CN100585024C - 镁及其合金的表面处理 - Google Patents
镁及其合金的表面处理 Download PDFInfo
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- CN100585024C CN100585024C CN03825005A CN03825005A CN100585024C CN 100585024 C CN100585024 C CN 100585024C CN 03825005 A CN03825005 A CN 03825005A CN 03825005 A CN03825005 A CN 03825005A CN 100585024 C CN100585024 C CN 100585024C
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- Prior art keywords
- polishing
- magnesium
- glazing
- alloy surface
- solution
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 239000011777 magnesium Substances 0.000 title claims abstract description 62
- 229910052749 magnesium Inorganic materials 0.000 title abstract description 29
- 229910045601 alloy Inorganic materials 0.000 title description 35
- 239000000956 alloy Substances 0.000 title description 35
- 238000004381 surface treatment Methods 0.000 title description 12
- 229910000861 Mg alloy Inorganic materials 0.000 claims abstract description 86
- 238000000034 method Methods 0.000 claims abstract description 78
- 238000005498 polishing Methods 0.000 claims abstract description 78
- 230000007797 corrosion Effects 0.000 claims abstract description 28
- 238000005260 corrosion Methods 0.000 claims abstract description 28
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004411 aluminium Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 46
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 46
- 239000000126 substance Substances 0.000 claims description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 238000002161 passivation Methods 0.000 claims description 39
- 238000004140 cleaning Methods 0.000 claims description 38
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 34
- 238000000576 coating method Methods 0.000 claims description 34
- 239000011248 coating agent Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 32
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 229910052742 iron Inorganic materials 0.000 claims description 26
- 239000003513 alkali Substances 0.000 claims description 18
- 238000002203 pretreatment Methods 0.000 claims description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 17
- 230000008569 process Effects 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 16
- 239000008151 electrolyte solution Substances 0.000 claims description 15
- 238000007789 sealing Methods 0.000 claims description 13
- 238000005238 degreasing Methods 0.000 claims description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
- 229910010272 inorganic material Inorganic materials 0.000 claims description 8
- 239000011147 inorganic material Substances 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- 239000000356 contaminant Substances 0.000 claims description 5
- 230000002829 reductive effect Effects 0.000 claims description 5
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 claims description 4
- 230000006378 damage Effects 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 238000005282 brightening Methods 0.000 abstract 2
- 238000005516 engineering process Methods 0.000 description 36
- 229910052751 metal Inorganic materials 0.000 description 33
- 239000002184 metal Substances 0.000 description 33
- 239000000843 powder Substances 0.000 description 24
- 238000012545 processing Methods 0.000 description 20
- 238000012360 testing method Methods 0.000 description 16
- 102100036214 Cannabinoid receptor 2 Human genes 0.000 description 14
- 101100060519 Homo sapiens CNR2 gene Proteins 0.000 description 14
- 238000011282 treatment Methods 0.000 description 13
- 235000011121 sodium hydroxide Nutrition 0.000 description 11
- 239000008399 tap water Substances 0.000 description 11
- 235000020679 tap water Nutrition 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 101100023519 Candida albicans (strain SC5314 / ATCC MYA-2876) MLT1 gene Proteins 0.000 description 8
- 101100437839 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) BPT1 gene Proteins 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 102100021066 Fibroblast growth factor receptor substrate 2 Human genes 0.000 description 7
- 101000818410 Homo sapiens Fibroblast growth factor receptor substrate 2 Proteins 0.000 description 7
- 229910000838 Al alloy Inorganic materials 0.000 description 6
- 102100033868 Cannabinoid receptor 1 Human genes 0.000 description 6
- 101000710899 Homo sapiens Cannabinoid receptor 1 Proteins 0.000 description 6
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 6
- 238000005266 casting Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 101001108245 Cavia porcellus Neuronal pentraxin-2 Proteins 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000004512 die casting Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 238000005204 segregation Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 108700026963 CB1a Proteins 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- WBIXZJYXIZPJRK-UHFFFAOYSA-N [Na].[Na].[Si](O)(O)(O)O Chemical compound [Na].[Na].[Si](O)(O)(O)O WBIXZJYXIZPJRK-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000007743 anodising Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 nickel Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 101150084325 FRS1 gene Proteins 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- 101100272701 Methylobacillus flagellatus (strain KT / ATCC 51484 / DSM 6875) bpt2 gene Proteins 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011221 initial treatment Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/30—Anodisation of magnesium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
- C23F3/02—Light metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
- C23F3/02—Light metals
- C23F3/03—Light metals with acidic solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/38—Chromatising
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- ing And Chemical Polishing (AREA)
- Chemical Treatment Of Metals (AREA)
- Printing Plates And Materials Therefor (AREA)
Abstract
Description
步骤号 | 操作 | 化学物 | 温度℃ | 时间分种 |
1 | 去油污* | DGA | 70-80 | 5 |
2 | 用水漂洗* | 自来水 | 15-50 | 0.5-1 |
3 | 磷酸腐蚀 | PE3 | 15-35 | 0.5 |
4 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
5 | 碱洗 | DGA | 70-80 | 1-1.5 |
6 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 去油污 | CW25 | 70-80 | 2-3 |
2 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 活化 | CB2a | 30-40 | 0.3 |
2 | 化学喷砂 | CB1(CB1a) | 30-40 | 1-5 |
3 | 碱洗 | CW25 | 70-80 | 5 |
4 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 化学喷砂 | CB1(CB1a) | 30-40 | 1-6 |
2 | 碱洗 | CW25 | 70-80 | 5 |
3 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 活化 | CB2a | 30-40 | 0.3-0.5 |
2 | 化学喷砂 | CB3 | 30-40 | 1-5 |
3 | 去铁 | FR1 | 20-40 | 0.5-1.5 |
4 | 用水漂洗 | 自来水 | 15-50 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 化学抛光 | EP3 | 35-45 | 2 |
2 | 直流抛光 | EP3 | 35-45 | 2-3 |
3 | 化学抛光 | EP3 | 35-45 | 1-1.5 |
4 | 乙二醇洗 | PG1 | 35-40 | 0.3 |
5 | 碱洗 | CW25 | 70-80 | 1.5-2 |
6 | 水洗 | 自来水 | 20-40 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 交流抛光 | EP3 | 35-45 | 1 |
2 | 直流抛光 | EP3 | 35-45 | 3-4 |
3 | 交流抛光 | EP3 | 35-45 | 0.3-0.5 |
4 | 乙二醇洗 | PG1 | 35-40 | 0.3 |
5 | 碱洗 | CW25 | 70-80 | 0.5-1 |
6 | 水洗 | 自来水 | 20-40 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 化学抛光 | EP3 | 35-45 | 2 |
2 | 直流抛光 | EP3 | 35-45 | 1-1.5 |
3 | 交流抛光 | EP3 | 35-45 | 0.2-0.5 |
4 | 乙二醇洗 | PG1 | 35-40 | 0.25-0.3 |
5 | 碱洗 | CW25 | 70-80 | 0.5-1 |
6 | 水洗 | 自来水 | 20-40 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 时间分钟 |
1 | 化学抛光 | EP4 | 35-45 | 0.3-2 |
2 | 碱洗 | CW7 | 70-80 | 0.2-0.75 |
3 | 水洗 | 自来水 | 20-40 | 0.5-1 |
步骤号 | 操作 | 化学物 | 温度℃ | 电压V | 时间分钟 |
1 | 电钝化 | BPT1 | 15-30 | 40-70 | 2 |
2 | 用水漂洗 | 去离子水 | 15-30 | - | 0.5-1 |
3 | 热空气干燥 | - | 70-110 | 1 |
步骤号 | 操作 | 化学物 | 温度℃ | 电压V | 时间分钟 |
1 | 电钝化 | BPT1 | 15-30 | 90-100 | 2 |
2 | 用水漂洗 | 去离子水 | 15-30 | - | 0.5-1 |
3 | 热空气干燥 | - | 70-110 | - | 1 |
步骤号 | 操作 | 化学物 | 温度℃ | 电压V | 时间分钟 |
1 | 电钝化 | BPT1 | 15-30 | 115-125 | 2 |
2 | 用水漂洗 | 去离子水 | 15-30 | - | 0.5-1 |
3 | 热空气干燥 | - | 70-110 | - | 1 |
精饰/合金 | AZ31挤压或板* | AM50铸造 | AZ91铸造 |
平 | |||
明亮 | E0+S4+T1 | E1+S2+T1 | E1+S1+T1 |
金属 | E0+S4+T2 | E1+S2+T2 | E1+S1+T2 |
珍珠 | E0+S4+T3 | E1+S2+T3 | E1+S1+T3 |
CB | |||
明亮 | E0+X3+S4+T1 | E1+X1+S2+T1 | E1+X1+S1+T1 |
金属 | E0+X3+S4+T2 | E1+X1+S2+T2 | E1+X1+S1+T2 |
珍珠 | E0+X3+S4+T3 | E1+X1+S2+T3 | E1+X1+S1+T3 |
试样 | 合金 | 试样数 | 精饰 | 钝化电压,V | 注释 |
CN1 | AZ31,Spectrolite板 | 2 | 温和CB,明亮,CB2A+CB3 | 50 | 涂粉末 |
CN2 | AZ31 | 2 | 粗糙CB,明亮,CB2A+CB1A | 50 | 涂粉末 |
CN3 | AZ31 | 2 | 温和CB,明亮,CB2A+CB3 | 50 | 涂粉末 |
CN4 | AZ31 | 2 | 温和CB,金属,CB2A+CB3 | 90 | 涂粉末 |
CN5 | AZ31 | 2 | 温和CB,珍珠,CB2A+CB3 | 120 | 涂粉末 |
CN6 | AZ31 | 2 | 平,明亮 | 50 | 涂粉末 |
CN7 | AZ31,挤压 | 2 | 温和CB,明亮,CB2A+CB3 | 50 | 涂粉末 |
CN8 | AZ31,挤压 | 2 | 粗糙CB,明亮,CB2A+CB1A | 50 | 涂粉末 |
CN9 | AZ31,挤压 | 2 | 平,明亮 | 50 | 涂粉末 |
CN10 | AZ31,Spectrolite板 | 2 | 剧烈CB,明亮,CB2A+CB1A | 50 | 涂粉末 |
CN11 | AZ31 | 2 | CB,明亮 | 50 | 无粉末涂层 |
CN12 | AZ31 | 2 | CB,金属 | 90 | 无粉末涂层 |
CN13 | AZ31 | 2 | CB,珍珠 | 120 | 无粉末涂层 |
Claims (30)
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NZ521269 | 2002-09-09 | ||
NZ52126902 | 2002-09-09 |
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CN1777706A CN1777706A (zh) | 2006-05-24 |
CN100585024C true CN100585024C (zh) | 2010-01-27 |
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CN03825005A Expired - Fee Related CN100585024C (zh) | 2002-09-09 | 2003-09-09 | 镁及其合金的表面处理 |
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US (1) | US20060130936A1 (zh) |
JP (1) | JP2005538249A (zh) |
CN (1) | CN100585024C (zh) |
AU (1) | AU2003265019B2 (zh) |
DE (1) | DE10393234T5 (zh) |
GB (1) | GB2407823B (zh) |
WO (1) | WO2004022818A1 (zh) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
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US20050211052A1 (en) * | 2004-03-29 | 2005-09-29 | Gigliotti Patrick J | Guitar having a metal plate insert |
DE102005027782A1 (de) * | 2005-06-15 | 2006-12-28 | Druckguss Heidenau Gmbh | Verfahren zur Oberflächenbehandlung von Magnesiumgussteilen |
CN101327710B (zh) * | 2007-06-22 | 2010-08-25 | 比亚迪股份有限公司 | 一种金属表面的装饰方法 |
CN101591799B (zh) * | 2008-05-30 | 2011-04-20 | 比亚迪股份有限公司 | 一种镁合金的电解抛光液及其表面抛光处理方法 |
RU2491371C2 (ru) * | 2009-01-09 | 2013-08-27 | Сумитомо Электрик Индастриз, Лтд. | Конструктивный элемент из магниевого сплава |
GB2469115B (en) | 2009-04-03 | 2013-08-21 | Keronite Internat Ltd | Process for the enhanced corrosion protection of valve metals |
KR101200526B1 (ko) * | 2010-06-09 | 2012-11-13 | 주식회사 엔유씨전자 | 마그네슘계 금속의 금속 질감을 구현할 수 있는 마그네슘 표면처리 방법 |
CN102400205B (zh) * | 2010-09-19 | 2014-07-23 | 宝山钢铁股份有限公司 | 一种快速评价沟槽腐蚀性能的电解质溶液 |
KR101178533B1 (ko) | 2010-12-28 | 2012-08-30 | 재단법인 포항산업과학연구원 | 마그네슘 합금 판재의 표면처리 방법 |
CN102198626B (zh) * | 2011-05-11 | 2012-08-22 | 北京科技大学 | 一种镁合金板带卷单、双面抛光装置 |
CN102393128B (zh) * | 2011-08-12 | 2013-07-24 | 贵州钢绳股份有限公司 | 磷化钢线表面脱水处理剂及其使用方法 |
US9644283B2 (en) * | 2011-09-30 | 2017-05-09 | Apple Inc. | Laser texturizing and anodization surface treatment |
WO2013160567A1 (fr) | 2012-04-25 | 2013-10-31 | Arcelormittal Investigacion Y Desarrollo, S.L. | Procédé de réalisation d'une tôle prélaquée à revêtements znalmg et tôle correspondante. |
CN102944455A (zh) * | 2012-10-24 | 2013-02-27 | 郑州飞机装备有限责任公司 | 辨别锻铝2a14纵向纹路的方法 |
CN104131294B (zh) * | 2014-07-01 | 2015-10-28 | 蚌埠市高华电子有限公司 | 一种具有抗菌效果的铝及铝合金混合抛光液及其制备方法 |
JP6532152B2 (ja) * | 2015-01-23 | 2019-06-19 | 福岡県 | 電解研磨液 |
CN104674332B (zh) * | 2015-03-23 | 2017-04-05 | 日照天一生物医疗科技有限公司 | 镁合金支架的处理液及处理方法 |
CN106929897A (zh) * | 2015-12-30 | 2017-07-07 | 比亚迪股份有限公司 | 一种铝合金壳体及其制备方法 |
CN106404477A (zh) * | 2016-08-23 | 2017-02-15 | 中国航空工业集团公司北京航空材料研究院 | 一种用于粉末高温合金电子背散射衍射分析的制样方法 |
DE102017222932A1 (de) * | 2017-12-15 | 2019-06-19 | Zf Friedrichshafen Ag | Chemisch unterstützte Feinstbearbeitung |
DE102018218393A1 (de) * | 2018-10-26 | 2020-04-30 | Aesculap Ag | Verfahren zum Oberflächenbehandeln eines Metall- oder Legierungsprodukts sowie ein Metall- oder Legierungsprodukt |
CN110257838B (zh) * | 2019-07-02 | 2021-02-19 | 佛山市南海区尚铭金属制品有限公司 | 铝型材喷粉前处理工艺 |
CN111893468A (zh) * | 2020-07-05 | 2020-11-06 | 江苏荣企新材料科技有限公司 | 一种铝镁合金金属框架表面抗腐蚀处理工艺 |
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US3222266A (en) * | 1958-08-20 | 1965-12-07 | Kaiser Aluminium Chem Corp | Method of enameling anodized aluminum |
US3766030A (en) * | 1971-12-27 | 1973-10-16 | Muroc Prod Corp | Method of electropolishing |
US4578156A (en) * | 1984-12-10 | 1986-03-25 | American Hoechst Corporation | Electrolytes for electrochemically treating metal plates |
US5683522A (en) * | 1995-03-30 | 1997-11-04 | Sundstrand Corporation | Process for applying a coating to a magnesium alloy product |
DE19744312A1 (de) * | 1997-10-07 | 1999-04-08 | Volkswagen Ag | Verfahren zum Verbinden von wenigstens zwei Fügepartnern aus einem Magnesiumwerkstoff |
DE19800035A1 (de) * | 1998-01-02 | 1999-07-08 | Volkswagen Ag | Verfahren zum Fügen von mindestens zwei Fügepartnern |
DE69913049D1 (de) * | 1998-02-23 | 2004-01-08 | Mitsui Mining & Smelting Co | Produkt auf magnesiumbasis mit erhöhtem glanz des basismetalls und korrosionsbeständigkeit und verfahren zu dessen herstellung |
US6596150B2 (en) * | 1998-05-28 | 2003-07-22 | Fuji Photo Film Co., Ltd. | Production method for an aluminum support for a lithographic printing plate |
JP2000219975A (ja) * | 1999-01-28 | 2000-08-08 | Nippon Parkerizing Co Ltd | 表面処理されたMg合金およびその表面処理方法 |
US6319819B1 (en) * | 2000-01-18 | 2001-11-20 | Advanced Micro Devices, Inc. | Process for passivating top interface of damascene-type Cu interconnect lines |
-
2003
- 2003-09-09 AU AU2003265019A patent/AU2003265019B2/en not_active Ceased
- 2003-09-09 JP JP2004533902A patent/JP2005538249A/ja active Pending
- 2003-09-09 WO PCT/NZ2003/000200 patent/WO2004022818A1/en active Application Filing
- 2003-09-09 CN CN03825005A patent/CN100585024C/zh not_active Expired - Fee Related
- 2003-09-09 GB GB0504294A patent/GB2407823B/en not_active Expired - Lifetime
- 2003-09-09 DE DE10393234T patent/DE10393234T5/de not_active Withdrawn
- 2003-09-09 US US10/526,961 patent/US20060130936A1/en not_active Abandoned
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WO2004022818A1 (en) | 2004-03-18 |
AU2003265019B2 (en) | 2008-08-14 |
GB0504294D0 (en) | 2005-04-06 |
US20060130936A1 (en) | 2006-06-22 |
AU2003265019A1 (en) | 2004-03-29 |
JP2005538249A (ja) | 2005-12-15 |
DE10393234T5 (de) | 2005-10-27 |
CN1777706A (zh) | 2006-05-24 |
GB2407823B (en) | 2005-11-09 |
GB2407823A (en) | 2005-05-11 |
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