CN106630633B - A kind of five color painting in the glaze polishing glazed tile and preparation method thereof - Google Patents
A kind of five color painting in the glaze polishing glazed tile and preparation method thereof Download PDFInfo
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- CN106630633B CN106630633B CN201611231101.5A CN201611231101A CN106630633B CN 106630633 B CN106630633 B CN 106630633B CN 201611231101 A CN201611231101 A CN 201611231101A CN 106630633 B CN106630633 B CN 106630633B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Engineering & Computer Science (AREA)
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- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
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Abstract
The present invention includes overglaze and polishing glaze, on the basis of the production technology not to existing glazed tile makes great change, formula composition of the emphasis to overglaze, polish the formula composition of glaze, overglaze melts the preferred of temperature difference with the polishing glaze beginning, the preferred and sequence of ink-jet printing ink color category, the adjustment and optimization of glazing process, to make five color painting in the glaze polishing glazed tile product pattern various colors obtained, clean mark is natural, it is bright in luster, three-dimensional sense is strong, smooth such as mirror, seemingly one block of transparent glass is covered on pattern, it is not more bright-coloured enough than overglaze color color to breach underglaze colour color, color global problem not abundant enough, also by traditional five color painting in the glaze technique, this Chinese culture rarity is led to a new high degree, to make the poetic and pictorial splendor of painting porcelain appear vividly on ceramic wall and floor bricks face, make us pleasing, with height Decorative and artistry；The technology has stronger universality simultaneously, is easy in industry promote.
Description
Technical field:
The present invention relates to the preparation technical field of glazed tile more particularly to a kind of five color painting in the glaze polishing glazed tile and its preparations
Method.
Background technique:
The picture light of underglaze colour is soft, non-discolouring, corrosion-resistant, do not wear, and this trailing is firstly appeared in the Tang Dynasty Changsha
Kiln, Song Dynasty Cizhouyao inherit this tradition, and Jing Dezhen is developed after the Yuan Dynasty, but the tone of underglaze colour is rich not as good as overglaze color
It is rich colorful, until the late Qing Dynasty Hunan Liling has initiated five color painting in the glaze, the tone of underglaze colour is just enable to enrich, but such as some rare
For example gorgeous bright red colour system of colour system or not ideal enough, bright red colour cast is dark, partially grey, not bright-coloured enough, and colour gamut is also not broad enough, and passes
The decoration of system five color painting in the glaze is applied on domestic ceramics or bone china, and in the glaze brick product of large-scale production
Upper rare report, therefore as can the top grade art that this five color painting in the glaze is developed in the Wall or floor tile technology of large-scale production is precious
Product make the poetic and pictorial splendor of painting porcelain appear vividly happy on ceramic wall and floor bricks face, making us the reward heart by the auxiliary patch of common Wall or floor tile
Mesh, aesthetic is strong, leads this Chinese culture rarity of traditional five color painting in the glaze technique to new high degree.
Summary of the invention:
It is an object of the invention to overcome disadvantages mentioned above, a kind of five color painting in the glaze polishing glazed tile and preparation method thereof is provided,
On the basis of not making great change to existing glazed tile production technology, matched by formula composition to overglaze, polishing glaze
The beginning of Fang Zucheng, overglaze and polishing glaze melt preferred, ink-jet printing ink type preferred, ink-jet printing ink the row of temperature difference
The adjustment and optimization of sequence, glazing process, to make glazed tile product pattern various colors, smoothly such as mirror, clear patterns obtained
It is natural, bright in luster, three-dimensional sense is strong, as one block of transparent glass is covered on pattern, the colour generation color of pattern after tested, red ash
Spend the L of the pattern color at 100%*(brightness) value is 56.2~58.3, a*(redness) value is 48.5~52.8, b*(yellowing) value
31.2~33.7, red and blue gray scale is respectively the L of the pattern color at 50%*(brightness) value is 51.6~53.3, a*(redness)
Value is 9.4~11.2, b*(yellowing) value is 6.8~12.6, and red and yellow gray scale is respectively the L of the pattern color at 50%*It is (bright
Degree) value be 63.6~68.5, a*(redness) value is 31.4~34.7, b*(yellowing) value is 39.2~43.5, red and brown gray scale
It is respectively the L of the pattern color at 50%*(brightness) value is 53.2~54.9, a*(redness) value is 34.8~37.4, b*(yellowing) value
It is 32.9~38.5.Breach that traditional five color painting in the glaze color development is not bright-coloured enough, colour gamut is not wide, especially bright red colour cast is dark, partially grey
Problem, by traditional five color painting in the glaze technique, this Chinese culture rarity is led to a new high degree, to make the poetics of painting porcelain
It draws meaning to appear vividly on ceramic wall and floor bricks, making us pleasing, and product glaze quality is good, corrosion resistance and resistance to soiling are strong, wear-resisting
Spend the defects of high, pin-free, glaze steeps；The technology has stronger universality simultaneously, is easy in industry promote.
In order to solve the above technical problems, the invention is realized by the following technical scheme:
A kind of five color painting in the glaze of the invention polishes glazed tile comprising:
Overglaze: it is prepared by following weight percent composition:
SiO259.2%~59.8%, Al2O316.2%~16.8%, CaO 7.2%~8%, MgO 0.3%~
0.9%, K2O 3%~4%, Na2O 0.8%~1.6%, TiO20.6%~1.2%, ZrO24.2%~4.8%, ZnO
2.6%~3.2%, B2O31.4%~2.2%, Li2O 0.2%~0.4%, CeO20.8%~1.2%, burning decrement
1.4%~1.8%, the sum of all components are 100%；
The auxiliary material that added weight percentage is 0.2%~0.4%, additional auxiliary material therein includes carboxymethyl
Cellulose and sodium tripolyphosphate；
The initial melting temperature of the overglaze be 790 DEG C~800 DEG C, glaze volume be 570~610g/ ㎡, the glaze volume be containing
Water glaze slip weight；
Ink-jet printed ink color and distributing order are as follows: blue-brown-yellow-pink colour-large red；
It polishes glaze: being prepared by following weight percent composition:
SiO249.2%~50.2%, Al2O312.2%~13.2%, CaO 11.5%~12.5%, MgO 0.4%
~0.8%, K2O 2.4%~3.2%, Na2O 0.6%~1.2%, TiO20.2%~0.6%, ZrO21.8%~
2.4%, BaO 5.8%~6.4%, B2O31%~2%, ZnO 4.2%~4.8%, SrO 1.2%~2%, burning decrement
4.5%~5.5%, the sum of all components are 100%；
The auxiliary material that added weight percentage is 0.3%~0.7%, additional auxiliary material therein includes carboxymethyl
Cellulose, sodium tripolyphosphate and waterglass；
The initial melting temperature of the polishing glaze is 840 DEG C~850 DEG C, and glaze volume is 480~500g/ ㎡, and the glaze volume is
Aqueous glaze slip weight；
Finished surface various colors, the smooth such as mirror, clear patterns nature, color of five color painting in the glaze polishing glazed tile of the invention
It is color it is bright-coloured, three-dimensional sense is strong, as one block of transparent glass is covered on pattern, the colour generation color of pattern after tested, red gray scale
The brightness L of pattern color at 100%*Value is 56.2~58.3, redness a*Value is 48.5~52.8, yellowing b*Value 31.2~
33.7, red and blue gray scale is respectively the brightness L of the pattern color at 50%*Value is 51.6~53.3, redness a*Value for 9.4~
11.2, yellowing b*Value is 6.8~12.6, and red and yellow gray scale is respectively the brightness L of the pattern color at 50%*Value for 63.6~
68.5, redness a*Value is 31.4~34.7, yellowing b*Value is 39.2~43.5, and red and brown gray scale is respectively the pattern at 50%
The brightness L of color*Value is 53.2~54.9, redness a*Value is 34.8~37.4, yellowing b*Value is 32.9~38.5.
The invention further relates to a kind of preparation methods of five color painting in the glaze polishing glazed tile comprising following steps:
A, the preparation of overglaze:
The weight percent of the component of overglaze are as follows:
SiO259.2%~59.8%, Al2O316.2%~16.8%, CaO 7.2%~8%, MgO 0.3%~
0.9%, K2O 3%~4%, Na2O 0.8%~1.6%, TiO20.6%~1.2%, ZrO24.2%~4.8%, ZnO
2.6%~3.2%, B2O31.4%~2.2%, Li2O 0.2%~0.4%, CeO20.8%~1.2%, burning decrement
1.4%~1.8%, the sum of all components are 100%；It is chosen by the weight percent content of above-mentioned overglaze component corresponding molten
Block, spodumene powder, silica flour, calcined oxide aluminium powder, calcium carbonate, burns talcum, titanium dioxide, zirconium silicate, cerium oxide, boron at feldspar powder
The auxiliary material that sour zinc, kaolin and added weight percentage are 0.2%~0.4%, it is thin through ball milling to add suitable water
Being broken into fineness is tailing over as mass percent 0.2%~0.4% and being 28%~30% moisture containing mass percent for 325 meshes
Glaze slip, through except iron be sieved up to overglaze it is spare；Additional auxiliary material therein includes carboxymethyl cellulose and tripolyphosphate
Sodium；
B, the preparation of glaze is polished:
Polish the weight percent of the component of glaze are as follows:
SiO249.2%~50.2%, Al2O312.2%~13.2%, CaO 11.5%~12.5%, MgO 0.4%
~0.8%, K2O 2.4%~3.2%, Na2O 0.6%~1.2%, TiO20.2%~0.6%, ZrO21.8%~
2.4%, BaO 5.8%~6.4%, B2O31%~2%, ZnO 4.2%~4.8%, SrO 1.2%~2%, burning decrement
4.5%~5.5%, the sum of all components are 100%；It is chosen by the weight percent content of above-mentioned polishing glaze component corresponding
Frit, silica flour, feldspar powder, calcium carbonate, titanium dioxide, zirconium silicate, zinc oxide, barium carbonate, strontium carbonate, kaolin, alumina powder
And the auxiliary material that added weight percentage is 0.3%~0.7%, add that suitable water is fine crushing through ball milling to be at fineness
325 meshes tail over be for mass percent 0.4%~0.5% and containing mass percent 28%~30% moisture glaze slip, warp
Except iron be sieved up to polishing glaze it is spare；Additional auxiliary material therein includes carboxymethyl cellulose, sodium tripolyphosphate and water glass
Glass；
C, the preparation and firing of product:
On the glazed tile green body for normally having applied ground coat enamel, then the overglaze that above-mentioned steps A is prepared is applied, the beginning of the overglaze
Melting temperatur is 790 DEG C~800 DEG C, and the glaze volume of overglaze is 570~610g/ ㎡, and the glaze volume is aqueous glaze slip weight, then
By ink-jet printed, ink-jet printed ink color and distributing order are as follows: blue-brown-yellow-pink colour-large red, then apply
The polishing glaze that step B is prepared is stated, the initial melting temperature of the polishing glaze is 840 DEG C~850 DEG C, and the glaze volume for polishing glaze is
480~500g/ ㎡, the glaze volume are aqueous glaze slip weight, then pass through side washing, apply prime cement, enter back into roller kilns glaze firing, most
High firing range is 1100 DEG C~1135 DEG C, and firing time range is 40~70 minutes, then by polishing, waxing, then
By edging to get finished product.
The present invention polishes the finished surface various colors, flat of the preparation method preparation of glazed tile by the five color painting in the glaze
Sliding such as mirror, clear patterns are natural, bright in luster, three-dimensional sense is strong, as one block of transparent glass is covered on pattern, pattern after tested
Colour generation color, the brightness L of the pattern color at red gray scale 100%*Value is 56.2~58.3, redness a*Value for 48.5~
52.8, yellowing b*Value 31.2~33.7, red and blue gray scale are respectively the brightness L of the pattern color at 50%*Value for 51.6~
53.3, redness a*Value is 9.4~11.2, yellowing b*Value is 6.8~12.6, and red and yellow gray scale is respectively the pattern face at 50%
The brightness L of color*Value is 63.6~68.5, redness a*Value is 31.4~34.7, yellowing b*Value is 39.2~43.5, red and brown
Gray scale is respectively the brightness L of the pattern color at 50%*Value is 53.2~54.9, redness a*Value is 34.8~37.4, yellowing b*Value is
32.9~38.5.
A kind of five color painting in the glaze polishing glazed tile of the invention and preparation method thereof, is formed and is polished glaze by opposite glaze formula
The optimization of composition, especially optimizes the additional amount of strontium carbonate and zirconium silicate, and introduces appropriate high refractive index oxide TiO2With
CeO2, especially BaCO3, gradually decomposed using the pattern of ink jet printing in high-temperature calcination, release CO2Property, it is suppressed that it is big
The decomposition of exposed cadmium sulfoselenide colorant in red ink obtains the pure bright-coloured red of colour generation, thus make to print under glaze
Pattern obtains higher brightness and colour gamut broadness degree.TiO simultaneously2And CeO2Addition help to improve the refractive index of glaze, facilitate
The colour generation of toner, suitable SrO are adjustable because of ZrSiO4Addition caused by frit viscosity increase, cause ink-jet printed
When black Organic substance in water is discharged, small shrinkage pool and pin hole can be left on polishing glaze, to influence the quality of product；Polish glaze
Compositional optimization makes the clear patterns, lucid and lively, well arranged, vertical of underglaze colour to ensure that polishing glaze has the transparency of height
Body-sensing is strong, and after polished waxing, seemingly one block of transparent glass is covered on pattern, therefore in polishing glaze composition, the ratio of Si/Al
The ratio for being worth control is convenient, and introduces CaO, K favorable to the transparency of glaze2O、Na2O、BaO、B2O3、ZnO、SrO
Equal oxides, while the wear-resisting property in order to guarantee product after polishing, and introduce suitable ZrO2、TiO2Equal oxides；Overglaze
On the one hand the optimization for melting temperature gap with the beginning of polishing glaze ensure that the pattern of ink jet printable product will not be because of the melting of polishing glaze
Hyperenergia and cause smudgy, on the other hand, the beginning for polishing glaze melts temperature higher than overglaze, it is ensured that overglaze and printing
The gas that ink is discharged in melting can smoothly be discharged, and will not close due to the melt of polishing glaze is premature to become glassy state
Stomata makes gas discharge difficulty that polishing glaze be caused the defects of pin hole, bubble occur；Ink-jet printing ink type preferably and row
The optimization of sequence ensure that the vividness of the color color development of pattern and the broad degree of colour gamut, because red, yellow, blue is ternary primary colours,
It can arbitrarily arrange in pairs or groups on the basis of this ternary primary colours and be tuned into colourful color, therefore bright red chromatic ink and pink colour ink are put
Later, it is primarily due to ZrO in bright red chromatic ink and pink colour ink2Content it is higher, specific gravity than blue and yellow ink it is big,
In high temperature firing, can be mixed because of the effect nature of gravity with brown, blue and yellow ink, it is different according to the gray scale of pattern,
Naturally different colors is generated, bright red chromatic ink and pink colour ink are such as put into front, brown, blue and yellow are put behind, then
Red can be covered by other dark colors, so that mixed colour brightness is inadequate, color is not bright-coloured, colour gamut is also not wide enough；Overglaze
It with the optimization of polishing glaze glazing process, on the one hand can greatly reduce the water content in glaze slip, reduce the water vapour in high temperature
Discharge amount, on the other hand the water content such as in glaze slip is excessively high, can make the dim pattern of ink jet printing, not fine and smooth clear enough, three-dimensional
It is poor to feel；Furthermore there are certain relationships, such as glaze volume can excessively largely effect on polishing glaze for the glaze volume and transparency for polishing glaze
Transparency.
A kind of five color painting in the glaze polishing glazed tile of the invention and preparation method thereof has the following advantages:
1, since the beginning for optimizing the formula composition of overglaze, the formula composition for polishing glaze, overglaze and polishing glaze melts temperature difference
Preferred, ink-jet printing ink type preferred, ink-jet printing ink sequence, the adjustment of glazing process and optimization, to make
Glazed tile product pattern various colors obtained, smooth such as mirror, pattern texture clear and natural, bright in luster, three-dimensional sense is strong, as one
Block transparent glass is covered on pattern, to breach, underglaze colour color is not more bright-coloured enough than overglaze color color, color is not abundant enough
Global problem, by five color painting in the glaze technique, this Chinese rarity is led to a new high degree, to make the poetics of painting porcelain
It draws meaning to appear vividly on Ceramic Tiles face, makes us pleasing, dicoration and artistry with height.
2, product pattern is rich in color, dazzlingly beautiful, after tested the colour generation color of pattern, the figure at red gray scale 100%
The L of case color*(brightness) value is 56.2~58.3, a*(redness) value is 48.5~52.8, b*(yellowing) value 31.2~33.7, it is red
Color and blue gray scale are respectively the L of the pattern color at 50%*(brightness) value is 51.6~53.3, a*(redness) value be 9.4~
11.2 b*(yellowing) value is 6.8~12.6, and red and yellow gray scale is respectively the L of the pattern color at 50%*(brightness) value is
63.6~68.5, a*(redness) value is 31.4~34.7, b*(yellowing) value is 39.2~43.5, and red and brown gray scale is respectively
The L of pattern color at 50%*(brightness) value is 53.2~54.9, a*(redness) value is 34.8~37.4, b*(yellowing) value is
32.9~38.5.
3, the product surface flatness, the modulus of rupture, flexural strength, resistance to acid and alkali, wearability, thermal shock resistance, radioactivity,
Lead-indium alloy reaches GB/T4100-2015, GB6566-2011 and HJ/T297-2006 standard requirements.
4, the product uses existing glazed tile production technology, makes the decoration technology and special decoration that five color painting in the glaze is special
Effect is able to copy on glaze brick product, it is easy to accomplish industrialized scale.
Detailed description of the invention:
Fig. 1 is the process flow chart for preparing a kind of five color painting in the glaze polishing glazed tile of the invention.
Specific embodiment:
Below with reference to embodiment, invention is further described in detail.
Embodiment 1
A kind of preparation method of five color painting in the glaze polishing glazed tile comprising following steps:
A, overglaze is prepared:
Chemical composition composition such as the following table 1 of overglaze:
The chemical composition table (weight percent, %) of table 1, overglaze
It prepares overglaze: choosing frit, feldspar powder, the spodumene powder, quartz of corresponding proportion by the chemical composition of table 1
Powder, calcium carbonate, burns talcum, titanium dioxide, zirconium silicate, cerium oxide, zinc borate, kaolin and added weight at calcined oxide aluminium powder
Percentage be 0.2%~0.4% auxiliary material carry out ingredient, add suitable water through ball milling it is fine crushing at fineness be 325 mesh
Sieve tail over be for mass percent 0.2%~0.4% and containing mass percent 28%~30% moisture glaze slip, through remove iron mistake
It sieves spare up to overglaze；Additional auxiliary material therein includes carboxymethyl cellulose and sodium tripolyphosphate；Frit selection therein
With architectural ceramics frit；
B, preparation polishing glaze:
Polish chemical composition such as the following table 2 of glaze:
Table 2, the chemical composition table (weight percent, %) for polishing glaze
Preparation polishing glaze: frit, silica flour, feldspar powder, the carbonic acid of corresponding proportion are chosen by the chemical composition of table 2
Calcium, titanium dioxide, zirconium silicate, zinc oxide, barium carbonate, strontium carbonate, kaolin, alumina powder and added weight percentage are
0.3%~0.7% auxiliary material, it at fineness is that 325 meshes tail over as quality hundred that it is fine crushing through ball milling, which to add suitable water,
Point than 0.4%~0.5% and containing mass percent be 28%~30% moisture glaze slip, through except iron be sieved up to polishing glaze it is standby
With；Additional auxiliary material therein includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass；Frit therein selects architectural ceramics
Use frit；
C, product is prepared:
The overglaze that above-mentioned steps are prepared is applied on the adobe surface for normally having applied ground coat enamel, the initial melting temperature of the overglaze is
790 DEG C~800 DEG C, the glaze volume of overglaze is 570~610g/ ㎡, and the glaze volume is aqueous glaze slip weight, then passes through ink-jet
Stamp, ink-jet printed ink color and distributing order are as follows: blue-brown-yellow-pink colour-large red, then apply above-mentioned steps B
The polishing glaze being prepared, it is described polishing glaze initial melting temperature be 840 DEG C~850 DEG C, polish glaze glaze volume be 480~
500g/ ㎡, the glaze volume are aqueous glaze slip weight, then pass through side washing, apply prime cement, enter back into roller kilns glaze firing, most high fever
It is 1100 DEG C~1135 DEG C at temperature range, firing time range is 40~70 minutes, then by polishing, waxing, using
Edging is to get finished product.
The ink of ink-jet printed ink such as Shandong state porcelain Kang Litai new material Science and Technology Ltd. production described in wherein:
Blue K2577, brown K2272, yellow K2379, pink colour K2171；The wherein bright red chromatic ink, in the patent Shen of applicant
It please number be 2015102298965, patent name " ceramic decoration high temperature scarlet color ink-jet ink and preparation method and its is answered
With " application for a patent for invention in have been disclosed.
The present invention is by a kind of above-mentioned preparation method of five color painting in the glaze polishing glazed tile, the glaze brick product figure being prepared
Case various colors, clean mark are natural, bright in luster, three-dimensional sense is strong, smooth such as mirror, and seemingly one block of transparent glass is covered on pattern
On, the colour generation color of pattern after tested, the L of the pattern color at red gray scale 100%*(brightness) value is 56.2~58.3, a*
(redness) value is 48.5~52.8, b*(yellowing) value 31.2~33.7, red and blue gray scale are respectively the pattern color at 50%
L*(brightness) value is 51.6~53.3, a*(redness) value is 9.4~11.2, b*(yellowing) value is 6.8~12.6, red and yellow
Color shade is respectively the L of the pattern color at 50%*(brightness) value is 63.6~68.5, a*(redness) value is 31.4~34.7, b*
(yellowing) value is 39.2~43.5, and red and brown gray scale is respectively the L of the pattern color at 50%*(brightness) value be 53.2~
54.9 a*(redness) value is 34.8~37.4, b*(yellowing) value is 32.9~38.5.It is inadequate to breach traditional five color painting in the glaze color development
It is bright-coloured, colour gamut is not wide, the problem that especially bright red colour cast is dark, partially grey, by this Chinese culture rarity of traditional five color painting in the glaze technique
It leads to a new high degree, so that the poetic and pictorial splendor of painting porcelain be made to appear vividly on ceramic wall and floor bricks, making us pleasing, and produces
The defects of product glaze quality is good, corrosion resistance and resistance to soiling are strong, wear resistance is high, pin-free, glaze steeps.Through testing product indices
Such as the following table 3:
Table 3: product quality inspection result
In conclusion only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form；It is all
The those of ordinary skill of the industry can implement the present invention by the above and swimmingly；But all technology people for being familiar with this profession
Member without departing from the scope of the present invention, repair by a little change for making using disclosed above technology contents
Decorations and the equivalent variations developed, are equivalent embodiment of the invention；Meanwhile all substantial technologicals according to the present invention are to the above reality
The change, modification and differentiation for applying any equivalent variations made by example, still fall within technical solution of the present invention protection scope it
It is interior.
Claims (3)
1. a kind of preparation method of five color painting in the glaze polishing glazed tile, it is characterised in that:
Itself the following steps are included:
A, the preparation of overglaze:
The weight percent of the component of overglaze are as follows:
SiO259.2%~59.8%, Al2O316.2%~16.8%, CaO 7.2%~8%, MgO 0.3%~0.9%,
K2O 3%~4%, Na2O 0.8%~1.6%, TiO20.6%~1.2%, ZrO24.2%~4.8%, ZnO 2.6%~
3.2%, B2O31.4%~2.2%, Li2O 0.2%~0.4%, CeO20.8%~1.2%, burning decrement 1.4%~
1.8%, the sum of all components are 100%；Corresponding frit, feldspar are chosen by the weight percent content of above-mentioned overglaze component
Powder, silica flour, calcined oxide aluminium powder, calcium carbonate, burns talcum, titanium dioxide, zirconium silicate, cerium oxide, zinc borate, height at spodumene powder
The auxiliary material that ridge soil and added weight percentage are 0.2%~0.4%, it is fine crushing at fineness through ball milling to add suitable water
For 325 meshes tail over be for mass percent 0.2%~0.4% and containing mass percent 28%~30% moisture glaze slip,
Through except iron be sieved up to overglaze it is spare；Additional auxiliary material therein includes carboxymethyl cellulose and sodium tripolyphosphate；
B, the preparation of glaze is polished:
Polish the weight percent of the component of glaze are as follows:
SiO249.2%~50.2%, Al2O312.2%~13.2%, CaO 11.5%~12.5%, MgO 0.4%~
0.8%, K2O 2.4%~3.2%, Na2O 0.6%~1.2%, TiO20.2%~0.6%, ZrO21.8%~2.4%,
BaO 5.8%~6.4%, B2O31%~2%, ZnO 4.2%~4.8%, SrO 1.2%~2%, burning decrement 4.5%~
5.5%, the sum of all components are 100%；Corresponding frit, stone are chosen by the weight percent content of above-mentioned polishing glaze component
Ying Fen, feldspar powder, calcium carbonate, titanium dioxide, zirconium silicate, zinc oxide, barium carbonate, strontium carbonate, kaolin, alumina powder and additional
The auxiliary material that weight percent is 0.3%~0.7%, it at fineness is 325 meshes that it is fine crushing through ball milling, which to add suitable water,
Tail over for mass percent 0.4%~0.5% and containing mass percent be 28%~30% moisture glaze slip, through except iron sieving be
It is spare glaze must to be polished；Additional auxiliary material therein includes carboxymethyl cellulose, sodium tripolyphosphate and waterglass；
C, the preparation and firing of product:
On the glazed tile green body for normally having applied ground coat enamel, then the overglaze that above-mentioned steps A is prepared is applied, the beginning of the overglaze molten temperature
Degree is 790 DEG C~800 DEG C, and the glaze volume of overglaze is 570~610g/ ㎡, and the glaze volume is aqueous glaze slip weight, is then passed through
Ink-jet printed, ink-jet printed ink color and distributing order are as follows: blue-brown-yellow-pink colour-large red, then apply above-mentioned step
The initial melting temperature of the polishing glaze that rapid B is prepared, the polishing glaze is 840 DEG C~850 DEG C, the glaze volume for polishing glaze is 480~
500g/ ㎡, the glaze volume are aqueous glaze slip weight, then pass through side washing, apply prime cement, enter back into roller kilns glaze firing, most high fever
It is 1100 DEG C~1135 DEG C at temperature range, firing time range is 40~70 minutes, then by polishing, waxing, using
Edging is to get finished product.
2. the preparation method of five color painting in the glaze polishing glazed tile according to claim 1, it is characterised in that:
The colour generation color of the finished surface of the preparation method preparation of glazed tile pattern after tested is polished by the five color painting in the glaze,
The brightness L of pattern color at red gray scale 100%*Value is 56.2~58.3, redness a*Value is 48.5~52.8, yellowing b*Value
31.2~33.7, red and blue gray scale is respectively the brightness L of the pattern color at 50%*Value is 51.6~53.3, redness a*Value is
9.4~11.2, yellowing b*Value is 6.8~12.6, and red and yellow gray scale is respectively the brightness L of the pattern color at 50%*Value is
63.6~68.5, redness a*Value is 31.4~34.7, yellowing b*Value is 39.2~43.5, and red and brown gray scale is respectively at 50%
Pattern color brightness L*Value is 53.2~54.9, redness a*Value is 34.8~37.4, yellowing b*Value is 32.9~38.5.
3. a kind of five color painting in the glaze polishes glazed tile, it is characterised in that:
Its preparation method according to claim 1 or 2 is prepared.
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| CN107129288B (en) * | 2017-05-11 | 2018-03-30 | 山东雅迪陶瓷有限公司 | Substitute environment-friendly type ceramic tile of natural jade stone material and preparation method thereof |
| CN107140836A (en) * | 2017-06-26 | 2017-09-08 | 平顶山学院 | A kind of brown ground opal blue mottled enamels and the fancy glaze porcelain using its preparation |
| CN108195773A (en) * | 2018-01-26 | 2018-06-22 | 山东农业大学 | A kind of test method of biomass decorative brick color |
| CN110256113A (en) * | 2019-07-01 | 2019-09-20 | 广东易成陶瓷实业有限公司 | A kind of ceramic large area overglaze color anticracking color technique of white clouds soil |
| CN110698067B (en) * | 2019-11-15 | 2022-04-15 | 佛山市东鹏陶瓷有限公司 | Wear-resistant glaze for preparing sanitary ceramics and method for preparing sanitary ceramics |
| CN111116043B (en) * | 2019-12-30 | 2022-07-12 | 江西新明珠建材有限公司 | 4-level wear-resistant glaze marble tile and manufacturing method thereof |
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| DE19852366C2 (en) * | 1998-11-13 | 2002-06-06 | Schott Glas | Highly heat-conducting body, process for its production and its use |
| CN104130024A (en) * | 2014-07-23 | 2014-11-05 | 广东宏陶陶瓷有限公司 | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile |
| CN104860720A (en) * | 2015-05-07 | 2015-08-26 | 广东宏陶陶瓷有限公司 | Ceramic decoration high-temperature bright red inkjet ink preparation method and application thereof |
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| DE19852366C2 (en) * | 1998-11-13 | 2002-06-06 | Schott Glas | Highly heat-conducting body, process for its production and its use |
| CN104130024A (en) * | 2014-07-23 | 2014-11-05 | 广东宏陶陶瓷有限公司 | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile |
| CN104860720A (en) * | 2015-05-07 | 2015-08-26 | 广东宏陶陶瓷有限公司 | Ceramic decoration high-temperature bright red inkjet ink preparation method and application thereof |
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