CN101050060A - Low temperature ceramic color without lead on glaze, and preparation method - Google Patents

Low temperature ceramic color without lead on glaze, and preparation method Download PDF

Info

Publication number
CN101050060A
CN101050060A CNA2007100155411A CN200710015541A CN101050060A CN 101050060 A CN101050060 A CN 101050060A CN A2007100155411 A CNA2007100155411 A CN A2007100155411A CN 200710015541 A CN200710015541 A CN 200710015541A CN 101050060 A CN101050060 A CN 101050060A
Authority
CN
China
Prior art keywords
flux
lead
low temperature
glaze
ceramic color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007100155411A
Other languages
Chinese (zh)
Other versions
CN101050060B (en
Inventor
徐博
钱鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUAWEI PIYMENTS CO Ltd ZIBO
Original Assignee
HUAWEI PIYMENTS CO Ltd ZIBO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUAWEI PIYMENTS CO Ltd ZIBO filed Critical HUAWEI PIYMENTS CO Ltd ZIBO
Priority to CN200710015541A priority Critical patent/CN101050060B/en
Publication of CN101050060A publication Critical patent/CN101050060A/en
Application granted granted Critical
Publication of CN101050060B publication Critical patent/CN101050060B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

This invention relates to a low-temperature lead-free overglaze pigment, which is composed of lead-free pigment 8-30 wt.%, and lead- and cadmium-free flux 70-92 wt.%. The flux is composed of: SiO2 30-60 wt%, B2O3 5-35 wt.%, Al2O3 1.5-15 wt.%, K2O 1.5-10 wt.%, Na2O 1.5-10 wt.%, Li2O 0-8 wt.%, ZnO 0-15 wt.%, CaO 0-5 wt.%, CoO 0-10 wt.%, BaO 0-5 wt.%, MgO 1-5 wt.%, ZrO2 0-10 wt.%, SnO2 0-10 wt.%, and TiO2 0-5 wt.%. The low-temperature lead-free overglaze pigment has such advantages as no toxic or side effects, compact structure, high chemical stability, low baking temperature, beautiful color, high resistance to acid and base, appropriate thermal expansion coefficient, good luster, good decoration effect, and simple preparation.

Description

Low temperature ceramic color without lead on glaze and preparation method thereof
Technical field
The present invention relates to a kind of low temperature ceramic color without lead on glaze and preparation method thereof, belong to the beramic color technical field.
Background technology
Ceramic trailing the most widely is over-glaze decoration.Over-glaze decoration is to use under 750 ℃～850 ℃ low temperature, thus add 30～50% plumbous oxide in traditional production technique, so that the roasting burning temperature range of colour on glazed ceramics is wide and color development is pure.But plumbous in the production and use of beramic color, caused that to the pollution of atmosphere, water resources with to the injury of human body common people pay close attention to, the plumbous stripping on meal, kitchenware surface potential carcinogenic substance especially especially constitutes a threat to people's health.In order to reduce and to eradicate plumbous murder by poisoning, unremitting effort is being done always by the scientific research and the production department of ceramic decoration industry both at home and abroad.
In English Patent CB2250285A, invented a kind of unleaded ceramic pigment flux, its formation (mot%): SiO 2: 50～70, Bi 2O 3: 10～40 Al 2O 3: 3～30, B 2O 3: 0～15, Li 2O:0～10, Na 2O:0～10, K 2O:0～10, MgO:0～5, CaO:0～10, ZnO:0～10, ZrO 2: 0～5, TiO 2: 0～5, SnO 2: 0～5, MoO 3: 0～3, rare earth: 0～3.
Invent the flux of leadless glaze paint among the Chinese patent CN1044595C and formed (mot%): SiO 2: 55～80, Bi 2O 3: 1～8.5, B 2O 3: 3～15, Al 2O 3: 1～9, K 2O:0～9, Na 2O:0～9, Li 2O:0～9, BaO:0～4, SrO:0～4, ZrSiO 4: 1.5～12, SnO 2: 0.3～8.5, La 2O 3: 0～1, MgO:0～3, CaO:0～6, ZnO:0～4, TiO 2: 0～3.
These two patents are not difficult to find out from the formation of flux, give the colour on glazed ceramics temperature low, bright characteristics in order to replace plumbous oxide, all application in various degree Bi 2O 3Low-melting advantage, but it is said the toxicity of bismuth, especially Bi not second to lead 2O 3Introducing cause the glass phase-splitting easily, be difficult for forming uniform vitreum and cause the flux short texture, thereby influence chemical stability, character acidproof, alkaline-resisting etch also can descend, not just also can not cause the colour generation of toner in flux, and the roasting temperature of burning of its pigment is all between 830～950 ℃, and temperature is higher, and energy consumption is big.
Summary of the invention
The object of the present invention is to provide a kind of low temperature ceramic color without lead on glaze, have no side effect, compact structure, chemical stability be good, roasting to burn that temperature is low, the complete perfection of colour system, acid and alkali-resistance etch, matched coefficients of thermal expansion, colour generation is pure, beautiful in colour, glossiness is high, good decorating effect; The present invention provides its simple and easy to do preparation method simultaneously.
Low temperature ceramic color without lead on glaze of the present invention is made up of the unleaded toner of weight 8～30% and 70～92% lead-free and cadmium-free flux, and the weight percent of flux consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～15%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 0～8%, ZnO 0～15%, CaO 0～5%, CoO 0～10%, BaO 0～5%, MgO 1～5%, ZrO 20～10%, SnO 20～10% and TiO 20～5%.
Be suitable for green, blue green, Hai Lan, lake orchid, vanadium orchid, pitch black, silver grey, white, iron is red, the west is red, the flux weight percent of ochre and beans tea pigment consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, ZnO 1～15%, CaO 0～5%, ZrO 20～10%, TiO 20～5% and MgO 1～5%.
The flux weight percent that is suitable for not having pink, the no cadmium yellow look pigment of gold consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, SnO 20～5%, CaO 0～5%, MgO 1～5, BaO 0～5% and TiO 20～5%.
Be suitable for having the flux weight percent of pink, dark red, purplish red, the purple blue class pigment of gold to consist of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, SnO 23～10%, TiO 20～5%, MgO 1～5%, BaO 0～5% and ZnO 0～5%.
Be suitable for containing cadmium class toner, the flux weight percent of cadmium yellow, cadmium red, cadmium phthalocyanine consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O1.5～8%, TiO 23～5%, ZrO 23～10%, ZnO 0～10% and MgO 1～5%.
The flux weight percent that is suitable for cobalt aluminate class pigment consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, ZrO 23～10%, CoO 0～10%, SnO 23～10%, ZnO 1～10%, MgO 1～5% and BaO 0～5%.
Raw materials used technical pure chemical industry raw material or the reagent purifying worker raw material of being of component in the flux of the present invention, unleaded toner use the common unleaded toner of industry to get final product, and market is on sale, can directly buy.
Flux of the present invention, oxide compound that need not be plumbous not only, the influence stability of also need not existing domestic and international correlation technique utilizing and the expensive Bi of color development 2O 3, only with the conventional rich real and inexpensive SiO of reserves 2Al 2O 3And B 2O 3Deng the network constituting body that forms even compact, this lays a good foundation to preparation colour generation beramic color pure, that chemical stability is good.By the composite fluxing agent that a large amount of basic metal and alkaline-earth metal are formed, when reducing the flux melt temperature, improved the acid resistance of pigment greatly by mixed alkali effect.The acidic oxide ZrO of macromolecule low bulk 2, TiO 2, SnO 2Make the structure of flux tightr Deng not only, and cut down the increase of the coefficient of expansion that the adding of basic metal and alkaline-earth metal causes.Each component in the flux not only makes its every physical and chemical index all satisfy international standard, and has avoided the roasting burning temperature height of similar products at home and abroad, the drawback that price is high through the experimental formula of a large amount of scientific and precises.
The preparation method of low temperature ceramic color without lead on glaze of the present invention, simple and easy to do, at first prepare flux, and then preparation pigment, carry out according to following step successively:
(1) preparation of flux: each the flux component raw material that will cross 80～120 mesh sieves mixes, and after the high-temperature fusion, after the cold water shrend, it is standby that oven dry makes unleaded flux;
(2) preparation of pigment: oven dry pulverizing after unleaded flux and the unleaded toner mixing and ball milling is made the work in-process powder;
(3) with half product powder resintering, increase the density and the vividness of pigment, pulverize through secondary ball milling again and make pigment product.
Wherein Kong Zhi optimal processing parameter is respectively:
The melt temperature of flux is 1250～1350 ℃.
The resintering temperature is 700～800 ℃.
The ball mill pulverizing fineness is controlled to be particle diameter＜10um before the resintering, and the ball mill pulverizing fineness is controlled to be particle diameter＜5um behind the resintering.
Low temperature ceramic color without lead on glaze of the present invention, unleaded stripping, have no side effect, compact structure, chemical stability be good, roasting to burn that temperature is low, the complete perfection of colour system, acid and alkali-resistance etch, matched coefficients of thermal expansion, colour generation is pure, beautiful in colour, glossiness is high, good decorating effect.
Low temperature ceramic color without lead on glaze of the present invention, using method is identical with common beramic color, and use temperature is 700～800 ℃, soaking time 8～20 minutes.
Through screen printing, directly print or be sprayed at the ceramic surface, under 700～800 ℃ of temperature, be incubated 8～20 minutes, it is as follows to survey its physicochemical property:
1. glossiness: 80～90%, utilize the digital glossometer of GM-26D type that color technical institute produces in the Japanese strain formula people's commune village, record 45 ° glossiness according to its technical qualification.
2. thermal expansivity: 4.0～7.0 * 10 -6C -1, utilize West Germany to produce 402E type electronic dilatometer.
3. chemical stability: lead release is 0.00mg/dm 2, the pigment variety quantity of cadmium release that part contains the cadmium toner is 0.1～0.26mg/dm 2, soaked 24 hours in 4% acetum down through 22 ± 2 ℃, or 60 ± 2 ℃ of following 0.5%NaCO 3Soak after 40 hours tone, the equal no change of color and luster in the solution.
Compare with existing beramic color, low temperature ceramic color without lead on glaze of the present invention has the following advantages:
1. thoroughly eradicate plumbous murder by poisoning, environment protection health.
2. the roasting temperature of burning is low, and under the well sold and in short supply day by day reality of the energy, energy-saving and cost-reducing just seeming means a great.
3. cost reduces, because of there not being expensive Bi 2O 3Introducing make production cost reduce greatly.
4. colour generation is pure, and glossiness is good, and the roasting temperature range of burning is wide, and chemical stability is good, the acid and alkali-resistance etch.
5. processing performance is good, is applicable to processing methodes such as screen printing, planography, aerograph, Freehandhand-drawing, repairing.
6. use range is wide, can be used for the decoration of multiple ceramics such as hard-paste, soft porcelain, stoneware, fine earthenware, sclerotin porcelain, glass-ceramic, is specially adapted to the decoration of leadless glaze pottery.
Embodiment
The invention will be further described below in conjunction with embodiment.
Low temperature ceramic color without lead on glaze embodiment 1-8 flux weight percent of the present invention is formed and the adapted toner sees Table 1.
Table 1, embodiment 1-8 flux weight percent are formed (%wt) and adapted toner information slip
Embodiment 1 2 3 4 5 6 7 8
SiO 2 44.0 47.3 50.5 39.0 44.6 52.5 50.5 53.5
B 2O 3 28.5 27.6 20.5 26.5 29.5 20.1 22.1 19.1
Al 2O 3 2.5 2.1 3.5 2.8 3.8 2.8 3.0 2.7
Li 2O 0.0 0.0 1.8 2.5 4.5 2.9 2.7 3.0
Na 2O 7.8 6.8 5.0 5.5 5.8 4.5 4.0 5.5
K 2O 3.5 4.5 2.2 7.5 3.6 4.5 5.0 3.5
CaO 1.9 1.5 0.0 0.0 2.5 0.0 0.0 0.0
MgO 1.5 1.2 1.5 3.5 1.7 2.3 2.5 2.3
SnO 2 0.0 0.0 4.5 6.2 0.0 0.0 0.0 0.0
ZrO 2 3.5 2.8 3.5 0.0 0.0 4.0 3.8 3.5
TiO 2 2.3 1.9 0.0 1.5 1.5 3.5 3.2 4.0
ZnO 4.5 4.3 1.5 3.5 0.0 2.9 3.2 2.9
CoO 0.0 0.0 5.5 0.0 0.0 0.0 0.0 0.0
BaO 0.0 0.0 0.0 1.5 2.5 0.0 0.0 0.0
Toner (%wt) Iron oxide red 20 Titanium chrome yellow 30 Cobalt aluminate 25 Golden red 6% Chromium tin pink 30 Cadmium yellow 20 Chrome green 15 cadmium yellows 5 Cadmium red 12 cadmium yellows 5
Material fineness (order) 110 100 100 120 80 90 100 100
Melt temperature (℃) 1250 1220 1250 1260 1300 1280 1230 1260
The resintering temperature (℃) 750 730 760 750 780 800 720 740
Ball mill pulverizing control particle diameter＜10um before the resintering, ball mill pulverizing control particle diameter＜5um behind the resintering.
The resintering ball mill pulverizing is after go out mill, oven dry, pulverizing aftertreatment, packing at last.
Embodiment 1-8 technical indicator detected result sees Table 2.
Table 2, embodiment 1-8 technical indicator detected result table
The embodiment sequence number Lead release (mg/dm 2) Quantity of cadmium release (mg/dm 2) Glossiness (%) The coefficient of expansion 10 -6C -1
Roasting burning temperature (℃) Roasting burning temperature (℃) Roasting burning temperature (℃)
700 750 800 700 750 800 700 750 800
1 0.00 0.00 0.00 0.00 0.00 0.00 69.8 77.9 78.2 6.23
2 0.00 0.00 0.00 0.00 0.00 0.00 68.0 75.9 77.5 6.18
3 0.00 0.00 0.00 0.00 0.00 0.00 70.1 72.9 73.6 6.09
4 0.00 0.00 0.00 0.00 0.00 0.00 68.7 78.6 79.0 6.12
5 0.00 0.00 0.00 0.00 0.00 0.00 68.3 73.8 75.0 6.55
*6 0.00 0.00 0.00 0.20 0.18 0.15 71.0 75.3 76.1 6.51
*7 0.00 0.00 0.00 0.22 0.16 0.15 68.2 74.1 76.3 6.32
*8 0.00 0.00 0.00 0.19 0.13 0.13 71.5 73.9 78.1 6.34
Annotate: band * person represents to contain cadmium in the toner composition of lead-free pigment.

Claims (10)

1, a kind of low temperature ceramic color without lead on glaze is characterized in that being made up of the unleaded toner of weight 8～30% and 70～92% lead-free and cadmium-free flux, and the weight percent of flux consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～15%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 0～8%, ZnO 0～15%, CaO 0～5%, CoO 0～10%, BaO 0～5%, MgO 1～5%, ZrO 20～10%, SnO 20～10% and TiO 20～5%.
2, low temperature ceramic color without lead on glaze according to claim 1, it is characterized in that being suitable for green, blue green, Hai Lan, lake orchid, vanadium orchid, pitch black, silver grey, white, iron is red, the west is red, the flux weight percent of ochre and beans tea pigment consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, ZnO 1～15%, CaO 0～5%, ZrO 20～10%, TiO 20～5% and MgO1～5%.
3, low temperature ceramic color without lead on glaze according to claim 1, the flux weight percent that it is characterized in that being suitable for not having pink, the no cadmium yellow look pigment of gold consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, SnO 20～5%, CaO 0～5%, MgO 1～5, BaO 0～5% and TiO 20～5%.
4, low temperature ceramic color without lead on glaze according to claim 1 is characterized in that being suitable for having the flux weight percent of pink, dark red, purplish red, the purple blue class pigment of gold to consist of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, SnO 23～10%, TiO 20～5%, MgO 1～5%, BaO 0～5% and ZnO 0～5%.
5, low temperature ceramic color without lead on glaze according to claim 1 is characterized in that being suitable for containing cadmium class toner, and the flux weight percent of cadmium yellow, cadmium red, cadmium phthalocyanine consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O1.5～8%, TiO 23～5%, ZrO 23～10%, ZnO 0～10% and MgO 1～5%.
6, low temperature ceramic color without lead on glaze according to claim 1 is characterized in that the flux weight percent that is suitable for cobalt aluminate class pigment consists of:
SiO 230～60%, B 2O 35～35%, Al 2O 31.5 K～10%, 2O 1.5～10%, Na 2O 1.5～10%, Li 2O 1.5～8%, ZrO 23～10%, CoO 0～10%, SnO 23～10%, ZnO 1～10%, MgO 1～5% and BaO 0～5%.
7, the described low temperature ceramic color without lead on glaze preparation method of a kind of claim 1 at first prepares flux, and then preparation pigment, it is characterized in that carrying out according to following step successively:
(1) preparation of flux: each the flux component raw material that will cross 80～120 mesh sieves mixes, and after the high-temperature fusion, after the cold water shrend, it is standby that oven dry makes unleaded flux;
(2) preparation of pigment: oven dry pulverizing after unleaded flux and the unleaded toner mixing and ball milling is made the work in-process powder;
(3) with behind the half product powder resintering, pulverizing makes pigment product through secondary ball milling.
8, low temperature ceramic color without lead on glaze preparation method according to claim 7, the melt temperature that it is characterized in that flux is 1250～1350 ℃.
9, low temperature ceramic color without lead on glaze preparation method according to claim 7 is characterized in that the resintering temperature is 700～800 ℃.
10, according to claim 7,8 or 9 described low temperature ceramic color without lead on glaze preparation methods, it is characterized in that the preceding ball mill pulverizing fineness of resintering is controlled to be particle diameter＜10um, the ball mill pulverizing fineness is controlled to be particle diameter＜5um behind the resintering.
CN200710015541A 2007-05-15 2007-05-15 Low temperature ceramic pigment without lead on glaze Expired - Fee Related CN101050060B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200710015541A CN101050060B (en) 2007-05-15 2007-05-15 Low temperature ceramic pigment without lead on glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200710015541A CN101050060B (en) 2007-05-15 2007-05-15 Low temperature ceramic pigment without lead on glaze

Publications (2)

Publication Number Publication Date
CN101050060A true CN101050060A (en) 2007-10-10
CN101050060B CN101050060B (en) 2010-05-19

Family

ID=38781693

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200710015541A Expired - Fee Related CN101050060B (en) 2007-05-15 2007-05-15 Low temperature ceramic pigment without lead on glaze

Country Status (1)

Country Link
CN (1) CN101050060B (en)

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100588630C (en) * 2008-08-04 2010-02-10 江苏拜富色釉料有限公司 Glass lead-free pigment and method for preparing the same
WO2010109218A1 (en) * 2009-03-25 2010-09-30 Johnson Matthey Public Limited Company Fire retardant comprising glass frit in combination with an additive
CN102718570A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free black frit for ceramic preparation
CN102718561A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free matte frit for preparing ceramics
CN102718562A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Leaded milky-white frit for ceramic preparation
CN102718558A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing matt frit for ceramics preparation
CN102718571A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Acid and alkali-resistant lead-free transparent frit for ceramics preparation
CN102718568A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Colored frit for ceramics preparation
CN102718565A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free opalescent frit
CN102718574A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Good-waterproofness lead-free transparent frit for preparing ceramics
CN102718566A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free yellow frit for ceramics preparation
CN102718564A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing opalescent frit
CN102718560A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing frit for low-temperature ceramics preparation
CN102718563A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Color-unchangeable lead-containing opalescent frit
CN102718569A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free red wear-resistant frit for ceramics preparation
CN102718557A (en) * 2012-05-31 2012-10-10 潮州宏业陶瓷制作厂有限公司 High-grade stripe iron red crystallization transmutation ceramic glaze for daily use
CN103466948A (en) * 2013-08-15 2013-12-25 河北省沙河玻璃技术研究院 Leadless environmentally-friendly glass glaze, preparation method thereof, and glazed surface preparation method
CN104387119A (en) * 2014-10-22 2015-03-04 华文蔚 Titanium dioxide photocatalytic self-cleaning ceramic and preparation method thereof
CN104513066A (en) * 2013-09-30 2015-04-15 佛山市柯林瓷砖护理用品有限公司 Low temperature ceramic glaze manufacturing method
RU2609501C1 (en) * 2015-12-07 2017-02-02 Юлия Алексеевна Щепочкина Glaze
CN107188414A (en) * 2017-07-17 2017-09-22 中国轻工业陶瓷研究所 A kind of unleaded rake pattern material base glaze and its application process
CN107201060A (en) * 2017-05-19 2017-09-26 淄博华为颜料有限公司 Lead-free low-temperature low cobalt ceramic glaze blueing pigment and its preparation method and application
CN107324654A (en) * 2017-07-17 2017-11-07 中国轻工业陶瓷研究所 A kind of snow-white pigment of unleaded powder enamel and its application process
CN107352800A (en) * 2017-07-17 2017-11-17 中国轻工业陶瓷研究所 A kind of unleaded enamel brightness base glaze and its application process
CN107540218A (en) * 2017-09-30 2018-01-05 浙江工业大学之江学院 A kind of matt pink crystalline glaze and the method for firing matt pink crystalline glaze
CN107673614A (en) * 2017-09-30 2018-02-09 浙江工业大学之江学院 A kind of matt Blue crystalline glaze material and the method for firing matt Blue crystalline glaze
CN110066109A (en) * 2019-05-28 2019-07-30 江西陶瓷工艺美术职业技术学院 A kind of traditional decoration pigment flux and its application method
CN110092638A (en) * 2019-04-18 2019-08-06 大宋官窑股份有限公司 A kind of brightness base glaze, brightness glaze pottery and preparation method thereof
CN111646701A (en) * 2020-06-06 2020-09-11 景德镇市民俗文化瓷业有限公司 Composite color ceramic overglaze pigment decoration method
CN112479728A (en) * 2020-12-23 2021-03-12 河南通宇冶材集团有限公司 Chromium-free environment-friendly fluxing agent for drainage agent, drainage agent and preparation method
CN116143399A (en) * 2022-11-03 2023-05-23 山东省淄博市博山长虹陶瓷装饰材料厂 Lead-free low-cadmium leaching ceramic pigment flux, ceramic pigment and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZW13689A1 (en) * 1988-11-19 1989-12-12 Johnson Matthey Plc Glass composition for use in glazes or enamels
DE102005004068B4 (en) * 2005-01-24 2008-01-17 Schott Ag Lead- and cadmium-free glass and process for glazing, enamelling and decorating of glasses or glass-ceramics as well as use of the glass
CN100465234C (en) * 2006-04-11 2009-03-04 山东省淄博市博山长虹陶瓷装饰材料厂 Lead-free low-cadmium stripping quantity selenium-cadmium dye, preparing method and using method thereof
CN100376502C (en) * 2006-06-14 2008-03-26 山东硅苑新材料科技股份有限公司 Leadfree fritted glaze suitable for secondary sintering

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100588630C (en) * 2008-08-04 2010-02-10 江苏拜富色釉料有限公司 Glass lead-free pigment and method for preparing the same
WO2010109218A1 (en) * 2009-03-25 2010-09-30 Johnson Matthey Public Limited Company Fire retardant comprising glass frit in combination with an additive
CN102718557A (en) * 2012-05-31 2012-10-10 潮州宏业陶瓷制作厂有限公司 High-grade stripe iron red crystallization transmutation ceramic glaze for daily use
CN102718557B (en) * 2012-05-31 2014-04-09 潮州宏业陶瓷制作厂有限公司 High-grade stripe iron red crystallization transmutation ceramic glaze for daily use
CN102718558A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing matt frit for ceramics preparation
CN102718564A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing opalescent frit
CN102718561A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free matte frit for preparing ceramics
CN102718562A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Leaded milky-white frit for ceramic preparation
CN102718565A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free opalescent frit
CN102718563A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Color-unchangeable lead-containing opalescent frit
CN102718560A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-containing frit for low-temperature ceramics preparation
CN102718566A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free yellow frit for ceramics preparation
CN102718574A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Good-waterproofness lead-free transparent frit for preparing ceramics
CN102718569A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free red wear-resistant frit for ceramics preparation
CN102718568A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Colored frit for ceramics preparation
CN102718571A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Acid and alkali-resistant lead-free transparent frit for ceramics preparation
CN102718570A (en) * 2012-06-12 2012-10-10 卡罗比亚釉料（昆山）有限公司 Lead-free black frit for ceramic preparation
CN103466948A (en) * 2013-08-15 2013-12-25 河北省沙河玻璃技术研究院 Leadless environmentally-friendly glass glaze, preparation method thereof, and glazed surface preparation method
CN104513066B (en) * 2013-09-30 2017-02-08 佛山市克里普斯科技有限公司 Low temperature ceramic glaze manufacturing method
CN104513066A (en) * 2013-09-30 2015-04-15 佛山市柯林瓷砖护理用品有限公司 Low temperature ceramic glaze manufacturing method
CN104387119A (en) * 2014-10-22 2015-03-04 华文蔚 Titanium dioxide photocatalytic self-cleaning ceramic and preparation method thereof
CN104387119B (en) * 2014-10-22 2016-11-30 五行科技股份有限公司 Photocatalystic self-cleaning TiO 2 ceramic and preparation method thereof
RU2609501C1 (en) * 2015-12-07 2017-02-02 Юлия Алексеевна Щепочкина Glaze
CN107201060B (en) * 2017-05-19 2019-05-17 淄博华为颜料有限公司 Lead-free low-temperature low cobalt ceramic glaze blueing pigment and its preparation method and application
CN107201060A (en) * 2017-05-19 2017-09-26 淄博华为颜料有限公司 Lead-free low-temperature low cobalt ceramic glaze blueing pigment and its preparation method and application
CN107324654A (en) * 2017-07-17 2017-11-07 中国轻工业陶瓷研究所 A kind of snow-white pigment of unleaded powder enamel and its application process
CN107188414A (en) * 2017-07-17 2017-09-22 中国轻工业陶瓷研究所 A kind of unleaded rake pattern material base glaze and its application process
CN107352800A (en) * 2017-07-17 2017-11-17 中国轻工业陶瓷研究所 A kind of unleaded enamel brightness base glaze and its application process
CN107540218B (en) * 2017-09-30 2021-01-05 浙江工业大学之江学院 Matte pink crystal glaze and method for firing matte pink crystal glaze
CN107540218A (en) * 2017-09-30 2018-01-05 浙江工业大学之江学院 A kind of matt pink crystalline glaze and the method for firing matt pink crystalline glaze
CN107673614A (en) * 2017-09-30 2018-02-09 浙江工业大学之江学院 A kind of matt Blue crystalline glaze material and the method for firing matt Blue crystalline glaze
CN110092638A (en) * 2019-04-18 2019-08-06 大宋官窑股份有限公司 A kind of brightness base glaze, brightness glaze pottery and preparation method thereof
CN110066109B (en) * 2019-05-28 2022-02-22 江西陶瓷工艺美术职业技术学院 Flux for antique pigment and application method thereof
CN110066109A (en) * 2019-05-28 2019-07-30 江西陶瓷工艺美术职业技术学院 A kind of traditional decoration pigment flux and its application method
CN111646701A (en) * 2020-06-06 2020-09-11 景德镇市民俗文化瓷业有限公司 Composite color ceramic overglaze pigment decoration method
CN111646701B (en) * 2020-06-06 2022-05-20 景德镇市民俗文化瓷业有限公司 Method for decorating composite color ceramic with overglaze pigment
CN112479728A (en) * 2020-12-23 2021-03-12 河南通宇冶材集团有限公司 Chromium-free environment-friendly fluxing agent for drainage agent, drainage agent and preparation method
CN112479728B (en) * 2020-12-23 2022-10-18 河南通宇冶材集团有限公司 Chromium-free environment-friendly fluxing agent for drainage agent, drainage agent and preparation method
CN116143399A (en) * 2022-11-03 2023-05-23 山东省淄博市博山长虹陶瓷装饰材料厂 Lead-free low-cadmium leaching ceramic pigment flux, ceramic pigment and preparation method thereof

Also Published As

Publication number Publication date
CN101050060B (en) 2010-05-19

Similar Documents

Publication Publication Date Title
CN101050060B (en) Low temperature ceramic pigment without lead on glaze
CN101050061B (en) Pigment without lead for glass
CN101054312A (en) Lead-free cadmium-free ceramic pigment on glaze and preparation method thereof
CN101759441B (en) Ceramic glaze and preparation process thereof
CN102643023B (en) Environmental-friendly black glaze for automotive glass and preparation method of black glaze
CN111233520B (en) Starry sky blue transmutation glaze, preparation method thereof and sanitary ceramic using glaze
CN1765836B (en) Ceramic glaze with metal sense of reality
CN101209903B (en) High-temperature resistant lead-less glass powder for glass fiber net printing ink, preparation and application thereof
CN101759440A (en) Lead-free ceramic glaze and preparation process thereof
CN101768016A (en) Enamel color ceramic glaze and production process and application thereof
CN103466948A (en) Leadless environmentally-friendly glass glaze, preparation method thereof, and glazed surface preparation method
CN104478217B (en) A kind of environmentally friendly copper ruby glass glaze, its preparation method and the method for copper ruby glass glaze paint is prepared by it
JPH05270860A (en) Lead-and cadmium-free glass composition for glazing, enameling and decorating and its use
CN108191239A (en) A kind of unleaded metallic luster gold glaze and preparation method thereof
CN86105779A (en) Coating glaze for low quality blank
CN101050059B (en) Covering layer without lead, cadmium of pigment without lead on ceramic glaze, and preparation method
CN101255065A (en) Low-temperature glaze leadless cadmium-free ceramic pigment flux
CN100528812C (en) Method for formulating moderate temperature bright red glaze
CN101066895A (en) Ceramic brightening glaze and its prepn process
CN107540388B (en) High-temperature pink ceramic, preparation method and application thereof
CN104973784A (en) Over-glaze lead-cadmium-free low-temperature ceramic pigment flux
CN1151989C (en) Overglaze cobalt blue pigment for ceramic and its preparation
CN102101794B (en) Production process of glazed low-temperature bright-red glaze and ceramic products thereof
CN1021112C (en) Low-temp. ceramic glazing dyestuff and its preparation method
CN103664230A (en) Lead-free ceramic pigment on low-temperature glaze

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20100519

Termination date: 20150515

EXPY Termination of patent right or utility model