CN101137436B - 碱稳定性离子液体 - Google Patents

碱稳定性离子液体 Download PDF

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CN101137436B
CN101137436B CN2006800056693A CN200680005669A CN101137436B CN 101137436 B CN101137436 B CN 101137436B CN 2006800056693 A CN2006800056693 A CN 2006800056693A CN 200680005669 A CN200680005669 A CN 200680005669A CN 101137436 B CN101137436 B CN 101137436B
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CN101137436A (zh
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马丁·约翰·厄尔
乌特·弗勒利希
苏珊·哈克
苏哈斯·卡特戴尔
拉法尔·马尔钦·卢卡西克
埃瓦·博格尔
纳塔里拉·弗拉迪米罗夫纳·普莱科瓦
肯尼斯·理查德·塞登
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Queens University of Belfast
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Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0500029D0 (en) * 2005-01-04 2005-02-09 Univ Belfast Basic ionic liquids
TW200710070A (en) * 2005-07-27 2007-03-16 Nippon Catalytic Chem Ind Solvent for reaction and production method using the same
JP2009502894A (ja) * 2005-07-27 2009-01-29 ビーピー ピー・エル・シー・ 脱水方法
GB2444614A (en) * 2005-09-30 2008-06-11 Bioniqs Ltd Alkanoyl ammonium salts as ionic liquids
JP2009541302A (ja) * 2006-07-24 2009-11-26 ザ プロクター アンド ギャンブル カンパニー シクロヘキセニルケトンのエピマー化方法及びアルドール縮合プロセスにおけるその利用
US8044120B2 (en) * 2006-10-13 2011-10-25 Basf Aktiengesellschaft Ionic liquids for solubilizing polymers
US8088917B2 (en) * 2007-06-01 2012-01-03 Invista North America S.A R.L. Ionic liquids
US7772293B2 (en) * 2007-07-31 2010-08-10 Invista North America S.A.R.L. Ionic liquid solvents and a process for the depolymerization of polyamides
WO2009045156A1 (en) * 2007-10-01 2009-04-09 Noziere Barbara Novel catalyst for aldol condensation reactions
US20100267596A1 (en) * 2007-12-14 2010-10-21 Base Se Method for improving the hydrolysis stability of ionic liquids
CN101723771B (zh) * 2008-10-20 2012-12-05 浙江医药股份有限公司新昌制药厂 功能离子液体催化制备β-氨基酮、酯、腈和酰胺衍生物的方法
EP2408950A4 (en) * 2009-03-17 2015-05-20 Commw Scient Ind Res Org ELECTRO-RECOVERY OF METALS
MD4062C1 (ro) * 2010-01-16 2011-03-31 Институт Химии Академии Наук Молдовы Compoziţie catalitică pentru reacţia Morita-Baylis-Hillman
JP2011219395A (ja) * 2010-04-07 2011-11-04 Kuraray Co Ltd α,β−不飽和アルデヒドの製造方法
AU2012271273B2 (en) 2011-06-17 2017-06-08 Fluidic, Inc. Metal-air cell with ion exchange material
JP6235470B2 (ja) * 2011-06-17 2017-11-22 フルイディック, インク.Fluidic, Inc. ジアルキルカーボネートの四級化を利用するヘテロイオン化合物の合成
ES2702487T3 (es) 2011-06-17 2019-03-01 Nantenergy Inc Líquido iónico que contiene iones sulfonato
CN102343278A (zh) * 2011-07-20 2012-02-08 北京工业大学 用于制备环氧环己烷的非均相催化剂的制备方法及其应用
CN102391060B (zh) * 2011-09-20 2013-10-23 浙江大学 催化羟基乙酰化的方法
CN102911151B (zh) * 2012-07-12 2014-10-22 盐城师范学院 一种水相合成苯并氧杂蒽衍生物的方法
CN102911793B (zh) * 2012-10-04 2013-10-23 盐城师范学院 一种功能化碱性离子液体及其在生物柴油制备中的应用
CN102876466B (zh) * 2012-10-05 2013-10-23 盐城师范学院 一种碱性离子液体催化酯交换反应的方法
US9287597B2 (en) 2012-11-14 2016-03-15 Fluidic, Inc. Ionic liquid containing hydroxamate and N-alkyl sulfamate ions
CN106232571B (zh) * 2014-04-22 2019-05-28 巴斯夫欧洲公司 在离子液体和酸性酯化催化剂的存在下制备羧酸酯的方法及其作为塑化剂的用途
CN104130263B (zh) * 2014-07-02 2016-09-07 东华大学 一种高折射率室温离子液体
CN107999130B (zh) * 2016-10-28 2022-02-08 中国石油化工股份有限公司 一种双环戊二烯/n-乙烯基咪唑共聚物型酯水解催化剂及其制备方法
CN106916109B (zh) * 2017-01-19 2019-11-05 河南大学 一种质子化吡唑类离子液体及利用其催化合成环状碳酸酯的方法
US10577327B2 (en) 2018-06-11 2020-03-03 King Abdulaziz University Pyridine based ionic fluoride for catalyzing indole and tetrazole formation
US11424484B2 (en) 2019-01-24 2022-08-23 Octet Scientific, Inc. Zinc battery electrolyte additive
CN117024365B (zh) * 2023-08-24 2025-06-24 山西师范大学 一种吡唑类离子液体及利用其催化Mannich反应的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US552241A (en) * 1895-12-31 emerson
NO790460L (no) * 1979-02-13 1980-08-14 Elkem Spigerverket As Fremstilling av et rent aluminiumoksyd fra loesninger inneholdende opploeste aluminiumioner og jernioner
US4207326A (en) * 1979-05-21 1980-06-10 Cilag-Chemie A.G. Antimicrobial quaternary pyrazole derivatives
US6326104B1 (en) * 1999-05-14 2001-12-04 Electrochemical Systems, Inc. Electrolytes for lithium rechargeable cells
JP2003500460A (ja) * 1999-05-26 2003-01-07 パーソナル ケミストリー イ ウプサラ アーベー マイクロ波補助化学変換におけるイオン液体の製造及び使用
GB9928290D0 (en) 1999-12-01 2000-01-26 Univ Belfast Process for preparing ambient temperature ionic liquids
JP2001247508A (ja) * 2000-03-06 2001-09-11 Central Glass Co Ltd オレフィン化合物の製造方法
JP2001247572A (ja) * 2000-03-06 2001-09-11 Central Glass Co Ltd ピリミジン誘導体塩
GB0023706D0 (en) * 2000-09-27 2000-11-08 Scionix Ltd Ionic liquids
JP2002275118A (ja) * 2001-03-15 2002-09-25 Central Glass Co Ltd アルドール反応生成物の製造方法
US6552232B2 (en) 2001-06-26 2003-04-22 Exxonmobil Research And Engineering Company Process for conducting aldol condensation reactions in ionic liquid media
DE10145747A1 (de) * 2001-09-17 2003-04-03 Solvent Innovation Gmbh Ionische Flüssigkeiten
DE10208822A1 (de) * 2002-03-01 2003-09-11 Solvent Innovation Gmbh Halogenfreie ionische Flüssigkeiten
WO2003106419A1 (ja) * 2002-06-01 2003-12-24 ダイキン工業株式会社 常温溶融塩、その製造方法及びその用途
FR2845084B1 (fr) * 2002-09-26 2009-07-17 Centre Nat Rech Scient Compositions contenant des liquides ioniques et leurs utilisations, notamment en synthese organique
DE10247578A1 (de) * 2002-10-13 2004-04-22 Solvent Innovation Gmbh Neuartige, funktionalisierte ionische Flüssigkeiten und Verfahren zu ihrer Herstellung
JP2004262896A (ja) * 2003-03-04 2004-09-24 Tosoh Corp 4級アンモニウム系常温溶融塩及び該化合物の製造法
JP2005225843A (ja) * 2004-02-16 2005-08-25 Tosoh Corp アルコキシアルキル基含有4級アンモニウム塩の製造方法
WO2006017148A2 (en) * 2004-07-09 2006-02-16 Sigma-Alrich Co. Optically enhanced chiral ionic liquids
GB0500029D0 (en) * 2005-01-04 2005-02-09 Univ Belfast Basic ionic liquids

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