CN102718574A - Good-waterproofness lead-free transparent frit for preparing ceramics - Google Patents
Good-waterproofness lead-free transparent frit for preparing ceramics Download PDFInfo
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- CN102718574A CN102718574A CN2012101915282A CN201210191528A CN102718574A CN 102718574 A CN102718574 A CN 102718574A CN 2012101915282 A CN2012101915282 A CN 2012101915282A CN 201210191528 A CN201210191528 A CN 201210191528A CN 102718574 A CN102718574 A CN 102718574A
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- lead
- waterproofness
- unleaded
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Abstract
The invention discloses a good-waterproofness lead-free transparent frit for preparing ceramics. The lead-free transparent frit is prepared from following raw materials in parts by weight: 50-60 parts of SiO, 5-10 parts of Al2O3, 1-5 parts of TiO2, 1-5 parts of CaO, 1-5 parts of ZnO and 10-20 parts of B2O3. According to the good-waterproofness lead-free transparent frit for preparing ceramics provided by the invention, the optimal composition and proportion are determined by the screening of a large amount of experiment, all the components are proportioned scientifically and reasonably, particularly, the waterproof property is good, water can not leak easily, the service life is long, lead does not exist, and the environment is protected.
Description
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Technical field
The present invention relates to a kind of frit for preparing ceramic usefulness, be specifically related to a kind of unleaded clear frit of good waterproof performance of ceramic usefulness.
Background technology
The ceramic goods are widely used in the daily life, as are widely used in kitchen, toilet, fields such as outdoor bathing place; But the frit that the general potting of prior art is used exists water resistance relatively poor, the long-time use, and ceramic tile is permeable easily; Bring inconvenience, and the pottery of prior art exists opaquely more, can cover the material color; Can not show the shortcomings such as quality of material, and be added with heavy metal lead more, the feature of environmental protection is relatively poor.Therefore, necessary on the basis of prior art, a kind of water resistance of research and development designs is good, the unleaded clear frit of Environmental Safety, transparent good waterproof performance.
Summary of the invention
Goal of the invention: technical problem to be solved by this invention is the deficiency that overcomes prior art, and a kind of metallic lead that do not add is provided, safety and environmental protection, transparent good, the unleaded clear frit of good waterproof performance.
Technical scheme: for solving above technical problem, the present invention takes following technical scheme:
A kind of unleaded clear frit of good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
250 ~ 60 parts, Al
2O
35 ~ 10 parts, TiO
21 ~ 5 part, 1 ~ 5 part of CaO, 1 ~ 5 part of ZnO, B
2O
310 ~ 20 parts.
As preferred version, the unleaded clear frit of above-described good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
250 ~ 55 parts, Al
2O
35 ~ 8 parts, TiO
21 ~ 3 part, 1 ~ 3 part of CaO, 1 ~ 3 part of ZnO, B
2O
310 ~ 15 parts.
As more preferably scheme, the unleaded clear frit of above-described good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
250 parts, Al
2O
38 parts, TiO
23 parts, 3 parts of CaO, 3 parts of ZnO, B
2O
315 parts.
The present invention is according to the specification of quality of potting with clear frit, confirms composition and the ratio of each component of the unleaded clear frit of good waterproof performance through a large amount of experiments, the unleaded clear frit of good waterproof performance provided by the invention; Various physico-chemical properties meet the requirements; Fire the smooth exquisiteness of the glaze that obtains, the transparency is good, and especially water resistance is good; Be difficult for permeable, long service life.The unleaded clear frit specific product parameter of this good waterproof performance is:
Thermal expansivity 66, change point (degree) 560, expansion softening temperature (degree) 640, sintering point (degree) 650, softening temperature (degree) 780, ball point (degree) 920, hemisphere point (degree) 1060, each item character meets the requirements, Functionality, quality and appealing design.
Beneficial effect: the unleaded clear frit of good waterproof performance provided by the invention is compared with prior art has following advantage:
The unleaded clear frit of the good waterproof performance of the ceramic usefulness of preparation provided by the invention is formed and proportioning according to the best of the preferred frit of a large amount of experiments, and the Ceramic glaze slickness for preparing with frit provided by the invention is good; Especially water resistance is good; Be difficult for permeable, long service life, and do not add the metal lead; Environmental protection, safety performance height, the scope of application is extensive.
Embodiment
Below in conjunction with specific embodiment; Further illustrate the present invention; Should understand these embodiment only be used to the present invention is described and be not used in the restriction scope of the present invention; After having read the present invention, those skilled in the art all fall within the application's accompanying claims institute restricted portion to the modification of the various equivalent form of values of the present invention.
Embodiment 1
A kind of unleaded clear frit of good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
260 parts, Al
2O
310 parts, TiO
25 parts, 5 parts of CaO, ZnO5 part, B
2O
320 parts, K
2CO
320 parts.
Embodiment 2
A kind of unleaded clear frit of good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
250 parts, Al
2O
35 parts, TiO
21 part, 1 part of CaO, 1 part of ZnO, B
2O
310 parts, K
2CO
310 parts.
Embodiment 3
A kind of unleaded clear frit of good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
255 parts, Al
2O
38 parts, TiO
23 parts, 3 parts of CaO, 3 parts of ZnO, B
2O
315 parts, Na
2CO
315 parts.
Embodiment 4
A kind of unleaded clear frit of good waterproof performance, it is processed by the raw material of following parts by weight:
SiO
250 parts, Al
2O
38 parts, TiO
23 parts, 3 parts of CaO, 3 parts of ZnO, B
2O
315 parts, Na
2CO
315 parts.
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (3)
1. the unleaded clear frit of a good waterproof performance is characterized in that, it is processed by the raw material of following parts by weight:
SiO
250 ~ 60 parts, Al
2O
35 ~ 10 parts, TiO
21 ~ 5 part, 1 ~ 5 part of CaO, 1 ~ 5 part of ZnO, B
2O
310 ~ 20 parts.
2. the unleaded clear frit of good waterproof performance according to claim 1 is characterized in that, it is processed by the raw material of following parts by weight:
SiO
250 ~ 55 parts, Al
2O
35 ~ 8 parts, TiO
21 ~ 3 part, 1 ~ 3 part of CaO, 1 ~ 3 part of ZnO, B
2O
310 ~ 15 parts.
3. the unleaded clear frit of good waterproof performance according to claim 1 is characterized in that, it is processed by the raw material of following parts by weight:
SiO
250 parts, Al
2O
38 parts, TiO
23 parts, 3 parts of CaO, 3 parts of ZnO, B
2O
315 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101915282A CN102718574A (en) | 2012-06-12 | 2012-06-12 | Good-waterproofness lead-free transparent frit for preparing ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101915282A CN102718574A (en) | 2012-06-12 | 2012-06-12 | Good-waterproofness lead-free transparent frit for preparing ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102718574A true CN102718574A (en) | 2012-10-10 |
Family
ID=46944481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101915282A Pending CN102718574A (en) | 2012-06-12 | 2012-06-12 | Good-waterproofness lead-free transparent frit for preparing ceramics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102718574A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050060A (en) * | 2007-05-15 | 2007-10-10 | 淄博华为颜料有限公司 | Low temperature ceramic color without lead on glaze, and preparation method |
| CN101585717A (en) * | 2009-06-22 | 2009-11-25 | 张垠 | Lead and cadmium free fritted glaze for bone China with high acid resistance and alkali resistance |
-
2012
- 2012-06-12 CN CN2012101915282A patent/CN102718574A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050060A (en) * | 2007-05-15 | 2007-10-10 | 淄博华为颜料有限公司 | Low temperature ceramic color without lead on glaze, and preparation method |
| CN101585717A (en) * | 2009-06-22 | 2009-11-25 | 张垠 | Lead and cadmium free fritted glaze for bone China with high acid resistance and alkali resistance |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121010 |