CN111116043B - 4-level wear-resistant glaze marble tile and manufacturing method thereof - Google Patents
4-level wear-resistant glaze marble tile and manufacturing method thereof Download PDFInfo
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- CN111116043B CN111116043B CN201911391853.1A CN201911391853A CN111116043B CN 111116043 B CN111116043 B CN 111116043B CN 201911391853 A CN201911391853 A CN 201911391853A CN 111116043 B CN111116043 B CN 111116043B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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Abstract
The invention relates to a 4-grade wear-resistant glaze marble tile, which comprises a blank layer, a cover glaze layer, a decorative layer and a wear-resistant glaze layer which are sequentially arranged from bottom to top, wherein the wear-resistant glaze layer comprises the following components in parts by weight: SiO2240 to 50 portions of Al2O315-20 parts of K2O2-3 parts, Na20.5 to 1 portion of O and TiO20.2-0.4 part of Fe2O30.2-0.5 part of P2O50.05-0.1 part of MnO, 0.001-0.01 part of MgO, 10-20 parts of CaO, 4-5 parts of BaO and 0.02-0.05 part of SrO. The ceramic tile provided by the invention adds alkaline earth metal and crystalline phase medium in the formula of the glaze wear-resistant layer, so that the ceramic tile can finally realize 4-level wear resistance of 2100 + 4500 turns, is strong in wear resistance and free of scratches.
Description
Technical Field
The invention relates to the technical field of marble tile production, in particular to a 4-grade wear-resistant glaze marble tile and a manufacturing method thereof.
Background
The wear resistance of the color glazed floor tile is an important index of the floor tile all the time, at present, the wear resistance of the glazed tile manufactured in the ceramic production generally only reaches 3-level wear resistance effect, scratches are easy to generate, the attractiveness is reduced, and the product quality and popularization are affected. Therefore, there is a need to further improve the wear resistance of ceramic surfaces, i.e. to develop grade 4 and above wear resistant glaze marble tile glaze.
CN109665871A discloses a process method for improving the surface wear resistance of polished crystal ceramic tiles, wherein the hardness of the surface wear-resistant glaze layer of the technical scheme reaches 4 grades in the specific embodiment. The technological method of the technical scheme mainly comprises 3 steps, S01 is to spray water to the surface of the dried and surface-cleaned ceramic tile adobe to wet the surface, and spread the overglaze to form an overglaze layer; s02, according to the designed pattern, spraying and printing decorative ink on the overglaze layer to form a decorative pattern layer; s03, uniformly distributing aluminum-silicon system dry particles on the decorative pattern layer to form an expansion coefficient adjusting layer; and then uniformly distributing the mixture of the aluminum-silicon system dry particles and the high-borosilicate system dry particles to form a surface wear-resistant glaze layer. The technical scheme mainly considers that the thermal expansion coefficient of the aluminum-silicon system dry grains is closer to that of a ceramic tile blank in the third step, so that a layer of aluminum-silicon system dry grains is firstly paved between a product surface wear-resistant glaze layer paved with high borosilicate system dry grains and the ceramic tile blank to serve as an expansion coefficient adjusting layer, a transition effect is achieved, and the possibility of surface cracking of the high borosilicate system dry grains is reduced. The technical scheme solves the cracking problem of the surface wear-resistant glaze layer, but the third step of manufacturing the surface wear-resistant glaze layer is very complicated and has higher cost, and the high-quality and high-gloss surface wear-resistant glaze layer is difficult to obtain.
WO2019015237A1 discloses ANTI-SLIP WEAR-RESISTANT GLAZE, ANTI-SLIP WEAR-RESISTANT EASY-CLEAN CERAMIC TILE, AND PREPARATION METHOD ceramic tile and a PREPARATION METHOD thereof, the PREPARATION METHOD of the ANTI-skid WEAR-RESISTANT easy-to-clean ceramic tile provided by the technical scheme comprises the following steps: (a) preparing a green body layer from the blank; (b) spreading a cover glaze on the blank layer to form a cover glaze layer; (c) ink-jet printing is carried out on the overglaze layer to prepare a decorative layer; (d) printing an anti-skid wear-resistant glaze on the decorative layer to form an anti-skid wear-resistant layer; (e) and (3) distributing and applying easy-to-clean protective glaze on the anti-skid wear-resistant layer to form an easy-to-clean protective layer. The antiskid wear-resistant glaze is prepared from the following raw materials, by mass, 90-110 parts of antiskid wear-resistant particles, 90-110 parts of printing paste and 0.2-0.4 part of sodium tripolyphosphate; the antiskid wear-resistant particles mainly comprise, by mass, 260-70 parts of SiO, 320-30 parts of Al2O, 30.01-1 parts of Fe2O30, 20.1-2 parts of TiO20, 1-5 parts of Na2O 1, 1-10 parts of K2O 1, 0.01-1 part of MgO, 0.1-5 parts of CaO0 and 0.1-2 parts of loss on ignition; the printing paste comprises, by mass, 2-3 parts of sodium carboxymethylcellulose, 40-60 parts of ethylene glycol and 40-60 parts of water. The wear-resistant layer provided by the technical scheme is composed of components, however, the components of the wear-resistant layer are complex, the preparation is complex, and in addition, an easily cleaned layer is additionally added on the surface.
In conclusion, the prior art still lacks a 4-grade wear-resistant glazed marble tile with simple process and a manufacturing method thereof.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, improve the components and the compositions of a blank layer, a cover glaze layer and a wear-resistant glaze layer, and provide a 4-level wear-resistant glaze marble tile which is convenient to manufacture and has high quality and a manufacturing method.
The utility model provides a4 level wear-resisting glaze marble ceramic tile, includes body layer, overglaze layer, decorative layer and the wear-resisting glaze layer that sets gradually from supreme down, its characterized in that, the wear-resisting glaze layer comprises the component of following parts by mass: SiO2240-50 parts of Al2O315-20 parts of K2O2-3 parts, Na20.5 to 1 portion of O and TiO20.2-0.4 part of Fe2O30.2-0.5 part of P2O50.05-0.1 part of MnO, 0.001-0.01 part of MgO, 10-20 parts of CaO, 4-5 parts of BaO and 0.02-0.05 part of SrO.
The method can improve the wear resistance of the glaze surface from two aspects, namely, the wear resistance of a crystal phase and the wear resistance of a glass phase. The components of the wear-resistant glaze layer of the invention properly increase the proportion of alkaline earth metals such as CaO, BaO and the like, and reduce Na2O and K2The proportion of alkali metals such as O, etc., so that the abrasion resistance of the glass phase in the glaze can be improved. Book (I)The initial melting and melting temperatures of the glaze are regulated and controlled by regulating and controlling the proportion of each component in the glaze, so that the wear resistance and transparency of the whole glaze are improved, and the purpose of achieving 4-grade wear resistance of the ceramic tile is achieved.
Preferably, SiO in the wear-resistant glaze layer component2、Al2O3And the mass ratio of CaO is controlled to be (5.5-6): (2-3): (1.5-2).
Preferably, the wear-resistant glaze layer also comprises ZrO20.01-0.1 portion.
Preferably, the wear-resistant glaze layer also comprises 5-8 parts of ZnO.
The proportion of silicon, aluminum and calcium in the glaze component is very important, and by controlling the proper proportion of silicon, aluminum and calcium, the glaze can separate out a wear-resistant crystalline phase in the cooling process, so that the wear resistance is improved. The wear-resistant crystalline phase medium is added into the glaze, so that the wear resistance of the glaze can be improved, the introduction amount of the wear-resistant medium cannot be too much, and otherwise, the wear resistance can be reduced. According to the invention, 0.01-0.1 part of ZrO2 is added into the components of the wear-resistant glaze layer, so that the wear resistance of the ceramic tile can be effectively improved. ZnO has strong crystallization tendency in glaze melt, ZnO introduced in the invention can play a role of crystallization, thereby improving the wear resistance, and in addition, ZnO can also increase the glaze luster, improve the glaze whiteness and promote opacification.
Preferably, the overglaze layer is a frit glaze, and the frit glaze mainly comprises the following components in parts by mass: SiO2250-60 parts of Al2O320-25 parts of CaO, 1-2 parts of CaO, 0.4-0.6 part of MgO and K2O2-4 parts, Na23-4 parts of O, 0.1-0.4 part of ZnO and 0.01 part of SrO;
preferably, the green body layer consists of the following components in parts by mass: 5-10 parts of J medium temperature sand, 5-10 parts of J34 potassium sodium sand, 5-10 parts of J high clay 1#5-10 parts, 5-10 parts of J36 potassium sodium sand, 1#5-10 parts of J medium temperature sand, 3#5-10 parts of J mixed mud, 2-8 parts of J mixed mud, 3# 3-8 parts of J talc mud, 15-10 parts of J34 potassium sodium sand, 2-5 parts of J mixed sand, 2-5 parts of mud feces, 10-15 parts of J30 sodium stone powder, 4-7 parts of J52 mud strips, 10-15 parts of J refined aluminum sand, 2-5 parts of J washing mud, 4-7 parts of raw material recovery slurry, 0.03-0.09 part of alkaline diluent and 0.3-1 part of water glass.
Preferably, the tile is a full body marble tile, the material for the tile blank layer is further added with a coloring material, the granularity of the coloring material is less than 325 meshes, and the water content is controlled to be less than 1%.
The invention also provides a preparation method of the 4-level wear-resistant glazed marble tile, which is characterized by comprising the following steps of:
the method comprises the following steps: pressing the blank layer material into a ceramic tile forming blank, and drying in a kiln to form a semi-finished blank;
step two: applying overglaze to the semi-finished blank in the step one according to a bell jar type glaze pouring process to form an overglaze layer;
step three: printing patterns on the surface glaze layer in the second step in an ink-jet mode to form a decorative layer;
step four: applying wear-resistant glaze on the decorative layer obtained in the third step to form a wear-resistant glaze layer;
step five: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to obtain the finished ceramic tile.
Preferably, the glazing mode of the wear-resistant glaze in the fourth step adopts a bell jar type glaze pouring process.
The silk-screen printing is a wear-resistant glazing method commonly used in the industry, and has the main advantages of simple plate making and printing method, low equipment investment and low cost, and has the main defects of low printing speed and poor printing level. In order to improve the glazing mode of the wear-resistant glaze, the invention adopts the bell-type glaze spraying process, can improve the production speed and effectively improve the definition of the layout.
Preferably, the quality control range of the wear resistant glaze is 50-55 g/tile, and the specification of the tile is 800cm by 800 cm.
The quality range of the wear-resistant glaze is critical, the use amount of the wear-resistant glaze can influence the final wear-resistant strength and the glaze transparency of the ceramic tile, the wear-resistant strength cannot be achieved when the use amount is small, and the color development and the transparency of the wear-resistant glaze are influenced when the use amount is large.
The invention has the following beneficial effects:
(1) the ceramic tile provided by the invention adds alkaline earth metal and crystalline phase medium in the formula of the glaze wear-resistant layer, so that the ceramic tile can finally realize 4-level wear resistance of 2100-4500 turns.
(2) The manufacturing method is simple and convenient, and the wear-resistant glaze can be directly applied to the decorative layer without adding a transition layer or adding a protective layer on the surface of the wear-resistant glaze layer.
(3) The invention adopts the bell-type glaze spraying process, can improve the production speed and effectively improve the definition of the layout.
Detailed Description
The following further illustrates embodiments of the invention:
examples of the invention
The specification of the ceramic tile prepared in the invention is 800cm by 800 cm.
Inventive example 1
A preparation method of a 4-grade wear-resistant glazed marble tile comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A1.
Wherein the blank layer consists of the following components in parts by weight: 5kg of J medium-temperature sand, 5kg of J34 potassium sodium sand, 5kg of J high clay 1#5, 5kg of J36 potassium sodium sand, 1#5kg of J medium-temperature sand, 5kg of J mixed mud 3#5, 2kg of J mixed mud, 1#3kg of J talc mud, 15kg of J34 potassium sodium sand, 2kg of J mixed sand, 2kg of mud feces, 10kg of J30 sodium stone powder, 4kg of J52 mud strips, 10kg of J fine aluminum sand, 2kg of J washing mud, 4kg of raw material recovery slurry, 0.03kg of alkaline diluent and 0.3kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze comprises the following components in parts by weight: SiO2250kg、Al2O3 20kg、CaO 1kg、MgO 0.4kg、K2O 2kg、Na2O3 kg, ZnO 0.1kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 40kg、Al2O3 15kg、K2O 2kg、Na2O 0.5kg、TiO2 0.2kg、Fe2O3 0.2kg、P2O50.05kg, MnO 0.01kg, MgO 0.3kg, CaO 10kg, BaO 4kg, SrO 0.02 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Inventive example 2
The difference between the embodiment and the invention embodiment 1 is that the glaze-resistant layer has different formula proportions, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A2.
Wherein the green body layer consists of the following components in parts by weight: 10kg of J medium-temperature sand, 10kg of J34 potassium sodium sand, 10kg of J high clay 1#10kg, 10kg of J36 potassium sodium sand, 1#10kg of J medium-temperature sand, 10kg of J mixed mud 3# 8kg, 8kg of J mixed mud, 8kg of J talc mud 1#8kg, 110 kg of J34 potassium sodium sand, 5kg of J mixed sand, 5kg of mud feces, 15kg of J30 sodium stone powder, 7kg of J52 mud strips, 15kg of J refined aluminum sand, 5kg of J water washing mud, 7kg of raw material recovery slurry, 0.09kg of alkaline diluent and 1kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze comprises the following components in parts by weight: SiO2260kg、Al2O3 25kg、CaO 2kg、MgO 0.6kg、K2O 4kg、Na2O4 kg, ZnO 0.4kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 50kg、Al2O3 20kg、K2O 3kg、Na2O 1kg、TiO2 0.4kg、Fe2O3 0.5kg、P2O50.1kg, MnO0.001 kg, MgO 0.6kg, CaO 20kg, BaO 5kg, SrO 0.05 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Inventive example 3
The difference between the embodiment and the invention embodiment 1 is that the glaze-resistant layer has different formula proportions, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A3.
Wherein the green body layer consists of the following components in parts by weight: 9.5kg of J medium-temperature sand, 29.5 kg of J34 potassium-sodium sand, 9kg of J high clay 1#9, 8.5kg of J36 potassium-sodium sand, 1#5kg of J medium-temperature sand, 3#5kg of J mixed mud, 4kg of J mixed mud, 1#4kg of J talc mud, 19.5 kg of J34 potassium-sodium sand, 4kg of J mixed sand, 2kg of mud feces, 12kg of J30 sodium stone powder, 6kg of J52 mud strip, 12kg of J fine aluminum sand, 3kg of J washing mud, 6kg of raw material recovery slurry, 0.05kg of alkaline diluent and 0.7kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze comprises the following components in parts by weight: SiO2255kg、Al2O3 25kg、CaO 1.5kg、MgO 0.5kg、K2O 2kg、Na2O3 kg, ZnO 0.2kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 45kg、Al2O3 20kg、K2O 2.5kg、Na2O 0.7kg、TiO2 0.3kg、Fe2O3 0.4kg、P2O50.06kg, MnO 0.01kg, MgO 0.5kg, CaO 15kg, BaO 4.5kg, SrO 0.03 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Inventive example 4
The difference between the embodiment and the invention embodiment 3 is that a proper amount of ZrO2 is added into the glaze-resistant layer formula, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the surface glaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A4.
Wherein the green body layer consists of the following components in parts by weight: 9.5kg of J medium-temperature sand, 29.5 kg of J34 potassium-sodium sand, 9kg of J high clay 1#9, 8.5kg of J36 potassium-sodium sand, 1#5kg of J medium-temperature sand, 3#5kg of J mixed mud, 4kg of J mixed mud, 1#4kg of J talc mud, 19.5 kg of J34 potassium-sodium sand, 4kg of J mixed sand, 2kg of mud feces, 12kg of J30 sodium stone powder, 6kg of J52 mud strip, 12kg of J fine aluminum sand, 3kg of J washing mud, 6kg of raw material recovery slurry, 0.05kg of alkaline diluent and 0.7kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze comprises the following components in parts by weight: SiO2255kg、Al2O3 25kg、CaO 1.5kg、MgO 0.5kg、K2O 2kg、Na2O3 kg, ZnO 0.2kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 45kg、Al2O3 20kg、K2O 2.5kg、Na2O 0.7kg、TiO2 0.3kg、Fe2O3 0.4kg、P2O50.06kg, MnO 0.01kg, MgO 0.5kg, CaO 15kg, BaO 4.5kg, SrO 0.03kg, ZrO20.04kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Inventive example 5
The difference between the embodiment and the invention embodiment 3 is that a proper amount of ZnO is added into the glaze-resistant layer formula, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A5.
Wherein the blank layer consists of the following components in parts by weight: 9.5kg of J medium-temperature sand, 29.5 kg of J34 potassium-sodium sand, 9kg of J high clay 1#9, 8.5kg of J36 potassium-sodium sand, 1#5kg of J medium-temperature sand, 3#5kg of J mixed mud, 4kg of J mixed mud, 1#4kg of J talc mud, 19.5 kg of J34 potassium-sodium sand, 4kg of J mixed sand, 2kg of mud feces, 12kg of J30 sodium stone powder, 6kg of J52 mud strip, 12kg of J fine aluminum sand, 3kg of J washing mud, 6kg of raw material recovery slurry, 0.05kg of alkaline diluent and 0.7kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 55kg、Al2O3 25kg、CaO 1.5kg、MgO 0.5kg、K2O 2kg、Na2O3 kg, ZnO 0.2kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 45kg、Al2O3 20kg、K2O 2.5kg、Na2O 0.7kg、TiO2 0.3kg、Fe2O3 0.4kg、P2O50.06kg, MnO 0.01kg, MgO 0.5kg, CaO 15kg, BaO 4.5kg, SrO 0.03kg, ZnO 6 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Inventive example 6
The difference between the embodiment and the invention embodiment 3 is that a proper amount of ZrO2 and ZnO is added into the glaze-resistant layer formula, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the surface glaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile A6.
Wherein the green body layer consists of the following components in parts by weight: 9.5kg of J medium-temperature sand, 29.5 kg of J34 potassium-sodium sand, 9kg of J high clay 1#9, 8.5kg of J36 potassium-sodium sand, 1#5kg of J medium-temperature sand, 3#5kg of J mixed mud, 4kg of J mixed mud, 1#4kg of J talc mud, 19.5 kg of J34 potassium-sodium sand, 4kg of J mixed sand, 2kg of mud feces, 12kg of J30 sodium stone powder, 6kg of J52 mud strip, 12kg of J fine aluminum sand, 3kg of J washing mud, 6kg of raw material recovery slurry, 0.05kg of alkaline diluent and 0.7kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 55kg、Al2O3 25kg、CaO 1.5kg、MgO 0.5kg、K2O 2kg、Na2O3 kg, ZnO 0.2kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 45kg、Al2O3 20kg、K2O 2.5kg、Na2O 0.7kg、TiO2 0.3kg、Fe2O3 0.4kg、P2O50.06kg, MnO 0.01kg, MgO 0.5kg, CaO 15kg, BaO 4.5kg, SrO 0.03kg, ZrO20.04kg, ZnO 6 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Comparative example 1
The difference between the embodiment and the invention embodiment 1 is that the formula of the glaze-resistant layer does not contain CaO, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile B1.
Wherein the green body layer consists of the following components in parts by weight: 5kg of J medium-temperature sand, 5kg of J34 potassium sodium sand, 5kg of J high clay 1#5, 5kg of J36 potassium sodium sand, 1#5kg of J medium-temperature sand, 5kg of J mixed mud 3#5, 2kg of J mixed mud, 1#3kg of J talc mud, 15kg of J34 potassium sodium sand, 2kg of J mixed sand, 2kg of mud feces, 10kg of J30 sodium stone powder, 4kg of J52 mud strips, 10kg of J fine aluminum sand, 2kg of J washing mud, 4kg of raw material recovery slurry, 0.03kg of alkaline diluent and 0.3kg of water glass. All the blank materials are mixed evenly according to the proportion of the formula, and then are pressed into the brick blank with the required specification, and the brick blank is put into a kiln to be fired into a semi-finished blank.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 50kg、Al2O3 20kg、CaO 1kg、MgO 0.4kg、K2O 2kg、Na2O3 kg, ZnO 0.1kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 40kg、Al2O3 15kg、K2O 2kg、Na2O 0.5kg、TiO2 0.2kg、Fe2O3 0.2kg、P2O50.05kg, MnO 0.01kg, MgO 0.3kg, BaO 4kg, SrO 0.02 kg. Pressing all the wear-resistant glaze materialsThe formula is mixed evenly according to the proportion, then water is added, the glaze material is added into a ball mill for crushing, and the flow rate ratio of the glaze is adjusted to be proper to pour out the glaze surface effect for later use.
Comparative example 2
The difference between the embodiment and the invention embodiment 1 is that BaO is not in the glaze-resistant layer formula, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the surface glaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile B2.
Wherein the green body layer consists of the following components in parts by weight: 5kg of J medium-temperature sand, 5kg of J34 potassium sodium sand, 5kg of J high clay 1#5, 5kg of J36 potassium sodium sand, 1#5kg of J medium-temperature sand, 5kg of J mixed mud 3#5, 2kg of J mixed mud, 1#3kg of J talc mud, 15kg of J34 potassium sodium sand, 2kg of J mixed sand, 2kg of mud feces, 10kg of J30 sodium stone powder, 4kg of J52 mud strips, 10kg of J fine aluminum sand, 2kg of J washing mud, 4kg of raw material recovery slurry, 0.03kg of alkaline diluent and 0.3kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 50kg、Al2O3 20kg、CaO 1kg、MgO 0.4kg、K2O 2kg、Na2O3 kg, ZnO 0.1kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 40kg、Al2O3 15kg、K2O 2kg、Na2O 0.5kg、TiO2 0.2kg、Fe2O3 0.2kg、P2O50.05kg, MnO 0.01kg, MgO 0.3kg, CaO 10kg, SrO 0.02 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Comparative example 3
The difference between the embodiment and the embodiment 1 of the invention lies in that the glazing method is different, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the overglaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: applying wear-resistant glaze on the decorative layer obtained in the second step by adopting a screen printing process to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 50 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile B3.
Wherein the green body layer consists of the following components in parts by weight: 5kg of J medium-temperature sand, 5kg of J34 potassium sodium sand, 5kg of J high clay 1#5, 5kg of J36 potassium sodium sand, 1#5kg of J medium-temperature sand, 5kg of J mixed mud 3#5, 2kg of J mixed mud, 1#3kg of J talc mud, 15kg of J34 potassium sodium sand, 2kg of J mixed sand, 2kg of mud feces, 10kg of J30 sodium stone powder, 4kg of J52 mud strips, 10kg of J fine aluminum sand, 2kg of J washing mud, 4kg of raw material recovery slurry, 0.03kg of alkaline diluent and 0.3kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 50kg、Al2O3 20kg、CaO 1kg、MgO 0.4kg、K2O 2kg、Na2O3 kg, ZnO 0.1kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, feeding into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to be in a closed stateThe glaze surface is properly sprayed for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 40kg、Al2O3 15kg、K2O 2kg、Na2O 0.5kg、TiO2 0.2kg、Fe2O3 0.2kg、P2O50.05kg, MnO 0.01kg, MgO 0.3kg, CaO 10kg, BaO 4kg, SrO 0.02 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Comparative example 4
The difference between the embodiment and the invention embodiment 1 is that the glazing amount is different, and the method specifically comprises the following steps:
the method comprises the following steps: applying a cover glaze to the semi-finished product blank according to a bell jar type glaze pouring process to form a cover glaze layer;
step two: printing patterns on the surface glaze layer in the first step in an ink-jet mode to form a decorative layer;
step three: performing bell-jar type glaze pouring on the decorative layer obtained in the second step to apply the wear-resistant glaze to form a wear-resistant glaze layer, wherein the quality control range of the wear-resistant glaze is 20 g;
step four: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to prepare the ceramic tile B4.
Wherein the green body layer consists of the following components in parts by weight: 5kg of J medium-temperature sand, 5kg of J34 potassium sodium sand, 5kg of J high clay 1#5, 5kg of J36 potassium sodium sand, 1#5kg of J medium-temperature sand, 5kg of J mixed mud 3#5, 2kg of J mixed mud, 1#3kg of J talc mud, 15kg of J34 potassium sodium sand, 2kg of J mixed sand, 2kg of mud feces, 10kg of J30 sodium stone powder, 4kg of J52 mud strips, 10kg of J fine aluminum sand, 2kg of J washing mud, 4kg of raw material recovery slurry, 0.03kg of alkaline diluent and 0.3kg of water glass. All the blank materials are mixed evenly according to the formula proportion, then pressed into the required specification of green bricks, and put into a kiln to be fired into semi-finished blank materials.
The overglaze layer is prepared from a frit glaze, and the frit glaze mainly comprises the following components in parts by weight: SiO22 50kg、Al2O3 20kg、CaO 1kg、MgO 0.4kg、K2O 2kg、Na2O3 kg, ZnO 0.1kg, SrO 0.01 kg. Mixing all glaze materials uniformly according to a formula ratio, adding water, grinding in a ball mill, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
The wear-resistant glaze layer comprises the following components in parts by weight: SiO22 40kg、Al2O3 15kg、K2O 2kg、Na2O 0.5kg、TiO2 0.2kg、Fe2O3 0.2kg、P2O50.05kg, MnO 0.01kg, MgO 0.3kg, CaO 10kg, BaO 4kg, SrO 0.02 kg. Mixing all wear-resistant glaze materials uniformly according to a formula ratio, adding water, adding the glaze materials into a ball mill for crushing, and adjusting the flow rate ratio of the glaze to a proper glaze spraying effect for later use.
Test examples
The prepared ceramic tiles A1-A6 and B1-B4 are subjected to wear resistance test according to the national standard GB/T3810.7-2016 ceramic tile test method part 7 of the national standard of the people's republic of China, namely the determination of the wear resistance of the surface of the glazed tile.
Summary of test results
| Test items | Wear resistance | Wear rating |
| A1 | 2100 turns | 4 stage |
| A2 | 2100 turns | 4 stage |
| A3 | 2500 rpm | 4 stage |
| A4 | 3000 turns | 4 stage |
| A5 | 3500 turn | 4 stage |
| A6 | 4500 revolutions | 4 stage |
| B1 | 1000 turn | Grade 3 |
| B2 | 1000 turn | Grade 3 |
| B3 | 2100 turns | 4 stage |
| B4 | 800 turn | Grade 3 |
The test result shows that: the wear-resisting property of the marble ceramic tile can reach 4 levels, and SiO is controlled in the formula of the wear-resisting glaze2、Al2O3The mass proportion of CaO is beneficial to improving the wear resistance of the ceramic tileThe wear resistance can be further improved by adding ZrO2 and ZnO in the wear-resistant glaze formula. In addition, the addition of alkaline earth metals such as CaO and BaO in the wear-resistant glaze greatly affects the wear resistance, so that the wear resistance of the ceramic tile is reduced from 4 to 3. The quality range of the wear-resistant glaze also has an influence on the wear resistance, and too low quality can cause the wear resistance to be reduced.
Variations and modifications to the above-described embodiments may occur to those skilled in the art based upon the disclosure and teachings of the above specification. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (9)
1. The utility model provides a4 level wear-resisting glaze marble ceramic tile, includes body layer, overglaze layer, decorative layer and the wear-resisting glaze layer that sets gradually from supreme down, its characterized in that, wear-resisting glaze layer includes the component by following parts by mass: SiO2240-50 parts of Al2O315-20 parts of K2O2-3 parts, Na20.5 to 1 portion of O and TiO20.2-0.4 part of Fe2O30.2-0.5 part of P2O50.05-0.1 part of MnO0.001-0.01 part of MgO 0.3-0.6 part of CaO 10-20 parts of BaO 4-5 parts of SrO 0.02-0.05 part of the wear-resistant glaze layer, wherein SiO is contained in the wear-resistant glaze layer2、Al2O3The mass ratio of CaO is (5.5-6): (2-3): (1.5-2).
2. The tile of claim 1, wherein the composition of the wear resistant glaze layer further comprises ZrO20.01-0.1 portion.
3. The grade 4 wear-resistant glazed marble tile according to claim 1, wherein the composition of the wear-resistant glaze layer further comprises ZnO 5-8 parts.
4. According toThe grade 4 wear-resistant glazed marble tile of claim 1, wherein the overglaze layer is prepared from a frit glaze comprising the following components in parts by mass: SiO2250-60 parts of Al2O320-25 parts of CaO, 1-2 parts of CaO, 0.4-0.6 part of MgO and K2O2-4 parts, Na23 to 4 portions of O, 0.1 to 0.4 portion of ZnO and 0.01 portion of SrO.
5. The grade 4 wear-resistant glazed marble tile according to claim 1, wherein the green body layer comprises the following components in parts by mass: 5-10 parts of J medium-temperature sand, 25-10 parts of J34 potassium sodium sand, 5-10 parts of J high clay 1#, 5-10 parts of J36 potassium sodium sand, 1#5-10 parts of J medium-temperature sand, 5-10 parts of J mixed mud 3# 5-8 parts of J mixed mud, 3-8 parts of J talc mud 1#3, 15-10 parts of J34 potassium sodium sand, 2-5 parts of J mixed sand, 2-5 parts of mud feces, 10-15 parts of J30 sodium stone powder, 4-7 parts of J52 mud strips, 10-15 parts of J refined aluminum sand, 2-5 parts of J washing mud, 4-7 parts of raw material recovery slurry, 0.03-0.09 part of alkaline diluent and 0.3-1 part of water glass.
6. The grade 4 wear-resistant glazed marble tile according to claim 1, wherein the tile is a full body marble tile, wherein the material of the green tile body layer is further added with pigment, wherein the pigment granularity is less than 325 meshes, and the water content is controlled below 1%.
7. A process for the preparation of a grade 4 wear resistant glazed marble tile according to any one of claims 1 to 6, comprising the steps of:
the method comprises the following steps: pressing the blank layer material into a ceramic tile forming blank, and drying in a kiln to form a semi-finished blank;
step two: applying overglaze to the semi-finished blank in the step one according to a bell jar type glaze pouring process to form an overglaze layer;
step three: printing patterns on the overglaze layer in the second step in an ink-jet mode to form a decorative layer;
step four: applying wear-resistant glaze on the decorative layer obtained in the third step to form a wear-resistant glaze layer;
step five: and drying and firing the semi-finished ceramic tile in front of a kiln, and then selecting qualified products for polishing and waxing to obtain the finished ceramic tile.
8. The preparation method according to claim 7, characterized in that the step four, the wear-resistant glaze is applied by a bell jar type glaze pouring process.
9. The method according to claim 7, wherein the wear resistant glaze has a quality control range of 50-55 g/tile, and the tile has a gauge of 800cm by 800 cm.
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| CN111960673B (en) * | 2020-08-26 | 2022-02-22 | 江西新明珠建材有限公司 | Manufacturing method of marble ceramic tile with glaze whiteness of 70 degrees |
| CN112707644A (en) * | 2020-12-24 | 2021-04-27 | 肇庆乐华陶瓷洁具有限公司 | Low-gloss transparent glaze, ceramic tile using same and preparation method thereof |
| CN114315332A (en) * | 2022-01-06 | 2022-04-12 | 广东中宏创展陶瓷有限公司 | Production process of skin-softening diamond luxury porcelain |
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