CN101066559A - 氢存储粉末和制备该粉末的方法 - Google Patents
氢存储粉末和制备该粉末的方法 Download PDFInfo
- Publication number
- CN101066559A CN101066559A CNA2007101051710A CN200710105171A CN101066559A CN 101066559 A CN101066559 A CN 101066559A CN A2007101051710 A CNA2007101051710 A CN A2007101051710A CN 200710105171 A CN200710105171 A CN 200710105171A CN 101066559 A CN101066559 A CN 101066559A
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- CN
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- Prior art keywords
- hydrogen storage
- powder
- alloy
- hydrogen
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 153
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 153
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 148
- 239000000843 powder Substances 0.000 title claims abstract description 70
- 238000003860 storage Methods 0.000 title claims abstract description 47
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- 239000000463 material Substances 0.000 claims abstract description 95
- 238000005984 hydrogenation reaction Methods 0.000 claims description 28
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 21
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- 150000004678 hydrides Chemical class 0.000 claims description 9
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- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 1
- 229910004247 CaCu Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910010340 TiFe Inorganic materials 0.000 description 1
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- 229910052791 calcium Inorganic materials 0.000 description 1
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- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
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- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/242—Hydrogen storage electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/14—Treatment of metallic powder
- B22F1/145—Chemical treatment, e.g. passivation or decarburisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/023—Hydrogen absorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0084—Solid storage mediums characterised by their shape, e.g. pellets, sintered shaped bodies, sheets, porous compacts, spongy metals, hollow particles, solids with cavities, layered solids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/383—Hydrogen absorbing alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Powder Metallurgy (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/575313 | 2000-05-19 | ||
| US09/575,313 US6461766B1 (en) | 1998-08-27 | 2000-05-19 | Hydrogen storage powder and process for preparing the same |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018130720A Division CN1327549C (zh) | 2000-05-19 | 2001-05-18 | 氢存储粉末和制备该粉末的方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101066559A true CN101066559A (zh) | 2007-11-07 |
Family
ID=24299803
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101051710A Pending CN101066559A (zh) | 2000-05-19 | 2001-05-18 | 氢存储粉末和制备该粉末的方法 |
| CNB018130720A Expired - Fee Related CN1327549C (zh) | 2000-05-19 | 2001-05-18 | 氢存储粉末和制备该粉末的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018130720A Expired - Fee Related CN1327549C (zh) | 2000-05-19 | 2001-05-18 | 氢存储粉末和制备该粉末的方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US6461766B1 (enExample) |
| EP (1) | EP1293003A4 (enExample) |
| JP (1) | JP5250170B2 (enExample) |
| CN (2) | CN101066559A (enExample) |
| AU (1) | AU2001264737A1 (enExample) |
| BR (1) | BR0110983A (enExample) |
| CA (1) | CA2409218A1 (enExample) |
| MX (1) | MXPA02011364A (enExample) |
| TW (1) | TW531919B (enExample) |
| WO (1) | WO2001091210A1 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6461766B1 (en) * | 1998-08-27 | 2002-10-08 | Ovonic Battery Company, Inc. | Hydrogen storage powder and process for preparing the same |
| US6841512B1 (en) * | 1999-04-12 | 2005-01-11 | Ovonic Battery Company, Inc. | Finely divided metal catalyst and method for making same |
| US6270719B1 (en) * | 1999-04-12 | 2001-08-07 | Ovonic Battery Company, Inc. | Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity |
| US6589686B2 (en) * | 2001-02-28 | 2003-07-08 | Ovonic Battery Company, Inc. | Method of fuel cell activation |
| US6864002B1 (en) * | 2001-10-19 | 2005-03-08 | Christopher K. Dyer | Fuel cell system and method for producing electrical energy |
| US20040016769A1 (en) * | 2002-03-15 | 2004-01-29 | Redmond Scott D. | Hydrogen storage, distribution, and recovery system |
| US7169489B2 (en) | 2002-03-15 | 2007-01-30 | Fuelsell Technologies, Inc. | Hydrogen storage, distribution, and recovery system |
| US7399325B1 (en) | 2002-03-15 | 2008-07-15 | Fuelsell Technologies, Inc. | Method and apparatus for a hydrogen fuel cassette distribution and recovery system |
| JP4183959B2 (ja) * | 2002-03-22 | 2008-11-19 | 株式会社日本製鋼所 | 水素吸蔵合金の製造方法 |
| US7011768B2 (en) | 2002-07-10 | 2006-03-14 | Fuelsell Technologies, Inc. | Methods for hydrogen storage using doped alanate compositions |
| US20040065171A1 (en) | 2002-10-02 | 2004-04-08 | Hearley Andrew K. | Soild-state hydrogen storage systems |
| US7365366B2 (en) * | 2003-01-06 | 2008-04-29 | Showa Denka K.K. | Boron phosphide-based semiconductor light-emitting device and production method thereof |
| US6830725B2 (en) * | 2003-04-01 | 2004-12-14 | Texaco Ovonic Battery Systems, Llc | Hydrogen storage alloys having a high porosity surface layer |
| US7250386B2 (en) * | 2003-07-18 | 2007-07-31 | Energy Conversion Devices, Inc. | Quantum limit catalysts and hydrogen storage materials |
| US7175826B2 (en) * | 2003-12-29 | 2007-02-13 | General Electric Company | Compositions and methods for hydrogen storage and recovery |
| NO325620B1 (no) * | 2003-10-21 | 2008-06-30 | Revolt Technology Ltd | Elektrode, fremgangsmate for fremstilling derav, metall/luft-brenselcelle og metallhydrid-battericelle |
| JP4908778B2 (ja) * | 2004-06-30 | 2012-04-04 | キヤノン株式会社 | 固体高分子型燃料電池の触媒層の製造方法および固体高分子型燃料電池の製造方法 |
| US20060057019A1 (en) | 2004-09-16 | 2006-03-16 | Kwo Young | Hydrogen storage alloys having reduced PCT hysteresis |
| RU2301723C1 (ru) * | 2005-11-14 | 2007-06-27 | Российская Федерация, от имени которой выступает государственный заказчик Федеральное агентство по атомной энергии | Способ получения мелкодисперсного порошка титана |
| US20070141464A1 (en) * | 2005-12-21 | 2007-06-21 | Qunjian Huang | Porous metal hydride electrode |
| WO2010016946A2 (en) * | 2008-08-08 | 2010-02-11 | Henkel Corporation | Low temperature curing compositions |
| US8246903B2 (en) * | 2008-09-09 | 2012-08-21 | H.C. Starck Inc. | Dynamic dehydriding of refractory metal powders |
| DE102009018874A1 (de) * | 2009-04-24 | 2010-11-04 | Systec System- Und Anlagentechnik Gmbh & Co.Kg | Nickelhaltiges Elektrodenmaterial |
| FR2950876B1 (fr) * | 2009-10-07 | 2012-02-10 | Commissariat Energie Atomique | Procede de traitement d'un materiau getter et procede d'encapsulation d'un tel materiau getter |
| WO2012166808A2 (en) * | 2011-06-01 | 2012-12-06 | Target Technology International, Ltd. | Nickel alloys for hydrogen storage and the generation of energy therefrom |
| CN103894602B (zh) * | 2012-12-27 | 2017-02-08 | 北京有色金属研究总院 | 一种提高稀土镁基储氢合金循环寿命的表面处理方法 |
| CN104919069B (zh) | 2013-01-07 | 2019-05-07 | 奥佛电池公司 | 金属氢化物合金 |
| US8877378B2 (en) | 2013-01-07 | 2014-11-04 | Ovonic Battery Company, Inc. | Metal hydride alloy with catalyst particles and channels |
| US9350014B2 (en) | 2013-01-07 | 2016-05-24 | Ovonic Battery Company, Inc. | Nanoscale nickel-based catalytic material |
| US20140194282A1 (en) * | 2013-01-07 | 2014-07-10 | Ovonic Battery Company, Inc. | Metal hydride alloy with catalytic particles |
| CN110820031A (zh) * | 2019-11-19 | 2020-02-21 | 有研工程技术研究院有限公司 | 一种微型吸气剂的制备方法 |
| US11266965B1 (en) | 2021-01-14 | 2022-03-08 | Shandong University | Ultra-low-speed rotating low-strain high-filling-rate hydrogen storage alloy reaction device and technology |
| KR20240039147A (ko) * | 2021-07-23 | 2024-03-26 | 하니스 아이피, 엘엘씨 | 비발화성 수소 저장 합금 및 당해 합금을 사용하는 수소 저장 시스템 |
| CN113735057A (zh) * | 2021-08-31 | 2021-12-03 | 苏州睿分电子科技有限公司 | 一种免活化储氢材料及其制备方法和装置 |
| CN114381644B (zh) * | 2021-12-10 | 2022-10-21 | 厚普清洁能源(集团)股份有限公司 | 一种钒钛基储氢合金粉末及其制备方法 |
| CN114619026B (zh) * | 2022-03-15 | 2024-01-12 | 厦门厦钨氢能科技有限公司 | 一种复合固态贮氢材料及其制备方法 |
| CN115519119A (zh) * | 2022-09-23 | 2022-12-27 | 江苏智仁景行新材料研究院有限公司 | 一种含内生氢化物的铝合金粉及其制备方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4457136A (en) * | 1981-03-23 | 1984-07-03 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Metal hydride reactor |
| US4402915A (en) * | 1981-05-06 | 1983-09-06 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Metal hydride reactor |
| US4623597A (en) * | 1982-04-28 | 1986-11-18 | Energy Conversion Devices, Inc. | Rechargeable battery and electrode used therein |
| US4551400A (en) * | 1984-04-18 | 1985-11-05 | Energy Conversion Devices, Inc. | Hydrogen storage materials and methods of sizing and preparing the same for electrochemical applications |
| US4923770A (en) * | 1985-03-29 | 1990-05-08 | The Standard Oil Company | Amorphous metal alloy compositions for reversible hydrogen storage and electrodes made therefrom |
| JPS62167201A (ja) * | 1986-01-17 | 1987-07-23 | Daido Steel Co Ltd | 水素貯蔵合金の活性化処理方法 |
| US4716088A (en) * | 1986-12-29 | 1987-12-29 | Energy Conversion Devices, Inc. | Activated rechargeable hydrogen storage electrode and method |
| US4728586A (en) * | 1986-12-29 | 1988-03-01 | Energy Conversion Devices, Inc. | Enhanced charge retention electrochemical hydrogen storage alloys and an enhanced charge retention electrochemical cell |
| US4893756A (en) | 1988-09-22 | 1990-01-16 | Energy Conversion Devices, Inc. | Hydride reactor apparatus for hydrogen comminution of metal hydride hydrogen storage material |
| US5536591A (en) * | 1990-04-26 | 1996-07-16 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys for nickel metal hydride batteries |
| US5185221A (en) * | 1992-02-06 | 1993-02-09 | Gates Energy Products, Inc. | Metal hydride electrode and electrochemical cell |
| US5248510A (en) * | 1992-02-18 | 1993-09-28 | Hughes Aircraft Company | Cobalt oxide passivation of nickel battery electrode substrates |
| DE4343321A1 (de) * | 1993-12-18 | 1995-06-22 | Varta Batterie | Elektrischer Akkumulator |
| US5695530A (en) * | 1994-03-14 | 1997-12-09 | Hong; Kuochih | Method for making high charging efficiency and fast oxygen recombination rechargeable hydride batteries |
| CA2184377C (en) * | 1994-03-31 | 2000-12-12 | Han Wu | Improved metal hydride hydrogen storage electrodes |
| CN1145694A (zh) * | 1994-03-31 | 1997-03-19 | 摩托罗拉公司 | 改进的金属氢化物储氢电极 |
| US5451474A (en) * | 1994-04-04 | 1995-09-19 | Motorola, Inc. | Metal hydride hydrogen storage electrodes |
| US5616432A (en) * | 1994-06-14 | 1997-04-01 | Ovonic Battery Company, Inc. | Electrochemical hydrogen storage alloys and batteries fabricated from Mg containing base alloys |
| AU4469196A (en) * | 1994-12-22 | 1996-07-10 | Energy Conversion Devices Inc. | Magnesium mechanical alloys for thermal hydrogen storage |
| JP3016064B2 (ja) * | 1995-09-27 | 2000-03-06 | 古河電池株式会社 | 電池用水素吸蔵合金粉末の製造方法 |
| US5840440A (en) * | 1995-11-20 | 1998-11-24 | Ovonic Battery Company, Inc. | Hydrogen storage materials having a high density of non-conventional useable hydrogen storing sites |
| US5682592A (en) * | 1996-07-16 | 1997-10-28 | Korea Institute Of Science And Technology | Fabrication method for paste-type metal hydride electrode |
| JP3223858B2 (ja) * | 1996-12-24 | 2001-10-29 | 松下電器産業株式会社 | アルカリ蓄電池とその正極活物質およびその製造方法 |
| EP0851515A3 (en) * | 1996-12-27 | 2004-10-27 | Canon Kabushiki Kaisha | Powdery material, electrode member, method for manufacturing same and secondary cell |
| US5932372A (en) * | 1997-01-02 | 1999-08-03 | Lightyear Technologies Inc. | Composite materials, processes for manufacturing the composites, composite electrode, hydrogen occluding composite, and electrochemical cell utilizing the composite |
| JPH10195575A (ja) * | 1997-01-10 | 1998-07-28 | Mitsubishi Materials Corp | 初期活性の良好な水素貯蔵合金 |
| JPH11130401A (ja) * | 1997-10-29 | 1999-05-18 | Toyota Central Res & Dev Lab Inc | 水素吸蔵合金の高活性化処理方法 |
| EP0940865A3 (en) * | 1998-03-05 | 2004-11-03 | Matsushita Electric Industrial Co., Ltd | Active materials for the positive electrode in alkaline storage battery and the manufacturing method of them |
| JPH11339789A (ja) * | 1998-05-26 | 1999-12-10 | Toshiba Battery Co Ltd | 金属酸化物・水素蓄電池 |
| JP2000073101A (ja) * | 1998-08-27 | 2000-03-07 | Daido Steel Co Ltd | 水素吸蔵合金粉末の製造方法 |
| US6461766B1 (en) * | 1998-08-27 | 2002-10-08 | Ovonic Battery Company, Inc. | Hydrogen storage powder and process for preparing the same |
| US6120936A (en) * | 1998-08-27 | 2000-09-19 | Ovonic Battery Company, Inc. | Method for powder formation of a hydrogen storage alloy |
| US6270719B1 (en) * | 1999-04-12 | 2001-08-07 | Ovonic Battery Company, Inc. | Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity |
-
2000
- 2000-05-19 US US09/575,313 patent/US6461766B1/en not_active Expired - Lifetime
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2001
- 2001-05-16 US US09/859,164 patent/US6740448B2/en not_active Expired - Lifetime
- 2001-05-18 MX MXPA02011364A patent/MXPA02011364A/es not_active Application Discontinuation
- 2001-05-18 EP EP01939193A patent/EP1293003A4/en not_active Withdrawn
- 2001-05-18 BR BR0110983-9A patent/BR0110983A/pt not_active Application Discontinuation
- 2001-05-18 CA CA002409218A patent/CA2409218A1/en not_active Abandoned
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- 2001-05-18 CN CNA2007101051710A patent/CN101066559A/zh active Pending
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|---|---|
| JP2003534637A (ja) | 2003-11-18 |
| US20030148180A1 (en) | 2003-08-07 |
| AU2001264737A1 (en) | 2001-12-03 |
| US6789757B2 (en) | 2004-09-14 |
| EP1293003A4 (en) | 2006-10-25 |
| TW531919B (en) | 2003-05-11 |
| CA2409218A1 (en) | 2001-11-29 |
| BR0110983A (pt) | 2003-12-30 |
| WO2001091210A1 (en) | 2001-11-29 |
| EP1293003A1 (en) | 2003-03-19 |
| MXPA02011364A (es) | 2004-01-26 |
| US6461766B1 (en) | 2002-10-08 |
| US20030038197A1 (en) | 2003-02-27 |
| JP5250170B2 (ja) | 2013-07-31 |
| CN1443377A (zh) | 2003-09-17 |
| US6740448B2 (en) | 2004-05-25 |
| CN1327549C (zh) | 2007-07-18 |
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