CN101119961A - 取代的对三氟甲基苯醚类化合物及其制备与应用 - Google Patents
取代的对三氟甲基苯醚类化合物及其制备与应用 Download PDFInfo
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Abstract
Description
Claims (8)
- 权 利 要 求 书1. 一种取代的对三氟甲基苯醚类化合物, 如通式 (I) 所示:式中:Q选自如下所示的 Qi、 Q2、 Q3、 Q4或 Q5Qr当 A= 时, 嘧啶的 4-位与氧相连, 6-位氧与苯环相连, Q=Q1 ;X选自氢、卤素、氰基、硝基、 —C^烷基、 c2—c12烯基、 C2— C12炔基、 C— C12 卤代垸基、 —Cu烷氧基、 — C12烷硫基、 C ~C12垸磺酰基、 — C12烷基碳基、 — C12垸氧基 d—C12烷基、 Cj—Cu垸氧基羰基、 Cr~C12烷氧基羰基 Q— C12垸基、 —C^卤代烷氧基 Cr~C12烷基、 任意取代胺基 d—C12垸基、 任意取代的芳氧基、 任意取代的芳 Ci—Cn垸基氧基、任意取代的芳基、杂芳基、任意取代的芳基 —C12 烷基、 杂芳基 C ~C12垸基或杂芳基 —C12烷氧基;及其立体异构体。
- 2. 根据权利要求 1所述的化合物, 其特征在于: 通式 (I) CPQ选自所述 Qt、 Q2、 Q3、 Q4或 Q5 ;A选 ill CH2或 ^^O^; 当八= z 、0^ 时, 嘧啶的 4-位与氧相连, 6-位氧与苯环相连, Q=Q1 ;X选自氢、 卤素、氰基、 硝基、 Q—C6垸基、 C2—〇6烯基、 C2— C6炔基、 — C6 卤代烷基、 Ct— C6烷氧基、 Q— C6烷硫基、 d—C6垸磺酰基、 Ci— C6垸基羰基、 d— C6 垸氧基 Cr~C6烷基、 d_C6烷氧基羰基、 Q— C6烷氧基羰基 C!—Qs垸基、 C ~C6 卤代垸氧基 — C6烷基、取代的胺基 Cr~C6垸基、取代的芳氧基、取代的芳^一¾ 垸基氧基、 取代的芳基、 杂芳基、 取代的芳基 d—C6烷基、 杂芳基 Cr~C6烷基或杂 芳基 一¾垸氧基。
- 3. 根据权利要求 2所述的化合物, 其特征在于: 通式 (I) 中Q选自所述 Qi、 Q2、 Q3、 Q4或 Qs;A选自当入= 时, 嘧啶的 4-位与氧相连, 6-位氧与苯环相连, Q=QI ;X选自氢、 卤素、 氰基、硝基、 Ci—C6垸基、 C2— C6烯基、 C2— 炔基、 d—C6 卤代垸基、 Ci— C6烷氧基、 d— C6烷硫基、 Ci— C6烷磺酰基、 Ci— C6烷基驟基、 C— C6 垸氧基 烷基、 —C6烷氧基羰基、 d—C6垸氧基羰基 d—C3烷基、 Cr~C3 卤代垸氧基 一¾烷基、取代的胺基 —C3垸基、取代或未取代的下述基团:苯基、 苯氧基、 苄基或 氧基。
- 4. 根据权利要求 3所述的化合物, 其特征在于: 通式 (I) 中Q选自所述 Q!、 Q2、 (¾、 或 Q4;A选自 CH2或当 吋, 嘧啶的 4-位与氧相连, 6-位氧与苯环相连, Q=Q1 ; X选自氢、 氯、 溴、 氟、 氛基或 一 烷基。
- 5. 根据权利耍求 1-4中任意一项所述的化合物的制备方法, 其特征在于: 通式(I)化合物 ώ通式(II )所示的取代的苯酚类化合物和用通.式 (in)所示的苄卤在碱性 条件下制得,(III)式中:R选自氯、 溴或碘;Q选自如下所示的 Qt、 Q2、 Q3、 Q4或 Q50Q4= H3CT"A选自 CH2或 V当 ; X选自氢、卤素、氰基、硝基、 Cr~C12垸基、 C2— C12烯基、 C2"~C12炔基、 —C12 卤代烷基、 —C12烷氧基、 Cr~C12烷硫基、 d—C^烷磺酰基、 —C^烷基羰基、 d— C12垸氧基 Q— C12烷基、 d—C12垸氧基羰基、 d~~C12垸氧基皴基 d—C12垸基、 d—C12卤代烷氧基 d—C12垸基、 任意取代胺基 C ~C12烷基、 任意取代的芳氧基、 任意取代的芳 Cr~C12烷基氧基、任意取代的芳基、杂芳基、任意取代的芳基 d—C12 垸基、 杂芳基 Cr~C12垸基或杂芳基 Cr~C12垸氧基。
- 6. 一种按权利要求 1所述的化合物在防治作物上害虫的应用。
- 7. 一种按权利要求 1所述的化合物在防治作物上病菌的应用。
- 8. 一种杀虫、 杀菌组合物, 其特征在于: 组合物中含有权利要求 Γ所述的通式 I化合物和农业上可接受的载体, 组合物中活性组分的重量百分含量为 0.1-99% 。
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CNB200510046765XA CN100443463C (zh) | 2005-06-28 | 2005-06-28 | 取代的对三氟甲基苯醚类化合物及其制备与应用 |
CN200510046765.X | 2005-06-28 | ||
PCT/CN2006/001337 WO2007000098A1 (fr) | 2005-06-28 | 2006-06-15 | P-trifluoromethylephenylethers substitues, leur preparation et leur utilisation |
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CN2006800050945A Active CN101119961B (zh) | 2005-06-28 | 2006-06-15 | 取代的对三氟甲基苯醚类化合物及其制备与应用 |
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US (1) | US7947734B2 (zh) |
EP (1) | EP1897866B1 (zh) |
JP (1) | JP4723642B2 (zh) |
KR (1) | KR100963911B1 (zh) |
CN (2) | CN100443463C (zh) |
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CN104415038A (zh) * | 2013-08-27 | 2015-03-18 | 中国中化股份有限公司 | 具有抗肿瘤活性的苯醚类化合物的应用 |
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EP2393775B1 (en) | 2009-02-05 | 2014-06-25 | Basf Se | Method for producing 2-halogenomethylphenyl acetic acid derivatives |
US20120331582A1 (en) | 2009-10-14 | 2012-12-27 | The University Of Western Ontario | Method to control spider mites |
US8772290B2 (en) | 2010-04-21 | 2014-07-08 | Oscotech Inc. | Alpha-arylmethoxyacrylate derivative, preparation method thereof, and pharmaceutical composition containing same |
EP2604118A1 (en) | 2011-12-15 | 2013-06-19 | Bayer CropScience AG | Active ingredient combinations having insecticidal and acaricidal properties |
AU2014294145B2 (en) | 2013-07-22 | 2017-06-01 | Sumitomo Chemical Company, Limited | Plant disease control composition and application for same |
JP6178010B2 (ja) | 2013-08-27 | 2017-08-09 | シノケム・コーポレーションSinochem Corporation | 抗腫瘍薬の製造のための置換ベンジルオキシ基含有エーテル化合物の適用 |
CN104430343B (zh) * | 2013-09-24 | 2017-02-15 | 沈阳中化农药化工研发有限公司 | 取代醚类及硫醚类化合物作为抗植物病毒剂的应用 |
EA031563B1 (ru) | 2013-10-03 | 2019-01-31 | Зингента Партисипейшнс Аг | Фунгицидные композиции |
RU2673722C2 (ru) | 2014-03-20 | 2018-11-29 | Мицуи Кемикалз Агро, Инк. | Композиция для борьбы с болезнями растений и способ борьбы с болезнями растений путем ее применения |
CN110105215A (zh) * | 2019-06-04 | 2019-08-09 | 扬州工业职业技术学院 | 一种石胆草乙酰化提取物及其在防治水稻纹枯病中的应用 |
CN115536543B (zh) * | 2022-11-10 | 2023-11-03 | 贵州大学 | 一种含异丙醇胺结构的三氯生类化合物及其制备方法和应用 |
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DE3623921A1 (de) * | 1986-07-16 | 1988-01-21 | Basf Ag | Oximether und diese enthaltende fungizide |
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CN104415038A (zh) * | 2013-08-27 | 2015-03-18 | 中国中化股份有限公司 | 具有抗肿瘤活性的苯醚类化合物的应用 |
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US7947734B2 (en) | 2011-05-24 |
CN1887847A (zh) | 2007-01-03 |
JP4723642B2 (ja) | 2011-07-13 |
BRPI0612552B1 (pt) | 2016-04-19 |
CN101119961B (zh) | 2010-05-19 |
WO2007000098A1 (fr) | 2007-01-04 |
CN100443463C (zh) | 2008-12-17 |
KR20070112880A (ko) | 2007-11-27 |
EP1897866A4 (en) | 2011-09-07 |
EP1897866B1 (en) | 2014-09-10 |
BRPI0612552A2 (pt) | 2010-11-23 |
KR100963911B1 (ko) | 2010-06-17 |
US20080188468A1 (en) | 2008-08-07 |
JP2008546815A (ja) | 2008-12-25 |
EP1897866A1 (en) | 2008-03-12 |
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