CN1850683A - Method for preparing flux for high-brightness pollution-less ceramic decorative material - Google Patents

Method for preparing flux for high-brightness pollution-less ceramic decorative material Download PDF

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Publication number
CN1850683A
CN1850683A CNA2006100843332A CN200610084333A CN1850683A CN 1850683 A CN1850683 A CN 1850683A CN A2006100843332 A CNA2006100843332 A CN A2006100843332A CN 200610084333 A CN200610084333 A CN 200610084333A CN 1850683 A CN1850683 A CN 1850683A
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CN
China
Prior art keywords
flux
glossiness
brightness
pollution
decorative material
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Application number
CNA2006100843332A
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Chinese (zh)
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CN100390089C (en
Inventor
曹春娥
郑乃章
沈华荣
熊春华
卢希龙
余峰
刘阳
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Jingdezhen Ceramic Institute
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Jingdezhen Ceramic Institute
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Priority to CNB2006100843332A priority Critical patent/CN100390089C/en
Publication of CN1850683A publication Critical patent/CN1850683A/en
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Publication of CN100390089C publication Critical patent/CN100390089C/en
Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
    • C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention relates to a method for preparing a high-glossiness, no-public harm flux for ceramic finishing material, adopting natural minerals and industrially chemical materials in weight percent: SiO2 40-50wt%; B2O3 25-35wt%;Al2O3 5-10wt%;Li2O 1.5-3.5wt%;K2O 3.5-5.5wt%; Na2O 2.5-4.5wt%;SrO 4.5-6.5wt%;CaO 4.0-7.0wt%; and fluoride 1.5-2.0wt%; uniformly mixing, melting, quenching, ball milling, and drying and making the flux. And glossiness of glazed ceramics can be up to 110.2-114.9%.

Description

A kind of high gloss, the nuisanceless ceramic decoration material preparation method of flux
Technical field
The invention belongs to the ceramic decoration material technical field, be specifically related to the preparation method of a kind of high gloss, nuisanceless ceramic decoration material usefulness flux.
Background technology
The research of nuisanceless ceramic decoration material, up to the present most still being positioned on the aspect that how to reduce lead, quantity of cadmium release fundamentally do not solve innoxious problem, therefore is difficult to adapt to harsh day by day harmful element stripping limit standard requirement.The basic outlet that addresses the above problem is to research and develop out toner on the acid-resistant glaze (as the surface by replica, coated etc.) and unleaded, cadmium pigment, accounts for wherein that pigment forms that 50～90% flux is unleaded, cadmium and totally nontoxic evil be its key point.With alkali borosilicate system is the nuisanceless flux of foundational development, has the advantages that cost is low, be easy to apply, but it still exists gloss, colour generation, the coefficient of expansion is undesirable and adapts to problem such as toner narrow range.For example interim by applicant's disclosed " DEVELOPMENT OF FLUX FOR OVERGLAZE RED PIGMENT " literary composition at " Chinese pottery industry " the 8th volume 4, the flux that this method obtains still exists and adapts to toner narrow range, the relatively poor deficiency of glossiness, is difficult to reach the Modern Decorative ideal effect.
Summary of the invention
The present invention is by further adjusting the proportioning of flux main, producing beyond thought good result aspect the technical indicators such as gloss, colour generation, the coefficient of expansion, obtained high gloss, colour generation good, combine intact, as to adapt to the toner wide ranges nuisanceless ceramic decoration material flux with glaze.
A kind of high gloss of the present invention, the nuisanceless ceramic decoration material preparation method of flux adopts natural mineral raw and industrial chemicals, and it consists of: SiO 2Be 40～50wt%; B 2O 3Be 25～35wt%; Al 2O 3Be 5～10wt%; Li 2O is 1.5～3.5wt%; K 2O is 3.5～5.5wt%; Na 2O is 2.5～4.5wt%; SrO is 4.5～6.5wt%; CaO is 4.0～7.0wt%; Fluorochemical is 1.5～2.0wt%;
Through mixing, found, quenching, ball milling, the dry goods that obtain.
The present invention has optimized prescription by a large amount of experiments, has reduced the appearance of defectives such as crystallization, milkiness, colour killing after the color painting color roasting on the ceramic glaze, has guaranteed that it can adapt to the main colorant of over-glaze decoration series; Glossiness, adaptation toner scope and the color roasting rear surface quality of nuisanceless flux have further been improved; The finished product colour generation was good, acidproof, alkaline-resisting after the over-glaze decoration pigment that this flux is deployed into was made the marble paper color roasting, and thermostability meets industry standard, and glossiness can reach the decorative effect that color painting on the lead glaze is arranged both at home and abroad up to 110.2～114.9%.Detect through national domestic ceramics quality supervision and test center, its lead, quantity of cadmium release only are trace (extraneous factor introducing), are lower than ISO6486-2:1999 (E) regulation and California, USA standard.
Embodiment
Example 1:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
43.2 4.9 30.8 1.6 4.4 3.4 5.8 4.3 1.6
Example 2:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
46.1 6.8 28.6 2.45 3.4 2.8 4.9 3.6 1.35
Example 3:
According to the form below is formed preparation flux, and glass melting temperature is 1300 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
45.5 5.4 28.3 1.5 4.5 3.4 5 4.7 1.7
Example 4:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
46.6 6.1 28.4 2.2 2.0 3.6 5.4 4 1.7
Example 5:
According to the form below is formed preparation flux, and glass melting temperature is 1280 ℃, is incubated 30 minutes, and ball milling is done standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
42.9 7.2 27.0 2.2 4.5 3.5 5.5 5.6 1.6
Toner and stand linseed oil are joined in the ground flux of the various embodiments described above gained, and marble paper is made in silk screen printing, and the melt temperature scope of using ZA-P type hot-stage microscope mensuration flux is carried out color roasting then to determine the color roasting temperature.
Gained ceramic product leading indicator detects as follows:
Glossiness: the glossiness of flower face after the color roasting of use WGG60-2 type vancometer mensuration marble paper;
Thermostability: check with reference to QB/T2455.2-1999;
Acidproof, alkaline resistance properties: check with reference to QB/T2455.2-1999;
Plumbous, quantity of cadmium release:, check with reference to GB/T3534-2002 according to ISO6486-2:1999 (E) regulation and California, USA standard.
Detected result sees the following form:
The embodiment numbering The color roasting temperature Glossiness Thermostability Plumbous, quantity of cadmium release Acidproof, alkali resistance
1 700～ 760℃ 114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
2 720～ 800℃ 112％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
3 780～ 850℃ 110.2～114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
4 700～ 800℃ 110.2～114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
5 700～ 800℃ 110.2％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster

Claims (1)

1, a kind of high gloss, the nuisanceless ceramic decoration material preparation method of flux adopts natural mineral raw and industrial chemicals, and it consists of: SiO 2Be 40～50wt%; B 2O 3Be 25～35wt%; Al 2O 3Be 5～10wt%; Li 2O is 1.5～3.5wt%; K 2O is 3.5～5.5wt%; Na 2O is 2.5～4.5wt%; SrO is 4.5～6.5wt%; CaO is 4.0～7.0wt%; Fluorochemical is 1.5～2.0wt%;
Through mixing, found, quenching, ball milling, the dry goods that obtain.
CNB2006100843332A 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material Expired - Fee Related CN100390089C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100843332A CN100390089C (en) 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100843332A CN100390089C (en) 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material

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CN1850683A true CN1850683A (en) 2006-10-25
CN100390089C CN100390089C (en) 2008-05-28

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011765A (en) * 2012-12-25 2013-04-03 青岛科技大学 Flux system for sintering ceramic body in liquid phase and preparation method thereof
CN105731797A (en) * 2016-01-23 2016-07-06 景德镇陶瓷学院 Preparation method for high-alkali-resistance lead-free ceramic glaze coloring fluxing agent for dish-washing machine
CN105753324A (en) * 2016-01-23 2016-07-13 景德镇陶瓷学院 Method for preparing high-alkali-resistance ceramic overglaze color fluxing agent by milling addition of silica sol
CN105753513A (en) * 2016-01-23 2016-07-13 景德镇陶瓷学院 Decoration method for ceramic over-glaze pigment with high corrosion resistance
CN110066109A (en) * 2019-05-28 2019-07-30 江西陶瓷工艺美术职业技术学院 A kind of traditional decoration pigment flux and its application method
CN111646701A (en) * 2020-06-06 2020-09-11 景德镇市民俗文化瓷业有限公司 Composite color ceramic overglaze pigment decoration method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1028221C (en) * 1990-07-24 1995-04-19 周国栋 Manufacturing method of red stone porcelain

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011765A (en) * 2012-12-25 2013-04-03 青岛科技大学 Flux system for sintering ceramic body in liquid phase and preparation method thereof
CN105731797A (en) * 2016-01-23 2016-07-06 景德镇陶瓷学院 Preparation method for high-alkali-resistance lead-free ceramic glaze coloring fluxing agent for dish-washing machine
CN105753324A (en) * 2016-01-23 2016-07-13 景德镇陶瓷学院 Method for preparing high-alkali-resistance ceramic overglaze color fluxing agent by milling addition of silica sol
CN105753513A (en) * 2016-01-23 2016-07-13 景德镇陶瓷学院 Decoration method for ceramic over-glaze pigment with high corrosion resistance
CN105731797B (en) * 2016-01-23 2017-12-26 景德镇陶瓷大学 A kind of preparation method of the high alkali resistance lead-free ceramicses overglaze color flux of use in dishwasher
CN105753324B (en) * 2016-01-23 2018-01-12 景德镇陶瓷大学 It is a kind of to grind the method for adding Ludox to prepare high alkali resistance ceramics overglaze color flux
CN110066109A (en) * 2019-05-28 2019-07-30 江西陶瓷工艺美术职业技术学院 A kind of traditional decoration pigment flux and its application method
CN110066109B (en) * 2019-05-28 2022-02-22 江西陶瓷工艺美术职业技术学院 Flux for antique pigment and application method thereof
CN111646701A (en) * 2020-06-06 2020-09-11 景德镇市民俗文化瓷业有限公司 Composite color ceramic overglaze pigment decoration method
CN111646701B (en) * 2020-06-06 2022-05-20 景德镇市民俗文化瓷业有限公司 Method for decorating composite color ceramic with overglaze pigment

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Granted publication date: 20080528

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