CN101010135B - 优化的液相氧化 - Google Patents

优化的液相氧化 Download PDF

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Publication number
CN101010135B
CN101010135B CN2005800295350A CN200580029535A CN101010135B CN 101010135 B CN101010135 B CN 101010135B CN 2005800295350 A CN2005800295350 A CN 2005800295350A CN 200580029535 A CN200580029535 A CN 200580029535A CN 101010135 B CN101010135 B CN 101010135B
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reaction medium
reactor
reaction
oxidation
bubbling column
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Chinese (zh)
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CN101010135A (zh
Inventor
A·G·万德斯
L·R·帕丁
W·S·斯特拉塞尔
M·德弗里德
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Grupo Petrotemex SA de CV
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Eastman Chemical Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/006—Baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872—Details of the fluidised bed reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
CN2005800295350A 2004-09-02 2005-08-29 优化的液相氧化 Expired - Lifetime CN101010135B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US60673104P 2004-09-02 2004-09-02
US60/606,731 2004-09-02
US63140004P 2004-11-29 2004-11-29
US60/631,400 2004-11-29
US11/154,396 2005-06-16
US11/154,396 US7572936B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
PCT/US2005/031051 WO2006028873A2 (en) 2004-09-02 2005-08-29 Optimized liquid-phase oxidation

Publications (2)

Publication Number Publication Date
CN101010135A CN101010135A (zh) 2007-08-01
CN101010135B true CN101010135B (zh) 2012-05-02

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CN2005800295350A Expired - Lifetime CN101010135B (zh) 2004-09-02 2005-08-29 优化的液相氧化

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US (2) US7572936B2 (enExample)
EP (1) EP1786557A2 (enExample)
JP (1) JP2008511664A (enExample)
KR (2) KR101281388B1 (enExample)
CN (1) CN101010135B (enExample)
BR (1) BRPI0514772A (enExample)
CA (1) CA2576851A1 (enExample)
MX (1) MX2007002506A (enExample)
RU (1) RU2363535C2 (enExample)
WO (1) WO2006028873A2 (enExample)

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US7504535B2 (en) * 2004-09-02 2009-03-17 Eastman Chemical Company Optimized liquid-phase oxidation
US20070155987A1 (en) * 2006-01-04 2007-07-05 O'meadhra Ruairi S Oxidative digestion with optimized agitation
US7326808B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system employing cooled mother liquor from oxidative digestion as feed to impurity purge system
US20070208194A1 (en) * 2006-03-01 2007-09-06 Woodruff Thomas E Oxidation system with sidedraw secondary reactor
US7501537B2 (en) * 2006-03-01 2009-03-10 Eastman Chemical Company Polycarboxylic acid production system employing oxidative digestion with reduced or eliminated upstream liquor exchange
US7393973B2 (en) * 2006-03-01 2008-07-01 Eastman Chemical Company Polycarboxylic acid production system with enhanced residence time distribution for oxidative digestion
US7326807B2 (en) * 2006-03-01 2008-02-05 Eastman Chemical Company Polycarboxylic acid production system with enhanced heating for oxidative digestion
US7420082B2 (en) * 2006-03-01 2008-09-02 Eastman Chemical Company Polycarboxylic acid production system employing hot liquor removal downstream of oxidative digestion
US7772424B2 (en) * 2006-03-01 2010-08-10 Eastman Chemical Company Polycarboxylic acid production system employing enhanced evaporative concentration downstream of oxidative digestion
US7816556B2 (en) * 2006-03-01 2010-10-19 Eastman Chemical Company Polycarboxylic acid production system employing enhanced multistage oxidative digestion
BRPI0721363A2 (pt) * 2007-02-28 2013-01-08 Hitachi Plant Technologies Ltd processos para a produÇço de um Ácido carboxÍlico aromÁtico bruto, e de um Ácido dicarboxÍlico aromÁtico bruto
US7872090B2 (en) * 2007-07-12 2011-01-18 Eastman Chemical Company Reactor system with optimized heating and phase separation
US9493389B2 (en) * 2008-10-31 2016-11-15 Grupo Petrotemex, S.A. De C.V. Dicarboxylic acid production with enhanced energy recovery
US9493387B2 (en) * 2008-10-31 2016-11-15 Grupo Petrotemex, S.A. De C.V. Dicarboxylic acid production with minimal wastewater generation
US9493388B2 (en) * 2008-10-31 2016-11-15 Grupo Petrotemex, S.A. De C.V. Dicarboxylic acid production with direct fired off-gas heating
WO2010105266A2 (en) * 2009-03-13 2010-09-16 University Of Utah Research Foundation Fluid-sparged helical channel reactor and associated methods
US8801837B2 (en) 2009-07-30 2014-08-12 Halliburton Energy Services, Inc. De-aerator dampener separator and related methods
US8647853B2 (en) 2009-12-15 2014-02-11 Ensovi, Llc Foam microreactor for multi-phase shear-sensitive reactions
RU2522609C2 (ru) * 2012-10-22 2014-07-20 Российская Федерация от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) Реактор для получения раствора диоксида хлора
CN109182111A (zh) * 2018-10-17 2019-01-11 太原理工大学 一种适用于农业废弃物沼气发酵的cstr反应器
CN111569788B (zh) * 2020-03-31 2023-04-11 南京延长反应技术研究院有限公司 对二甲苯制备对苯二甲酸的外置微界面氧化系统及方法

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KR20070054692A (ko) 2007-05-29
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US8114356B2 (en) 2012-02-14
WO2006028873A3 (en) 2006-08-31
EP1786557A2 (en) 2007-05-23
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RU2007111928A (ru) 2008-10-10
KR101281388B1 (ko) 2013-07-02
WO2006028873A2 (en) 2006-03-16
US7572936B2 (en) 2009-08-11
CA2576851A1 (en) 2006-03-16
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US20090257930A1 (en) 2009-10-15
RU2363535C2 (ru) 2009-08-10

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