| CN108641479A (en) * | 2018-04-13 | 2018-10-12 | 山东国瓷康立泰新材料科技有限公司 | A kind of inkjet printing super white ceramic ink and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 北京矿冶研究总院编: "《冶金和材料学术会议论文集（第一辑）》", 31 December 1994, 冶金工业出版社 * |
| 夏兆扬主编: "《简明自然科学小词典 第三分册 化学》", 31 October 1990, 水利电力出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11084759B2 (en) | Low-shrinkage, high-strength, and large ceramic plate and manufacturing method thereof | |
| CN101445687B (en) | Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof | |
| CN109651883B (en) | Black ceramic ink and preparation method thereof | |
| CN107201083B (en) | Inkjet anti-skid glass ink and preparation method thereof | |
| JP2009215385A (en) | Blue pigment with infrared reflectivity, coating material using the same, and resin composition | |
| CN108641483A (en) | A kind of ceramic ink jet printing ink and preparation method thereof promoting color development | |
| CN108251048A (en) | Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof | |
| CN108384312B (en) | High-temperature cutting-resistant black ink and preparation method thereof | |
| CN107793846A (en) | A kind of water nano mill base and preparation method thereof | |
| CN107987612B (en) | Water-based Jing porcelain Single-pass high-speed ink-jet printing thermal transfer ink and preparation method thereof | |
| CN113337157A (en) | Reflective film weak solvent inkjet ink and preparation method and application thereof | |
| CN107033672A (en) | A kind of big red ink of refractory ceramics and preparation method thereof | |
| CN109535837B (en) | Ceramic ink capable of improving color development effect of cobalt-containing ink and preparation method and use method thereof | |
| CN112812620A (en) | Color development solvent digital ink and preparation method thereof | |
| CN109504179B (en) | Matte effect printing ink for ceramic glaze and preparation method thereof | |
| CN104961471A (en) | Cast film slurry of ultrathin lamination flaky inductor and manufacturing method for cast film of ultrathin lamination flaky inductor | |
| CN109082226B (en) | Preparation method of wet color-changing super-hydrophobic surface | |
| CN113603363A (en) | Self-cleaning phase-splitting opal glaze and preparation method thereof | |
| CN108587250B (en) | Composite pigment surface modifier and application method thereof | |
| CN115849713B (en) | Digital satin protective glaze and product and preparation method thereof | |
| CN111154335A (en) | High-stability emulsion ink | |
| CN107163684A (en) | A kind of ceramic white ink and preparation method thereof | |
| CN104231756B (en) | A kind of nano modification mill base material and preparation method thereof | |
| CN110373046B (en) | Disperse red FS150% dye composition | |
| CN105111822A (en) | Solvent of bismuth-oxide-base ink for glass digital inkjet printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210518 |
|
| RJ01 | Rejection of invention patent application after publication |