CN111646701A - Composite color ceramic overglaze pigment decoration method - Google Patents
Composite color ceramic overglaze pigment decoration method Download PDFInfo
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- CN111646701A CN111646701A CN202010508907.4A CN202010508907A CN111646701A CN 111646701 A CN111646701 A CN 111646701A CN 202010508907 A CN202010508907 A CN 202010508907A CN 111646701 A CN111646701 A CN 111646701A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The present invention relates to a method for decorating composite colour ceramic by using overglaze pigment, and its leadless flux chemical percentage composition is SiO235~45%、B2O330~40%、Al2O310~15%、SrO 2~6%、Na2O 2~4%、K2O 2~5%、CaO 2~8%、MgO 1~5%、BaO 1~5%、Bi2O32-4 percent of lead-free color assistant agent, 2-5 percent of zirconium silicate nanofiber, 5-10 percent of zinc oxide nanofiber and 85-90 percent of glaze ceramic pigment, the formula composition of the fusing agent and the color assistant agent is adjusted, the fluidity, glossiness, color development effect and stereoscopic impression of the pigment are reasonably controlled, the one-time exhibition of artistic effects of various traditional ceramic decoration techniques is realized, the decoration flow and process of the traditional techniques are simplified, and simultaneously the used raw materials are completely green and environment-friendlyHas no side effect on human body, thereby having wide market space.
Description
Technical Field
The invention relates to the technical field of ceramics, in particular to a method for decorating composite colored ceramics by using an overglaze pigment.
Background
The glass white base is made up of natural minerals such as white marble and arsenicum, and solvent such as aluminium frit and potassium nitrate. The glass white is fused with color materials, so that various colors are pulverized, and the characters, flowers, birds, mountains and waters drawn by the method have light and shade, depth and yin and yang, and the layering sense and the stereoscopic sense are increased, thereby forming a light and elegant artistic style. Is prepared by color filling and washing and dyeing processes (the furnace temperature is 760 ℃ to 780 ℃).
The ancient colour is also called hard colour, it adopts red, yellow, green, blue, purple, black and golden biological departments, and uses lines to draw and fill colour, and its pen method is rigid and hard, and has the patterns of characters, flowers and birds, landscape and beast, etc., and it can ask folk connotation, such as riches and honour of peony, good fortune and longevity, beautiful flowers and stories of "Xiwuji" etc.. The technological process includes the steps of painting white blank with raw material and alum red, washing and dyeing with alum red, spreading other colors, spreading and painting, and sintering in kiln at 780-800 deg.c to obtain the ancient color porcelain.
The new color is an ancient name of an ocean color, and belongs to a low-temperature glazing process. The new color pigment is made of various metal oxides such as copper, tin, manganese, cobalt and the like, so that the new color pigment has pure color, bright and attractive appearance, obvious impact on visual effect, brightness and gorgeous appearance, and accords with the aesthetic characteristics of modern people.
By contrast, the Jingdezhen pastel, the old pastel and the new pastel respectively show distinctive decorative effects on the surface of the ceramic, so that a plurality of different fluxes are required to be used when the pastel, the old pastel and the new pastel are decorated on the surface of the ceramic glaze at present, and a plurality of baking colors are required to realize the decoration of a plurality of techniques on one surface of the ceramic, so that the process is very complicated, the production cost is high, and the prosperous development of the traditional decoration technique of the Jingdezhen in a new period is seriously hindered.
Disclosure of Invention
The invention provides a composite color ceramic glaze pigment decoration method which is suitable for various decoration techniques, pure in color, high in glossiness, low in cost and environment-friendly, and aims to overcome the limitation problem that the traditional single decoration technique of Jingdezhen is single in expression.
The technical scheme of the invention is as follows: the method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2235~45%、B2O330~40%、Al2O310~15%、SrO 2~6%、Na2O 2~4%、K2O 2~5%、CaO 2~8%、MgO 1~5%、BaO 1~5%、Bi2O3Weighing 2-4% of a lead-free flux raw material;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with water or kerosene, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the mixture into an electric furnace for color baking, heating the mixture to 750-780 ℃ at a heating rate of 5 ℃/min, preserving heat for 20min, and cooling the mixture along with the furnace to obtain a composite color ceramic overglaze pigment decorative product.
The parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1250-1280 ℃, and the heat preservation time is 120 min.
The parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
The glossiness of the composite color ceramic overglaze pigment decoration product in the third step is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
The decorative effect of the six-step composite color ceramic overglaze pigment decorative product comprises one or more of ancient color, pink color and new color.
The invention improves the high-temperature melting range, high-temperature fluidity and adaptability to glaze surface of the glaze pigment by controlling the chemical components of the lead-free flux, not only realizes the full fusion of the flux and the pigment, but also enhances the glossiness of the glaze pigment.
According to the invention, the composite nano-fiber is added into the color assistant as a raw material, so that the binding capacity of the pigment and the flux is improved, and the color development effect and the stereoscopic impression of the glaze pigment are enhanced.
The invention is to enrich the ceramic glaze color decoration effect, carry forward the traditional ceramic decoration technique of our country, the inventor innovates the pigment decoration method on the compound color ceramic glaze through the many years of attentive research to the traditional powder color, ancient color, new color decoration technique of Jingdezhen, the invention reasonably controls the fluidity, glossiness, color development effect, and stereoscopic impression of the pigment by adjusting the formula composition of the fusing agent and the toner, realizes the creation of a plurality of decoration techniques such as ancient color, powder color, new color on an artistic work, and carries out technical innovation on the firing temperature of the original decoration technique, realizes the firing at the same kiln temperature, the product blank glaze is combined stably, the color performance is stable, the glaze surface glossiness is bright, and has the remarkable characteristics of bright color, rich color, contrast, strong expressive force, and the like, and is applied to the ceramic painting creation, and is favorable for the author to fully utilize the material characteristics to express the theme and thought and idea The emotion can fully show the talent and intelligence of the author, so that the work achieves the ideal effect of the author. Meanwhile, the composite color ceramic overglaze pigment has rich raw material sources, low price and no side effect on human bodies, is completely green and environment-friendly, and has wide market space.
Detailed Description
To further illustrate the present invention and the technical means and effects thereof adopted to achieve the predetermined object, the present invention will be described in detail with reference to the preferred embodiments as follows:
example 1
The method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2236%、B2O340%、Al2O311%、SrO 2%、Na2O 2%、K2O2%、CaO 2%、MgO 1%、BaO 1%、Bi2O33 percent of lead-free flux raw material is weighed;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with water, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the dried mixture into an electric furnace for color baking, heating the mixture to 770 ℃ at a heating rate of 5 ℃/min, keeping the temperature for 20min, and cooling the mixture along with the furnace to obtain the composite color ceramic overglaze pigment decorative product.
The parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1280 ℃, and the heat preservation time is 120 min.
The parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
When the pigment for decorating the pastel is prepared in the third step, the pigment comprises the following components in percentage by weight: 5% of zirconium silicate nanofiber, 5% of zinc oxide nanofiber and 90% of glazed ceramic pigment;
when preparing the pigment for antique decoration, the pigment comprises the following components in percentage by weight: 4% of zirconium silicate nanofiber, 7% of zinc oxide nanofiber and 89% of glazed ceramic pigment;
when preparing the new color pigment for decoration, the weight percentage of the pigment is as follows: 3% of zirconium silicate nanofiber, 10% of zinc oxide nanofiber and 87% of glazed ceramic pigment.
When the pigment for decorating the pink color is prepared in the fifth step, the weight percentage of the lead-free flux to the lead-free color assistant agent is 72% to 28%;
when the pigment for antique decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 77% to 23%;
when the novel color pigment for decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 85% to 15%.
The glossiness of the composite color ceramic overglaze pigment decorative product is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
Example 2
The method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2243%、B2O330%、Al2O314%、SrO 3%、Na2O 2%、K2O2%、CaO 2%、MgO 1%、BaO 1%、Bi2O3Weighing 2% of lead-free flux raw material;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with kerosene, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the mixture into an electric furnace for color baking, heating the mixture to 760 ℃ at a heating rate of 5 ℃/min, preserving the heat for 20min, and cooling the mixture along with the furnace to obtain a composite color ceramic overglaze pigment decorative product.
The parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1260 ℃, and the heat preservation time is 120 min.
The parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
When the pigment for decorating the pastel is prepared in the third step, the pigment comprises the following components in percentage by weight: 5% of zirconium silicate nanofiber, 5% of zinc oxide nanofiber and 90% of glazed ceramic pigment;
when preparing the pigment for antique decoration, the pigment comprises the following components in percentage by weight: 4% of zirconium silicate nanofiber, 7% of zinc oxide nanofiber and 89% of glazed ceramic pigment;
when preparing the new color pigment for decoration, the weight percentage of the pigment is as follows: 3% of zirconium silicate nanofiber, 10% of zinc oxide nanofiber and 87% of glazed ceramic pigment.
When the pigment for decorating the pink color is prepared in the fifth step, the weight percentage of the lead-free flux to the lead-free color assistant agent is 76% to 24%;
when the pigment for antique decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 84% to 16%;
when the novel color pigment for decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 70% to 30%.
The glossiness of the composite color ceramic overglaze pigment decorative product is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
Example 3
The method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2237%、B2O333%、Al2O310%、SrO 2%、Na2O 3%、K2O3%、CaO 4%、MgO 2%、BaO 3%、Bi2O33 percent of lead-free flux raw material is weighed;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with water, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the dried mixture into an electric furnace for color baking, heating the mixture to 760 ℃ at a heating rate of 5 ℃/min, preserving the heat for 20min, and cooling the mixture along with the furnace to obtain a composite color ceramic overglaze pigment decorative product.
The parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1250 ℃, and the heat preservation time is 120 min.
The parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
When the pastel prepared in the third step is used for decoration, the pastel comprises the following components in percentage by weight: 5% of zirconium silicate nanofiber, 5% of zinc oxide nanofiber and 90% of glazed ceramic pigment;
when preparing the pigment for antique decoration, the pigment comprises the following components in percentage by weight: 4% of zirconium silicate nanofiber, 7% of zinc oxide nanofiber and 89% of glazed ceramic pigment;
when preparing the new color pigment for decoration, the weight percentage of the pigment is as follows: 3% of zirconium silicate nanofiber, 10% of zinc oxide nanofiber and 87% of glazed ceramic pigment.
When the pigment for decorating the pink color is prepared in the fifth step, the weight percentage of the lead-free flux to the lead-free color assistant agent is 82% to 18%;
when the pigment for antique decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 74% to 26%;
when the novel color pigment for decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 75% to 25%.
The glossiness of the composite color ceramic overglaze pigment decorative product is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
Example 4
The method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2235%、B2O330%、Al2O310%、SrO 4%、Na2O 2%、K2O2%、CaO 6%、MgO 5%、BaO 4%、Bi2O3Weighing 2% of lead-free flux raw material;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with kerosene, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the mixture into an electric furnace for color baking, heating the mixture to 760 ℃ at a heating rate of 5 ℃/min, preserving the heat for 20min, and cooling the mixture along with the furnace to obtain a composite color ceramic overglaze pigment decorative product.
The parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1250 ℃, and the heat preservation time is 120 min.
The parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
When the pigment for decorating the pastel is prepared in the third step, the pigment comprises the following components in percentage by weight: 5% of zirconium silicate nanofiber, 5% of zinc oxide nanofiber and 90% of glazed ceramic pigment;
when preparing the pigment for antique decoration, the pigment comprises the following components in percentage by weight: 4% of zirconium silicate nanofiber, 7% of zinc oxide nanofiber and 89% of glazed ceramic pigment;
when preparing the new color pigment for decoration, the weight percentage of the pigment is as follows: 3% of zirconium silicate nanofiber, 10% of zinc oxide nanofiber and 87% of glazed ceramic pigment.
When the pigment for decorating the pink color is prepared in the fifth step, the weight percentage of the lead-free flux to the lead-free color assistant agent is 73% to 27%;
when the pigment for antique decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 80% to 20%;
when the novel color pigment for decoration is prepared, the weight percentage of the lead-free flux to the lead-free color assistant agent is 78% to 22%.
The glossiness of the composite color ceramic overglaze pigment decorative product is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
Claims (5)
1. The method for decorating the composite color ceramic by using the overglaze pigment is characterized by comprising the following steps:
the method comprises the following steps: the composition comprises the following chemical percentages: SiO 2235~45%、B2O330~40%、Al2O310~15%、SrO 2~6%、Na2O 2~4%、K2O 2~5%、CaO 2~8%、MgO 1~5%、BaO 1~5%、Bi2O3Weighing 2-4% of a lead-free flux raw material;
step two: grinding, melting at high temperature, water quenching and cooling, ball milling, sieving and drying the raw materials of the lead-free flux weighed in the step one to obtain the lead-free flux for later use;
step three: the composition comprises the following components in percentage by weight: 2-5% of zirconium silicate nanofiber, 5-10% of zinc oxide nanofiber and 85-90% of glazed ceramic pigment;
step four: uniformly mixing the raw materials of the lead-free toner weighed in the step three, and sieving to obtain the lead-free toner for later use;
step five: uniformly mixing the lead-free flux obtained in the step two and the lead-free color assistant obtained in the step four according to the weight percentage of 70-85% to 15-30% to obtain the composite color ceramic glaze pigment;
step six: and (4) mixing the pigment obtained in the fifth step with water or kerosene, coating the mixture on a flat porcelain plate according to the content of a decorative pattern, drying the mixture, putting the mixture into an electric furnace for color baking, heating the mixture to 750-780 ℃ at a heating rate of 5 ℃/min, preserving heat for 20min, and cooling the mixture along with the furnace to obtain a composite color ceramic overglaze pigment decorative product.
2. The composite color ceramic overglaze pigment decoration method of claim 1, wherein: the parameters of the high-temperature melting process in the second step are as follows: the heating rate is 10 ℃/min, the highest melting temperature is 1250-1280 ℃, and the heat preservation time is 120 min.
3. The composite color ceramic overglaze pigment decoration method of claim 1, wherein: the parameters of the sieving procedure in the step two are as follows: sieving with 350 mesh sieve to obtain 0 residue; the parameters of the sieving procedure in the fourth step are as follows: sieving with 250 mesh sieve to obtain 0 residue.
4. The composite color ceramic overglaze pigment decoration method of claim 1, wherein: the glossiness of the composite color ceramic overglaze pigment decoration product in the third step is 100-110%; the acid and alkali resistance is grade A; the lead and cadmium elution amount is lower than ISO 6486-2: 1999(E) Provisions and the U.S. California Standard.
5. The composite color ceramic overglaze pigment decoration method of claim 1, wherein: the decorative effect of the six-step composite color ceramic overglaze pigment decorative product comprises one or more of ancient color, pink color and new color.
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