CN101048518A - 利用Ca还原的Ti的制造方法以及制造装置 - Google Patents
利用Ca还原的Ti的制造方法以及制造装置 Download PDFInfo
- Publication number
- CN101048518A CN101048518A CNA2005800368031A CN200580036803A CN101048518A CN 101048518 A CN101048518 A CN 101048518A CN A2005800368031 A CNA2005800368031 A CN A2005800368031A CN 200580036803 A CN200580036803 A CN 200580036803A CN 101048518 A CN101048518 A CN 101048518A
- Authority
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- China
- Prior art keywords
- fused salt
- reactive tank
- electrolyzer
- reductive
- continuum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 72
- 230000008569 process Effects 0.000 title claims abstract description 13
- 230000009467 reduction Effects 0.000 title abstract description 24
- 150000003839 salts Chemical class 0.000 claims abstract description 111
- 238000004519 manufacturing process Methods 0.000 claims abstract description 64
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 22
- 230000002829 reductive effect Effects 0.000 claims description 24
- 238000009434 installation Methods 0.000 claims description 22
- 230000032258 transport Effects 0.000 claims description 8
- 238000005363 electrowinning Methods 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- 238000012423 maintenance Methods 0.000 claims description 5
- 230000007246 mechanism Effects 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 238000006722 reduction reaction Methods 0.000 abstract description 34
- 238000006243 chemical reaction Methods 0.000 abstract description 28
- 239000001110 calcium chloride Substances 0.000 abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 abstract description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract description 4
- 229910003074 TiCl4 Inorganic materials 0.000 abstract description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 235000011148 calcium chloride Nutrition 0.000 abstract 3
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000011575 calcium Substances 0.000 description 106
- 239000010936 titanium Substances 0.000 description 92
- 239000007788 liquid Substances 0.000 description 32
- 229910052751 metal Inorganic materials 0.000 description 27
- 239000002184 metal Substances 0.000 description 27
- 239000011777 magnesium Substances 0.000 description 23
- 239000000460 chlorine Substances 0.000 description 11
- 150000003609 titanium compounds Chemical class 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910010413 TiO 2 Inorganic materials 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- -1 simultaneously Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 210000002706 plastid Anatomy 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/02—Electrolytic production, recovery or refining of metals by electrolysis of melts of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1268—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams
- C22B34/1272—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using alkali or alkaline-earth metals or amalgams reduction of titanium halides, e.g. Kroll process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/129—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds by dissociation, e.g. thermic dissociation of titanium tetraiodide, or by electrolysis or with the use of an electric arc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
- C25C3/28—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium of titanium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/007—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells comprising at least a movable electrode
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004317842A JP2006124813A (ja) | 2004-11-01 | 2004-11-01 | Ｃａ還元によるＴｉの製造方法及び装置 |
| JP317842/2004 | 2004-11-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101048518A true CN101048518A (zh) | 2007-10-03 |
Family
ID=36319062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800368031A Pending CN101048518A (zh) | 2004-11-01 | 2005-10-26 | 利用Ca还原的Ti的制造方法以及制造装置 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20080217184A1 (ru) |
| EP (1) | EP1816221A1 (ru) |
| JP (1) | JP2006124813A (ru) |
| CN (1) | CN101048518A (ru) |
| AU (1) | AU2005301828B2 (ru) |
| CA (1) | CA2585454A1 (ru) |
| EA (1) | EA011005B1 (ru) |
| NO (1) | NO20072710L (ru) |
| UA (1) | UA84095C2 (ru) |
| WO (1) | WO2006049050A1 (ru) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103237926A (zh) * | 2010-11-18 | 2013-08-07 | 金属电解有限公司 | 用于电解还原固体进料的方法和系统 |
| CN103290433A (zh) * | 2013-06-26 | 2013-09-11 | 石嘴山市天合铁合金有限公司 | 一种双电解槽熔盐电解制备纯钛的装置及其工艺 |
| US9725815B2 (en) | 2010-11-18 | 2017-08-08 | Metalysis Limited | Electrolysis apparatus |
| CN108546964A (zh) * | 2018-05-29 | 2018-09-18 | 钢研晟华科技股份有限公司 | 一种金属钛的制备装置以及制备方法 |
| CN109763148A (zh) * | 2019-01-14 | 2019-05-17 | 浙江海虹控股集团有限公司 | 一种连续电解制备高纯金属钛粉的装置和方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4193984B2 (ja) * | 2003-08-28 | 2008-12-10 | 株式会社大阪チタニウムテクノロジーズ | 金属製造装置 |
| WO2009008121A1 (ja) * | 2007-07-12 | 2009-01-15 | Toho Titanium Co., Ltd. | 高純度金属カルシウムの製造方法、同高純度金属カルシウムを用いた金属チタンの製造方法および同高純度金属カルシウムの製造装置 |
| CN110983378B (zh) * | 2019-11-15 | 2020-12-18 | 北京理工大学 | 可溶阳极在熔盐中制备金属铝和四氯化钛的装置及方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2205854A (en) * | 1937-07-10 | 1940-06-25 | Kroll Wilhelm | Method for manufacturing titanium and alloys thereof |
| US2847297A (en) * | 1952-08-23 | 1958-08-12 | Nat Res Corp | Method of producing titanium crystals |
| US2845386A (en) * | 1954-03-16 | 1958-07-29 | Du Pont | Production of metals |
| US2890112A (en) * | 1954-10-15 | 1959-06-09 | Du Pont | Method of producing titanium metal |
| US4487677A (en) * | 1983-04-11 | 1984-12-11 | Metals Production Research, Inc. | Electrolytic recovery system for obtaining titanium metal from its ore |
| FR2582019B1 (fr) * | 1985-05-17 | 1987-06-26 | Extramet Sa | Procede pour la production de metaux par reduction de sels metalliques, metaux ainsi obtenus et dispositif pour sa mise en oeuvre |
| DE4038065C1 (ru) * | 1990-11-29 | 1991-10-17 | Heraeus Gmbh W C | |
| US20030145682A1 (en) * | 1994-08-01 | 2003-08-07 | Kroftt-Brakston International, Inc. | Gel of elemental material or alloy and liquid metal and salt |
| JP2002129250A (ja) * | 2000-10-30 | 2002-05-09 | Katsutoshi Ono | 金属チタンの製造方法 |
| JP3718691B2 (ja) * | 2002-04-18 | 2005-11-24 | 財団法人生産技術研究奨励会 | チタンの製造方法、純金属の製造方法、及び純金属の製造装置 |
-
2004
- 2004-11-01 JP JP2004317842A patent/JP2006124813A/ja active Pending
-
2005
- 2005-10-26 WO PCT/JP2005/019655 patent/WO2006049050A1/ja active Application Filing
- 2005-10-26 EP EP05799311A patent/EP1816221A1/en not_active Withdrawn
- 2005-10-26 US US11/665,976 patent/US20080217184A1/en not_active Abandoned
- 2005-10-26 CA CA002585454A patent/CA2585454A1/en not_active Abandoned
- 2005-10-26 CN CNA2005800368031A patent/CN101048518A/zh active Pending
- 2005-10-26 AU AU2005301828A patent/AU2005301828B2/en not_active Ceased
- 2005-10-26 UA UAA200706037A patent/UA84095C2/ru unknown
- 2005-10-26 EA EA200700988A patent/EA011005B1/ru not_active IP Right Cessation
-
2007
- 2007-05-29 NO NO20072710A patent/NO20072710L/no not_active Application Discontinuation
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103237926A (zh) * | 2010-11-18 | 2013-08-07 | 金属电解有限公司 | 用于电解还原固体进料的方法和系统 |
| US9725815B2 (en) | 2010-11-18 | 2017-08-08 | Metalysis Limited | Electrolysis apparatus |
| CN103290433A (zh) * | 2013-06-26 | 2013-09-11 | 石嘴山市天合铁合金有限公司 | 一种双电解槽熔盐电解制备纯钛的装置及其工艺 |
| WO2014205963A1 (zh) * | 2013-06-26 | 2014-12-31 | 石嘴山市天和铁合金有限公司 | 一种双电解槽熔盐电解制备纯钛的装置及其工艺 |
| CN103290433B (zh) * | 2013-06-26 | 2016-01-20 | 石嘴山市天和铁合金有限公司 | 一种双电解槽熔盐电解制备纯钛的装置及其工艺 |
| CN108546964A (zh) * | 2018-05-29 | 2018-09-18 | 钢研晟华科技股份有限公司 | 一种金属钛的制备装置以及制备方法 |
| CN109763148A (zh) * | 2019-01-14 | 2019-05-17 | 浙江海虹控股集团有限公司 | 一种连续电解制备高纯金属钛粉的装置和方法 |
| CN109763148B (zh) * | 2019-01-14 | 2020-11-03 | 浙江海虹控股集团有限公司 | 一种连续电解制备高纯金属钛粉的装置和方法 |
| US11821096B2 (en) | 2019-01-14 | 2023-11-21 | Zhejiang Haihong Holding Group Co., Ltd. | Device and method for preparing high-purity titanium powder by continuous electrolysis |
Also Published As
| Publication number | Publication date |
|---|---|
| NO20072710L (no) | 2007-06-26 |
| AU2005301828B2 (en) | 2008-07-24 |
| AU2005301828A1 (en) | 2006-05-11 |
| EA011005B1 (ru) | 2008-12-30 |
| UA84095C2 (ru) | 2008-09-10 |
| US20080217184A1 (en) | 2008-09-11 |
| CA2585454A1 (en) | 2006-05-11 |
| EP1816221A1 (en) | 2007-08-08 |
| WO2006049050A1 (ja) | 2006-05-11 |
| EA200700988A1 (ru) | 2007-10-26 |
| JP2006124813A (ja) | 2006-05-18 |
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Effective date of abandoning: 20071003 |
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