CN104609897B - Gold glaze for building and preparation and application thereof - Google Patents
Gold glaze for building and preparation and application thereof Download PDFInfo
- Publication number
- CN104609897B CN104609897B CN201410728871.5A CN201410728871A CN104609897B CN 104609897 B CN104609897 B CN 104609897B CN 201410728871 A CN201410728871 A CN 201410728871A CN 104609897 B CN104609897 B CN 104609897B
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- parts
- building
- frit
- glaze
- gold
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000010931 gold Substances 0.000 title claims abstract description 47
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010453 quartz Substances 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 10
- 239000004575 stone Substances 0.000 claims abstract description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 235000019738 Limestone Nutrition 0.000 claims abstract description 9
- 229910052925 anhydrite Inorganic materials 0.000 claims abstract description 9
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000006028 limestone Substances 0.000 claims abstract description 9
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 9
- 239000000454 talc Substances 0.000 claims abstract description 9
- 229910052623 talc Inorganic materials 0.000 claims abstract description 9
- 235000012222 talc Nutrition 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 9
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005303 weighing Methods 0.000 claims description 10
- 238000010304 firing Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The present invention relates to a kind of gold glaze for building, be made up of each component of following parts by weight: frit 52～58 parts, sphene 15～17 parts, zircon 8～9 parts, limestone 6～7 parts, 3～4 parts of quartz, burn 6～7 parts of Talcum, CMC 8～10 parts, sodium tripolyphosphate 0.5～0.8 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 32～35 parts, 8～10 parts of quartz, brium carbonate 2～3 parts, zinc oxide 7～9 parts, 25～28 parts, Plumbum preparatium, 0.1～0.2 part of Sha Fulai stone。The invention still further relates to the preparation and application of described gold glaze for building, its gold glaze porcelain products for building prepared, its glossiness is high, and Heat stability is good, lead release is low, and surface is the gloss of Gold production, it is adaptable to all kinds of top-grade building porcelain。
Description
Technical field
The present invention relates to building ceramic glaze field, more particularly, to a kind of gold glaze for building and preparation and application thereof。
Background technology
The architectural pottery industry of China is developed rapidly in the time of nearly more than ten years, advantages for development and opportunity by inside and outside, become the production and consumption big country of world architecture pottery, the more than half architectural pottery in the whole world originates from China, it can be seen that China's architectural pottery occupies consequence on international arena。And gold symbol is noble, glorious, luxurious, brilliant, numerous high-grade clubs all like decorates to show status by gold。The existing architectural pottery glaze performance with golden colour lustre is all general at present, therefore, develops a kind of gold glaze that can gold be combined with architectural pottery too impatient to wait。
Summary of the invention
It is an object of the invention to for above-mentioned problem, it is provided that a kind of gold glaze for building and preparation and application thereof。
The object of the invention is achieved by the following technical programs:
A kind of gold glaze for building is provided, is made up of each component of following parts by weight: frit 52～58 parts, sphene 15～17 parts, zircon 8～9 parts, limestone 6～7 parts, 3～4 parts of quartz, burn 6～7 parts of Talcum, CMC8～10 part, sodium tripolyphosphate 0.5～0.8 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 32～35 parts, 8～10 parts of quartz, brium carbonate 2～3 parts, zinc oxide 7～9 parts, 25～28 parts, Plumbum preparatium, 0.1～0.2 part of Sha Fulai stone。
Preferably, described gold glaze for building is made up of each component of following parts by weight: frit 54 parts, sphene 16 parts, zircon 8 parts, limestone 7 parts, 4 parts of quartz, burn 7 parts of Talcum, CMC8 part, sodium tripolyphosphate 0.5 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 34 parts, 9 parts of quartz, brium carbonate 3 parts, zinc oxide 7 parts, 27 parts, Plumbum preparatium, 0.1 part of Sha Fulai stone。
The preparation method that present invention also offers described gold glaze for building, comprises the following steps:
S1. weighing by frit formula, mix homogeneously, found, shrend obtains frit；
S2. weighing by gold glaze formula, with material: ball: water=1:2:0.5～0.6 enters ball milling, after going out mill, 300 mesh sieves tail over 0.2%～0.4%, obtain gold glaze for building。
Preferably, the glass melting temperature in S1 is 1120～1180 DEG C。
Present invention also offers the using method of described gold glaze for building: glaze spraying 2～3 times on porcelain for building, enter kiln oxidizing flame and burn till, firing temperature 1150～1180 DEG C, firing period 0.5h, temperature is down to 1000～1020 DEG C, natural cooling after insulation 0.5h, obtains the porcelain for building of inaurate。
Experiments show that, various raw-material proportionings and burn till etc. the impact of gold glaze glazing effect is very big。
When lead content is too low, is then difficult to form metallic luster, and lead content is higher, then toxicity is relatively big, therefore controls at optimum proportioning by Plumbum preparatium content in the application, and first introduces in frit, is re-introduced into glaze after high temperature melting。Add the Sha Fulai stone of trace, the more lustrous and more transparent profit of gold glaze paint can be made uniform, be more nearly with gold。
Gold glaze belongs to crystalline glaze, and metal-oxide is supersaturation in high temperature, precipitating metal gloss thing in cooling procedure, therefore, only strictly controls the temperature and time fired and be incubated well, just can obtain high-quality gold glaze。
Compared with prior art, the method have the advantages that
The invention provides a kind of gold glaze for building, with its gold glaze porcelain products for building prepared, its glossiness is high, and Heat stability is good, lead release is low, and surface is the gloss of Gold production, it is adaptable to all kinds of top-grade building porcelain。
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated。
Embodiment 1
Present embodiment discloses a kind of gold glaze for building, be made up of each component of following parts by weight: frit 54 parts, sphene 16 parts, zircon 8 parts, limestone 7 parts, 4 parts of quartz, burn 7 parts of Talcum, CMC8 part, sodium tripolyphosphate 0.5 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 34 parts, 9 parts of quartz, brium carbonate 3 parts, zinc oxide 7 parts, 27 parts, Plumbum preparatium, 0.1 part of Sha Fulai stone。
Embodiment 2
Present embodiment discloses a kind of gold glaze for building, be made up of each component of following parts by weight: frit 52 parts, sphene 15 parts, zircon 9 parts, limestone 6 parts, 3 parts of quartz, burn 6 parts of Talcum, CMC9 part, sodium tripolyphosphate 0.8 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 32 parts, 10 parts of quartz, brium carbonate 2 parts, zinc oxide 9 parts, 28 parts, Plumbum preparatium, 0.2 part of Sha Fulai stone。
Embodiment 3
Present embodiment discloses a kind of gold glaze for building, be made up of each component of following parts by weight: frit 58 parts, sphene 17 parts, zircon 8.5 parts, limestone 6.5 parts, 3.8 parts of quartz, burn 6.7 parts of Talcum, CMC8.8 part, sodium tripolyphosphate 0.6 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 35 parts, 8 parts of quartz, brium carbonate 2.5 parts, zinc oxide 8 parts, 25 parts, Plumbum preparatium, 0.1 part of Sha Fulai stone。
Embodiment 4
Present embodiment discloses a kind of gold glaze for building, be made up of each component of following parts by weight: frit 55 parts, sphene 16.5 parts, zircon 8 parts, limestone 6 parts, 3.8 parts of quartz, burn 6.2 parts of Talcum, CMC9.4 part, sodium tripolyphosphate 0.56 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 34 parts, 8.7 parts of quartz, brium carbonate 2.2 parts, zinc oxide 7.3 parts, 26.1 parts, Plumbum preparatium, 0.2 part of Sha Fulai stone。
Embodiment 5
The components by weight percent of Example 1～4 any embodiment prepares gold glaze for building, and preparation process is as follows:
S1. weighing by frit formula, mix homogeneously, found for 1120 DEG C, shrend obtains frit；
S2. weighing by gold glaze formula, with material: ball: water=1:2:0.5 enters ball milling, after going out mill, 300 mesh sieves tail over 0.2%, obtain gold glaze for building。
Embodiment 6
The components by weight percent of Example 1～4 any embodiment prepares gold glaze for building, and preparation process is as follows:
S1. weighing by frit formula, mix homogeneously, found for 1180 DEG C, shrend obtains frit；
S2. weighing by gold glaze formula, with material: ball: water=1:2:0.6 enters ball milling, after going out mill, 300 mesh sieves tail over 0.4%, obtain gold glaze for building。
Embodiment 7
The components by weight percent of Example 1～4 any embodiment prepares gold glaze for building, and preparation process is as follows:
S1. weighing by frit formula, mix homogeneously, found for 1150 DEG C, shrend obtains frit；
S2. weighing by gold glaze formula, with material: ball: water=1:2:0.55 enters ball milling, after going out mill, 300 mesh sieves tail over 0.3%, obtain gold glaze for building。
Embodiment 8
Gold glaze for building prepared by embodiment 5～7 any embodiment, using method is as follows:
Glaze spraying 3 times on porcelain for building, enter kiln oxidizing flame and burn till, firing temperature 1150 DEG C, firing period 0.5h, and temperature is down to 1020 DEG C, natural cooling after insulation 0.5h, obtain the porcelain for building of inaurate, and its performance is as shown in the table。
| Water absorption rate (%) | Glossiness | Heat stability | Lead release (mg/L) |
| 0.4 | 142 | Flawless is once answered in 140 DEG C to 20 DEG C heat exchanges。 | 0.1 |
Claims (5)
1. a gold glaze for building, it is characterised in that be made up of each component of following parts by weight: frit 52～58 parts, sphene 15～17 parts, zircon 8～9 parts, limestone 6～7 parts, 3～4 parts of quartz, burns 6～7 parts of Talcum, CMC8～10 part, sodium tripolyphosphate 0.5～0.8 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 32～35 parts, 8～10 parts of quartz, brium carbonate 2～3 parts, zinc oxide 7～9 parts, 25～28 parts, Plumbum preparatium, 0.1～0.2 part of Sha Fulai stone。
2. gold glaze for building according to claim 1, it is characterised in that be made up of each component of following parts by weight: frit 54 parts, sphene 16 parts, zircon 8 parts, limestone 7 parts, 4 parts of quartz, burns 7 parts of Talcum, CMC8 part, sodium tripolyphosphate 0.5 part, wherein, described frit is made up of each component of following parts by weight: Anhydrite 34 parts, 9 parts of quartz, brium carbonate 3 parts, zinc oxide 7 parts, 27 parts, Plumbum preparatium, 0.1 part of Sha Fulai stone。
3. the preparation method of gold glaze for building according to claim 1 or claim 2, it is characterised in that comprise the following steps:
S1. weighing by frit formula, mix homogeneously, found, shrend obtains frit；
S2. weighing by gold glaze formula, with material: ball: water=1:2:0.5～0.6 enters ball milling, after going out mill, 300 mesh sieves tail over 0.2%～0.4%, obtain gold glaze for building。
4. the preparation method of gold glaze for building according to claim 3, it is characterised in that the glass melting temperature in S1 is 1120～1180 DEG C。
5. the using method of gold glaze for building according to claim 1 or claim 2, it is characterized in that, glaze spraying 2～3 times on porcelain for building, enter kiln oxidizing flame to burn till, firing temperature 1150～1180 DEG C, firing period 0.5h, temperature is down to 1000～1020 DEG C, natural cooling after insulation 0.5h, obtains the porcelain for building of inaurate。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410728871.5A CN104609897B (en) | 2014-12-05 | 2014-12-05 | Gold glaze for building and preparation and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410728871.5A CN104609897B (en) | 2014-12-05 | 2014-12-05 | Gold glaze for building and preparation and application thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104609897A CN104609897A (en) | 2015-05-13 |
| CN104609897B true CN104609897B (en) | 2016-06-22 |
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| CN201410728871.5A Active CN104609897B (en) | 2014-12-05 | 2014-12-05 | Gold glaze for building and preparation and application thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237042B (en) * | 2015-11-09 | 2017-12-01 | 醴陵陶润实业发展有限公司 | Gold glaze with metallic luster and preparation method thereof |
| CN107382064B (en) * | 2017-08-15 | 2020-04-07 | 德化县德鸿陶瓷有限公司 | Gold wire glaze and method for manufacturing art porcelain by using same |
| CN107324653A (en) * | 2017-08-17 | 2017-11-07 | 福建省德化县华晨陶瓷有限公司 | Gold glaze and the method that gold glaze ceramic is made of it |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033138A (en) * | 2007-02-05 | 2007-09-12 | 桂林工学院 | Process of preparing chromium doping tin sphene type coloring material |
| CN101948335A (en) * | 2010-08-24 | 2011-01-19 | 霍镰泉 | Novel low temperature frit, crystal floor tile and method for producing crystal floor tile |
| CN102557736A (en) * | 2011-12-13 | 2012-07-11 | 黄喜波 | Ultra-flat transparent frit and preparation method thereof |
| CN102826872A (en) * | 2012-08-17 | 2012-12-19 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN104130024A (en) * | 2014-07-23 | 2014-11-05 | 广东宏陶陶瓷有限公司 | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile |
-
2014
- 2014-12-05 CN CN201410728871.5A patent/CN104609897B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033138A (en) * | 2007-02-05 | 2007-09-12 | 桂林工学院 | Process of preparing chromium doping tin sphene type coloring material |
| CN101948335A (en) * | 2010-08-24 | 2011-01-19 | 霍镰泉 | Novel low temperature frit, crystal floor tile and method for producing crystal floor tile |
| CN102557736A (en) * | 2011-12-13 | 2012-07-11 | 黄喜波 | Ultra-flat transparent frit and preparation method thereof |
| CN102826872A (en) * | 2012-08-17 | 2012-12-19 | 广东宏陶陶瓷有限公司 | Formula and preparation method of national flag bright red glazed brick |
| CN104130024A (en) * | 2014-07-23 | 2014-11-05 | 广东宏陶陶瓷有限公司 | High-temperature bright-red printing glaze, preparation method and preparation method of glazed tile |
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| Publication number | Publication date |
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| CN104609897A (en) | 2015-05-13 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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Inventor after: Xiao Fei Inventor after: Yi Liqun Inventor after: Chen Xiulin Inventor after: Deng Guangxing Inventor before: Li Ting |
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Effective date of registration: 20160525 Address after: 511356, No. 4, Xin'an Road, Yonghe Economic Zone, Guangzhou economic and Technological Development Zone, Guangdong, Guangzhou Applicant after: Mei Ke (Guangzhou) chemical Limited by Share Ltd Address before: 521000, Guangdong Province, Chaozhou Maple Creek Maple 21 village 4 horizontal Applicant before: Li Ting |
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Address after: 511356 No. 4 Xin'an Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong Patentee after: Meike (Guangzhou) new material Co.,Ltd. Address before: 511356 No. 4 Xin'an Road, Yonghe Economic Zone, Guangzhou Economic and Technological Development Zone, Guangzhou, Guangdong Patentee before: MATRIX GUANGZHOU CHEMICALS Corp. |
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Denomination of invention: Gold glaze for building and its preparation and application method Effective date of registration: 20210915 Granted publication date: 20160622 Pledgee: Industrial Commercial Bank of China Ltd. Guangzhou branch Yuexiu Pledgor: Meike (Guangzhou) new material Co.,Ltd. Registration number: Y2021440000291 |