CN100390089C - Method for preparing flux for high-brightness pollution-less ceramic decorative material - Google Patents

Method for preparing flux for high-brightness pollution-less ceramic decorative material Download PDF

Info

Publication number
CN100390089C
CN100390089C CNB2006100843332A CN200610084333A CN100390089C CN 100390089 C CN100390089 C CN 100390089C CN B2006100843332 A CNB2006100843332 A CN B2006100843332A CN 200610084333 A CN200610084333 A CN 200610084333A CN 100390089 C CN100390089 C CN 100390089C
Authority
CN
China
Prior art keywords
flux
materials
brightness
fluxing agent
ceramic decorative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2006100843332A
Other languages
Chinese (zh)
Other versions
CN1850683A (en
Inventor
曹春娥
郑乃章
沈华荣
熊春华
卢希龙
余峰
刘阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jingdezhen Ceramic Institute
Original Assignee
Jingdezhen Ceramic Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jingdezhen Ceramic Institute filed Critical Jingdezhen Ceramic Institute
Priority to CNB2006100843332A priority Critical patent/CN100390089C/en
Publication of CN1850683A publication Critical patent/CN1850683A/en
Application granted granted Critical
Publication of CN100390089C publication Critical patent/CN100390089C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
    • C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention relates to a method for preparing a fluxing agent with high luster and no nuisance for ceramic decorative materials. The fluxing agent is made from natural raw mineral materials and industrial chemical materials: 40 to 50 wt% of SiO2, 25 to 35 wt% of B2O3, 5 to 10 wt% of Al2O3, 1.5 to 3.5 wt% of Li2O, 3.5 to 5.5 wt% of K2O, 2.5 to 4.5 wt% of Na2O, 4.5 to 6.5 wt% of SrO, 4.0 to 7.0 wt% of CaO and 1.5 to 2.0 wt% of fluoride; the raw materials are uniformly mixed, smelted, quenched, milled into balls, and dried, and thus, the product is prepared. The present invention optimizes the recipe, and thus, the fluxing agent with high luster, good coloration, good combination with glaze, wide adaptive coloration agents and no nuisance for ceramic decorative materials is prepared. The brightness of the ceramic product can achieve 110.2 to 114.9% after color baking, and the decorating effect of coloring pigment of native and foreign lead containing glaze is achieved.

Description

A kind of high gloss, the nuisanceless ceramic decoration material preparation method of flux
Technical field
The invention belongs to the ceramic decoration material technical field, be specifically related to the preparation method of a kind of high gloss, nuisanceless ceramic decoration material usefulness flux.
Background technology
The research of nuisanceless ceramic decoration material, up to the present most still being positioned on the aspect that how to reduce lead, quantity of cadmium release fundamentally do not solve innoxious problem, therefore is difficult to adapt to harsh day by day harmful element stripping limit standard requirement.The basic outlet that addresses the above problem is to research and develop out toner on the acid-resistant glaze (as the surface by replica, coated etc.) and unleaded, cadmium pigment, accounts for wherein that pigment forms that 50～90% flux is unleaded, cadmium and totally nontoxic evil be its key point.With alkali borosilicate system is the nuisanceless flux of foundational development, has the advantages that cost is low, be easy to apply, but it still exists gloss, colour generation, the coefficient of expansion is undesirable and adapts to problem such as toner narrow range.For example interim by applicant's disclosed " DEVELOPMENT OF FLUX FOR OVERGLAZE RED PIGMENT " literary composition at " Chinese pottery industry " the 8th volume 4, the flux that this method obtains still exists and adapts to toner narrow range, the relatively poor deficiency of glossiness, is difficult to reach the Modern Decorative ideal effect.
Summary of the invention
The present invention is by further adjusting the proportioning of flux main, producing beyond thought good result aspect the technical indicators such as gloss, colour generation, the coefficient of expansion, obtained high gloss, colour generation good, combine intact, as to adapt to the toner wide ranges nuisanceless ceramic decoration material flux with glaze.
A kind of high gloss of the present invention, the nuisanceless ceramic decoration material preparation method of flux adopts natural mineral raw and industrial chemicals, and it consists of: SiO 2Be 40～50wt%; B 2O 3Be 25～35wt%; Al 2O 3Be 5～10wt%; Li 2O is 1.5～3.5wt%; K 2O is 3.5～5.5wt%; Na 2O is 2.5～4.5wt%; SrO is 4.5～6.5wt%; CaO is 4.0～7.0wt%; Fluorochemical is 1.5～2.0wt%;
Through mixing, found, quenching, ball milling, the dry goods that obtain.
The present invention has optimized prescription by a large amount of experiments, has reduced the appearance of defectives such as crystallization, milkiness, colour killing after the color painting color roasting on the ceramic glaze, has guaranteed that it can adapt to the main colorant of over-glaze decoration series; Glossiness, adaptation toner scope and the color roasting rear surface quality of nuisanceless flux have further been improved; The finished product colour generation was good, acidproof, alkaline-resisting after the over-glaze decoration pigment that this flux is deployed into was made the marble paper color roasting, and thermostability meets industry standard, and glossiness can reach the decorative effect that color painting on the lead glaze is arranged both at home and abroad up to 110.2～114.9%.Detect through national domestic ceramics quality supervision and test center, its lead, quantity of cadmium release only are trace (extraneous factor introducing), are lower than ISO6486-2:1999 (E) regulation and California, USA standard.
Embodiment
Example 1:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
43.2 4.9 30.8 1.6 4.4 3.4 5.8 4.3 1.6
Example 2:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
46.1 6.8 28.6 2.45 3.4 2.8 4.9 3.6 1.35
Example 3:
According to the form below is formed preparation flux, and glass melting temperature is 1300 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
45.5 5.4 28.3 1.5 4.5 3.4 5 4.7 1.7
Example 4:
According to the form below is formed preparation flux, and glass melting temperature is 1250 ℃, is incubated 30 minutes, ball milling drying for standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
46.6 6.1 28.4 2.2 2.0 3.6 5.4 4 1.7
Example 5:
According to the form below is formed preparation flux, and glass melting temperature is 1280 ℃, is incubated 30 minutes, and ball milling is done standby behind the quenching.
SiO 2 Al 2O 3 B 2O 3 Li 2O K 2O Na 2O CaO SrO F
42.9 7.2 27.0 2.2 4.5 3.5 5.5 5.6 1.6
Toner and stand linseed oil are joined in the ground flux of the various embodiments described above gained, and marble paper is made in silk screen printing, and the melt temperature scope of using ZA-P type hot-stage microscope mensuration flux is carried out color roasting then to determine the color roasting temperature.
Gained ceramic product leading indicator detects as follows:
Glossiness: the glossiness of flower face after the color roasting of use WGG60-2 type vancometer mensuration marble paper;
Thermostability: check with reference to QB/T2455.2-1999;
Acidproof, alkaline resistance properties: check with reference to QB/T2455.2-1999;
Plumbous, quantity of cadmium release:, check with reference to GB/T3534-2002 according to ISO6486-2:1999 (E) regulation and California, USA standard.
Detected result sees the following form:
The embodiment numbering The color roasting temperature Glossiness Thermostability Plumbous, quantity of cadmium release Acidproof, alkali resistance
1 700～ 760℃ 114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
2 720～ 800℃ 112％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
3 780～ 850℃ 110.2～114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
4 700～ 800℃ 110.2～114.9％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster
5 700～ 800℃ 110.2％ 3 are not had be full of cracks Be lower than standard Tone, the obvious no change of color and luster

Claims (1)

1. a high gloss, nuisanceless ceramic decoration material adopt natural mineral raw and industrial chemicals with the preparation method of flux, and it consists of: SiO 2Be 40～50wt%; B 2O 3Be 25～35wt%; Al 2O 3Be 5～10wt%; Li 2O is 1.5～3.5wt%; K 2O is 3.5～5.5wt%; Na 2O is 2.5～4.5wt%; SrO is 4.5～6.5wt%; CaO is 4.0～7.0wt%; Fluorochemical is 1.5～2.0wt%;
Through mixing, found, quenching, ball milling, the dry goods that obtain.
CNB2006100843332A 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material Expired - Fee Related CN100390089C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100843332A CN100390089C (en) 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100843332A CN100390089C (en) 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material

Publications (2)

Publication Number Publication Date
CN1850683A CN1850683A (en) 2006-10-25
CN100390089C true CN100390089C (en) 2008-05-28

Family

ID=37132185

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2006100843332A Expired - Fee Related CN100390089C (en) 2006-05-16 2006-05-16 Method for preparing flux for high-brightness pollution-less ceramic decorative material

Country Status (1)

Country Link
CN (1) CN100390089C (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103011765A (en) * 2012-12-25 2013-04-03 青岛科技大学 Flux system for sintering ceramic body in liquid phase and preparation method thereof
CN105753324B (en) * 2016-01-23 2018-01-12 景德镇陶瓷大学 It is a kind of to grind the method for adding Ludox to prepare high alkali resistance ceramics overglaze color flux
CN105753513B (en) * 2016-01-23 2018-04-20 景德镇陶瓷大学 A kind of trailing of highly corrosion resistant ceramic glazing dyestuff
CN105731797B (en) * 2016-01-23 2017-12-26 景德镇陶瓷大学 A kind of preparation method of the high alkali resistance lead-free ceramicses overglaze color flux of use in dishwasher
CN110066109B (en) * 2019-05-28 2022-02-22 江西陶瓷工艺美术职业技术学院 Flux for antique pigment and application method thereof
CN111646701B (en) * 2020-06-06 2022-05-20 景德镇市民俗文化瓷业有限公司 Method for decorating composite color ceramic with overglaze pigment

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1048211A (en) * 1990-07-24 1991-01-02 周国栋 The manufacture method of red stone porcelain

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1048211A (en) * 1990-07-24 1991-01-02 周国栋 The manufacture method of red stone porcelain

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
釉上彩红色颜料熔剂的研制. 曹春娥等.中国陶瓷工业，第8卷第4期. 2001
釉上彩红色颜料熔剂的研制. 曹春娥等.中国陶瓷工业，第8卷第4期. 2001 *

Also Published As

Publication number Publication date
CN1850683A (en) 2006-10-25

Similar Documents

Publication Publication Date Title
CN106673438B (en) There is unreal star stone glazed tile of aventurine effect and preparation method thereof on a kind of surface
CN100390089C (en) Method for preparing flux for high-brightness pollution-less ceramic decorative material
CN110734303A (en) Porcelain archaized brick with matt, fine and soft glaze surface and preparation method thereof
CN107188412A (en) A kind of raw material matting glaze and its preparation method and application
CN103642317A (en) Low temperature ceramic inkjet ink
CN102010126A (en) Lead-free frit for glass color ceramic glaze and preparation method thereof
CN103332968B (en) Full-polishing glaze production process and prepared product
CN106278387B (en) There is the glazed tile and preparation method thereof of gold decorative effect on surface
CN101585717A (en) Lead and cadmium free fritted glaze for bone China with high acid resistance and alkali resistance
CN108484123A (en) A kind of Ceramic Tiles and preparation method thereof of high additive metallurgical steel slag waste material
CN105461354A (en) Domestic porcelain transfer printing lead-free glaze and preparation method thereof
CN105753325B (en) A kind of trailing of high alkali resistance ceramic glazing dyestuff
CN108191239A (en) A kind of unleaded metallic luster gold glaze and preparation method thereof
CN100528812C (en) Method for formulating moderate temperature bright red glaze
CN101050059B (en) Covering layer without lead, cadmium of pigment without lead on ceramic glaze, and preparation method
CN104973784B (en) Lead and cadmium free low-temp ceramics flux for pigment on glaze
CN105753324B (en) It is a kind of to grind the method for adding Ludox to prepare high alkali resistance ceramics overglaze color flux
CN106147395A (en) The big red ink of refractory ceramics and preparation method
CN107352800B (en) A kind of unleaded enamel brightness base glaze and its application method
CN113800770A (en) Intermediate-temperature double-layer transmutation fancy glaze and manufacturing method thereof
CN107540388A (en) High temperature powder enamel ceramics, preparation method and its purposes
CN111533450A (en) Microcrystalline foam board produced by utilizing lepidolite tailings and preparation method thereof
CN109133621B (en) Titanium color glaze for enamel
CN103011905B (en) Lead-free open-flame fast-firing full-frit bone-china glaze and preparation method for same
CN105776864A (en) High-transparency frit and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20080528

Termination date: 20160516