CN105753325B - A kind of trailing of high alkali resistance ceramic glazing dyestuff - Google Patents
A kind of trailing of high alkali resistance ceramic glazing dyestuff Download PDFInfo
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- CN105753325B CN105753325B CN201610044259.5A CN201610044259A CN105753325B CN 105753325 B CN105753325 B CN 105753325B CN 201610044259 A CN201610044259 A CN 201610044259A CN 105753325 B CN105753325 B CN 105753325B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
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- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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Abstract
The present invention discloses a kind of trailing of high alkali resistance ceramic glazing dyestuff, is formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate 3.7%, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, quartz raw material is added without when taking flux dispensing, the quartz raw material lacked is coordinated into supplement with the form of Ludox after flux is founded, then color roasting, then secondary color roasting is carried out after coating Ludox, sodium silicate and KP1, forms high silicon cap layer.The present invention substitutes quartz and the compound addition of transition metal oxide and using triple protections such as high silicon cap layer by using Ludox; obtained alkali resistance, which reaches, to be met the resistance to machine testing that washes the dishes of European Union and reaches color painting on the ceramic glaze of 0 grade of standard; the glass melting temperature of flux is reduced simultaneously; energy consumption is significantly reduced, therefore there is significant economic benefit.
Description
Technical field
The invention belongs to ceramic glazing dyestuff technical field, and in particular to a kind of decoration of high alkali resistance ceramic glazing dyestuff
Method.
Background technology
In recent years, the continuous quickening increasingly improved with rhythm of life of people's living standard, is greatly promoted food and drink, trip
The rapid development of the service trades such as trip, increasing food and beverage enterprise even average family start to eat to domestic ceramics from dish-washing machine
Tool etc. is cleaned.But alkaline auxiliary lotion, defoamer, oxidant, the surfactant contained in the cleaning solution used in dish-washing machine
With thickener etc., there is very strong corrosivity to Conventional Portland product, especially have to traditional overglaze color ceramic stronger
Corrosiveness, the overglaze color pottery after dish-washing machine cleans for a long time easily produces permanent surface damage, such as fade,
White opacity, iridescence, corrosion trace etc., have had a strong impact on their reuse, have improved use cost.
In addition, European Union is more and more harsher for the examination criteria of pottery machine washable, cause China's overglaze color decoration
Tableware for daily use, hotel porcelain etc. be difficult to it is up to standard, thus can not smooth export sales, brought to China's domestic ceramics industry very big
Impact.Important component of the flux as ceramic overglaze color, it is heavy to closing for the corrosion proof influence of ornament materials on glaze
Want.
Ceramic decoration material refers to the materials such as all kinds of pigment for decorating ceramic articles, decal paper, wherein with glaze
Based on decorative pigment.It is traditional but ceramic glazing dyestuff is mainly formulated by substantial amounts of flux and a certain amount of colorant
Decal paper forms various pigment according to specific color theory plus printings such as black oil simultaneously.The lead of ceramic decoration material
For the performances such as quantity of cadmium release, corrosion resistance in addition to the performance of colorant itself, it depends primarily on the flux that content is up to more than 70%,
Therefore there is significant impact to performances such as corrosion resistances in flux.
The development of nano material is maked rapid progress, and constantly opens up new application field.Low melting point is the main spy of nano material
One of sign.Nano level Ludox is mixed with flux, the melting temperature of silica will be greatly reduced, in relatively low temperature
Just eutectic can be formed with flux under degree, silica preferably can be dissolved in flux at a temperature of color roasting, forms glass network
Structure, strengthen the acid resistance of flux, alkali resistance, wearability, microhardness, etc. performance indications.In addition, some siliceous inorganic salts are such as
It sodium metasilicate, potassium silicate etc., can at a lower temperature melt, form high siliceous material, if these siliceous inorganic salts are applied
Be overlying on the flux of color roasting, carry out secondary color roasting, then these inorganic salts be easy to bottom flux formed eutectic, potassium,
Sodium etc. permeates downwards, and the molecule level silicon oxide decomposed is then trapped in top layer, one layer of fine and close high silica glass is formed, as one layer
The armor, flux is played a protective role, enhance the physical and chemical performance of flux.The content of the invention
The technical problem to be solved in the present invention is to provide a kind of technique is simple, green, alkali resistance is excellent, is adapted to wash the dishes
The trailing for the high alkali resistance ceramic glazing dyestuff that machine uses.
The present invention is achieved by the following technical programs：A kind of trailing of high alkali resistance ceramic glazing dyestuff, its
It is characterised by comprising the following steps：
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, weigh
Other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, it is standby that drying obtains flux；
Step 3：By flux obtained by step 2 and thin Ludox after 35~38 ﹕ 62~65 are mixed by weight percentage, by melting
Ceramic pigment on 20 ~ 33% additional glaze of agent weight, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing；
Step 4：Pigment obtained by step 3 is coated uniformly on flat porcelain plate, electric furnace color roasting is put into after drying, by 5 DEG C/
Min heating rate, 900 DEG C are warming up to, and are incubated 30min, furnace cooling；
Step 5：One or more in thick Ludox, sodium silicate, KP1 are mixed simultaneously, are coated uniformly on
Color roasting sample surfaces obtained by step 4, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, and soaking time is
30min, heating rate are 5 DEG C/min, and furnace cooling obtains color painting decorative product on high alkali resistance ceramic glaze.
The weight percentage of silica is 30% in the thin Ludox, average grain diameter 6nm.
The weight percentage of silica is 30% in the thick Ludox, average grain diameter 20nm.
Ceramic pigment is ceramic pigment on glaze that color roasting temperature is 850 ~ 950 DEG C on the glaze.
The modulus of the sodium silicate is 1, solid content 60%.
The modulus of the KP1 is 1, solid content 50%.
The thick Ludox, sodium silicate, KP1 mix in any proportion.
This patent is added without quartz raw material during flux dispensing, therefore, flux dispensing can using the method for mill plus Ludox
Found at a lower temperature, the quartz lacked is coordinated with flux in different proportions with Ludox to be supplemented, then color roasting, simultaneously
Coating carries out secondary color roasting after mixed liquor is made by Ludox, sodium silicate and KP1 etc., forms high silicon cap layer.One side
Face, compared with quartzy bulky grain, what it is due to addition is nano level Ludox, SiO therein2Can be at a temperature of relatively low color roasting
Eutectic is formed with flux, gained sample has higher glossiness；On the other hand, it is equal or even more due to having dissolved in
SiO2So that glass network structure is finer and close, and chemical stability, the physical property of flux color roasting sample greatly improve；The
Three, the quartz raw material of infusibility is added without during due to founding, the glass melting temperature than flux on traditional glaze substantially reduces.4th, it is secondary
The cap layer that color roasting is formed is because of its SiO2Content is high, and its chemical stability is high, further increases the alkali resistance of sample.
The present invention substitutes quartz and the compound addition of transition metal oxide and using high by using Ludox in summary
The triple protections such as silicon cap layer, are made the lead-free ceramicses overglaze color pigment that alkali resistance is excellent, is adapted to dish-washing machine to use, and its alkali resistance reaches
To meeting the resistance to 0 grade of standard optimal shown in machine testing standard that washes the dishes of European Union, while the glass melting temperature of flux is reduced, be greatly reduced
Energy consumption, therefore the pigment can be obviously improved China's domestic ceramics quality, have significant economic benefit.
Embodiment
Further to illustrate the present invention to reach the technological means and effect that predetermined goal of the invention is taken, below in conjunction with
Preferred embodiment, the present invention is described in detail：
Embodiment 1
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 38g obtained by step 2 is mixed with thin Ludox 62g, ceramic pigment on the additional dark blue glaze in sea
7.9g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.1g moduluses, the sodium silicate that solid content is 60% is coated uniformly on color roasting sample obtained by step 4
Product surface, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating rate 5
DEG C/min, furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, and after testing, its glossiness is sample after color roasting
104%, alkali resistance grade is 0 grade.
Embodiment 2
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 38g obtained by step 2 is mixed with thin Ludox 62g, ceramic pigment on the additional dark blue glaze in sea
9.5g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.04g moduluses, the sodium silicate and 0.06g moduluses that solid content is 60% are 1, solid content 50%
KP1 be coated uniformly on color roasting sample surfaces obtained by step 4, electric furnace is put into after drying and carries out color roasting again, color roasting temperature
For 920 DEG C, soaking time 30min, heating rate is 5 DEG C/min, and furnace cooling obtains color painting on high alkali resistance ceramic glaze
Sample is decorated, after testing, its glossiness is 103% to sample after color roasting, and alkali resistance grade is 0 grade.
Embodiment 3
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 38g obtained by step 2 is mixed with thin Ludox 62g, ceramic pigment on the additional dark blue glaze in sea
12.6g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.03g moduluses, the sodium silicate and 0.03g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.04g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 102%, and alkali resistance grade is 0 grade.
Embodiment 4
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 37g obtained by step 2 is mixed with thin Ludox 63g, ceramic pigment on additional praseodymium zirconium yellow glaze
7.4g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.05g moduluses, the sodium silicate and 0.02g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.03g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 99%, and alkali resistance grade is 0 grade.
Embodiment 5
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 37g obtained by step 2 is mixed with thin Ludox 63g, ceramic pigment on additional praseodymium zirconium yellow glaze
9.3g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.1g moduluses, the KP1 that solid content is 50% is coated uniformly on color roasting sample obtained by step 4
Product surface, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating rate 5
DEG C/min, furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, and after testing, its glossiness is sample after color roasting
100%, alkali resistance grade is 0 grade.
Embodiment 6
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 37g obtained by step 2 is mixed with thin Ludox 63g, ceramic pigment on additional praseodymium zirconium yellow glaze
12.3g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.03g moduluses, the sodium silicate and 0.07g weight percentages that solid content is 60% are 30%,
The thick Ludox that average grain diameter is 0.02nm is coated uniformly on color roasting sample surfaces obtained by step 4, and electric furnace progress is put into after drying
Color roasting again, color roasting temperature are 920 DEG C, soaking time 30min, and heating rate is 5 DEG C/min, and furnace cooling obtains high alkali resistance
Color painting decorates sample on ceramic glaze, and after testing, its glossiness is 101% to sample after color roasting, and alkali resistance grade is 0 grade.
Embodiment 7
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 36g obtained by step 2 is mixed with thin Ludox 64g, ceramic pigment on additional chrome green glaze
7.2g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.04g moduluses, the sodium silicate and 0.04g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.02g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 100%, and alkali resistance grade is 0 grade.
Embodiment 8
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 36g obtained by step 2 is mixed with thin Ludox 64g, ceramic pigment on additional chrome green glaze
9.0g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.02g moduluses, the KP1 and 0.08g weight percentages that solid content is 50% are 30%,
The thick Ludox that average grain diameter is 20nm is coated uniformly on color roasting sample surfaces obtained by step 4, and electric furnace is put into after drying and is carried out again
Color roasting, color roasting temperature are 920 DEG C, soaking time 30min, and heating rate is 5 DEG C/min, and furnace cooling obtains high alkali resistance pottery
Color painting decorates sample on enamel, and after testing, its glossiness is 99% to sample after color roasting, and alkali resistance grade is 0 grade.
Embodiment 9
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 36g obtained by step 2 is mixed with thin Ludox 64g, ceramic pigment on additional chrome green glaze
12.0g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.02g moduluses, the sodium silicate and 0.05g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.03g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 101%, and alkali resistance grade is 0 grade.
Embodiment 10
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 35g obtained by step 2 is mixed with thin Ludox 65g, ceramic pigment on additional gorgeous black glaze
7.0g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.02g moduluses, the sodium silicate and 0.06g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.02g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 102%, and alkali resistance grade is 0 grade.
Embodiment 11
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 35g obtained by step 2 is mixed with thin Ludox 65g, ceramic pigment on additional gorgeous black glaze
8.8g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 1 by 0.02g moduluses, the sodium silicate and 0.02g moduluses that solid content is 60% are 1, solid content 50%
KP1 and 0.06g weight percentages be 30%, average grain diameter is coated uniformly on step 4 institute for 20nm thick Ludox
Color roasting sample surfaces are obtained, electric furnace is put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min, heating
Speed is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, after color roasting sample after testing, its
Glossiness is 99%, and alkali resistance grade is 0 grade.
Embodiment 12
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate
3.7%th, potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, by total
Weight 100g weighs other raw materials in addition to quartz；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then will
Corundum crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high temperature
Melt pours into rapidly quenching in cold water, then after wet ball grinding, crosses 380 mesh sieves, be dried for standby；
Step 3：After flux 35g obtained by step 2 is mixed with thin Ludox 65g, ceramic pigment on additional gorgeous black glaze
11.6g, obtains color painting on high alkali resistance ceramic glaze afterwards by evenly mixing, and the weight percent of silica contains in the thin Ludox
Measure as 30%, average grain diameter 6nm；
Step 4：Pigment 0.4g obtained by step 3 is coated uniformly on flat porcelain plate by 60 × 60mm areas, put after drying
Enter electric furnace color roasting, by 5 DEG C/min heating rate, be warming up to 900 DEG C, and be incubated 30min, furnace cooling；
Step 5：It is 30% by 0.1g weight percentages, average grain diameter is that 20nm thick Ludox is coated uniformly on step
Four gained color roasting sample surfaces, electric furnace being put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min,
Heating rate is 5 DEG C/min, and furnace cooling obtains color painting decoration sample on high alkali resistance ceramic glaze, and sample is through inspection after color roasting
Survey, its glossiness is 98%, and alkali resistance grade is 0 grade.
The test and evaluation method of glossiness and alkali resistance
The gloss of the WGG-60A types Grossmeters test color roasting sample produced with Shanghai Xin Rui instrument and meters Co., Ltd
Degree, with EU criteria BS EN 12875-4:2006“Mechanical dishwashing resistance of
utensils-Part 4：Rapid test for domestic ceramic articles " carry out alkali resistance survey to sample
Examination, with EU criteria BS EN 12875-2:Assessment for classification method Assessment for classification in 2002 standards, its standard are as shown in the table：
European Union's Assessment for classification standard
| Grade | Cosmetic variation |
| 0 | Without visual change |
| 1 | Slight visual change |
| 2 | Obvious visual change |
Claims (6)
1. a kind of trailing of high alkali resistance ceramic glazing dyestuff, it is characterised in that comprise the following steps：
Step 1：Formed by formula as below percentage by weight：Quartz 24%, boric acid 46.7%, aluminum oxide 11.7%, lithium carbonate 3.7%,
Potassium nitrate 1.6%, sodium carbonate 1.2%, precipitated calcium carbonate 6.5%, niobium pentaoxide 0.7%, tantalum pentoxide 3.9%, weigh except quartz
Other outer raw materials；
Step 2：The mixing abrasive lapping that step 1 is weighed is uniform, after crossing 60 mesh sieves, is fitted into corundum crucible, then by corundum
Crucible is put into electric furnace and founded, and by 5 DEG C/min heating rate, is warming up to 1150 DEG C, and after being incubated 60min, by high-temperature fusant
Quenching in cold water is poured into rapidly, then after wet ball grinding, crosses 380 mesh sieves, it is standby that drying obtains flux；
Step 3：After flux obtained by step 2 is mixed with thin Ludox by weight 35~38 ﹕ 62~65, by flux weight
Ceramic pigment on 20 ~ 33% additional glaze, obtain high alkali resistance ceramic glazing dyestuff afterwards by evenly mixing；
Step 4：Pigment obtained by step 3 is coated uniformly on flat porcelain plate, electric furnace color roasting is put into after drying, by 5 DEG C/min's
Heating rate, 900 DEG C are warming up to, and are incubated 30min, furnace cooling；
Step 5：One or more in thick Ludox, sodium silicate, KP1 are mixed simultaneously, are coated uniformly on step
Four gained color roasting sample surfaces, electric furnace being put into after drying and carries out color roasting again, color roasting temperature is 920 DEG C, soaking time 30min,
Heating rate is 5 DEG C/min, and furnace cooling obtains high alkali resistance ceramic glazing dyestuff decorative product；
The weight percentage of silica is 30% in the thin Ludox, average grain diameter 6nm.
2. according to the method for claim 1, it is characterised in that：The weight percentage of silica is in the thick Ludox
30%, average grain diameter 20nm.
3. according to the method for claim 1, it is characterised in that：Ceramic pigment is that color roasting temperature is 850 ~ 950 on the glaze
DEG C glaze on ceramic pigment.
4. according to the method for claim 1, it is characterised in that：The modulus of the sodium silicate is 1, solid content 60%.
5. according to the method for claim 1, it is characterised in that：The modulus of the KP1 is 1, solid content 50%.
6. according to the method for claim 1, it is characterised in that：The thick Ludox, sodium silicate, KP1 are by any
Ratio mixes.
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| CN107858018A (en) * | 2017-10-17 | 2018-03-30 | 重庆工业职业技术学院 | The special colouring pigment of ceramic sintering |
| CN110128854B (en) * | 2019-05-28 | 2021-01-15 | 江苏拜富科技股份有限公司 | Acid and alkali resistant flux for low temperature corrosion resistant pigment for ceramic wine bottle |
| CN111072283A (en) * | 2019-12-28 | 2020-04-28 | 福建省德化县溢茂工艺有限公司 | Preparation process for preparing high-alkali-resistance ceramic glazing solvent by grinding and adding silica sol |
| CN112624614B (en) * | 2020-12-25 | 2022-05-20 | 唐山北方瓷都陶瓷集团卫生陶瓷有限责任公司 | High-wear-resistance ceramic glaze and preparation method thereof |
| CN113105267B (en) * | 2021-04-13 | 2023-01-31 | 景德镇陶瓷大学 | Ceramic stained paper additive, ceramic stained paper, selenium-rich ceramic and preparation method |
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| EP0665192A1 (en) * | 1994-01-31 | 1995-08-02 | COOKSON MATTHEY CERAMICS & MATERIALS LIMITED | Lead and cadmium free glass flux compositions |
| CN102234202A (en) * | 2010-04-27 | 2011-11-09 | 重庆工商大学 | Preparation method and glazing technology of ultra-low temperature red glaze additive |
| CN103044082A (en) * | 2012-12-24 | 2013-04-17 | 醴陵市红玉红瓷陶瓷研究中心 | Luminescent glaze for enamel painted porcelain and preparation method and application thereof |
| CN105198495A (en) * | 2015-10-20 | 2015-12-30 | 佛山市华意陶瓷颜料有限公司 | Small-particle-diameter praseodymium zirconium yellow ceramic pigment and preparation method thereof |
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2016
- 2016-01-23 CN CN201610044259.5A patent/CN105753325B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0665192A1 (en) * | 1994-01-31 | 1995-08-02 | COOKSON MATTHEY CERAMICS & MATERIALS LIMITED | Lead and cadmium free glass flux compositions |
| CN102234202A (en) * | 2010-04-27 | 2011-11-09 | 重庆工商大学 | Preparation method and glazing technology of ultra-low temperature red glaze additive |
| CN103044082A (en) * | 2012-12-24 | 2013-04-17 | 醴陵市红玉红瓷陶瓷研究中心 | Luminescent glaze for enamel painted porcelain and preparation method and application thereof |
| CN105198495A (en) * | 2015-10-20 | 2015-12-30 | 佛山市华意陶瓷颜料有限公司 | Small-particle-diameter praseodymium zirconium yellow ceramic pigment and preparation method thereof |
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