CN117550919B - Wax polished marble tile and preparation method thereof - Google Patents
Wax polished marble tile and preparation method thereof Download PDFInfo
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- CN117550919B CN117550919B CN202410037413.0A CN202410037413A CN117550919B CN 117550919 B CN117550919 B CN 117550919B CN 202410037413 A CN202410037413 A CN 202410037413A CN 117550919 B CN117550919 B CN 117550919B
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- 239000004579 marble Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 83
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 20
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 20
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 20
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052637 diopside Inorganic materials 0.000 claims abstract description 18
- 239000010456 wollastonite Substances 0.000 claims abstract description 17
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 17
- 239000010434 nepheline Substances 0.000 claims abstract description 16
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 16
- 239000006004 Quartz sand Substances 0.000 claims abstract description 15
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 15
- 239000000292 calcium oxide Substances 0.000 claims abstract description 15
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004575 stone Substances 0.000 claims abstract description 15
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 13
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 10
- RCMWGBKVFBTLCW-UHFFFAOYSA-N barium(2+);dioxido(dioxo)molybdenum Chemical compound [Ba+2].[O-][Mo]([O-])(=O)=O RCMWGBKVFBTLCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021538 borax Inorganic materials 0.000 claims abstract description 10
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 10
- 229910001610 cryolite Inorganic materials 0.000 claims abstract description 10
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims abstract description 10
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 10
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims abstract description 10
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims abstract description 10
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 10
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 10
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 10
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract description 10
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000001035 drying Methods 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 25
- 238000000498 ball milling Methods 0.000 claims description 21
- 238000005245 sintering Methods 0.000 claims description 18
- 239000000919 ceramic Substances 0.000 claims description 13
- 238000007873 sieving Methods 0.000 claims description 11
- 210000003298 dental enamel Anatomy 0.000 claims description 10
- 239000002699 waste material Substances 0.000 claims description 10
- 229910052661 anorthite Inorganic materials 0.000 claims description 8
- 229910052878 cordierite Inorganic materials 0.000 claims description 8
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 claims description 8
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910021532 Calcite Inorganic materials 0.000 claims description 7
- 239000010459 dolomite Substances 0.000 claims description 7
- 229910000514 dolomite Inorganic materials 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 7
- 229910052845 zircon Inorganic materials 0.000 claims description 7
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 7
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000007650 screen-printing Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 11
- 238000002834 transmittance Methods 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 105
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000011468 face brick Substances 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
- C04B2235/3248—Zirconates or hafnates, e.g. zircon
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
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- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention belongs to the technical field of marble tile preparation, and particularly relates to a wax polished marble tile and a preparation method thereof. The wax polished marble tile consists of a green body, a ground coat layer, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials: kaolin, bauxite, borax, lithium porcelain stone, cryolite, strontium carbonate, magnesium oxide, calcium oxide, cerium oxide and zirconium oxide; the wear-resistant glaze layer is composed of the following raw materials: quartz sand, mullite, diopside, nepheline, wollastonite whiskers, barium molybdate, and niobium pentoxide. The green body, the ground glaze layer, the pattern decorative layer, the wax glaze layer and the wear-resistant layer are mutually matched, the adaptability between the layers is strong, the prepared wax marble tile has good light transmittance and good wear resistance, and therefore the practicability and the surface effect of the wax marble tile are improved.
Description
Technical Field
The invention belongs to the technical field of marble tile preparation, and particularly relates to a wax polished marble tile and a preparation method thereof.
Background
The natural marble is widely applied to building wall and ground paving by the natural and primitive textures and bright and beautiful colors, and is a high-grade beautiful decorative material. However, as a product of nature, various drawbacks are inevitable, such as: strong radiation, large chromatic aberration, multiple flaws, easy dirt seepage, difficult management, high price, long supply period, non-renewable and the like. In order to solve these problems, marble tiles having realistic decorative effects of natural marble and superior properties of tiles have been developed. The marble tile is a new tile product after tiles, polished tiles, archaized tiles and microcrystalline tiles, has the texture, color, texture, handfeel and visual effect of natural marble, completely achieves the vivid effect of the natural marble, has decorative effect even better than the natural marble, simultaneously abandons various natural defects of the natural marble, has remarkable and extraordinary performance in the aspects of water absorption, flatness, flexural strength and other using performances, wins the favor of vast consumers, and is one of main stream products in the field of tiles.
In the current ceramic industry, ceramic tile glazes are typically three major types of glazes, distinguished by their apparent optical visual effect. The first is "matt glaze", also called "matt glaze", the glaze exhibits an opaque, opaque effect, the light is totally reflected at the surface layer, the microstructure belongs to a microcrystalline sintered body, if compared with a liquid, like a "suspension". The second is 'opaque glaze', the glaze is transparent but opaque, the microstructure is microcrystalline glass, a part of light is reflected at the surface layer, a part of light enters the glaze layer to generate diffuse reflection, and if the liquid is used for metaphorical purposes, the glass looks like 'milk'. The third is "transparent glaze", commonly called "crystal glaze", the glaze surface shows the light transmission, transparent effect, a small amount of light is reflected at the surface layer, after most light enters the glaze layer and is refracted, produce the secondary reflection at the blank glaze interface layer, microstructure belongs to amorphous glass body, if compare with the liquid, it is like "clear water, edible oil". The new appearance of the wax glaze has the effect of frosted glass, belongs to a glaze between the 'opaque glaze' and the 'transparent glaze', is a novel decorative glaze of a crystalline matt glaze system, has weak reflection of the wax glaze to light, has velvet luster on a smooth surface, is primitive and gorgeous, is resistant to people and is stable, deposited, soft, smooth, comfortable and fine, and gives people the feeling of stability, softness and delicacy. The wax glaze is applied to marble tiles, and is particularly suitable for decorating wall paintings, face bricks, sculptures and the like according to the characteristic that the wax glaze is elegant and clean. However, compared with other tile products, a fatal defect of the wax-polished marble tile is poor wear resistance, and the original bright surface is easy to scratch due to abrasion and other reasons in the use process, so that the surface effect and the practicability of the wax-polished marble tile are affected. And the traditional wax-light glaze is opaque and cannot be used in underglaze color decoration, so that the application range and the applicable scene are smaller, and the popularization and the application are difficult.
Therefore, it is necessary to explore a new wax-polished marble tile.
Disclosure of Invention
The purpose of the invention is that: the wax polished marble tile has good light transmittance and good wear resistance, so that the practicability and the surface effect of the wax polished marble tile are improved; the invention also provides a preparation method thereof.
The invention relates to a wax polished marble tile, which consists of a green body, a ground coat layer, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials in parts by weight: 37-38 parts of kaolin, 15-17 parts of bauxite, 12-14 parts of borax, 6-8 parts of lithium porcelain stone, 3-5 parts of cryolite, 1-2 parts of strontium carbonate, 5-7 parts of magnesium oxide, 7-9 parts of calcium oxide, 4-6 parts of cerium oxide and 7-8 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 22-24 parts of quartz sand, 11-13 parts of mullite, 10-12 parts of diopside, 7-9 parts of nepheline, 5-8 parts of wollastonite whisker, 4-7 parts of barium molybdate and 1-1.5 parts of niobium pentoxide.
Wherein:
in the wax glaze, the addition of kaolin and bauxite controls Al in the wax glaze 2 O 3 And SiO 2 The high-temperature viscosity and the transparency of the wax glaze are increased, excessive crystallization is avoided, the mixture of borax, lithium porcelain stone, cryolite and strontium carbonate is used as an opacifier to promote the formation of wax glaze microcrystals, and magnesium oxide, calcium oxide, zirconium oxide and cerium oxide are simultaneously introduced as auxiliary opacifying materials, so that the wax glaze has good suspension property, the bonding strength of the glaze is ensured, and the prepared wax glaze has better elasticity and wear resistance.
In the wear-resistant glaze layer, quartz sand, mullite and diopside are used as main raw materials, and a mullite phase and a cordierite phase are formed by calcining, so that the mechanical properties of the wear-resistant glaze layer are fundamentally ensured, and nepheline is used as a fluxing agent to be added. In addition, a mixture of wollastonite whiskers, barium molybdate and niobium pentoxide is added to the wear-resistant glaze layer. The wollastonite whisker has excellent corrosion resistance, mechanical property and extremely low thermal expansion coefficient, is applied to the wear-resistant glaze layer, effectively improves the fluidity of the wear-resistant glaze, ensures the bonding strength between the glaze layers, and improves the compactness of the wear-resistant glaze layer, thereby improving the mechanical strength of the wear-resistant glaze layer. The barium molybdate is added to reduce the sintering temperature of the wear-resistant glaze, and simultaneously improve the compactness, the wear resistance and the transparency of the wear-resistant glaze and reduce the deformation rate of a wear-resistant glaze layer, while the addition of the niobium pentoxide plays a role of refining grains, so that the mechanical property of the wear-resistant glaze can be further improved by controlling a small amount of addition.
The green body consists of the following raw materials in parts by weight: 52-53 parts of quartz sand, 37-39 parts of bauxite, 23-25 parts of kaolin, 19-21 parts of ceramic waste, 12-14 parts of red mud, 4-6 parts of calcite, 15-17 parts of diopside, 7-9 parts of anorthite and 5-7 parts of zircon sand.
The ceramic waste comprises the following chemical components in percentage by mass: siO (SiO) 2 61.58%、Al 2 O 3 26.42%、Fe 2 O 3 0.26%、CaO 1.03%、MgO 0.88%、K 2 O 3.08%、Na 2 O3.55% and loss on ignition 3.20%.
Anorthite, zircon sand, calcite and diopside are added into the green body, wherein the anorthite has low thermal expansion coefficient, and the addition of the anorthite increases the mechanical strength of the ceramic green body and reduces the sintering temperature of the green body. The addition of zircon sand can improve the hardness, wear resistance and strength of the blank. The addition of calcite can reduce the firing temperature of the green body, and a large amount of diopside is added in the green body, because the solid phase reaction speed of the diopside and other raw materials is slower, in the fired green body, more muddy diopside residues exist, and the residues play a role of a framework at high temperature and are similar to that of newly-formed mineral mullite, so that the mechanical strength of the green body is fundamentally ensured.
The ground coat layer consists of the following raw materials in parts by weight: 42-45 parts of quartz stone, 20-22 parts of kaolin, 14-16 parts of flint clay, 12-14 parts of dolomite, 5-7 parts of cordierite, 6-8 parts of wollastonite, 19-21 parts of potassium feldspar, 11-13 parts of nepheline and 13-15 parts of calcined talc.
Besides potassium feldspar, nepheline and talcum are added into the ground coat layer to reduce the sintering temperature and promote the formation of a glass phase, dolomite, cordierite and wollastonite are also added into the ground coat layer, wherein the introduction of the dolomite into the ground coat can promote the dissolution of quartz and the formation of mullite. And cordierite is added into the ground coat layer to reduce the thermal expansion coefficient of the glaze layer, so that the adaptability of the blank glaze is ensured. The addition of wollastonite can reduce the firing shrinkage and the thermal expansion in the firing process, and improve the mechanical strength of the base glaze.
The preparation method of the wax polished marble tile provided by the invention comprises the following steps:
(1) Wet ball grinding the raw material of the green body into slurry, drying to obtain powder, and then compression molding to prepare the green body;
(2) The green body is coated with ground enamel after being dried, so as to form a ground enamel layer;
(3) Screen printing a preset marble pattern on the ground glaze layer to form a pattern decorative layer;
(4) Coating wax glaze on the pattern decorative layer to form a wax glaze layer;
(5) And (3) spreading wear-resistant glaze on the wax polished glaze layer to form a wear-resistant glaze layer, and finally drying and sintering to prepare the wax polished marble tile.
Wherein:
the mass of water added in the wet ball milling in the step (1) accounts for 24-27% of the sum of the mass of the raw material of the green body and the mass of water, and the ball milling time is 16-18h.
The drying temperature in the step (1) is 110-115 ℃ and the drying time is 8-8.5h.
The pressure of the molding in the step (1) is 120-125MPa.
In the step (2), the ground coat raw material is ball-milled by a wet method and then screened by a 300-mesh sieve, wherein the mass of the added water accounts for 40-45% of the sum of the mass of the water and the ground coat raw material.
The drying temperature in the step (2) is 110-115 ℃ and the drying time is 3-3.5h.
The wax glaze in the step (4) is prepared by ball milling the raw materials of the wax glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 85-88% of the sum of the mass of the water and the raw materials of the wax glaze layer.
The wear-resistant glaze in the step (5) is prepared by ball milling raw materials of a wear-resistant glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 80-82% of the sum of the mass of the raw materials of the wear-resistant glaze layer and the water.
The drying temperature in the step (5) is 550-570 ℃ and the drying time is 3-3.5h.
The sintering temperature in the step (5) is 1260-1270 ℃ and the sintering time is 1.0-1.2h.
Compared with the prior art, the invention has the following beneficial effects:
(1) The green body, the ground coat, the pattern decorative layer, the wax light glaze layer and the wear-resistant glaze layer of the wax light marble tile are mutually matched, the adaptability between the layers is strong, the prepared wax light marble tile has good light transmittance and good wear resistance, and therefore the practicability and the surface effect of the wax light marble tile are improved.
(2) The preparation method of the wax polished marble tile has the advantages of simple process, easy parameter control, good pattern effect of the prepared wax polished marble tile, excellent wear resistance and soft surface.
Detailed Description
The invention is further described below with reference to examples.
Example 1
The wax polished marble tile of the embodiment 1 comprises a green body, a ground coat layer, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer comprises the following raw materials in parts by weight: 37.5 parts of kaolin, 16 parts of bauxite, 13 parts of borax, 7 parts of lithium porcelain stone, 4 parts of cryolite, 1.5 parts of strontium carbonate, 6 parts of magnesium oxide, 8 parts of calcium oxide, 5 parts of cerium oxide and 7.5 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 23 parts of quartz sand, 12 parts of mullite, 11 parts of diopside, 8 parts of nepheline, 6.5 parts of wollastonite whisker, 5.5 parts of barium molybdate and 1.3 parts of niobium pentoxide.
Wherein:
the green body consists of the following raw materials in parts by weight: 52.5 parts of quartz sand, 38 parts of bauxite, 24 parts of kaolin, 20 parts of ceramic waste, 13 parts of red mud, 5 parts of calcite, 16 parts of diopside, 8 parts of anorthite and 6 parts of zircon sand.
The ceramic waste comprises the following chemical components in percentage by mass: siO (SiO) 2 61.58%、Al 2 O 3 26.42%、Fe 2 O 3 0.26%、CaO 1.03%、MgO 0.88%、K 2 O 3.08%、Na 2 O3.55% and loss on ignition 3.20%.
The ground coat layer consists of the following raw materials in parts by weight: 43.5 parts of quartz stone, 21 parts of kaolin, 15 parts of flint clay, 13 parts of dolomite, 6 parts of cordierite, 7 parts of wollastonite, 20 parts of potassium feldspar, 12 parts of nepheline and 14 parts of calcined talc.
The preparation method of the wax polished marble tile of the embodiment 1 comprises the following steps:
(1) Wet ball grinding the raw material of the green body into slurry, drying to obtain powder, and then compression molding to prepare the green body;
(2) The green body is coated with ground enamel after being dried, so as to form a ground enamel layer;
(3) Screen printing a preset marble pattern on the ground glaze layer to form a pattern decorative layer;
(4) Coating wax glaze on the pattern decorative layer to form a wax glaze layer;
(5) And (3) spreading wear-resistant glaze on the wax polished glaze layer to form a wear-resistant glaze layer, and finally drying and sintering to prepare the wax polished marble tile.
Wherein:
the mass of water added during wet ball milling in the step (1) accounts for 25.5 percent of the sum of the mass of the raw material of the green body and the mass of water, and the ball milling time is 17 hours.
The drying temperature in the step (1) is 113 ℃, and the drying time is 8.3h.
The pressure of the molding in the step (1) is 123MPa.
In the step (2), the ground coat raw material is ball-milled by a wet method and then screened by a 300-mesh sieve, wherein the mass of added water accounts for 43% of the sum of the mass of water and the ground coat raw material.
The drying temperature in the step (2) is 113 ℃, and the drying time is 3.3h.
The wax glaze in the step (4) is prepared by ball milling the raw material of the wax glaze layer by a wet method and sieving the raw material by a 300-mesh sieve, wherein the mass of added water accounts for 86% of the sum of the mass of water and the mass of the raw material of the wax glaze layer.
The wear-resistant glaze in the step (5) is prepared by ball milling raw materials of a wear-resistant glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 81 percent of the sum of the mass of water and the mass of the raw materials of the wear-resistant glaze layer.
The drying temperature in the step (5) is 560 ℃ and the drying time is 3.3h.
In the step (5), the sintering temperature is 1265 ℃ and the sintering time is 1.1h.
Example 2
The wax polished marble tile of the embodiment 2 comprises a green body, a ground coat, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer comprises the following raw materials in parts by weight: 38 parts of kaolin, 15 parts of bauxite, 14 parts of borax, 8 parts of lithium porcelain stone, 3 parts of cryolite, 2 parts of strontium carbonate, 7 parts of magnesium oxide, 7 parts of calcium oxide, 6 parts of cerium oxide and 8 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 24 parts of quartz sand, 11 parts of mullite, 10 parts of diopside, 7 parts of nepheline, 5 parts of wollastonite whisker, 7 parts of barium molybdate and 1 part of niobium pentoxide.
Wherein:
the green body consists of the following raw materials in parts by weight: 53 parts of quartz sand, 37 parts of bauxite, 23 parts of kaolin, 19 parts of ceramic waste, 14 parts of red mud, 6 parts of calcite, 17 parts of diopside, 7 parts of anorthite and 7 parts of zircon sand.
The ceramic waste comprises the following chemical components in percentage by mass: siO (SiO) 2 61.58%、Al 2 O 3 26.42%、Fe 2 O 3 0.26%、CaO 1.03%、MgO 0.88%、K 2 O 3.08%、Na 2 O3.55% and loss on ignition 3.20%.
The ground coat layer consists of the following raw materials in parts by weight: 45 parts of quartz stone, 20 parts of kaolin, 14 parts of flint clay, 14 parts of dolomite, 7 parts of cordierite, 6 parts of wollastonite, 21 parts of potassium feldspar, 11 parts of nepheline and 13 parts of calcined talc.
The preparation method of the wax polished marble tile of the embodiment 2 comprises the following steps:
(1) Wet ball grinding the raw material of the green body into slurry, drying to obtain powder, and then compression molding to prepare the green body;
(2) The green body is coated with ground enamel after being dried, so as to form a ground enamel layer;
(3) Screen printing a preset marble pattern on the ground glaze layer to form a pattern decorative layer;
(4) Coating wax glaze on the pattern decorative layer to form a wax glaze layer;
(5) And (3) spreading wear-resistant glaze on the wax polished glaze layer to form a wear-resistant glaze layer, and finally drying and sintering to prepare the wax polished marble tile.
Wherein:
the mass of water added during wet ball milling in the step (1) accounts for 27% of the sum of the mass of the raw material of the green body and the mass of water, and the ball milling time is 18 hours.
The drying temperature in the step (1) is 115 ℃ and the drying time is 8.5h.
The pressure of the molding in the step (1) is 125MPa.
In the step (2), the ground coat raw material is ball-milled by a wet method and then screened by a 300-mesh sieve, wherein the mass of added water accounts for 40% of the sum of the mass of water and the ground coat raw material.
The drying temperature in the step (2) is 110 ℃, and the drying time is 3.5h.
The wax glaze in the step (4) is prepared by ball milling the raw material of the wax glaze layer by a wet method and sieving the raw material by a 300-mesh sieve, wherein the mass of added water accounts for 88% of the sum of the mass of water and the mass of the raw material of the wax glaze layer.
The wear-resistant glaze in the step (5) is prepared by ball milling raw materials of a wear-resistant glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 82% of the sum of the mass of water and the mass of the raw materials of the wear-resistant glaze layer.
The drying temperature in the step (5) is 570 ℃, and the drying time is 3.5h.
The sintering temperature in the step (5) is 1270 ℃ and the sintering time is 1.2h.
Example 3
The wax polished marble tile of the embodiment 3 comprises a green body, a ground coat layer, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer comprises the following raw materials in parts by weight: 37 parts of kaolin, 17 parts of bauxite, 12 parts of borax, 6 parts of lithium porcelain stone, 5 parts of cryolite, 1 part of strontium carbonate, 5 parts of magnesium oxide, 9 parts of calcium oxide, 4 parts of cerium oxide and 7 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 22 parts of quartz sand, 13 parts of mullite, 12 parts of diopside, 9 parts of nepheline, 8 parts of wollastonite whisker, 4 parts of barium molybdate and 1.5 parts of niobium pentoxide.
Wherein:
the green body consists of the following raw materials in parts by weight: 52 parts of quartz sand, 39 parts of bauxite, 25 parts of kaolin, 21 parts of ceramic waste, 12 parts of red mud, 4 parts of calcite, 15 parts of diopside, 9 parts of anorthite and 5 parts of zircon sand.
The ceramic waste comprises the following chemical components in percentage by mass: siO (SiO) 2 61.58%、Al 2 O 3 26.42%、Fe 2 O 3 0.26%、CaO 1.03%、MgO 0.88%、K 2 O 3.08%、Na 2 O3.55% and loss on ignition 3.20%.
The ground coat layer consists of the following raw materials in parts by weight: 42 parts of quartz stone, 22 parts of kaolin, 16 parts of flint clay, 12 parts of dolomite, 5 parts of cordierite, 8 parts of wollastonite, 19 parts of potassium feldspar, 13 parts of nepheline and 15 parts of calcined talc.
The preparation method of the wax polished marble tile of the embodiment 3 comprises the following steps:
(1) Wet ball grinding the raw material of the green body into slurry, drying to obtain powder, and then compression molding to prepare the green body;
(2) The green body is coated with ground enamel after being dried, so as to form a ground enamel layer;
(3) Screen printing a preset marble pattern on the ground glaze layer to form a pattern decorative layer;
(4) Coating wax glaze on the pattern decorative layer to form a wax glaze layer;
(5) And (3) spreading wear-resistant glaze on the wax polished glaze layer to form a wear-resistant glaze layer, and finally drying and sintering to prepare the wax polished marble tile.
Wherein:
the mass of water added during wet ball milling in the step (1) accounts for 24% of the sum of the mass of the raw material of the green body and the mass of water, and the ball milling time is 16 hours.
The drying temperature in the step (1) is 110 ℃, and the drying time is 8 hours.
The pressure of the molding in the step (1) is 120MPa.
In the step (2), the ground coat raw material is ball-milled by a wet method and then screened by a 300-mesh sieve, wherein the mass of added water accounts for 45% of the sum of the mass of water and the ground coat raw material.
The drying temperature in the step (2) is 115 ℃ and the drying time is 3 hours.
The wax glaze in the step (4) is prepared by ball milling the raw material of the wax glaze layer by a wet method and sieving the raw material by a 300-mesh sieve, wherein the mass of added water accounts for 85% of the sum of the mass of water and the mass of the raw material of the wax glaze layer.
The wear-resistant glaze in the step (5) is prepared by ball milling raw materials of a wear-resistant glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 80% of the sum of the mass of water and the mass of the raw materials of the wear-resistant glaze layer.
The drying temperature in the step (5) is 550 ℃, and the drying time is 3 hours.
In the step (5), the sintering temperature is 1260 ℃ and the sintering time is 1.0h.
Comparative example 1
The preparation method of the wax polished marble tile of this comparative example 1 is the same as that of example 1, except that the raw material composition is different. The wax polished marble tile of the comparative example 1 consists of a green body, a ground coat, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials in parts by weight: 37.5 parts of kaolin, 16 parts of bauxite, 13 parts of borax, 7 parts of lithium porcelain stone, 4 parts of cryolite, 1.5 parts of strontium carbonate, 6 parts of magnesium oxide, 8 parts of calcium oxide, 5 parts of cerium oxide and 7.5 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 23 parts of quartz sand, 12 parts of mullite, 11 parts of diopside, 8 parts of nepheline, 5.5 parts of barium molybdate and 1.3 parts of niobium pentoxide.
Comparative example 2
The preparation method of the wax polished marble tile of this comparative example 2 is the same as that of example 1, except that the raw material composition is different. The wax polished marble tile of the comparative example 2 consists of a green body, a ground coat, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials in parts by weight: 37.5 parts of kaolin, 16 parts of bauxite, 13 parts of borax, 7 parts of lithium porcelain stone, 4 parts of cryolite, 1.5 parts of strontium carbonate, 6 parts of magnesium oxide, 8 parts of calcium oxide, 5 parts of cerium oxide and 7.5 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 23 parts of quartz sand, 12 parts of mullite, 11 parts of diopside, 8 parts of nepheline, 6.5 parts of wollastonite whisker and 1.3 parts of niobium pentoxide.
Comparative example 3
The preparation method of the wax polished marble tile of this comparative example 3 is the same as that of example 1, except that the raw material composition is different. The wax polished marble tile of the comparative example 3 consists of a green body, a ground coat, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials in parts by weight: 37.5 parts of kaolin, 16 parts of bauxite, 13 parts of borax, 7 parts of lithium porcelain stone, 4 parts of cryolite, 1.5 parts of strontium carbonate, 6 parts of magnesium oxide, 8 parts of calcium oxide, 5 parts of cerium oxide and 7.5 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 23 parts of quartz sand, 12 parts of mullite, 11 parts of diopside, 8 parts of nepheline, 6.5 parts of wollastonite whisker and 5.5 parts of barium molybdate.
The wax polished marble tiles prepared in examples 1-3 and comparative examples 1-3 were subjected to performance tests, the results of which are shown in Table 1 below:
TABLE 1 results of Performance test of wax polished marble tiles
Claims (10)
1. A wax polished marble tile, characterized in that: the decorative coating consists of a green body, a ground coat, a pattern decorative layer, a wax polished glaze layer and a wear-resistant glaze layer, wherein the wax polished glaze layer consists of the following raw materials in parts by weight: 37-38 parts of kaolin, 15-17 parts of bauxite, 12-14 parts of borax, 6-8 parts of lithium porcelain stone, 3-5 parts of cryolite, 1-2 parts of strontium carbonate, 5-7 parts of magnesium oxide, 7-9 parts of calcium oxide, 4-6 parts of cerium oxide and 7-8 parts of zirconium oxide; the wear-resistant glaze layer consists of the following raw materials in parts by weight: 22-24 parts of quartz sand, 11-13 parts of mullite, 10-12 parts of diopside, 7-9 parts of nepheline, 5-8 parts of wollastonite whisker, 4-7 parts of barium molybdate and 1-1.5 parts of niobium pentoxide.
2. The wax polished marble tile of claim 1, wherein: the green body consists of the following raw materials in parts by weight: 52-53 parts of quartz sand, 37-39 parts of bauxite, 23-25 parts of kaolin, 19-21 parts of ceramic waste, 12-14 parts of red mud, 4-6 parts of calcite, 15-17 parts of diopside, 7-9 parts of anorthite and 5-7 parts of zircon sand.
3. A wax polished marble tile as in claim 2, wherein: the ceramic waste comprises the following chemical components in percentage by mass: siO (SiO) 2 61.58%、Al 2 O 3 26.42%、Fe 2 O 3 0.26%、CaO 1.03%、MgO 0.88%、K 2 O 3.08%、Na 2 O3.55% and loss on ignition 3.20%.
4. The wax polished marble tile of claim 1, wherein: the ground coat layer consists of the following raw materials in parts by weight: 42-45 parts of quartz stone, 20-22 parts of kaolin, 14-16 parts of flint clay, 12-14 parts of dolomite, 5-7 parts of cordierite, 6-8 parts of wollastonite, 19-21 parts of potassium feldspar, 11-13 parts of nepheline and 13-15 parts of calcined talc.
5. A method for preparing a wax polished marble tile as defined in claim 1, wherein: the method comprises the following steps:
(1) Wet ball grinding the raw material of the green body into slurry, drying to obtain powder, and then compression molding to prepare the green body;
(2) The green body is coated with ground enamel after being dried, so as to form a ground enamel layer;
(3) Screen printing a preset marble pattern on the ground glaze layer to form a pattern decorative layer;
(4) Coating wax glaze on the pattern decorative layer to form a wax glaze layer;
(5) And (3) spreading wear-resistant glaze on the wax polished glaze layer to form a wear-resistant glaze layer, and finally drying and sintering to prepare the wax polished marble tile.
6. The method for preparing a wax polished marble tile according to claim 5, wherein: the mass of water added in the wet ball milling in the step (1) accounts for 24-27% of the sum of the mass of the raw material of the green body and the mass of water, and the ball milling time is 16-18h.
7. The method for preparing a wax polished marble tile according to claim 5, wherein: the drying temperature in the step (1) is 110-115 ℃ and the drying time is 8-8.5h;
the pressure of the compression molding in the step (1) is 120-125MPa.
8. The method for preparing a wax polished marble tile according to claim 5, wherein: the step (2) is prepared by ball milling the raw materials of the ground coat by a wet method and sieving the ground coat by a 300-mesh sieve, wherein the mass of added water accounts for 40-45% of the sum of the mass of the water and the raw materials of the ground coat;
the drying temperature in the step (2) is 110-115 ℃ and the drying time is 3-3.5h.
9. The method for preparing a wax polished marble tile according to claim 5, wherein: the wax glaze in the step (4) is prepared by ball milling the raw materials of the wax glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 85-88% of the sum of the mass of the water and the raw materials of the wax glaze layer.
10. The method for preparing a wax polished marble tile according to claim 5, wherein: the wear-resistant glaze in the step (5) is prepared by ball milling raw materials of a wear-resistant glaze layer by a wet method and sieving the raw materials with a 300-mesh sieve, wherein the mass of added water accounts for 80-82% of the sum of the mass of the water and the raw materials of the wear-resistant glaze layer;
the drying temperature in the step (5) is 550-570 ℃ and the drying time is 3-3.5h;
the sintering temperature in the step (5) is 1260-1270 ℃ and the sintering time is 1.0-1.2h.
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| CN217557526U (en) * | 2022-02-12 | 2022-10-11 | 肇庆市玉山陶瓷工业有限公司 | Large-size ultrawhite wear-resistant marble tile |
| CN115806389A (en) * | 2023-01-28 | 2023-03-17 | 吴绍昌 | Lithium-free heat-resistant earthenware pot enamel and preparation process thereof |
| CN116143410A (en) * | 2023-03-02 | 2023-05-23 | 广东简一(集团)陶瓷有限公司 | Marble crystal glaze, marble tile using marble crystal glaze and preparation process of marble crystal glaze |
| CN116854375A (en) * | 2023-06-29 | 2023-10-10 | 佛山市三水区康立泰无机合成材料有限公司 | Waxy dry grain glaze, waxy ceramic tile with 3D stereoscopic effect and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106495742B (en) * | 2016-11-07 | 2019-09-24 | 美丽大道有限公司 | Anti- wax stone bonding glaze, anti-wax stone bonding ceramics and its preparation process |
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| WO2005002530A1 (en) * | 2003-07-04 | 2005-01-13 | Nanon A/S | A method of producing a silanized composite filler and a method of producing a composite material |
| CN102992812A (en) * | 2012-12-04 | 2013-03-27 | 陕西科技大学 | Microcrystal-reinforced transparent leadless fritted glaze and preparation method thereof |
| RU2526091C1 (en) * | 2013-07-08 | 2014-08-20 | Юлия Алексеевна Щепочкина | Charge composition of glaze |
| CN107129150A (en) * | 2017-06-27 | 2017-09-05 | 佛山市大千色釉料有限公司 | A kind of high abrasion glaze for glazed tile and preparation method thereof |
| CN217557526U (en) * | 2022-02-12 | 2022-10-11 | 肇庆市玉山陶瓷工业有限公司 | Large-size ultrawhite wear-resistant marble tile |
| CN115806389A (en) * | 2023-01-28 | 2023-03-17 | 吴绍昌 | Lithium-free heat-resistant earthenware pot enamel and preparation process thereof |
| CN116143410A (en) * | 2023-03-02 | 2023-05-23 | 广东简一(集团)陶瓷有限公司 | Marble crystal glaze, marble tile using marble crystal glaze and preparation process of marble crystal glaze |
| CN116854375A (en) * | 2023-06-29 | 2023-10-10 | 佛山市三水区康立泰无机合成材料有限公司 | Waxy dry grain glaze, waxy ceramic tile with 3D stereoscopic effect and preparation method thereof |
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