CN105271752B - A kind of preparation method of low gloss colour enamel glaze - Google Patents
A kind of preparation method of low gloss colour enamel glaze Download PDFInfo
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- CN105271752B CN105271752B CN201510665559.0A CN201510665559A CN105271752B CN 105271752 B CN105271752 B CN 105271752B CN 201510665559 A CN201510665559 A CN 201510665559A CN 105271752 B CN105271752 B CN 105271752B
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- glaze
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- enamel
- low gloss
- novel
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 238000000498 ball milling Methods 0.000 claims abstract description 18
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 239000000375 suspending agent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 11
- 239000000037 vitreous enamel Substances 0.000 claims abstract description 10
- 238000010304 firing Methods 0.000 claims abstract description 7
- 238000005303 weighing Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
- 239000010960 cold rolled steel Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- 238000002386 leaching Methods 0.000 claims description 5
- 210000001161 mammalian embryo Anatomy 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000002585 base Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 230000001458 anti-acid effect Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 239000006224 matting agent Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 230000008033 biological extinction Effects 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 4
- -1 mill addition Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Abstract
The present invention relates to the enamel glaze delustrings in enamel applications, and in particular to a kind of preparation method of low gloss colour enamel glaze, wherein the composition of low gloss colour vitreous enamel includes base glaze, colorant, auxiliary agent, suspending agent, novel delustering agent, water, by quality component：Base glaze：100 parts, novel delustering agent：2~8 parts, colorant：1~5 part, auxiliary agent：0.1~0.3 part, suspending agent：5~8 parts, water：45~55 parts；Include batch weighing, ball milling, drying, firing using the method that above-mentioned low gloss colour vitreous enamel prepares glaze.Novel delustering agent is added to the gloss that enamel glaze is reduced in glaze formula by the present invention, in combination with special preparation method, the gloss of enamel glaze can be not only reduced, meets technology rule method requirement, the anti acid alkali performance for the enamel glaze that can also be improved simultaneously, corrosion resistance etc..
Description
Technical field
The present invention relates to the enamel glaze delustrings in enamel applications, and in particular to a kind of system of low gloss colour enamel glaze
Preparation Method.
Background technology
Currently, applied to tunnel and the decoration board with enamel panel layer of the outer curtain wall of heavy construction, required in technical specification of security
Compared with low-luster.With traditional extinction method, some color glaze-surface gloss are extremely difficult to design requirement, and brought by delustring
Cost is also very high or even some chromatic colours can not do the effect of low gloss at all, therefore in order to meet code requirement, maximum
Change meets the needs of client, and reduces production cost, and our unit technical staff researches and develops experiment and shown that a kind of low gloss is colored
The preparation method of enamel glaze.
Invention content
Present invention is generally directed to traditional enamel glaze extinction material consumption is big, the bad problem of extinction effect, invention
The preparation method of a kind of low gloss colour vitreous enamel and low gloss colour enamel glaze, is added using a kind of novel delustering agent
Enter into glaze formula to reduce the gloss of enamel glaze, in combination with special preparation method, can not only reduce vitreous enamel
The gloss in face meets technology rule method requirement, while the anti acid alkali performance for the enamel glaze that can also be improved, corrosion resistance etc..
The above-mentioned technical problem of the present invention is carried out by the following technical programs：A kind of low gloss colour enamel
Glaze, composition includes base glaze, colorant, auxiliary agent, suspending agent, novel delustering agent, water, by quality component：
Base glaze：100 parts
Novel delustering agent：2~8 parts
Colorant：1~5 part
Auxiliary agent：0.1~0.3 part
Suspending agent：5~8 parts
Water：45~55 parts.
Using above-mentioned low gloss colour vitreous enamel, the preparation method of low gloss colour enamel glaze includes the following steps：
Step 1：Batch weighing
By base glaze, novel delustering agent, colorant, suspending agent and water according to above-mentioned quality component dispensing, each component electronics day
It is fitted into the ball grinder for the Quick ball grinder that capacity is 1L after flat progress precise；
Step 2：Ball milling
Ball grinder is placed on ball mill stationary fixture and is fixed, ball milling 10~30 minutes under the rotating speed of 1400r/min；
Ball milling is to fineness degree in 0.1~0.25mm, or 140 mesh standard sieves of mistake, and unit weight is in 1.62~1.76g/ml；
Step 3：Spraying drying
Gained glaze slip crosses 80 mesh standard sieves after ball milling, then leaching ward off or wet spray by way of glaze slip is sprayed at cold rolling
On steel plate, it is to be dried 3~5 minutes in 110~130 DEG C of drying boxes to be then placed in temperature；
Step 4：Firing
Plate embryo after drying is placed in the firing furnace that temperature is 800~820 DEG C, is burnt into 3.5~4.5 minutes.
Preferably, the novel delustering agent includes SiO2、Al2O3、K2O、H2O, mass percent are：
SiO2：42.3%~45.6%
Al2O3：36.2%~39.5%
K2O：10.1%~11.8%
H2O：4.0%~4.5%.
Preferably, the base glaze is the one or several kinds in antimony glaze, titanium glaze or zironium glaze.
Preferably, the colorant described in the step is pigment made from nonferrous metal oxides.
Preferably, the auxiliary agent is one or both of fluxing agent, electrolyte.
Preferably, the precision of the electronic balance is 0.01g.
Preferably, the cold-rolled steel sheet is 1.5mm thick cold rolled steel sheets.
In conclusion the present invention has the following advantages that compared with prior art：
Novel delustering agent is added in glaze formula by the present invention, to reduce the gloss of enamel glaze, in combination with
Special preparation method can not only reduce the gloss of enamel glaze, meet technology rule method requirement, while what can also be improved wards off
The anti acid alkali performance of ceramic glaze surface, corrosion resistance etc.；The preparation method of the present invention is conducive to save material, reduces cost, operability
Height has been reached the glossiness requirement being difficult to realize using traditional preparation methods, has improved the presentation quality of enamel glaze, effectively keep
Former coloured vividness.
Specific implementation mode
With reference to embodiment, the present invention is further described.
Embodiment 1：
One, raw material：
（1）Antimony glaze 200g, pigment 3g, mill addition 0.1g, suspending agent 6g, water 50g；
（2）Novel delustering agent 4g, wherein novel delustering agent contains 42.3% SiO2, 39.5% Al2O3, 10.1%
K2O, 4.5% H2O, additionally it contained a small amount of Na, Ca, Mg, Ti, Cr, Mn, Fe etc.；
（3）Auxiliary agent 0.3g, auxiliary agent are fluxing agent and electrolyte.
Two, preparation method：
（1）The electronic balance for being 0.01g with precision is accurate by antimony glaze, novel delustering agent, mill addition, suspending agent, water, auxiliary agent
It is put into after weighing in KM-2 type Quick ball grinder standard configuration ball grinders；
（2）Ball grinder is placed on ball mill stationary fixture and is fixed, ball milling 12 minutes under the rotating speed of 1400r/min；
Ball milling is to fineness degree in 0.2mm or so（Cross 140 mesh standard sieves）, unit weight 1.72g/ml；
（3）Glaze slip obtained by ball milling crosses 80 mesh standard sieves, then leaching ward off or wet spray by way of glaze slip is sprayed at
On 1.5mm thickness BTC1 cold-rolled steel sheets, it is to be dried 3 minutes in 120 DEG C of drying boxes to be then placed in temperature；
（4）Plate embryo after drying is placed in the firing furnace that temperature is 800 DEG C, is burnt into 4.5 minutes.
Prepared enamel glaze glossiness is 67.0, and effect can refer to following table：
Same amount of novel delustering agent is compared with conventional matting agent as can be seen from the above table, novel delustering agent extinction effect
It is good and smaller than conventional matting agent to color influence degree itself, if using conventional matting agent, even if color can reach
The usage amount of standard, conventional matting agent will be higher by 3~4 times, so novel delustering agent is more suitable in low gloss and bright-colored
It is used in the case of degree.
The gloss value G and Lab values are used Britain SHEEN boards colour difference meter to be measured with D65/10 ° of light source visual angle and obtained,
Wherein L is lightness, and a values are by the red degree to variation, and G is gloss value.
Embodiment 2：
One, raw material：
（1）Antimony glaze 200g, pigment 3g, mill addition 0.1g, suspending agent 6g, water 50g；
（2）Novel delustering agent 4g, wherein novel delustering agent contains 45.6% SiO2, 36.2% Al2O3, 11.8%
K2O, 4.0% H2O, additionally it contained a small amount of Na, Ca, Mg, Ti, Cr, Mn, Fe etc.；
（3）Auxiliary agent 0.3g, auxiliary agent are fluxing agent and electrolyte.
Two, preparation method：
（1）The electronic balance for being 0.01g with precision is accurate by antimony glaze, novel delustering agent, mill addition, suspending agent, water, auxiliary agent
It is put into after weighing in KM-2 type Quick ball grinder standard configuration ball grinders；
（2）Ball grinder is placed on ball mill stationary fixture and is fixed, ball milling 12 minutes under the rotating speed of 1400r/min；
Ball milling is to fineness degree in 0.2mm or so（Cross 140 mesh standard sieves）, unit weight 1.65g/ml；
（3）Glaze slip obtained by ball milling crosses 80 mesh standard sieves, then leaching ward off or wet spray by way of glaze slip is sprayed at
On 1.5mm thickness BTC1 cold-rolled steel sheets, it is to be dried 4 minutes in 120 DEG C of drying boxes to be then placed in temperature；
（4）Plate embryo after drying is placed in the firing furnace that temperature is 810 DEG C, is burnt into 4 minutes.
Prepared enamel glaze glossiness is 50.2, and effect can refer to following table：
Same amount of novel delustering agent is compared with conventional matting agent as can be seen from the above table, novel delustering agent extinction effect
It is good and smaller than conventional matting agent to color influence degree itself, if using conventional matting agent, even if color can reach
The usage amount of standard, conventional matting agent will be higher by 3~4 times, so novel delustering agent is more suitable in low gloss and bright-colored
It is used in the case of degree.
The gloss value G and Lab values are used Britain SHEEN boards colour difference meter to be measured with D65/10 ° of light source visual angle and obtained,
Wherein L is lightness, and a values are by the red degree to variation, and G is gloss value.
Embodiment 3：
One, raw material：
（1）Antimony glaze 200g, pigment 3g, mill addition 0.1g, suspending agent 6g, water 50g；
（2）Novel delustering agent 4g, wherein novel delustering agent contains 44.5% SiO2, 37.5% Al2O3, 11.0%
K2O, 4.2% H2O, additionally it contained a small amount of Na, Ca, Mg, Ti, Cr, Mn, Fe etc.；
（3）Auxiliary agent 0.3g, auxiliary agent are fluxing agent and electrolyte.
Two, preparation method：
（1）The electronic balance for being 0.01g with precision is accurate by antimony glaze, novel delustering agent, mill addition, suspending agent, water, auxiliary agent
It is put into after weighing in KM-2 type Quick ball grinder standard configuration ball grinders；
（2）Ball grinder is placed on ball mill stationary fixture and is fixed, ball milling 12 minutes under the rotating speed of 1400r/min；
Ball milling is to fineness degree in 0.2mm or so（Cross 140 mesh standard sieves）, unit weight 1.72g/ml；
（3）Glaze slip obtained by ball milling crosses 80 mesh standard sieves, then leaching ward off or wet spray by way of glaze slip is sprayed at
On 1.5mm thickness BTC1 cold-rolled steel sheets, it is to be dried 5 minutes in 120 DEG C of drying boxes to be then placed in temperature；
（4）Plate embryo after drying is placed in the firing furnace that temperature is 820 DEG C, is burnt into 3.5 minutes.
Prepared enamel glaze glossiness is 70.5, and effect can refer to following table：
Same amount of novel delustering agent is compared with conventional matting agent as can be seen from the above table, novel delustering agent extinction effect
It is good and smaller than conventional matting agent to color influence degree itself, if using conventional matting agent, even if color can reach
The usage amount of standard, conventional matting agent will be higher by 3~4 times, so novel delustering agent is more suitable in low gloss and bright-colored
It is used in the case of degree.
The gloss value G and Lab values are used Britain SHEEN boards colour difference meter to be measured with D65/10 ° of light source visual angle and obtained,
Wherein L is lightness, and a values are by the red degree to variation, and G is gloss value.
Specific embodiments are merely illustrative of the spirit of the present invention described in text.The technical field of the invention
Technical staff can make various modifications or additions to the described embodiments or substitute by a similar method,
However, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Claims (6)
1. a kind of low gloss colour vitreous enamel, composition includes base glaze, colorant, auxiliary agent, suspending agent, novel delustering agent, water, by matter
Measure component：
Base glaze：100 parts
Novel delustering agent：2 ~ 8 parts
Colorant：1 ~ 5 part
Auxiliary agent：0.1 ~ 0.3 part
Suspending agent：5 ~ 8 parts
Water：45 ~ 55 parts；
Using above-mentioned low gloss colour vitreous enamel, the preparation method of low gloss colour enamel glaze includes the following steps：
Step 1：Batch weighing
By base glaze, novel delustering agent, colorant, suspending agent and water according to above-mentioned quality component dispensing, each component electronic balance into
It is fitted into after row precise in the ball grinder for the Quick ball grinder that capacity is 1L；
Step 2：Ball milling
Ball grinder is placed on ball mill stationary fixture and is fixed, ball milling 10~30 minutes under the rotating speed of 1400r/min；Ball milling
140 mesh standard sieves are being crossed to fineness degree, unit weight is in 1.62~1.76g/ml；
Step 3：Spraying drying
Gained glaze slip crosses 80 mesh standard sieves after ball milling, then leaching ward off or wet spray by way of glaze slip is sprayed at cold-rolled steel sheet
On, it is to be dried 3 ~ 5 minutes in 110~130 DEG C of drying boxes to be then placed in temperature；
Step 4：Firing
Plate embryo after drying is placed in the firing furnace that temperature is 800 ~ 820 DEG C, is burnt into 3.5 ~ 4.5 minutes；
The delustering agent includes SiO2、Al2O3、K2O、H2O, mass percent are：
SiO2：42.3%~45.6%
Al2O3：36.2%~39.5%
K2O：10.1%~11.8%
H2O： 4.0%~4.5%；
Above-mentioned substance component total content is 100%.
2. low gloss colour vitreous enamel according to claim 1, which is characterized in that the base glaze be antimony glaze, titanium glaze or
One or several kinds in zironium glaze.
3. low gloss colour vitreous enamel according to claim 2, which is characterized in that the colorant aoxidizes for non-ferrous metal
Pigment made from object.
4. low gloss colour vitreous enamel according to claim 2, which is characterized in that the auxiliary agent is fluxing agent, electrolysis
One or both of matter.
5. the preparation method of low gloss colour enamel glaze according to claim 1, which is characterized in that the electronic balance
Precision be 0.01g.
6. the preparation method of low gloss colour enamel glaze according to claim 1, which is characterized in that the cold-rolled steel sheet
For 1.5mm thick cold rolled steel sheets.
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| CN201510665559.0A CN105271752B (en) | 2015-10-16 | 2015-10-16 | A kind of preparation method of low gloss colour enamel glaze |
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| CN201510665559.0A CN105271752B (en) | 2015-10-16 | 2015-10-16 | A kind of preparation method of low gloss colour enamel glaze |
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| CN105271752B true CN105271752B (en) | 2018-11-09 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106430960A (en) * | 2016-08-31 | 2017-02-22 | 浙江开尔新材料股份有限公司 | Preparation method of pearl enamel |
| CN110255905B (en) * | 2019-07-02 | 2022-06-03 | 浙江开尔新材料股份有限公司 | Antibacterial enamel glaze slurry, preparation method and preparation method of antibacterial enamel plate |
| CN110255904B (en) * | 2019-07-02 | 2022-02-18 | 浙江开尔新材料股份有限公司 | Glaze slip capable of removing formaldehyde, preparation method and preparation method of enamel plate capable of removing formaldehyde |
| CN110372208B (en) * | 2019-07-02 | 2021-12-31 | 浙江开尔新材料股份有限公司 | Enamel glaze slip capable of releasing negative ions and method for preparing negative ion enamel plate by using enamel glaze slip |
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| JP4073920B2 (en) * | 2005-02-25 | 2008-04-09 | 日本コンベヤ株式会社 | Abrasion and corrosion resistant belt conveyor rollers |
| CN102001864A (en) * | 2010-12-04 | 2011-04-06 | 黄俊杰 | Heat-resistant porcelain glaze |
| CN102617191A (en) * | 2012-04-12 | 2012-08-01 | 东莞市高诚陶瓷制品有限公司 | Low temperature metal color glaze material and application method thereof |
| CN103215591B (en) * | 2013-02-01 | 2015-05-27 | 浙江开尔新材料股份有限公司 | Preparation method of imitated-metal enameled steel sheet |
| CN103224736B (en) * | 2013-04-08 | 2014-09-10 | 佛山市道氏科技有限公司 | Matte glaze ink for ceramic jet printing and preparation method thereof |
| CN103922812B (en) * | 2014-04-21 | 2015-06-10 | 佛山市金丝玉玛装饰材料有限公司 | Matte-underglazed glazed brick and fabrication process thereof |
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