CN101094926A - 从树脂洗出液流中提取镍和钴 - Google Patents
从树脂洗出液流中提取镍和钴 Download PDFInfo
- Publication number
- CN101094926A CN101094926A CNA2005800456511A CN200580045651A CN101094926A CN 101094926 A CN101094926 A CN 101094926A CN A2005800456511 A CNA2005800456511 A CN A2005800456511A CN 200580045651 A CN200580045651 A CN 200580045651A CN 101094926 A CN101094926 A CN 101094926A
- Authority
- CN
- China
- Prior art keywords
- nickel
- cobalt
- resin
- ore pulp
- leaching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 247
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 110
- 239000010941 cobalt Substances 0.000 title claims abstract description 109
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 109
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 109
- 239000011347 resin Substances 0.000 title claims abstract description 82
- 229920005989 resin Polymers 0.000 title claims abstract description 82
- 238000000605 extraction Methods 0.000 title description 20
- 238000000034 method Methods 0.000 claims abstract description 96
- 230000008569 process Effects 0.000 claims abstract description 30
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000010949 copper Substances 0.000 claims abstract description 23
- 239000012535 impurity Substances 0.000 claims abstract description 23
- 239000011572 manganese Substances 0.000 claims abstract description 22
- 239000011701 zinc Substances 0.000 claims abstract description 21
- 229910052802 copper Inorganic materials 0.000 claims abstract description 18
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 16
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 15
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 claims abstract description 12
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 11
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 72
- 238000002386 leaching Methods 0.000 claims description 62
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 36
- 239000002253 acid Substances 0.000 claims description 35
- 229910001710 laterite Inorganic materials 0.000 claims description 34
- 239000011504 laterite Substances 0.000 claims description 34
- 239000000047 product Substances 0.000 claims description 34
- 229910052742 iron Inorganic materials 0.000 claims description 33
- 239000011777 magnesium Substances 0.000 claims description 32
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 23
- 229910052749 magnesium Inorganic materials 0.000 claims description 23
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000002002 slurry Substances 0.000 claims description 15
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 14
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000006386 neutralization reaction Methods 0.000 claims description 11
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003456 ion exchange resin Substances 0.000 claims description 9
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 9
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 8
- 239000000395 magnesium oxide Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- 239000001117 sulphuric acid Substances 0.000 claims description 8
- 235000011149 sulphuric acid Nutrition 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 229910001447 ferric ion Inorganic materials 0.000 claims description 7
- 238000005554 pickling Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 238000010306 acid treatment Methods 0.000 claims description 5
- QUXFOKCUIZCKGS-UHFFFAOYSA-N bis(2,4,4-trimethylpentyl)phosphinic acid Chemical group CC(C)(C)CC(C)CP(O)(=O)CC(C)CC(C)(C)C QUXFOKCUIZCKGS-UHFFFAOYSA-N 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 5
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910001429 cobalt ion Inorganic materials 0.000 claims description 3
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 3
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 229910001453 nickel ion Inorganic materials 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- ZOCLAPYLSUCOGI-UHFFFAOYSA-M potassium hydrosulfide Chemical compound [SH-].[K+] ZOCLAPYLSUCOGI-UHFFFAOYSA-M 0.000 claims description 3
- WOXFMYVTSLAQMO-UHFFFAOYSA-N 2-Pyridinemethanamine Chemical group NCC1=CC=CC=N1 WOXFMYVTSLAQMO-UHFFFAOYSA-N 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 claims description 2
- 229910001448 ferrous ion Inorganic materials 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 229960001708 magnesium carbonate Drugs 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims description 2
- 238000011084 recovery Methods 0.000 abstract description 5
- 235000013495 cobalt Nutrition 0.000 description 85
- 239000000243 solution Substances 0.000 description 48
- 238000005406 washing Methods 0.000 description 27
- 238000012360 testing method Methods 0.000 description 22
- 229940091250 magnesium supplement Drugs 0.000 description 18
- 229910000863 Ferronickel Inorganic materials 0.000 description 14
- 238000001556 precipitation Methods 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 10
- 238000000638 solvent extraction Methods 0.000 description 10
- 238000003723 Smelting Methods 0.000 description 8
- 239000000284 extract Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 235000012245 magnesium oxide Nutrition 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 239000012065 filter cake Substances 0.000 description 6
- 238000009854 hydrometallurgy Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 235000019738 Limestone Nutrition 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 230000008021 deposition Effects 0.000 description 5
- 239000006028 limestone Substances 0.000 description 5
- 238000005363 electrowinning Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 229910052935 jarosite Inorganic materials 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 229910017518 Cu Zn Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000009853 pyrometallurgy Methods 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- CNJLMVZFWLNOEP-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[4.1.0]heptan-5-one Chemical compound O=C1C(C)CCC2C(C)(C)C12 CNJLMVZFWLNOEP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229910017709 Ni Co Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052598 goethite Inorganic materials 0.000 description 2
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229960000869 magnesium oxide Drugs 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000003828 vacuum filtration Methods 0.000 description 2
- KXZQYLBVMZGIKC-UHFFFAOYSA-N 1-pyridin-2-yl-n-(pyridin-2-ylmethyl)methanamine Chemical group C=1C=CC=NC=1CNCC1=CC=CC=N1 KXZQYLBVMZGIKC-UHFFFAOYSA-N 0.000 description 1
- 229910020630 Co Ni Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M bisulphate group Chemical group S([O-])(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229940090961 chromium dioxide Drugs 0.000 description 1
- AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium(IV) oxide Inorganic materials O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005206 flow analysis Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C22B23/0461—Treatment or purification of solutions, e.g. obtained by leaching by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
- C22B23/0484—Separation of nickel from cobalt in acidic type solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3842—Phosphinic acid, e.g. H2P(O)(OH)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2004907370A AU2004907370A0 (en) | 2004-12-30 | Extraction of nickel and cobalt from a resin eluate stream | |
| AU2004907370 | 2004-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101094926A true CN101094926A (zh) | 2007-12-26 |
Family
ID=36614416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800456511A Pending CN101094926A (zh) | 2004-12-30 | 2005-12-23 | 从树脂洗出液流中提取镍和钴 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP1841891A4 (fr) |
| JP (1) | JP2008527164A (fr) |
| KR (1) | KR20070094819A (fr) |
| CN (1) | CN101094926A (fr) |
| AP (1) | AP2007004030A0 (fr) |
| BR (1) | BRPI0519687A2 (fr) |
| CA (1) | CA2593706A1 (fr) |
| EA (1) | EA010771B1 (fr) |
| GT (1) | GT200500393A (fr) |
| WO (1) | WO2006069416A1 (fr) |
| ZA (1) | ZA200704566B (fr) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101643859B (zh) * | 2008-08-07 | 2011-04-20 | 北京有色金属研究总院 | 萃取色层分离净化钴溶液的工艺方法 |
| CN102245515A (zh) * | 2008-12-03 | 2011-11-16 | 海卓恩克科技有限公司 | 废水处理系统和方法 |
| CN102268537A (zh) * | 2011-08-15 | 2011-12-07 | 广西银亿科技矿冶有限公司 | 一种从红土镍矿中提取钴镍的方法 |
| CN104745813A (zh) * | 2013-12-31 | 2015-07-01 | 北京有色金属研究总院 | 高镁低镍硫化矿生物浸出过程中综合回收镍镁的方法 |
| CN108660324A (zh) * | 2018-05-21 | 2018-10-16 | 金川集团股份有限公司 | 一种从镍铜合金氯化浸出液中提取镍、钴、铜的方法 |
| CN109867400A (zh) * | 2019-02-19 | 2019-06-11 | 北京中科康仑环境科技研究院有限公司 | 一种镍（钴）萃余液的深度去除镍、钴的方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2007288123B2 (en) * | 2006-08-23 | 2011-06-02 | Murrin Murrin Operations Pty Ltd | Improved hydrometallurgical method for the extraction of nickel from laterite ores |
| US7935171B2 (en) | 2006-08-23 | 2011-05-03 | Bhp Billiton Ssm Development Pty Ltd. | Production of metallic nickel with low iron content |
| AU2007100902B4 (en) * | 2006-08-23 | 2007-10-25 | Murrin Murrin Operations Pty Ltd | Improved Hydrometallurgical Method for the Extraction of Nickel from Laterite Ores |
| BRPI0612374B1 (pt) * | 2006-11-10 | 2015-08-11 | Vale Sa | Processo de recuperação de níquel e cobalto a partir de minérios lateríticos empregando resina de troca iônica e produto contendo níquel ou cobalto |
| BRPI0605892B1 (pt) * | 2006-12-29 | 2015-09-01 | Vale Sa | Processo de recuperação de níquel e cobalto a partir de um eluato de resina de troca iônica |
| AU2008286193B2 (en) * | 2007-08-07 | 2011-10-27 | Bhp Billiton Ssm Development Pty Ltd | Atmospheric acid leach process for laterites |
| US20090056501A1 (en) * | 2007-08-29 | 2009-03-05 | Vale Inco Limited | Hydrometallurgical process using resin-neutralized-solution of a heap leaching effluent |
| US8147782B2 (en) | 2007-09-28 | 2012-04-03 | Vale Inco Limited | Producing nickel hydroxide suitable for pelletization with iron-containing ore and for stainless steel manufacture |
| JP5157943B2 (ja) | 2009-02-04 | 2013-03-06 | 住友金属鉱山株式会社 | 硫酸酸性水溶液からのニッケル回収方法 |
| JP5881952B2 (ja) * | 2011-01-24 | 2016-03-09 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| CN104445424A (zh) * | 2014-11-12 | 2015-03-25 | 浙江华友钴业股份有限公司 | 一种含锰废液制取高纯硫酸锰的方法 |
| JP6604255B2 (ja) * | 2016-04-05 | 2019-11-13 | 住友金属鉱山株式会社 | 有機溶媒中の不純物除去方法 |
| KR101950314B1 (ko) * | 2017-08-31 | 2019-02-20 | 고려아연 주식회사 | 니켈 산화광으로부터 습식 및 건식 공정을 조합한 경제적 니켈 제련 공법 |
| JP2019173063A (ja) * | 2018-03-27 | 2019-10-10 | 住友金属鉱山株式会社 | 水溶液からのニッケルとコバルトの回収方法 |
| KR102178219B1 (ko) * | 2019-02-13 | 2020-11-12 | 고려아연 주식회사 | 니켈 황화광으로부터 습식 및 건식 공정을 조합한 경제적 니켈 제련공법 |
| JP7338283B2 (ja) * | 2019-07-12 | 2023-09-05 | 住友金属鉱山株式会社 | スカンジウムの回収方法 |
| CN111115903A (zh) * | 2020-01-06 | 2020-05-08 | 湖南中伟新能源科技有限公司 | 一种两级离子交换除四钴废水中钴的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE871963A (fr) * | 1978-11-13 | 1979-03-01 | Daihachi Chem Ind | Separation de cobalt et de nickel moyennant une extraction par solvant |
| US4382016A (en) | 1981-05-14 | 1983-05-03 | American Cyanamid Company | Extractant for the selective removal of cobalt(II) from aqueous solutions |
| JPS60231420A (ja) * | 1983-12-28 | 1985-11-18 | Daihachi Kagaku Kogyosho:Kk | コバルトおよびニッケルを含有する水溶液からコバルトを分離する方法 |
| WO1996020291A1 (fr) | 1994-12-27 | 1996-07-04 | Bhp Minerals International Inc. | Recuperation du nickel et du cobalt contenus dans des minerais laterises |
| US20010001650A1 (en) * | 1999-03-09 | 2001-05-24 | William P.C. Duyvesteyn | Recovery of nickel and cobalt from ore |
| JP3122948B1 (ja) * | 1999-07-02 | 2001-01-09 | 株式会社高純度化学研究所 | 高純度コバルトの製造方法 |
| JP2001049362A (ja) * | 1999-08-06 | 2001-02-20 | Matsushita Sangyo Kk | 重金属スラッジからの有価金属回収方法および装置 |
| US6350420B1 (en) * | 1999-10-15 | 2002-02-26 | Bhp Minerals International, Inc. | Resin-in-pulp method for recovery of nickel and cobalt |
| US6387239B1 (en) * | 1999-11-17 | 2002-05-14 | Bhp Minerals International, Inc. | Recovery of metals from ore |
| WO2002022897A1 (fr) * | 2000-09-15 | 2002-03-21 | Commonwealth Scientific And Industrial Research Organisation | Recuperation de nickel et de cobalt dans des solutions de lixiviation |
| AUPR207200A0 (en) * | 2000-12-13 | 2001-01-11 | QNI Limited | Hydroxide solids enrichment by slurry contact |
-
2005
- 2005-12-23 AP AP2007004030A patent/AP2007004030A0/xx unknown
- 2005-12-23 CA CA002593706A patent/CA2593706A1/fr not_active Abandoned
- 2005-12-23 BR BRPI0519687-6A patent/BRPI0519687A2/pt not_active IP Right Cessation
- 2005-12-23 CN CNA2005800456511A patent/CN101094926A/zh active Pending
- 2005-12-23 JP JP2007548644A patent/JP2008527164A/ja active Pending
- 2005-12-23 KR KR1020077017513A patent/KR20070094819A/ko not_active Application Discontinuation
- 2005-12-23 EP EP05819247A patent/EP1841891A4/fr not_active Withdrawn
- 2005-12-23 EA EA200701407A patent/EA010771B1/ru not_active IP Right Cessation
- 2005-12-23 WO PCT/AU2005/001950 patent/WO2006069416A1/fr active Application Filing
- 2005-12-29 GT GT200500393A patent/GT200500393A/es unknown
-
2007
- 2007-06-07 ZA ZA200704566A patent/ZA200704566B/xx unknown
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643859B (zh) * | 2008-08-07 | 2011-04-20 | 北京有色金属研究总院 | 萃取色层分离净化钴溶液的工艺方法 |
| CN102245515B (zh) * | 2008-12-03 | 2013-06-19 | 海卓恩克科技有限公司 | 废水处理系统和方法 |
| CN102256903A (zh) * | 2008-12-03 | 2011-11-23 | 海卓恩克科技有限公司 | 用于废水处理的系统和方法 |
| CN102256705A (zh) * | 2008-12-03 | 2011-11-23 | 海卓恩克科技有限公司 | 用于废水处理的系统和方法 |
| CN102355933A (zh) * | 2008-12-03 | 2012-02-15 | 海卓恩克科技有限公司 | 用于废水处理的系统和方法 |
| CN102245515A (zh) * | 2008-12-03 | 2011-11-16 | 海卓恩克科技有限公司 | 废水处理系统和方法 |
| CN102256903B (zh) * | 2008-12-03 | 2013-12-11 | 海卓恩克科技有限公司 | 用于废水处理的系统和方法 |
| CN102355933B (zh) * | 2008-12-03 | 2014-12-10 | 海卓恩克科技有限公司 | 用于废水处理的系统和方法 |
| CN102268537A (zh) * | 2011-08-15 | 2011-12-07 | 广西银亿科技矿冶有限公司 | 一种从红土镍矿中提取钴镍的方法 |
| CN104745813A (zh) * | 2013-12-31 | 2015-07-01 | 北京有色金属研究总院 | 高镁低镍硫化矿生物浸出过程中综合回收镍镁的方法 |
| CN104745813B (zh) * | 2013-12-31 | 2017-02-15 | 北京有色金属研究总院 | 高镁低镍硫化矿生物浸出过程中综合回收镍镁的方法 |
| CN108660324A (zh) * | 2018-05-21 | 2018-10-16 | 金川集团股份有限公司 | 一种从镍铜合金氯化浸出液中提取镍、钴、铜的方法 |
| CN109867400A (zh) * | 2019-02-19 | 2019-06-11 | 北京中科康仑环境科技研究院有限公司 | 一种镍（钴）萃余液的深度去除镍、钴的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1841891A4 (fr) | 2008-06-25 |
| JP2008527164A (ja) | 2008-07-24 |
| WO2006069416A9 (fr) | 2007-10-18 |
| BRPI0519687A2 (pt) | 2009-03-03 |
| GT200500393A (es) | 2006-09-20 |
| ZA200704566B (en) | 2008-08-27 |
| CA2593706A1 (fr) | 2006-07-06 |
| AP2007004030A0 (en) | 2007-06-30 |
| EP1841891A1 (fr) | 2007-10-10 |
| EA010771B1 (ru) | 2008-10-30 |
| WO2006069416A1 (fr) | 2006-07-06 |
| KR20070094819A (ko) | 2007-09-21 |
| EA200701407A1 (ru) | 2007-10-26 |
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